- Title
- Catalytic behavior of osmium (II), rhodium (III) and ruthenium (II) Phthalocyanines towards the electrooxidation of cysteine on glassy carbon electrodes
- Creator
- Sekota, Mantoa, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 1997
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/293290
- Identifier
- vital:57072
- Identifier
- xlink:href=" https://doi.org/10.1002/elan.1140091608"
- Description
- Glassy carbon electrodes (GCE's) modified with phthalocyanine complexes of Rh, Ru and Os are employed for the catalytic oxidation of cysteine. When cyanide and dimethylsulfoxide (DMSO) are used as axial ligands giving (DMSO)(Cl)RhIIIPc, [(CN)2RhIIIPc]−, (DMSO)2OsPcII, and [(DMSO)2Ru(II)Pc]·2DMSO complexes, the peak currents for the oxidation of cysteine increase after each scan, indicating an increase in the catalytic activity of the electrode with repetitive scanning. This improvement in the catalytic activity of the GCE after the first scan is attributed to the formation of dimeric π cation radical species at the electrode surface.
- Format
- computer, online resource, application/pdf, 1 online resource (5 pages), pdf
- Publisher
- Wiley Library Online
- Language
- English
- Relation
- Electroanalysis, Sekota, M. and Nyokong, T., 1997. Catalytic behavior of osmium (II), rhodium (III) and ruthenium (II) Phthalocyanines towards the electrooxidation of cysteine on glassy carbon electrodes. Electroanalysis, 9(16), pp.1257-1261, Electroanalysis volume 9 number 16 p. 1257 1997 1521-4109
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Wiley Library Online Terms of Use Statement (https://onlinelibrary.wiley.com/terms-and-conditions)
- Rights
- Closed Access
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- Visitors: 394
- Downloads: 32
Collections
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
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