- Title
- Creating the Ideal Push-Pull System for Electrocatalysis A Comparative Study on Symmetrical and Asymmetrical Cardanol-based Cobalt Phthalocyanines
- Creator
- Nkhahle, Reitumetse, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2021
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/${Handle}
- Identifier
- vital:44452
- Identifier
- xlink:href="https://doi.org/10.1002/elan.202060019"
- Description
- A symmetrical cardanol-based cobalt phthalocyanine (Pc) along with its asymmetrical acid-based derivatives were synthesized and applied in the electrocatalysis of hydrazine. Despite the inhibition of electron movement by the bulky cardanol-based substituent throughout the series of molecules, an ideal combination of substituents was established in GCE-3 (2,9,16-tris(3- pentadecylphenoxy)-23-mono propionic acid phthalocyanato cobalt (II)) where a limit of detection (LoD) value of 5.10 μM (signal to noise ratio=5) was recorded for the detection of hydrazine. The results obtained serve as an illustration that the combination of electron-donating and electron-withdrawing substituents has a significant influence on the complete functioning of the phthalocyanine molecule(s) being investigated.
- Format
- computer, online resource, application/pdf, 1 online resource (12 pages), pdf
- Publisher
- Wiley Library Online
- Language
- English
- Relation
- Electroanalysis, Nkhahle, R. and Nyokong, T., 2021. Creating the Ideal Push‐Pull System for Electrocatalysis: A Comparative Study on Symmetrical and Asymmetrical Cardanol‐based Cobalt Phthalocyanines. Electroanalysis, 33(1), pp.11-22, Electroanalysis volume 33 number 1 p. 11 2021 1521-4109
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Wiley Library Online Terms of Use Statement (https://onlinelibrary.wiley.com/terms-and-conditions)
- Rights
- Closed Access
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Collections
Nyokong, Tebello (Distinguished Professor)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Creating the Ideal Push‐Pull System for Electrocatalysis.pdf | 1 MB | Adobe Acrobat PDF | View Details Download |