- Title
- Synthesis and photophysical properties of peripherally and non-peripherally mercaptopyridine substituted metal free, Mg (II) and Al (III) phthalocyanines
- Creator
- Arslanoğlu, Yasin, Idowu, Mopelela, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2012
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/243248
- Identifier
- vital:51131
- Identifier
- xlink:href="https://doi.org/10.1016/j.saa.2012.04.004"
- Description
- The syntheses and photophysical properties of metallophthalocyanines containing Mg2+ and Al3+ as central metal ions and their unmetallated derivative (complexes 3–8) tetra- substituted at the non-peripheral (α) and peripheral (β) positions with 2-mercaptopyridine are reported. The trends in triplet and fluorescence quantum yields are described for these compounds. The complexes exhibited relatively high triplet quantum yields (ΦT) ranging from 0.33 to 0.54 and fluorescence quantum yields (ΦF) ranging from 0.02 to 0.29. Triplet state lifetimes of the complexes were long ranging from 120 to 460 μs, indicating a potential use of these complexes as photosensitizers.
- Format
- computer, online resource, application/pdf, 1 online resource (7 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Arslanoğlu, Y., Idowu, M. and Nyokong, T., 2012. Synthesis and photophysical properties of peripherally and non-peripherally mercaptopyridine substituted metal free, Mg (II) and Al (III) phthalocyanines. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 95, pp.407-413, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy volume 95 p. 407 2012 1386-1425
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Synthesis and photophysical properties of peripherally and non-peripherally mercaptopyridine.pdf | 679 KB | Adobe Acrobat PDF | View Details Download |