- Title
- Spectroelectrochemical studies of tin (IV) diphthalocyanine
- Creator
- Nensala, Ngudiankama, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 1996
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/293436
- Identifier
- vital:57085
- Identifier
- xlink:href="https://doi.org/10.1016/0277-5387(95)00325-1"
- Description
- Cyclic voltammetry of tin(IV) diphthalocyanine (Pc2Sn) in dichloromethane containing TEAP shows two reduction couples at −0.56 and −0.89 versus saturated calomel electrode (SCE) and one oxidation couple at 0.35 V versus SCE; all were quasireversible one-electron couples. The oxidation couple corresponds to [Pc(−1)SnIVPc(−2)+/Pc(−2)SnIVPc(−2) and the reduction couples to Pc(−2)SnIVPc(−2)/[Pc(−3)SnIVPc(−2)]− and [Pc(−3)SnIVPc(−2)]−/[Pc(−3)SnIVPc(−3)]2−, respectively. The electronic absorption spectra of the various reduced or oxidized tin(IV) diphthalocyanine species are reported.
- Format
- computer, online resource, application/pdf, 1 online resource (6 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Polyhedron, Nensala, N. and Nyokong, T., 1996. Spectroelectrochemical studies of tin (IV) diphthalocyanine. Polyhedron, 15(5-6), pp.867-872, Polyhedron volume 15 number 5-6 p. 867 1996 0277-5387
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Collections
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details | SOURCE1 | Spectroelectrochemical studies of tin (IV) diphthalocyanine.pdf | 642 KB | Adobe Acrobat PDF | View Details |