- Title
- Complexes of mercury(II) and zinc(II) with primary aromatic amines
- Creator
- Haigh, John M, Van Dam, M A, Thornton, D A
- Date
- 1967
- Type
- text
- Type
- Article
- Identifier
- vital:6370
- Identifier
- http://hdl.handle.net/10962/d1006072
- Description
- A series of amine complexes has been prepared by reaction of zinc chloride and mercuric chloride with primary aromatic amines. A detailed assignment of the bands in the infra-red spectra of the complexes in the range 4000-625 cm [superscript]-1 is presented. The symmetric and asymmetric N-H stretching frequencies follow the relationship v(sym) = 345.5+ 0.876v(asym). The C-N stretching frequencies exhibit a linear relationship with the Hammett α-functions for the m- and p-substituted amines.
- Format
- 10 pages, pdf
- Language
- English
- Relation
- Haigh, J.M. and van Dam, M.A. and Thornton, D.A. (1967) Complexes of mercury(II) and zinc(II) with primary aromatic amines. Journal of the South African Chemical Institute, 20 . pp. 113-122.
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