- Title
- Effects of the number of ring substituents of cobalt carboxyphthalocyanines on the electrocatalytic detection of nitrite, cysteine and melatonin
- Creator
- Matemadombo, Fungisai, Sehlotho, Nthapo, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2009
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/263408
- Identifier
- vital:53625
- Identifier
- xlink:href="https://doi.org/10.1142/S108842460900125X"
- Description
- Cobalt phthalocyanine (CoPc), cobalt tetracarboxy phthalocyanine (CoTCPc) and cobalt octacarboxy phthalocyanine (CoOCPc), adsorbed onto glassy carbon electrodes, have been used for the electrocatalytic detection of nitrite, L-cysteine and melatonin. The modified electrodes electrocatalytically detected nitrite around 800 mV vs.Ag|AgCl, a value less positive compared to that of an unmodified glassy carbon electrode (at 950 mV vs.Ag|AgCl) and also gave detection limits in the 10-7 M range for nitrite detection. L-cysteine was detected by the modified electrodes at potentials between 0.50 to 0.65 V vs.Ag|AgCl, with L-cysteine detection limits also in the 10-7 M range. The detection limits for melatonin ranged from 10-7 to 10-6 M. CoPc-modified electrodes displayed good separation of interferents (tryptophan and ascorbic acid) in the presence of melatonin. Analyses of commercial melatonin tablets using modified electrodes gave excellent agreement with manufacturer's value for all modified electrodes of this work.
- Format
- computer, online resource, application/pdf, 1 online resource (13 pages), pdf
- Publisher
- World Scientific Publishing
- Language
- English
- Relation
- Journal of Porphyrins and Phthalocyanines, Matemadombo, F., Sehlotho, N. and Nyokong, T., 2009. Effects of the number of ring substituents of cobalt carboxyphthalocyanines on the electrocatalytic detection of nitrite, cysteine and melatonin. Journal of Porphyrins and Phthalocyanines, 13(08n09), pp.986-997, Journal of Porphyrins and Phthalocyanines volume 13 number 08n09 p. 986 2009 1099-1409
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the World Scientific Copyright and Permissions Statement (https://0-www.worldscientific.com.wam.seals.ac.za/page/permissions)
- Rights
- Closed Access
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Collections
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Effects of the number of ring substituents of cobalt carboxyphthalocyanines.pdf | 700 KB | Adobe Acrobat PDF | View Details Download |