- Title
- Photophysicochemical behaviour of anionic indium phthalocyanine when grafted onto AgxAuy and porous silica nanoparticles
- Creator
- Dube, Edith, Oluwole, David O, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2017
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/188899
- Identifier
- vital:44796
- Identifier
- xlink:href="https://doi.org/10.1016/j.jlumin.2017.05.071"
- Description
- This work reports on the synthesis of glutathione functionalised Ag3Au1 (Ag rich alloy, denoted as AgAu) and Ag1Au3 (Au rich alloy – denoted as AuAg) nano alloys as well as aminopropyl triethoxylsilane capped Ag1Au3 doped silica nanoparticles (NPs). The NPs were covalently linked to indium(III) chloride 2,9(10),16(17),23(24)–tetra–(3–carboxyphenoxy)phthalocyanine (1) via amide bond to form 1–AgAuNPs–GSH and 1–AuAgNPs–GSH. The AgAuNPs were also doped into aminopropyl triethoxylsilane (APTES) silica NPs (SiNPs-APTES) followed by linkage to complex 1 to form 1–AgAu-SiNPs–APTES. The photophysicochemical behaviour of complex 1 and its nanoconjugates were investigated. Decrease in the fluorescence quantum yields and lifetimes was observed in the conjugates in comparison to 1 alone. The singlet oxygen quantum yield for 1–AgAuNPs–GSH and 1–AuAgNPs–GSH decreased probably due to the screening effect caused by the NPs, while that of 1–AgAu-SiNPs–APTES increased in dimethylsulfoxide probably due to the permeability of the porous silica matrix to molecular oxygen.
- Format
- computer, online resource, application/pdf, 1 online resource (11 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Journal of Luminescence, Dube, E., Oluwole, D.O. and Nyokong, T., 2017. Photophysicochemical behaviour of anionic indium phthalocyanine when grafted onto AgxAuy and porous silica nanoparticles. Journal of Luminescence, 190, pp.353-363, Journal of Luminescence volume 190 p. 353 2017 0022-2313
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Collections
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details | SOURCE1 | Photophysicochemical behaviour of anionic indium phthalocyanine.pdf | 696 KB | Adobe Acrobat PDF | View Details |