- Title
- Electroanalysis of thiocyanate using a novel glassy carbon electrode modified by aryl radicals and cobalt tetracarboxyphthalocyanine
- Creator
- Matemadombo, Fungisai, Westbroek, Philippe, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2007
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/268750
- Identifier
- vital:54228
- Identifier
- xlink:href="https://doi.org/10.1016/j.electacta.2007.06.064"
- Description
- Electrochemical grafting of 4-nitrobenzenediazonium tetrafluoroborate onto a glassy carbon electrode (GCE) results in the formation of a nitrophenyl radical, which reacts with the surface to form a covalent bond (grafting) and results in a nitrophenyl modified electrode. The nitro group is electrochemically reduced to a NH2 group. Cobalt tetracarboxyphthalocyanine (CoTCPc) complex is then attached to the NH2 group using 1-ethyl-3-(3-dimethylaminopropyl)-carbodiimide (EDC) and N-hydroxysuccinimide (NHS) as coupling agents. The new CoTCPc modified electrode was characterized using cyclic voltammetry and then employed for the catalytic oxidation of thiocyanate.
- Format
- computer, online resource, application/pdf, 1 online resource (7 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Elec Acta, Matemadombo, F., Westbroek, P. and Nyokong, T., 2007. Electroanalysis of thiocyanate using a novel glassy carbon electrode modified by aryl radicals and cobalt tetracarboxyphthalocyanine. Electrochimica acta, 53(2), pp.480-486, Elec Acta volume 53 number 2 p. 480 2007 1873-3859
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Electroanalysis of thiocyanate using a novel glassy carbon electrode.pdf | 640 KB | Adobe Acrobat PDF | View Details Download |