- Title
- Substituted catechols as complexing agents for the determination of bismuth, lead, copper and cadmium by adsorptive stripping voltammetry
- Creator
- Limson, Janice L, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 1997
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/293311
- Identifier
- vital:57074
- Identifier
- xlink:href="https://doi.org/10.1016/S0003-2670(96)00585-5"
- Description
- Copper, cadmium, lead and bismuth (> 5 μg ml−1) are determined by adsorptive cathodic stripping voltammetry (AdCSV) on a mercury film glassy carbon electrode, using catechol, 4-methylcatechol, 4-t-butylcatechol and resorcinol as complexing ligands. Complexes of lead, copper and bismuth with resorcinol showed the largest increase in current with increase in metal concentration, whereas complexes of these metals with 4-t-butylcatechol showed the lowest current response. Cadmium showed a different behaviour from the other three metals in that the highest current response was observed with 4-methylcatechol. The four metals could be determined simultaneously in the presence of resorcinol, although considerable interference was observed between bismuth and copper.
- Format
- computer, online resource, application/pdf, 1 online resource (9 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Analytica Chimica Acta, Limson, J. and Nyokong, T., 1997. Substituted catechols as complexing agents for the determination of bismuth, lead, copper and cadmium by adsorptive stripping voltammetry. Analytica chimica acta, 344(1-2), pp.87-95, Analytica Chimica Acta volume 344 number 1-2 p. 87 1997 0003-2670
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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