- Title
- Cyclic voltammetry and spectroelectrochemistry of a novel manganese phthalocyanine substituted with hexynyl groups
- Creator
- Quinton, Damien, Antunes, Edith M, Griveau, Sophie, Nyokong, Tebello, Bedioui, Fethi
- Subject
- To be catalogued
- Date
- 2011
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/248450
- Identifier
- vital:51687
- Identifier
- xlink:href="https://doi.org/10.1016/j.inoche.2010.11.029"
- Description
- We report here on the synthesis of a new manganese phthalocyanine complex, namely Mn tetrakis(5-hexyn-oxy) phthalocyanine (3), specifically designed to possess an alkyne moiety for its potential use in controlled immobilization on electrodes via the so called “click” chemistry reaction. The electrochemical activity of complex 3 was investigated by cyclic voltammetry and the nature of the observed redox couples was elucidated by spectroelectrochemistry. This work has also shown that the reduction of Mn(III)Pc complex to Mn(II)Pc is accompanied by the formation of MnPc μ-oxo species. Further reduction results in the formation of Mn(II)Pc(− 3) rather than Mn(I)Pc(− 2).
- Format
- computer, online resource, application/pdf, 1 online resource (3 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Inorganic Chemistry Communications, Quinton, D., Antunes, E., Griveau, S., Nyokong, T. and Bedioui, F., 2011. Cyclic voltammetry and spectroelectrochemistry of a novel manganese phthalocyanine substituted with hexynyl groups. Inorganic Chemistry Communications, 14(1), pp.330-332, Inorganic Chemistry Communications volume 14 number 1 p. 330 2011 1387-7003
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Antunes, Edith Martins (Dr)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
SDG 03. Good Health and Well-Being
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|---|---|---|---|---|---|---|---|
| View Details | SOURCE1 | Cyclic voltammetry and spectroelectrochemistry of a novel manganese phthalocyanine substituted.pdf | 666 KB | Adobe Acrobat PDF | View Details |