- Title
- Electrochemical and photophysical characterization of non-peripherally-octaalkyl substituted dichlorotin (IV) phthalocyanine and tetrabenzotriazaporphyrin compounds
- Creator
- Khene, Samson M, Cammidge, Andrew N, Cook, Michael J, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2007
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/271216
- Identifier
- vital:54522
- Identifier
- xlink:href="https://doi.org/10.1142/S1088424607000886"
- Description
- Three non-peripherally substituted tin(IV) macrocylic compounds, octahexylphthalocyaninato dichlorotin(IV) (3a), octahexyltetrabenzo-5,10,15- triazaporphyrinato dichlorotin(IV) (3b) and octadecylphthalocyaninato dichlorotin(IV) (3c) were synthesized and their photophysical and electrochemical behavior studied. Complex 3b, containing a CH group in place of one of the aza nitrogen atoms of the phthalocyanine core, shows a split Q-band due to its lower symmetry. The triplet state quantum yields were found to be lower than would be expected on the basis of the heavy atom effect of tin as the central metal for phthalocyanine derivatives (3a and 3c). In contrast, 3b shows a triplet quantum yield ΦT = 0.78. The triplet state lifetimes were solvent dependent, and were higher in tetrahydrofuran than in toluene. Cyclic voltammetry and spectroelectrochemistry of the complexes revealed only ring-based redox processes.
- Format
- computer, online resource, application/pdf, 1 online resource (11 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Journal of Porphyrins and Phthalocyanines, Khene, S., Cammidge, A.N., Cook, M.J. and Nyokong, T., 2007. Electrochemical and photophysical characterization of non-peripherally-octaalkyl substituted dichlorotin (IV) phthalocyanine and tetrabenzotriazaporphyrin compounds. Journal of Porphyrins and Phthalocyanines, 11(10), pp.761-770, Journal of Porphyrins and Phthalocyanines volume 11 number 10 p. 761 2007 1088-4246
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the World Scientific Copyright and Permissions Statement (https://0-www.worldscientific.com.wam.seals.ac.za/page/permissions)
- Rights
- Closed Access
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Khene, Samson Mielie (Assoc Prof)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
SDG 03. Good Health and Well-Being
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details | SOURCE1 | Electrochemical and photophysical characterization of non-peripherally-octaalkyl substituted dichlorotin.pdf | 797 KB | Adobe Acrobat PDF | View Details |