- Title
- Nonlinear optical properties of metal free thio alkyl and tert-butyl phenoxy phthalocyanine
- Creator
- Joseph, Otto
- ThesisAdvisor
- Khene, Samson
- ThesisAdvisor
- Britton, Johnathan
- Subject
- Nonlinear optics
- Subject
- Phthalocyanines
- Subject
- Time-dependent density functional theory
- Subject
- Magnetic circular dichroism
- Subject
- Reverse saturable absorption (RSA)
- Subject
- Real Time Dependent Density Functional Theory (RT-TDDFT)
- Date
- 2021-10
- Type
- Master's theses
- Type
- text
- Identifier
- http://hdl.handle.net/10962/190712
- Identifier
- vital:45021
- Description
- This work reports on the nonlinear optical properties of tetra - and octa substituted phthalocyanines (Pcs) utilising pentane thiol and 4-tertbutyl phenol as substituents. Their nonlinear absorption coefficient (𝛽) and absorption cross sections were determined using the Z-scan technique with a 10 ns pulse laser at 532 nm. The molecular second order hyperpolarizability Im[γ] was observed and the following Im[γ] trend was obtained for 𝛼-H2Pc(SC5H11)4 isomers, 5.93 ×10−31 (Cs) 2.24×10−32(D2h) > 1.21×10−32(C4h) > 1.05×10−32 (C2v) esu, respectively, in chloroform. Symmetry was seen to have an effect on the observed reverse saturable absorption (RSA) response. Based on the five level model rate equation nonlinear fit of the RSA response curves and Real Time Time Dependant Density Functional Theory (RT-TDDFT) results, the singlet excited state population dynamics was found to play a significant role in producing the observed Im[γ] trend.
- Description
- Thesis (MSc) -- Faculty of Science, Chemistry, 2021
- Format
- computer, online resource, application/pdf, 1 online resource (126 pages), pdf
- Publisher
- Rhodes University, Faculty of Science, Chemistry
- Language
- English
- Rights
- Joseph, Otto
- Rights
- Attribution 4.0 International (CC BY 4.0)
- Rights
- Open Access
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| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | JOSEPH-MSC-TR21-227.pdf | 4 MB | Adobe Acrobat PDF | View Details Download |