- Title
- Solvent promoted tautomerism in thione-containing tetraazatricyclics: evidence from 1H NMR spectroscopy and transition state studies
- Creator
- Odame, Felix, Tshentu, Zenixole R, Lobb, Kevin A
- Subject
- To be catalogued
- Date
- 2022
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/453198
- Identifier
- vital:75230
- Identifier
- xlink:href="https://link.springer.com/article/10.1007/s00894-022-05204-w"
- Description
- Tautomerism in the nitro substituted thione-containing traazatricyclics has been investigated. Evidence from 1 H NMR indicating the existence of the tautomers has been augmented with computational studies providing evidence of the stability or otherwise of these tautomers. The role of water and DMSO in the formation of the tautomers has been explained. The role of the nitro group in assisting in the formation of the tautomers has been discussed.
- Format
- computer, online resource, application/pdf, 1 online resource (9 pages), pdf
- Publisher
- Springer
- Language
- English
- Relation
- Journal of Molecular Modeling, Odame, F., Tshentu, Z.R. and Lobb, K., 2022. Solvent promoted tautomerism in thione-containing tetraazatricyclics: evidence from 1H NMR spectroscopy and transition state studies. Journal of Molecular Modeling, 28(8), p.215, Journal of Molecular Modeling volume 28 number 8 p. 215 2022 0948-5023
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the SpringerLink Terms of Use Statement ( https://link.springer.com/termsandconditions)
- Rights
- Closed Access
- Hits: 66
- Visitors: 61
- Downloads: 2
Collections
Lobb, Kevin Allan (Assoc Prof)
RU Department of Chemistry
SDG 03. Good Health and Well-Being
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details | SOURCE1 | Solvent promoted tautomerism in thione-containing tetraazatricyclics.pdf | 901 KB | Adobe Acrobat PDF | View Details |