- Title
- Electropolymerizable iron (III) and cobalt (II) dicyanophenoxy tetraphenylporphyrin complexes
- Creator
- Ozoemena, Kenneth I, Zhao, Zhixin, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2006
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/286080
- Identifier
- vital:56236
- Identifier
- xlink:href="https://doi.org/10.1016/j.inoche.2005.11.024"
- Description
- Solution and solid phase electrochemical features of 5-[4-(3,4-dicyanophenoxy)phenyl],10,15,20-triphenylporphyrin complexes of iron(III) (FeCNOTPP(Cl)) and cobalt(II) (CoCNOTPP) have been described. These novel asymmetric dicyanophenoxy-derivatised cobalt and iron porphyrin complexes were electropolymerised onto glassy carbon electrodes, which in aqueous solutions, gave surface concentrations (ca. 10−10 mol cm−2) typical of monolayer coverages. The films also exhibited excellent stability and electrocatalysis towards the direct detection of important analytes as nitrite, nitric oxide, and hydrogen peroxide in aqueous solutions.
- Format
- computer, online resource, application/pdf, 1 online resource (5 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Inorganic Chemistry Communications, Ozoemena, K.I., Zhao, Z. and Nyokong, T., 2006. Electropolymerizable iron (III) and cobalt (II) dicyanophenoxy tetraphenylporphyrin complexes: Potential electrocatalysts. Inorganic Chemistry Communications, 9(2), pp.223-227, Inorganic Chemistry Communications volume 9 number 2 p. 223 2006 1879-0259
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
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