- Title
- Enhanced upconversion emission of Er3+-Yb3+ co-doped Ba5 (PO4) 3OH powder phosphor for application in photodynamic therapy
- Creator
- Mokoena, Puseletso P, Poluwole, David O, Nyokong, Tebello, Swart, Hendrik C, Ntwaeaborwa, Odireleng M
- Subject
- To be catalogued
- Date
- 2021
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/185035
- Identifier
- vital:44318
- Identifier
- xlink:href="https://doi.org/10.1016/j.sna.2021.113014"
- Description
- Er3+-Yb3+ co-doped Ba5(PO4)3OH nanoparticle powder phosphors were successfully synthesized by urea combustion method. The resulting powder phosphors were characterized using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), high resolution scanning electron microscopy (HRSEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS) and photoluminescence spectroscopy (PL). XRD data confirmed crystallization of pure hexagonal phase of Ba5(PO4)3OH and HRSEM images showed formation of ellipsoidal particles. XPS data combined with EDS analysis confirmed the materials composition that corresponds with identification of all the chemical elements constituting the materials. The in vitro dark cytotoxicity of the particles confirmed lack of cytocidal behaviour in the absence of light, but considerable photodynamic therapy (PDT) activity was observed upon illumination. Upon excitation using a 980 nm laser, multiple emission peaks in the green and red regions corresponding to the optical transitions of Er3+ ion were observed. Upon co-doping with Yb3+, upconverted red emission was detected and this was attributable to non-radiative energy transfer from Yb3+ to Er3+. The proposed mechanism of upconversion photoluminescence is discussed.
- Format
- computer, online resource, application/pdf, 1 online resource (10 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Sensors and Actuators A: Physical, Mokoena, P.P., Oluwole, D.O., Nyokong, T., Swart, H.C. and Ntwaeaborwa, O.M., 2021. Enhanced upconversion emission of Er3+-Yb3+ co-doped Ba5 (PO4) 3OH powder phosphor for application in photodynamic therapy. Sensors and Actuators A: Physical, p.113014, Sensors and Actuators A: Physical p. 113014 2021 0924-4247
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
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