- Title
- Polyamide nanofiber membranes functionalized with zinc phthalocyanines
- Creator
- Goethals, Annelies, Mugadza, Tawanda, Arslanoglu, Yasin, Zugle, Ruphino, Antunes, Edith M, Van Hulle, Stijn W, Nyokong, Tebello, De Clerck, Karen
- Subject
- To be catalogued
- Date
- 2014
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/241505
- Identifier
- vital:50945
- Identifier
- xlink:href="https://doi.org/10.1002/app.40486"
- Description
- Electrospinning is an efficient method for the production of polyamide nanofiber membranes that are suitable for water filtration. Previous studies have shown that nanofiber membranes have high clean water permeability. The pathogen removal efficiency can be improved by functionalization with (organic) biocides. However, these membranes, like other membranes, are vulnerable to fouling which reduces the filtration efficiency. Therefore the present article investigates the potential of zinc phthalocyanines, which can produce singlet oxygen in the presence of visible light, as a functionalizing agent. The polyamide nanofiber membranes were functionalized with phthalocyanines using both a pre-functionalizing and post-functionalizing method. Only the post-functionalization method shows to result in nanofiber membranes capable of producing singlet oxygen. After 30 min 45% of 1,2-diphenylisobenzofuran (DPBF), used as an oxygen quencher, was removed by reaction with singlet oxygen. This resulted in a removal rate of 0.33 mol DBPF mol−1Zn min−1. During short term leaching tests, phthalocyanines could not be detected.
- Format
- computer, online resource, application/pdf, 1 online resource (7 pages), pdf
- Publisher
- Wiley Library Online
- Language
- English
- Relation
- Journal of Applied Polymer Science, Goethals, A., Mugadza, T., Arslanoglu, Y., Zugle, R., Antunes, E., Van Hulle, S.W., Nyokong, T. and De Clerck, K., 2014. Polyamide nanofiber membranes functionalized with zinc phthalocyanines. Journal of Applied Polymer Science, 131(13), Journal of Applied Polymer Science volume 131 number 13 2014 1097-4628
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Wiley Library Online Terms of Use Statement (https://onlinelibrary.wiley.com/terms-and-conditions)
- Rights
- Open Access
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Antunes, Edith Martins (Dr)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
SDG 03. Good Health and Well-Being
| Thumbnail | File | Description | Size | Format | |||
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| View Details | SOURCE1 | Polyamide nanofiber membranes functionalized with zinc phthalocyanines.pdf | 539 KB | Adobe Acrobat PDF | View Details |