- Title
- Push-pull type Co (III) corroles
- Creator
- Niu, Yingjie, Zhu, Weihua, Mack, John, Dubazana, Nadine, Nyokong, Tebello, Fu, Bo, Xu, Haijun, Liang, Xu
- Subject
- To be catalogued
- Date
- 2021
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/190826
- Identifier
- vital:45032
- Identifier
- xlink:href="https://doi.org/10.1142/S1088424621500279"
- Description
- The rational design and preparation of three A2B type Co(III)triarylcorroles with push- and pull-substituents are reported. The structure-property relationships were identified by comparing their optically spectroscopic and electrochemical properties to trends predicted in DFT and TD-DFT calculations. The results demonstrate that the Co(III)triarylcorroles are highly efficient catalysts for electrocatalyzed hydrogen evolutions (HERs) and oxygen reductions (ORRs), and that their reactivity can be modulated by changing the meso-B-substituent of the Co(III)Corroles.
- Format
- computer, online resource, application/pdf, 1 online resource (9 pages), pdf
- Publisher
- World Scientific
- Language
- English
- Relation
- Journal of Porphyrins and Phthalocyanines, Niu, Y., Zhu, W., Mack, J., Dubazana, N., Nyokong, T., Fu, B., Xu, H. and Liang, X., 2021. Push-pull type Co (III) corroles: Synthesis, electronic structure and electrochemical catalysis. Journal of Porphyrins and Phthalocyanines, 25(04), pp.289-297, Journal of Porphyrins and Phthalocyanines volume 25 number 04 p. 289 2021 1099-1409
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the World Scientific Copyright and Permissions Statement (https://www.worldscientific.com.wam.seals.ac.za/page/permissions)
- Rights
- Closed Access
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Mack, John (Associate Prof)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
SDG 03. Good Health and Well-Being
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Push-pull type Co (III) corroles Synthesis, electronic structure.pdf | 669 KB | Adobe Acrobat PDF | View Details Download |