- Title
- Synthesis and electrochemical characterisation of new tantalum (V) alkythio phthalocyanines
- Creator
- Chauke, Vongani, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2010
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/249093
- Identifier
- vital:51777
- Identifier
- xlink:href="https://doi.org/10.1016/j.ica.2010.05.003"
- Description
- The synthesis and electrochemical characterisation of octa-pentylthio (4a) and octa-octylthio (4b) – phthalocyaninato tantalum (III) hydroxide are hereby reported. These TaPc complexes absorb in the near infrared region (∼800 nm in dichloromethane). They show good solubility in most common solvents especially non-viscous solvents such as dichloromethane and chloroform. NMR, mass and infrared spectroscopy and elemental analysis confirmed the structures and purity of the synthesised complexes. The cyclic voltammograms (CVs) showed reversible reduction couples and irreversible oxidation peaks. The latter exhibited adsorption behavior. The reduction processes were observed at −0.74 and −1.13 V (versus Ag|AgCl) for 4a, and −0.67, −1.02 and −1.48 V (versus Ag|AgCl) for 4b. Spectroelectrochemistry confirmed one metal reduction, with the rest of the redox processes being centered on the phthalocyanine ring.
- Format
- computer, online resource, application/pdf, 1 online resource (8 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Inorganica Chimica Acta, Chauke, V. and Nyokong, T., 2010. Synthesis and electrochemical characterisation of new tantalum (V) alkythio phthalocyanines. Inorganica Chimica Acta, 363(14), pp.3662-3669, Inorganica Chimica Acta volume 363 number 14 p. 3662 2010 1873-3255
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Collections
Nyokong, Tebello (Distinguished Professor)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details | SOURCE1 | Synthesis and electrochemical characterisation of new tantalum (V) alkythio phthalocyanines.pdf | 690 KB | Adobe Acrobat PDF | View Details |