- Title
- Synthesis, Characterization, and Electronic Structures of Porphyrins Fused with Polycyclic Aromatic Ring Systems
- Creator
- Okujima, Tetsuo, Mack, John, Nakamura, Jun, Kubheka, Gugu, Nyokong, Tebello, Zhu, Hua, Komobuchi, Naoki, Ono, Noboru, Yamada, Hiroko, Uno, Hidemitsu, Kobayashi, Nagao
- Subject
- To be catalogued
- Date
- 2016
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/240360
- Identifier
- vital:50827
- Identifier
- xlink:href="https://doi.org/10.1002/chem.201602213"
- Description
- A series of porphyrins fused with acenaphthylene, phenanthroline, and benzofluoranthene polycyclic aromatic rings were prepared by means of a 3+1 porphyrin synthesis approach and subsequent retro-Diels–Alder reaction of bicyclo[2.2.2]octadiene-fused precursors. Analysis of the magnetic circular dichroism spectra and the results of time-dependent DFT calculations are used to identify the reasons for the trends observed in the wavelengths and relative intensities of the Q bands of the products. Michl's perimeter model is used as a conceptual framework to explain the changes in the relative energies of the frontier π-molecular orbitals.
- Format
- computer, online resource, application/pdf, 1 online resource (9 pages), pdf
- Publisher
- Wiley Library Online
- Language
- English
- Relation
- Chemistry–A European Journal, Okujima, T., Mack, J., Nakamura, J., Kubheka, G., Nyokong, T., Zhu, H., Komobuchi, N., Ono, N., Yamada, H., Uno, H. and Kobayashi, N., 2016. Synthesis, Characterization, and Electronic Structures of Porphyrins Fused with Polycyclic Aromatic Ring Systems. Chemistry–A European Journal, 22(41), pp.14730-14738, Chemistry–A European Journal volume 22 number 41 p. 14730 2016 1521-3765
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Wiley Library Online Terms of Use Statement (https://onlinelibrary.wiley.com/terms-and-conditions)
- Rights
- Closed Access
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Collections
Mack, John (Associate Prof)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
SDG 03. Good Health and Well-Being
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Synthesis, Characterization, and Electronic Structures of Porphyrins.pdf | 848 KB | Adobe Acrobat PDF | View Details Download |