- Title
- Adsorption and separation of platinum and palladium by polyamine functionalized polystyrene-based beads and nanofibers
- Creator
- Fayemi, Omolola E, Ogunlaja, Adeniyi S, Kempgens, Pierre F M, Antunes, Edith M, Torto, Nelson, Nyokong, Tebello, Tshentu, Zenixole R
- Subject
- To be catalogued
- Date
- 2013
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/241694
- Identifier
- vital:50961
- Identifier
- xlink:href="https://doi.org/10.1016/j.mineng.2013.06.006"
- Description
- Adsorption and separation of platinum and palladium chlorido species (PtCl62- and PdCl42-) on polystyrene beads as well as nanofibers functionalized with ammonium centres based on ethylenediamine (EDA), diethylenetriamine (DETA), triethylenetetramine (TETA) and tris-(2-aminoethyl)amine (TAEA) are described. The functionalized sorbent materials were characterized by microanalysis, SEM, XPS, BET and FTIR. The surface area of the functionalized fibers was in the range 69–241 m2/g while it was 73–107 m2/g for the beads. The adsorption and loading capacities of the sorption materials were investigated using both the batch and column studies at 1 M HCl concentration. The adsorption studies for both PtCl62- and PdCl42- on the different sorbent materials fit the Langmuir isotherm with R2 values >0.99. The highest loading capacity of Pt and Pd were 7.4 mg/g and 4.3 mg/g respectively for the nanofiber sorbent material based on ethylenediamine (EDA) while the beads with ethylenediamine (EDA) gave 1.0 mg/g and 0.2 mg/g for Pt and Pd respectively. Metals loaded on the sorbent materials were recovered by using 3% m/v thiourea solution as the eluting agent with quantitative desorption efficiency under the selected experimental conditions. Separation of platinum from palladium was partially achieved by selective stripping of PtCl62- with 0.5 M of NaClO4 in 1.0 M HCl while PdCl42- was eluted with 0.5 M thiourea in 1.0 M HCl. Separation of platinum from iridium and rhodium under 1 M HCl concentration was successful on triethylenetriamine (TETA)-functionalized Merrifield beads. This material (M-TETA) showed selectivity for platinum albeit the low loading capacity.
- Format
- computer, online resource, application/pdf, 1 online resource (10 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Minerals Engineering, Fayemi, O.E., Ogunlaja, A.S., Kempgens, P.F., Antunes, E., Torto, N., Nyokong, T. and Tshentu, Z.R., 2013. Adsorption and separation of platinum and palladium by polyamine functionalized polystyrene-based beads and nanofibers. Minerals Engineering, 53, pp.256-265, Minerals Engineering volume 53 p. 256 2013 0892-6875
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Collections
Tshentu, Zenixole Richman (Dr)
Torto, Nelson (Prof)
Antunes, Edith Martins (Dr)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details | SOURCE1 | Adsorption and separation of platinum and palladium by polyamine functionalized.pdf | 738 KB | Adobe Acrobat PDF | View Details |