- Title
- Facile synthesis, spectroscopic and electrochemical properties, and theoretical calculations of porphyrin dimers with a bridging amide-bonded xanthene moiety
- Creator
- Liang, Xu, Xu, Li, Li, Minzhi, Mack, John, Stone, Justin, Nyokong, Tebello, Jiang, Yu, Kobayashi, Nagao, Zhu, Weihua
- Type
- Article
- Identifier
- vital:7292
- Identifier
- http://hdl.handle.net/10962/d1020355
- Description
- A free base porphyrin dimer bridged by a flexible amide-bonded xanthene moiety and its binuclear zinc(II) complex zinc(II) complex were synthesized and characterized. Structural characterization by MS and 1H NMR spectroscopy confirmed the bridged porphyrin dimer structure. The properties of the dimers were characterized by IR, UV-visible absorption, fluorescence and magnetic circular dichroism (MCD) spectroscopy, and electrochemistry studies. Theoretical calculations were carried out to analyze the electronic structures of porphyrin dimers with a bridging amide-bonded xanthene moiety.
- Description
- Original publication is available at http://dx.doi.org/10.1142/S1088424615500492
- Format
- 11 p., pdf
- Publisher
- World Scientific Publishing
- Language
- English
- Relation
- Liang, X., Xu, L., Li, M., Mack, J., Stone, J., Nyokong, T., Jiang, Y., Kobayashi, N. & Zhu, W. 2015. Facile synthesis, spectroscopic and electrochemical properties, and theoretical calculations of porphyrin dimers with a bridging amide-bonded xanthene moiety. Journal of Porphyrins and Phthalocyanines, 19(7):819–829. Available: http://dx.doi.org/10.1142/S1088424615500492.
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Mack, John (Associate Prof)
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
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