- Title
- Photophysical studies of graphene quantum dots-Pyrene-derivatized porphyrins conjugates when encapsulated within Pluronic F127 micelles
- Creator
- Managa, Muthumuni, Achadu, Ojodomo John, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2018
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/187971
- Identifier
- vital:44714
- Identifier
- xlink:href="https://doi.org/10.1016/j.dyepig.2017.09.031"
- Description
- Pyrene-derivatized H2, GaCl, and Zn porphyrins were immobilized on graphene quantum dots (GQDs) to form (GQDs-H2TPrP, GQDs-GaClTPrP, and GQDs-ZnTPrP) conjugates through the π-π stacking interaction method followed by encapsulating into Pluronic F127 micelles to form (GQDs-H2TPrP + F127, GQDs-GaClTPrP + F127, and GQDs-ZnTPrP + F127). Spectroscopic evidence shows that the resultant conjugates were stable due to the strong π-π stacking interaction between the GQDs and the porphyrins. The fluorescence and singlet oxygen generating behaviour of the porphyrins were investigated following incorporation. GQDs-GaClTPrP + F127 showed highest values of the binding constant (Kb). The Stern-Volmer constant (Ksv) for GQDs-ZnTPrP + F127 were the highest compared to other porphyrins derivatives.
- Format
- computer, online resource, application/pdf, 1 online resource (12 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Dyes and Pigments, Managa, M., Achadu, O.J. and Nyokong, T., 2018. Photophysical studies of graphene quantum dots-Pyrene-derivatized porphyrins conjugates when encapsulated within Pluronic F127 micelles. Dyes and Pigments, 148, pp.405-416, Dyes and Pigments volume 148 p. 405 2018 0143-7208
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Nyokong, Tebello (Distinguished Professor)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
RU Department of Chemistry
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