- Title
- Electrooxidation of Chlorophenols Catalyzed by Nickel Octadecylphthalocyanine Adsorbed on Single‐Walled Carbon Nanotubes
- Creator
- Khene, Samson, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2011
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/247198
- Identifier
- vital:51555
- Identifier
- xlink:href="https://doi.org/10.1002/elan.201100155"
- Description
- We described the synthesis of nickel octadecylphthalocyanine (NiPc(C10H21)8), followed by its adsorption on single-walled carbon nanotubes (SWCNT) to form SWCNT-NiPc(C10H21)8 conjugates. SWCNT-NiPc(C10H21)8 was used to modify a glassy carbon electrode (GCE) and for the electrooxidation of 4-chlorophenol and 2,4-dichlorophenol. The SWCNT and NiPc(C10H21)8 have a synergistic effect on each other in terms of improving electrocatalysis for the detection of chlorophenols. The stability of the electrode improved in the presence of NiPc(C10H21)8 or NiPc compared to the bare GCE. The presence of SWCNT improves the electrocatalytic behaviour of NiPc(C10H21)8 but not of unsubstituted NiPc. All modified electrodes showed improved stability towards the detection of 2,4-dichlorophenol. The best stability for 4-CP detection was observed in the presence of SWCNT for NiPc(C10H21)8.
- Format
- computer, online resource, application/pdf, 1 online resource (11 pages), pdf
- Publisher
- Wiley Library Online
- Language
- English
- Relation
- Electroanalysis, Khene, S. and Nyokong, T., 2011. Electrooxidation of Chlorophenols Catalyzed by Nickel Octadecylphthalocyanine Adsorbed on Single‐Walled Carbon Nanotubes. Electroanalysis, 23(8), pp.1901-1911, Electroanalysis volume 23 number 8 p. 1901 2011 1521-4109
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Wiley Library Online Terms of Use Statement (https://onlinelibrary.wiley.com/terms-and-conditions)
- Rights
- Closed Access
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Khene, Samson Mielie (Assoc Prof)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
SDG 03. Good Health and Well-Being
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details | SOURCE1 | Electrooxidation of Chlorophenols Catalyzed by Nickel Octadecylphthalocyanine.pdf | 695 KB | Adobe Acrobat PDF | View Details |