- Title
- The effects of carbon nanotubes on the electrocatalysis of hydrogen peroxide by metallo-phthalocyanines
- Creator
- Mashazi, Philani N, Mugadza, Tawanda, Sosibo, Ndabenhle, Mdluli, Phumlani, Vilakazi, Sibulelo, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2011
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/247174
- Identifier
- vital:51553
- Identifier
- xlink:href="https://doi.org/10.1016/j.talanta.2011.07.069"
- Description
- The pre-grafted screen-printed gold electrode modified with phenyl-amino monolayer was investigated for covalent immobilization of phenyl-amine functionalized single-walled carbon nanotubes (PA-SWCNT) and metal tetra-amino phthalocyanine (MTAPc) using Schiff-base reactions with benzene-1,4-dicarbaldehyde (BDCA) as cross-linker. The PA-SWCNT and MTAPc modified electrodes were applied as hybrids for electrochemical sensing of H2O2. The step-by-step fabrication of the electrode was followed using electrochemistry, impedance spectroscopy, scanning electron microscopy and Raman spectroscopy and all these techniques confirmed the fabrication and the immobilization of PA-SWCNT, MnTAPc and CoTAPc onto gold surfaces. The apparent electron transfer constant (kapp) showed that the carbon nanotubes and metallo-phthalocyanines hybrids possess good electron transfer properties compared to the bare, pre-grafted and the MTAPc modified gold electrode surfaces without PA-SWCNT. The electrochemical sensing of hydrogen peroxide was successful with PA-SWCNT–MTAPc hybrid systems showing higher electrocatalytic currents compared to the other electrodes. The analytical parameters obtained using chronoamperometry gave good linearity at H2O2 concentrations ranging from 1.0 to 30.0 μmol L−1. The values for the limit of detection (LoD) were found to be of the orders of 10−7 M using the 3δ for all the electrodes. The PA-SWCNT–MTAPc modified SPAuEs were much more sensitive compared to PA–MTAPc modified SPAuEs.
- Format
- computer, online resource, application/pdf, 1 online resource (10 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Talanta, Mashazi, P., Mugadza, T., Sosibo, N., Mdluli, P., Vilakazi, S. and Nyokong, T., 2011. The effects of carbon nanotubes on the electrocatalysis of hydrogen peroxide by metallo-phthalocyanines. Talanta, 85(4), pp.2202-2211, Talanta volume 85 number 4 p. 2202 2011 0039-9140
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Mashazi, Philani N (Associate Prof)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
SDG 03. Good Health and Well-Being
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| View Details | SOURCE1 | The effects of carbon nanotubes on the electrocatalysis of hydrogen peroxide.pdf | 653 KB | Adobe Acrobat PDF | View Details |