- Title
- Core-modified rubyrins with phenanthrene-fused pyrrole rings
- Creator
- Yuan, Xuemei, Li, Minzhi, Meng, Ting, Mack, John, Soy, Rodah, Nyokong, Tebello, Zhu, Weihua, Xu, Haijun, Liang, Xu
- Subject
- To be catalogued
- Date
- 2018
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/234568
- Identifier
- vital:50209
- Identifier
- xlink:href="https://doi.org/10.1016/j.dyepig.2018.05.045"
- Description
- Three fused-ring-expanded rubyrins with modified macrocyclic core have been synthesized and characterized. A series of spectroscopic, electrochemical measurements and a set of theoretical calculations demonstrate that the core-modification of the inner core of rubyrins has a large influence on the electronic structure. Colorimetric changes are observe that demonstrate that these core-modified rubyrins could be used as selective Hg2+ ion sensors. These properties can be fine-tuned by introducing lipophilic substituents on the meso-aryl rings.
- Format
- computer, online resource, application/pdf, 1 online resource (7 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Dyes and Pigments, Yuan, X., Li, M., Meng, T., Mack, J., Soy, R., Nyokong, T., Zhu, W., Xu, H. and Liang, X., 2018. Core-modified rubyrins with phenanthrene-fused pyrrole rings: Highly selective and tunable response to Hg2+ ions. Dyes and Pigments, 158, pp.188-194, Dyes and Pigments volume 158 p. 188 2018 1873-3743
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Mack, John (Associate Prof)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
SDG 03. Good Health and Well-Being
| Thumbnail | File | Description | Size | Format | |||
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| View Details | SOURCE1 | Core-modified rubyrins with phenanthrene-fused pyrrole rings.pdf | 691 KB | Adobe Acrobat PDF | View Details |