- Title
- The reaction of cyanide with iron (II) hexadecachlorophthalocyanine
- Creator
- Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 1995
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/293447
- Identifier
- vital:57086
- Identifier
- xlink:href="https://doi.org/10.1016/0277-5387(94)00291-L"
- Description
- Kinetics and equilibria for the reaction between cyanide and iron(II) hexadecachlorophthalocyanine ((Cl)16PcFe(DMSO)2, where Pc(−2) = phthalocyanine dianion) in dimethyl sulphoxide (DMSO) are reported. Only the spectrophotometric changes due to the formation of the dicyano, [(Cl)16PcFe(CN)2]2−, complex were observed. This complex is formed with the equilibrium constant, K3 = 1.6 × 103 dm3 mol−1 and a rate constant of k3f = 4.2 × 10−3 dm3 mol−1 s−1. The K2[(Cl)16PcFe(CN)2] complex dissolves in DMSO and dimethyl formamide (DMF) with ϵ = 110 000 and 92 000 dm3 mol−1 cm−1, respectively.
- Format
- computer, online resource, application/pdf, 1 online resource (6 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Polyhedron, Nyokong, T., 1995. The reaction of cyanide with iron (II) hexadecachlorophthalocyanine. Polyhedron, 14(5), pp.643-648, Polyhedron volume 14 number 5 p. 643 1995 1873-3719
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Collections
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
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