- Title
- DBU-Mediated cleavage of aryl-and heteroaryl disulfides
- Creator
- Nyoni, Dubekile, Lobb, Kevin A, Kaye, Perry T, Cairab, Mino R
- Subject
- To be catalogued
- Date
- 2012
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/448884
- Identifier
- vital:74768
- Description
- The capacity of the nitrogen nucleophile, 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) to reduce aryl- and heteroaryl disulfides to the corresponding mercaptans is demonstrated. While dicarboxylated disulfide analogues afford the mono-DBU disulfide salts, as confirmed by X-ray crystallography, the corresponding methyl esters are cleaved normally.
- Format
- computer, online resource, application/pdf, 1 online resource (8 pages), pdf
- Publisher
- ARKIVOC
- Language
- English
- Relation
- Arkivoc, Nyoni, D., Lobb, K.A., Kaye, P.T. and Cairab, M.R., 2012. DBU-Mediated cleavage of aryl-and heteroaryl disulfides. Arkivoc, 6, pp.245-252, Arkivoc volume 6 p. 245 2012 1551-7012
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the ARKIVOC Open Access Statement (https://www.arkat-usa.org/about-arkivoc/)
- Rights
- Open Access
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