- Title
- Layer by Layer Electrode Surface Functionalisation Using Carbon Nanotubes, Electrochemical Grafting of Azide‐Alkyne Functions and Click Chemistry
- Creator
- Coates, Megan, Griveau, Sophie, Bedioui, Fethi, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2012
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/243509
- Identifier
- vital:51159
- Identifier
- xlink:href="https://doi.org/10.1002/elan.201200240"
- Description
- Ferrocene was covalently bonded to a layer of adsorbed single-walled carbon nanotubes on a glassy carbon electrode surface using electrochemical grafting and click chemistry. Grafting of the 4-azidobenzenediazonium salt onto the surface was accomplished by electrochemical reduction. The surface-bound azide groups, with the use of a copper(I) catalyst, were reacted with ethynylferrocene to form covalent 1,2,3-triazole bonds by click chemistry. This layer by layer construction of the electrode surface results in stable electrodes by combining good electrical conductivity and increased surface area of the nanotubes with the versatility of the Sharpless click reaction.
- Format
- computer, online resource, application/pdf, 1 online resource (6 pages), pdf
- Publisher
- Wiley Library Online
- Language
- English
- Relation
- Electroanalysis, Coates, M., Griveau, S., Bedioui, F. and Nyokong, T., 2012. Layer by Layer Electrode Surface Functionalisation Using Carbon Nanotubes, Electrochemical Grafting of Azide‐Alkyne Functions and Click Chemistry. Electroanalysis, 24(9), pp.1833-1838, Electroanalysis volume 24 number 9 p. 1833 2012 1040-0397
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Wiley Library Online Terms of Use Statement (https://onlinelibrary.wiley.com/terms-and-conditions)
- Rights
- Closed Access
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Collections
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Layer by Layer Electrode Surface Functionalisation Using Carbon Nanotubes.pdf | 650 KB | Adobe Acrobat PDF | View Details Download |