- Title
- Elucidation of the complex Baylis-Hillman reaction of 3-methoxy-2-nitrobenzaldehyde with methyl vinyl ketone
- Creator
- Idahosa, Kenudi C, Molefe, Duduzile M, Pakade, Vusumzi E, Brown, Michael E
- Date
- 2011
- Type
- Article
- Identifier
- vital:6574
- Identifier
- http://hdl.handle.net/10962/d1004137
- Description
- DABCO-catalyzed reaction of 3-methoxy-2-nitrobenzaldehyde with methyl vinyl ketone (MVK) affords a mixture of products, comprising the ‘normal’ Baylis-Hillman adduct, theMVKdimer and a pair of diastereomeric bis-(MVK)Baylis-Hillman adducts. 1HNMRspectroscopy-based kinetic studies have provided clear insights into the competing pathways and product distribution in this complex reaction.
- Format
- 7 pages, pdf
- Language
- English
- Relation
- Idahosa, K.C. and Molefe, D.M. and Pakade, V.E. and Brown, M.E. (2011) Elucidation of the Complex Baylis-Hillman Reaction of 3-Methoxy-2-nitrobenzaldehyde with Methyl Vinyl Ketone. South African Journal of Chemistry, 64 . pp. 144-150.
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Brown, Michael Ewart 1938- (Prof)
RU Department of Chemistry
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