- Title
- The Electrochemical Behavior of Gold Nanoparticle‐Tantalum (V) Phthalocyanine Composites
- Creator
- Chauke, Vongani, Chidawanyika, Wadzanai J U, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2011
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/247915
- Identifier
- vital:51629
- Identifier
- xlink:href="https://doi.org/10.1002/elan.201000521"
- Description
- The formation of gold nanoparticle (AuNP) composites with tantalum phthalocyanines (TaPc) complexes {1a and 1b (Figure 1)} is reported. The TaPc-AuNPs conjugates were characterised by atomic force microscopy (AFM) and transmission electron microscopy. The AFM analyses show that conjugates of TaPc with AuNPs are more aggregated when compared to AuNPs alone. The conjugates and TaPc complexes were immobilized on a gold electrode by drop and dry method and these were characterized by electrochemical impedance spectroscopy. The charge transfer behaviour of AuNPs was enhanced in the presence of TaPc complexes. All the modified electrodes showed electrocatalytic oxidation of bisphenol A. The limits of detection for complexes 1a and 1b were 4.78×10−10 and 2.76×10−10 mol L−1, respectively.
- Format
- computer, online resource, application/pdf, 1 online resource (10 pages), pdf
- Publisher
- Wiley Library Online
- Language
- English
- Relation
- Electroanalysis, Chauke, V.P., Chidawanyika, W. and Nyokong, T., 2011. The Electrochemical Behavior of Gold Nanoparticle‐Tantalum (V) Phthalocyanine Composites: Applications Towards the Electroanalysis of Bisphenol A. Electroanalysis, 23(2), pp.487-496, Electroanalysis volume 23 number 2 p. 487 2011 1521-4109
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Wiley Library Online Terms of Use Statement (https://onlinelibrary.wiley.com/terms-and-conditions)
- Rights
- Closed Access
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Collections
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
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