- Title
- Cyclic voltammetry and photooxidation of molybdenum (V) phthalocyanine
- Creator
- Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 1994
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/295475
- Identifier
- vital:57344
- Identifier
- xlink:href="https://doi.org/10.1016/S0277-5387(00)86594-8"
- Description
- Cyclic voltammetry of OMoV(OH)Pc in chloronaphthalene shows two quasi-reversible oxidation couples at 0.38 and 1.22 V and three quasi-reversible reduction couples at −0.74, −1.15 and −1.85 V vs S.C.E. Bulk electrolysis of OMoV(OH)Pc (Pc2 = phthalocyanine dianion) shows that the first oxidation couple is due to the oxidation of the central MoV metal to MoVI and the first reduction couple due to reduction to OMoIVPc. Cyclic voltammetry and spectroelectrochemistry in DMSO also showed redox activity at the metal. Further reductions or oxidations in OMoVPc complexes occur at the phthalocyanine ring. OMoV(OH)Pc is readily photooxidized at the metal in the presence dichloromethane or dichlorobenzene, with the formation of OMoVIPc species.
- Format
- computer, online resource, application/pdf, 1 online resource (6 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Polyhedron, Nyokong, T., 1994. Cyclic voltammetry and photooxidation of molybdenum (V) phthalocyanine. Polyhedron, 13(2), pp.215-220, Polyhedron volume 13 number 2 p. 215 1994 1873-3719
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Collections
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
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