Electrochemical Detection of Nitrite on Electrodes Modified by Click Chemistry Using Asymmetrical Co (II) and Mn (III) Phthalocyanines Containing Push-Pull Substituents
- Nkhahle, Reitumetse, Nyokong, Tebello
- Authors: Nkhahle, Reitumetse , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/231425 , vital:49886 , xlink:href="https://doi.org/10.1149/1945-7111/ac377f"
- Description: The more conventional route to synthesizing asymmetric push-pull phthalocyanines (Pcs) involves pairing electron-donating substituents with electron-withdrawing groups in either an A3B or AB3 manner. In this work, a push-pull system fashioned from a substituent bearing different functional groups was created. Symmetric and asymmetric cobalt and manganese Pcs in which acetaminophen was the dominant substituent were synthesized where the asymmetric analogues bore an alkyne-terminated substituent. These complexes were applied as sensors towards the electro-oxidation of nitrite. In addition to comparing the asymmetric Pcs to the symmetric counterparts, an assessment on the different central metals as well as the method of electrode modification was made. From the studies performed, the results showed that the manganese complexes are generally better suited (more so when clicked on to the electrode) in the electrocatalysis of nitrite with a limit of detection and a catalytic rate values of 2.15 μM and 6.91 × 106 s−1 M−1 being recorded for the asymmetric MnPc.
- Full Text:
- Date Issued: 2021
- Authors: Nkhahle, Reitumetse , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/231425 , vital:49886 , xlink:href="https://doi.org/10.1149/1945-7111/ac377f"
- Description: The more conventional route to synthesizing asymmetric push-pull phthalocyanines (Pcs) involves pairing electron-donating substituents with electron-withdrawing groups in either an A3B or AB3 manner. In this work, a push-pull system fashioned from a substituent bearing different functional groups was created. Symmetric and asymmetric cobalt and manganese Pcs in which acetaminophen was the dominant substituent were synthesized where the asymmetric analogues bore an alkyne-terminated substituent. These complexes were applied as sensors towards the electro-oxidation of nitrite. In addition to comparing the asymmetric Pcs to the symmetric counterparts, an assessment on the different central metals as well as the method of electrode modification was made. From the studies performed, the results showed that the manganese complexes are generally better suited (more so when clicked on to the electrode) in the electrocatalysis of nitrite with a limit of detection and a catalytic rate values of 2.15 μM and 6.91 × 106 s−1 M−1 being recorded for the asymmetric MnPc.
- Full Text:
- Date Issued: 2021
Analysis of non-peptidic compounds as potential malarial inhibitors against plasmodial cysteine proteases via integrated virtual screening workflow
- Musyoka, Thommas M, Kanzi, Aquillah M, Lobb, Kevin A, Tastan Bishop, Özlem
- Authors: Musyoka, Thommas M , Kanzi, Aquillah M , Lobb, Kevin A , Tastan Bishop, Özlem
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123074 , vital:35403 , https://doi.10.1080/07391102.2015.1108231
- Description: Malaria is an infectious disease caused by a diverse group of erythrocytic protozoan parasites of the genus Plasmodium. It remains an exigent public health problem in the tropical areas of Africa, South America and parts of Asia and continues to take its toll in morbidity and mortality with half of the world’s population under a permanent risk of infection leading to more than half a million deaths annually (WHO, 2013). Five Plasmodium species, namely P. falciparum (Pf ), P. vivax (Pv), P. ovale (Po), P. malariae (Pm) and P. knowlesi (Pk), are known to infect humans with Pf responsible for more than 90% of the malarial fatalities reported in sub-Saharan Africa. The predominance of Pf is attributed to its adaptability (Ashley, McGready, Proux, & Nosten, 2006; Prugnolle et al., 2011). Although the high occurrence of the Duffy negative trait among African populations lowers the threat posed by Pv, it is the most frequent and widely causative agent of benign tertian malaria in other parts of the world (Mendis, Sina, Marchesini, & Carter, 2001). In addition to the listed human malarial parasite forms, several other Plasmodium species, which infect non-human laboratory models, have been identified and are of significant importance in understanding the parasite biology, the host–parasite interactions and in the drug development process (Langhorne et al., 2011).
- Full Text:
- Date Issued: 2016
- Authors: Musyoka, Thommas M , Kanzi, Aquillah M , Lobb, Kevin A , Tastan Bishop, Özlem
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123074 , vital:35403 , https://doi.10.1080/07391102.2015.1108231
- Description: Malaria is an infectious disease caused by a diverse group of erythrocytic protozoan parasites of the genus Plasmodium. It remains an exigent public health problem in the tropical areas of Africa, South America and parts of Asia and continues to take its toll in morbidity and mortality with half of the world’s population under a permanent risk of infection leading to more than half a million deaths annually (WHO, 2013). Five Plasmodium species, namely P. falciparum (Pf ), P. vivax (Pv), P. ovale (Po), P. malariae (Pm) and P. knowlesi (Pk), are known to infect humans with Pf responsible for more than 90% of the malarial fatalities reported in sub-Saharan Africa. The predominance of Pf is attributed to its adaptability (Ashley, McGready, Proux, & Nosten, 2006; Prugnolle et al., 2011). Although the high occurrence of the Duffy negative trait among African populations lowers the threat posed by Pv, it is the most frequent and widely causative agent of benign tertian malaria in other parts of the world (Mendis, Sina, Marchesini, & Carter, 2001). In addition to the listed human malarial parasite forms, several other Plasmodium species, which infect non-human laboratory models, have been identified and are of significant importance in understanding the parasite biology, the host–parasite interactions and in the drug development process (Langhorne et al., 2011).
- Full Text:
- Date Issued: 2016
Are people responsive to a more sustainable, decentralized, and user-driven management of urban metabolism?:
- Chelleri, Lorenzo, Kua, Harn W, Rodriguez Sanchez, Juan P, Nahiduzzaman, Kh M, Thondhlana, Gladman
- Authors: Chelleri, Lorenzo , Kua, Harn W , Rodriguez Sanchez, Juan P , Nahiduzzaman, Kh M , Thondhlana, Gladman
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144299 , vital:38329 , https://orcid.org/0000-0001-8253-0264
- Description: Smart, green, and resilient city paradigms have been mainly promoted through top-down and technocratic approaches. However, based on the notion to return to “the right to the city”, emerging community-driven initiatives are providing self-managed infrastructures contributing to urban sustainability transitions. This paper explores the relevance of the behavioral aspects of people-centered approaches in dealing with two different facets of urban metabolism: physical infrastructure (involvement with the management of decentralized infrastructures) and consumption patterns (involvement in proactive reduction of resources used). In the first case we assessed community perceptions about the roles, benefits, and willingness to proactively engage in the management of decentralized green infrastructures in Bogotá City, Colombia. For the second facet, we measured the effectiveness of change agents in re-shaping energy consumption decisions within urban social networks in South Africa and Saudi Arabia. This paper’s results show that pre-determined and standardized strategies do not guarantee positive, nor homogeneous, results in terms of meeting sustainability targets, or promoting community involvement. Hence, a better integration of people-centered and top-down approaches is needed through context-dependent policies, for enhancing both users’ appreciation of and commitment to urban metabolism participative management.
- Full Text:
- Date Issued: 2016
- Authors: Chelleri, Lorenzo , Kua, Harn W , Rodriguez Sanchez, Juan P , Nahiduzzaman, Kh M , Thondhlana, Gladman
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144299 , vital:38329 , https://orcid.org/0000-0001-8253-0264
- Description: Smart, green, and resilient city paradigms have been mainly promoted through top-down and technocratic approaches. However, based on the notion to return to “the right to the city”, emerging community-driven initiatives are providing self-managed infrastructures contributing to urban sustainability transitions. This paper explores the relevance of the behavioral aspects of people-centered approaches in dealing with two different facets of urban metabolism: physical infrastructure (involvement with the management of decentralized infrastructures) and consumption patterns (involvement in proactive reduction of resources used). In the first case we assessed community perceptions about the roles, benefits, and willingness to proactively engage in the management of decentralized green infrastructures in Bogotá City, Colombia. For the second facet, we measured the effectiveness of change agents in re-shaping energy consumption decisions within urban social networks in South Africa and Saudi Arabia. This paper’s results show that pre-determined and standardized strategies do not guarantee positive, nor homogeneous, results in terms of meeting sustainability targets, or promoting community involvement. Hence, a better integration of people-centered and top-down approaches is needed through context-dependent policies, for enhancing both users’ appreciation of and commitment to urban metabolism participative management.
- Full Text:
- Date Issued: 2016
Assessment of water quality based on diatom indices in a small temperate river system, Kowie River, South Africa
- Dalu, Tatenda, Bere, Taurai, Froneman, P William
- Authors: Dalu, Tatenda , Bere, Taurai , Froneman, P William
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123896 , vital:35514 , http://dx.doi.org/10.4314/wsa.v42i2.02
- Description: This study aimed to assess the impact of land use patterns on water quality and benthic diatom community structure and to test the applicability of diatom indices developed in other regions of the world to a small temperate southern African river system. Sampling was conducted at eight study sites along the length of the river on four separate occasions. Multivariate data analyses were performed on the diatom community dataset to specify the main gradients of floristic variation and to detect and visualize similarities in diatom samples in relation to land-use patterns within the catchment. One hundred and twelve (112) diatom species belonging to 36 genera were recorded during the study. Canonical correspondence analysis (CCA) demonstrated that variations in the benthic diatom community structure were best explained by ammonium, nitrate, conductivity, pH, temperature, resistivity and water flow. OMNIDIA was used for calculation of selected diatom water quality indices. A number of the indices, e.g., the trophic diatom index (TDI), eutrophication/pollution index and biological index of water quality (BIWQ), either under- or over-estimated the water quality of the system. With few exceptions, there were no significant correlations (p> 0.05) between the diatom indices’ values and the nutrient variables. The absence of any significant correlations between the diatom indices’ values and selected physico-chemical variables suggests that indices developed in other regions of the world may not be suitable for temperate southern African rivers.
- Full Text:
- Date Issued: 2016
- Authors: Dalu, Tatenda , Bere, Taurai , Froneman, P William
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123896 , vital:35514 , http://dx.doi.org/10.4314/wsa.v42i2.02
- Description: This study aimed to assess the impact of land use patterns on water quality and benthic diatom community structure and to test the applicability of diatom indices developed in other regions of the world to a small temperate southern African river system. Sampling was conducted at eight study sites along the length of the river on four separate occasions. Multivariate data analyses were performed on the diatom community dataset to specify the main gradients of floristic variation and to detect and visualize similarities in diatom samples in relation to land-use patterns within the catchment. One hundred and twelve (112) diatom species belonging to 36 genera were recorded during the study. Canonical correspondence analysis (CCA) demonstrated that variations in the benthic diatom community structure were best explained by ammonium, nitrate, conductivity, pH, temperature, resistivity and water flow. OMNIDIA was used for calculation of selected diatom water quality indices. A number of the indices, e.g., the trophic diatom index (TDI), eutrophication/pollution index and biological index of water quality (BIWQ), either under- or over-estimated the water quality of the system. With few exceptions, there were no significant correlations (p> 0.05) between the diatom indices’ values and the nutrient variables. The absence of any significant correlations between the diatom indices’ values and selected physico-chemical variables suggests that indices developed in other regions of the world may not be suitable for temperate southern African rivers.
- Full Text:
- Date Issued: 2016
From global to regional and back again: common climate stressors of marine ecosystems relevant for adaptation across five ocean warming hotspots
- Popova, Ekaterina, Yool, Andrew, Byfield, Valborg, Cochrane, Kevern L, Coward, Andrew C, Salim, Shyam S, Gasalla, Maria A, Henson, S.A, Hobday, Alistair J, Pecl, Gretta T, Sauer, Warwick H H, Roberts, Michael J
- Authors: Popova, Ekaterina , Yool, Andrew , Byfield, Valborg , Cochrane, Kevern L , Coward, Andrew C , Salim, Shyam S , Gasalla, Maria A , Henson, S.A , Hobday, Alistair J , Pecl, Gretta T , Sauer, Warwick H H , Roberts, Michael J
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124514 , vital:35623 , https://doi.10.1111/gcb.13247
- Description: Ocean warming ‘hotspots’ are regions characterized by above-average temperature increases over recent years, for which there are significant consequences for both living marine resources and the societies that depend on them. As such, they represent early warning systems for understanding the impacts of marine climate change, and test-beds for developing adaptation options for coping with those impacts. Here, we examine five hotspots off the coasts of eastern Australia, South Africa, Madagascar, India and Brazil. These particular hotspots have underpinned a large international partnership that is working towards improving community adaptation by characterizing, assessing and projecting the likely future of coastal-marine food resources through the provision and sharing of knowledge. To inform this effort, we employ a high-resolution global ocean model forced by Representative Concentration Pathway 8.5 and simulated to year 2099. In addition to the sea surface temperature, we analyse projected stratification, nutrient supply, primary production, anthropogenic CO2-driven ocean acidification, deoxygenation and ocean circulation. Our simulation finds that the temperature-defined hotspots studied here will continue to experience warming but, with the exception of eastern Australia, may not remain the fastest warming ocean areas over the next century as the strongest warming is projected to occur in the subpolar and polar areas of the Northern Hemisphere. Additionally, we find that recent rapid change in SST is not necessarily an indicator that these areas are also hotspots of the other climatic stressors examined. However, a consistent facet of the hotspots studied here is that they are all strongly influenced by ocean circulation, which has already shown changes in the recent past and is projected to undergo further strong change into the future. In addition to the fast warming, change in local ocean circulation represents a distinct feature of present and future climate change impacting marine ecosystems in these areas.
- Full Text:
- Date Issued: 2016
- Authors: Popova, Ekaterina , Yool, Andrew , Byfield, Valborg , Cochrane, Kevern L , Coward, Andrew C , Salim, Shyam S , Gasalla, Maria A , Henson, S.A , Hobday, Alistair J , Pecl, Gretta T , Sauer, Warwick H H , Roberts, Michael J
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124514 , vital:35623 , https://doi.10.1111/gcb.13247
- Description: Ocean warming ‘hotspots’ are regions characterized by above-average temperature increases over recent years, for which there are significant consequences for both living marine resources and the societies that depend on them. As such, they represent early warning systems for understanding the impacts of marine climate change, and test-beds for developing adaptation options for coping with those impacts. Here, we examine five hotspots off the coasts of eastern Australia, South Africa, Madagascar, India and Brazil. These particular hotspots have underpinned a large international partnership that is working towards improving community adaptation by characterizing, assessing and projecting the likely future of coastal-marine food resources through the provision and sharing of knowledge. To inform this effort, we employ a high-resolution global ocean model forced by Representative Concentration Pathway 8.5 and simulated to year 2099. In addition to the sea surface temperature, we analyse projected stratification, nutrient supply, primary production, anthropogenic CO2-driven ocean acidification, deoxygenation and ocean circulation. Our simulation finds that the temperature-defined hotspots studied here will continue to experience warming but, with the exception of eastern Australia, may not remain the fastest warming ocean areas over the next century as the strongest warming is projected to occur in the subpolar and polar areas of the Northern Hemisphere. Additionally, we find that recent rapid change in SST is not necessarily an indicator that these areas are also hotspots of the other climatic stressors examined. However, a consistent facet of the hotspots studied here is that they are all strongly influenced by ocean circulation, which has already shown changes in the recent past and is projected to undergo further strong change into the future. In addition to the fast warming, change in local ocean circulation represents a distinct feature of present and future climate change impacting marine ecosystems in these areas.
- Full Text:
- Date Issued: 2016
Planning adaptation to climate change in fast-warming marine regions with seafood-dependent coastal communities
- Hobday, Alistair J, Cochrane, Kevern L, Howard, James, Aswani, Shankar, Byfield, Val, Duggan, Greg, Duna, Elethu, Dutra, Leo X C, Frusher, Stewart D, Fulton, Elizabeth A, Gammage, Louise, Gasalla, Maria A, Griffiths, Chevon, Guissamulo, Almeida, Haward, Marcus, Jarre, Astrid, Jennings, Sarah M, Jordan, Tia, Joyner, Jessica, Ramani, Narayana K, Shanmugasundaram, Swathi L P, Malherbe, Willem, Ortega-Cisneros, Kelly, Paytan, Adina, Pecl, Gretta T, Plagányi, Éva E, Popova, Ekaterina E, Razafindrainibe, Haja, Roberts, Michael J, Rohit, Prathiba, Sainulabdeen, Shyam S, Sauer, Warwick H H, Valappil, Sathianandan T, Zacharia, Paryiappanal U, Van Putten, E Ingrid
- Authors: Hobday, Alistair J , Cochrane, Kevern L , Howard, James , Aswani, Shankar , Byfield, Val , Duggan, Greg , Duna, Elethu , Dutra, Leo X C , Frusher, Stewart D , Fulton, Elizabeth A , Gammage, Louise , Gasalla, Maria A , Griffiths, Chevon , Guissamulo, Almeida , Haward, Marcus , Jarre, Astrid , Jennings, Sarah M , Jordan, Tia , Joyner, Jessica , Ramani, Narayana K , Shanmugasundaram, Swathi L P , Malherbe, Willem , Ortega-Cisneros, Kelly , Paytan, Adina , Pecl, Gretta T , Plagányi, Éva E , Popova, Ekaterina E , Razafindrainibe, Haja , Roberts, Michael J , Rohit, Prathiba , Sainulabdeen, Shyam S , Sauer, Warwick H H , Valappil, Sathianandan T , Zacharia, Paryiappanal U , Van Putten, E Ingrid
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125675 , vital:35806 , https://doi.10.1007/s11160-016-9419-0
- Description: Many coastal communities rely on living marine resources for livelihoods and food security. These resources are commonly under stress from overfishing, pollution, coastal development and habitat degradation. Climate change is an additional stressor beginning to impact coastal systems and communities, but may also lead to opportunities for some species and the people they sustain. We describe the research approach for a multi-country project, focused on the southern hemisphere, designed to contribute to improving fishing community adaptation efforts by characterizing, assessing and predicting the future of coastal-marine food resources, and codeveloping adaptation options through the provision and sharing of knowledge across fast-warming marine regions (i.e. marine ‘hotspots’). These hotspots represent natural laboratories for observing change and concomitant human adaptive responses, and for developing adaptation options and management strategies. Focusing on adaptation options and strategies for enhancing coastal resilience at the local level will contribute to capacity building and local empowerment in order to minimise negative outcomes and take advantage of opportunities arising from climate change. However, developing comparative approaches across regions that differ in political institutions, socio-economic community demographics, resource dependency and research capacity is challenging. Here, we describe physical, biological, social and governance tools to allow hotspot comparisons, and several methods to evaluate and enhance interactions within a multi-nation research team. Strong partnerships within and between the focal regions are critical to scientific and political support for development of effective approaches to reduce future vulnerability. Comparing these hotspot regions will enhance local adaptation responses and generate outcomes applicable to other regions.
- Full Text:
- Date Issued: 2016
- Authors: Hobday, Alistair J , Cochrane, Kevern L , Howard, James , Aswani, Shankar , Byfield, Val , Duggan, Greg , Duna, Elethu , Dutra, Leo X C , Frusher, Stewart D , Fulton, Elizabeth A , Gammage, Louise , Gasalla, Maria A , Griffiths, Chevon , Guissamulo, Almeida , Haward, Marcus , Jarre, Astrid , Jennings, Sarah M , Jordan, Tia , Joyner, Jessica , Ramani, Narayana K , Shanmugasundaram, Swathi L P , Malherbe, Willem , Ortega-Cisneros, Kelly , Paytan, Adina , Pecl, Gretta T , Plagányi, Éva E , Popova, Ekaterina E , Razafindrainibe, Haja , Roberts, Michael J , Rohit, Prathiba , Sainulabdeen, Shyam S , Sauer, Warwick H H , Valappil, Sathianandan T , Zacharia, Paryiappanal U , Van Putten, E Ingrid
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125675 , vital:35806 , https://doi.10.1007/s11160-016-9419-0
- Description: Many coastal communities rely on living marine resources for livelihoods and food security. These resources are commonly under stress from overfishing, pollution, coastal development and habitat degradation. Climate change is an additional stressor beginning to impact coastal systems and communities, but may also lead to opportunities for some species and the people they sustain. We describe the research approach for a multi-country project, focused on the southern hemisphere, designed to contribute to improving fishing community adaptation efforts by characterizing, assessing and predicting the future of coastal-marine food resources, and codeveloping adaptation options through the provision and sharing of knowledge across fast-warming marine regions (i.e. marine ‘hotspots’). These hotspots represent natural laboratories for observing change and concomitant human adaptive responses, and for developing adaptation options and management strategies. Focusing on adaptation options and strategies for enhancing coastal resilience at the local level will contribute to capacity building and local empowerment in order to minimise negative outcomes and take advantage of opportunities arising from climate change. However, developing comparative approaches across regions that differ in political institutions, socio-economic community demographics, resource dependency and research capacity is challenging. Here, we describe physical, biological, social and governance tools to allow hotspot comparisons, and several methods to evaluate and enhance interactions within a multi-nation research team. Strong partnerships within and between the focal regions are critical to scientific and political support for development of effective approaches to reduce future vulnerability. Comparing these hotspot regions will enhance local adaptation responses and generate outcomes applicable to other regions.
- Full Text:
- Date Issued: 2016
Lipophilic M(α,α′-OC5H11)8phthalocyanines (M = H2 and Ni(II)): synthesis, electronic structure, and their utility for highly efficient carbonyl reductions
- Jiang, Yu, Li, Minzhi, Liang, Xu, Mack, John, Wildervanck, Martijn, Nyokong, Tebello, Qin, Mingfeng, Zhu, Weihua
- Authors: Jiang, Yu , Li, Minzhi , Liang, Xu , Mack, John , Wildervanck, Martijn , Nyokong, Tebello , Qin, Mingfeng , Zhu, Weihua
- Date: 2015-10-07
- Subjects: Dalton Transactions (2015), 44, 18237-18246, doi:10.1039/c5dt03256c
- Language: English
- Type: Article
- Identifier: vital:7282 , http://hdl.handle.net/10962/d1020322
- Description: A lipophilic and electron-rich phthalocyanine (α,α′-n-OC5H11)8-H2Pc and its nickel(II) complex (α,α′-n-OC5H11)8-Ni(II)Pc have been synthesized and characterized. Detailed analyses of the electronic structure were carried out by spectroscopy, electrochemistry, spectroelectrochemistry, and TD-DFT calculations. A series of experiments demonstrate that the (α,α′-n-OC5H11)8-Ni(II)Pc complex can be used as a catalyst for highly efficient carbonyl reductions. , Original publication is available at http://dx.doi.org/10.1039/C5DT03256C
- Full Text:
- Authors: Jiang, Yu , Li, Minzhi , Liang, Xu , Mack, John , Wildervanck, Martijn , Nyokong, Tebello , Qin, Mingfeng , Zhu, Weihua
- Date: 2015-10-07
- Subjects: Dalton Transactions (2015), 44, 18237-18246, doi:10.1039/c5dt03256c
- Language: English
- Type: Article
- Identifier: vital:7282 , http://hdl.handle.net/10962/d1020322
- Description: A lipophilic and electron-rich phthalocyanine (α,α′-n-OC5H11)8-H2Pc and its nickel(II) complex (α,α′-n-OC5H11)8-Ni(II)Pc have been synthesized and characterized. Detailed analyses of the electronic structure were carried out by spectroscopy, electrochemistry, spectroelectrochemistry, and TD-DFT calculations. A series of experiments demonstrate that the (α,α′-n-OC5H11)8-Ni(II)Pc complex can be used as a catalyst for highly efficient carbonyl reductions. , Original publication is available at http://dx.doi.org/10.1039/C5DT03256C
- Full Text:
Use of microbial fuel cells in the beneficiation of algal biomass for bioelectricity production
- Mtambanengwe, Kudzai Tapiwanashe Esau
- Authors: Mtambanengwe, Kudzai Tapiwanashe Esau
- Date: 2015-04-10
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/480334 , vital:78432
- Description: Microbial fuel cells (MFCs) offer an alternative technology that is able to convert organic matter into electrical energy by making use of bacterial biomass as the biocatalysts. Performance of the MFCs is dependent on many factors such as substrate, biocatalyst, electrode material and optimum operational conditions including temperature and pH. Significant research has been conducted on the use of different substrates to fuel the MFC. The possibility of harvesting energy from organic waste sources in the MFC makes the technology attractive. In this study, we have investigated the use of Chlorella, Arthrospira and a mixed algal consortium obtained from the local wastewater treatment facility in Grahamstown, courtesy of the Institute for Environmental Biotechnology, Rhodes University (EBRU) as feedstock in an MFC with Enterobacter cloacae as the biocatalyst. Pre-treatment of the algae-based feedstock was studied as well as the influence of treatment on nutrient release and biocatalyst performance during growth studies and MFC operations. Sonication, autoclaving and a combination of the two were used as the pre-treatment methods. Pre-treatment resulted in the release of nutrients from algal cells to the media. Peak nutrient realease was observed when a combination of sonicating and autoclaving was employed. Sonicating and autoclaving the mixed consortium from EBRU resulted in an MFC peak power density of 101.2 (± 4.58) mW.m-2. This represented more than 80% of the peak power density obtained in RCM medium. Operational conditions during MFC studies such as pH, temperature, nutrient utilisation by the biocatalyst and performance of the proton exchange membrane were measured during the course of the study. Growth kinetics and MFC operations were shown to be optimal when the substrate feedstock was acidic. However, for longer MFC operations (120 hours), total power output was greater by 3 to 5 fold when the feedstock was at acidic pH (4-6) than when the pH of the substrate feedstock was alkaline (8 and 9). Further MFC studies were performed on the effect of electrode materials including activated carbon fibre and carbon paper. The study examined also the use of live Chlorella and Arthrospira cultures as biocathodes in an MFC. We also showed that activated carbon fibre performs well as an electrode catalyst for both anode and cathode without any need of modification. Biocathode studies showed that the main limiting factor to biocathodes performance was light irradiance. , Thesis (MSc) -- Faculty of Science, Biotechnology Innovation Centre, 2015
- Full Text:
- Date Issued: 2015-04-10
- Authors: Mtambanengwe, Kudzai Tapiwanashe Esau
- Date: 2015-04-10
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/480334 , vital:78432
- Description: Microbial fuel cells (MFCs) offer an alternative technology that is able to convert organic matter into electrical energy by making use of bacterial biomass as the biocatalysts. Performance of the MFCs is dependent on many factors such as substrate, biocatalyst, electrode material and optimum operational conditions including temperature and pH. Significant research has been conducted on the use of different substrates to fuel the MFC. The possibility of harvesting energy from organic waste sources in the MFC makes the technology attractive. In this study, we have investigated the use of Chlorella, Arthrospira and a mixed algal consortium obtained from the local wastewater treatment facility in Grahamstown, courtesy of the Institute for Environmental Biotechnology, Rhodes University (EBRU) as feedstock in an MFC with Enterobacter cloacae as the biocatalyst. Pre-treatment of the algae-based feedstock was studied as well as the influence of treatment on nutrient release and biocatalyst performance during growth studies and MFC operations. Sonication, autoclaving and a combination of the two were used as the pre-treatment methods. Pre-treatment resulted in the release of nutrients from algal cells to the media. Peak nutrient realease was observed when a combination of sonicating and autoclaving was employed. Sonicating and autoclaving the mixed consortium from EBRU resulted in an MFC peak power density of 101.2 (± 4.58) mW.m-2. This represented more than 80% of the peak power density obtained in RCM medium. Operational conditions during MFC studies such as pH, temperature, nutrient utilisation by the biocatalyst and performance of the proton exchange membrane were measured during the course of the study. Growth kinetics and MFC operations were shown to be optimal when the substrate feedstock was acidic. However, for longer MFC operations (120 hours), total power output was greater by 3 to 5 fold when the feedstock was at acidic pH (4-6) than when the pH of the substrate feedstock was alkaline (8 and 9). Further MFC studies were performed on the effect of electrode materials including activated carbon fibre and carbon paper. The study examined also the use of live Chlorella and Arthrospira cultures as biocathodes in an MFC. We also showed that activated carbon fibre performs well as an electrode catalyst for both anode and cathode without any need of modification. Biocathode studies showed that the main limiting factor to biocathodes performance was light irradiance. , Thesis (MSc) -- Faculty of Science, Biotechnology Innovation Centre, 2015
- Full Text:
- Date Issued: 2015-04-10
"I want to kill myself!": identity documents and mental health in the South African Daily Sun tabloid
- Authors: Boshoff, Priscilla A
- Date: 2015
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/143549 , vital:38256 , ISBN , https://ischp.files.wordpress.com/2015/08/ischp_2015_abstract_booklet.pdf
- Description: An Identity Document (ID) is needed by South Africans to study, apply for a pension or get married. However, Home Affairs, the state department responsible for issuing them, is poorly managed. The popular Daily Sun tabloid newspaper mediates for its five million working class readers the frustration caused by this incompetency in its “Horror Affairs” column. Readers tell their stories about (not) getting their IDs, stories often of suicide, depression and “giving up” on life. Using a Lacanian frame, and through a close reading of “Horror Affairs” texts, I argue that this tabloid plays a therapeutic role for its socially marginalised readers by mediating the “invisibility” engendered by the modernising state and its administrative technologies. Given the concern about high rates of mental health illness in South Africa, the research also demonstrates how popular culture forms can alert health care practitioners to issues which may otherwise go unnoticed.
- Full Text:
- Date Issued: 2015
- Authors: Boshoff, Priscilla A
- Date: 2015
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/143549 , vital:38256 , ISBN , https://ischp.files.wordpress.com/2015/08/ischp_2015_abstract_booklet.pdf
- Description: An Identity Document (ID) is needed by South Africans to study, apply for a pension or get married. However, Home Affairs, the state department responsible for issuing them, is poorly managed. The popular Daily Sun tabloid newspaper mediates for its five million working class readers the frustration caused by this incompetency in its “Horror Affairs” column. Readers tell their stories about (not) getting their IDs, stories often of suicide, depression and “giving up” on life. Using a Lacanian frame, and through a close reading of “Horror Affairs” texts, I argue that this tabloid plays a therapeutic role for its socially marginalised readers by mediating the “invisibility” engendered by the modernising state and its administrative technologies. Given the concern about high rates of mental health illness in South Africa, the research also demonstrates how popular culture forms can alert health care practitioners to issues which may otherwise go unnoticed.
- Full Text:
- Date Issued: 2015
"I've always known this place, familiar as a room in our house" : engaging with memory, loss and nostalgia through sculpture
- Authors: Reed, Kesayne
- Date: 2015
- Subjects: Memory in art , Loss (Psychology) in art , Nostalgia in art , Sculpture -- Themes, motives , Art therapy , Sculpture -- Exhibitions
- Language: English
- Type: Thesis , Masters , MFA
- Identifier: vital:2513 , http://hdl.handle.net/10962/d1020022
- Description: My exhibition draws on Andreas Huyssen's notion of memory sculpture to articulate my own sense of loss and trauma, due to the divorce of my parents. Within my work I explore the effects that divorce had on me and how it has disturbed my normative understanding of home and family. I have created scenarios alluding to the family home that I have manipulated in order to convey a sense of nostalgia and loss. By growing salt crystals over found objects and/or cladding them in salt, I attempt to suggest the dual motifs of preservation (a nostalgic clinging to the past) and destruction (due to the salt’s corrosive properties). In this way, the salt-crusted objects serve as a metaphor for a memory that has become stagnant, and is both destructive and regressive. The objects encapsulate the mind’s coping methods to loss. In my mini thesis, I discuss characteristics of memory sculpture as a response to trauma, drawing on Sigmund Freud's differentiation between mourning and melancholia. I also unpack how objects and traces (such as photographs) may act as nostalgic triggers, inducing a state of melancholic attachment to an idealised past. I address these concerns in relation to selected works by Doris Salcedo and Bridget Baker, and also situate them in relation to my own art practice.
- Full Text:
- Date Issued: 2015
- Authors: Reed, Kesayne
- Date: 2015
- Subjects: Memory in art , Loss (Psychology) in art , Nostalgia in art , Sculpture -- Themes, motives , Art therapy , Sculpture -- Exhibitions
- Language: English
- Type: Thesis , Masters , MFA
- Identifier: vital:2513 , http://hdl.handle.net/10962/d1020022
- Description: My exhibition draws on Andreas Huyssen's notion of memory sculpture to articulate my own sense of loss and trauma, due to the divorce of my parents. Within my work I explore the effects that divorce had on me and how it has disturbed my normative understanding of home and family. I have created scenarios alluding to the family home that I have manipulated in order to convey a sense of nostalgia and loss. By growing salt crystals over found objects and/or cladding them in salt, I attempt to suggest the dual motifs of preservation (a nostalgic clinging to the past) and destruction (due to the salt’s corrosive properties). In this way, the salt-crusted objects serve as a metaphor for a memory that has become stagnant, and is both destructive and regressive. The objects encapsulate the mind’s coping methods to loss. In my mini thesis, I discuss characteristics of memory sculpture as a response to trauma, drawing on Sigmund Freud's differentiation between mourning and melancholia. I also unpack how objects and traces (such as photographs) may act as nostalgic triggers, inducing a state of melancholic attachment to an idealised past. I address these concerns in relation to selected works by Doris Salcedo and Bridget Baker, and also situate them in relation to my own art practice.
- Full Text:
- Date Issued: 2015
"Soap operas as a platform for disseminating health information regarding ART and the use of 'reel' versus 'real' role models"
- Authors: Deiner, Catherine Anne
- Date: 2015
- Subjects: Isidingo (Television program) , Television soap operas -- South Africa , Health in mass media , Mass media in health education -- South Africa , Antiretroviral agents -- South Africa , Public health -- Moral and ethical aspects , HIV-positive women -- South Africa -- Grahamstown
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3542 , http://hdl.handle.net/10962/d1017783
- Description: The media, through development communication and edutainment, plays a critical role in the transformation of societies. In line with this, this thesis discusses the extent to which commercially driven prosocial soap operas can provide a platform for public health messaging, in the context of the HIV/AIDS epidemic in South Africa, for antiretroviral treatment (ART) and for encouraging ART adherence to foster national development. Furthermore, this thesis examined the potential of celebrities as HIV/AIDS ambassadors and the potential of both fictional characters and ‘real-life’ celebrities to disseminate these health messages. Although the HIV/AIDS epidemic in South Africa is stabilising, this is not the time to relax the communication around the disease, particularly regarding adherence to ARVs, considering that South Africa has the largest ARV rollout in the world. The qualitative methodological approach taken for this thesis is a three-step approach examining the intended message, the text and the appropriated message by viewers. Firstly, a thematic content analysis of an episode of Isidingo, that illustrated Nandipha as HIV-positive and the side-effects that came with her ART adherence, and the 3Talk interview with Lesego Motsepe, where she announced that she was weaning herself off ART, was done in order to understand the intended health messaging in the soap opera and the health message disseminated by an HIV-positive actress with regards to ART. Thereafter interview responses by the production team as well as by HIV-positive viewers, using ARVs, were thematised. In addition media texts which provided commentary on the use of a celebrity as a HIV-positive role model were examined. In doing this, this thesis has offered up the meanings of how HIV-positive women taking ARVs and living in Makana experience and understand the media, particularly health messaging relating to ARVs. The findings of this study suggest that commercial soap operas are the perfect platform to address HIV/AIDS and that prosocial health messaging regarding ARV adherence is still necessary in this country. Soap operas have the potential to have an educational angle. Although, HIV-positive individuals serve as better role models as they are authentic; given human nature, fictional characters, such as Nandipha Matabane in Isidingo, may be more sustainable role models as their message can be scientifically-based and well-researched. Realistic characters serve as role models whose behaviour is to be emulated. Soap operas appeal to a wide audience and so storylines can be tailor-made according to the times and the needs in terms of health issues and messaging. Thus, soap operas are not a single platform but rather one which can be exploited to maximum advantage for public health messaging.
- Full Text:
- Date Issued: 2015
- Authors: Deiner, Catherine Anne
- Date: 2015
- Subjects: Isidingo (Television program) , Television soap operas -- South Africa , Health in mass media , Mass media in health education -- South Africa , Antiretroviral agents -- South Africa , Public health -- Moral and ethical aspects , HIV-positive women -- South Africa -- Grahamstown
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3542 , http://hdl.handle.net/10962/d1017783
- Description: The media, through development communication and edutainment, plays a critical role in the transformation of societies. In line with this, this thesis discusses the extent to which commercially driven prosocial soap operas can provide a platform for public health messaging, in the context of the HIV/AIDS epidemic in South Africa, for antiretroviral treatment (ART) and for encouraging ART adherence to foster national development. Furthermore, this thesis examined the potential of celebrities as HIV/AIDS ambassadors and the potential of both fictional characters and ‘real-life’ celebrities to disseminate these health messages. Although the HIV/AIDS epidemic in South Africa is stabilising, this is not the time to relax the communication around the disease, particularly regarding adherence to ARVs, considering that South Africa has the largest ARV rollout in the world. The qualitative methodological approach taken for this thesis is a three-step approach examining the intended message, the text and the appropriated message by viewers. Firstly, a thematic content analysis of an episode of Isidingo, that illustrated Nandipha as HIV-positive and the side-effects that came with her ART adherence, and the 3Talk interview with Lesego Motsepe, where she announced that she was weaning herself off ART, was done in order to understand the intended health messaging in the soap opera and the health message disseminated by an HIV-positive actress with regards to ART. Thereafter interview responses by the production team as well as by HIV-positive viewers, using ARVs, were thematised. In addition media texts which provided commentary on the use of a celebrity as a HIV-positive role model were examined. In doing this, this thesis has offered up the meanings of how HIV-positive women taking ARVs and living in Makana experience and understand the media, particularly health messaging relating to ARVs. The findings of this study suggest that commercial soap operas are the perfect platform to address HIV/AIDS and that prosocial health messaging regarding ARV adherence is still necessary in this country. Soap operas have the potential to have an educational angle. Although, HIV-positive individuals serve as better role models as they are authentic; given human nature, fictional characters, such as Nandipha Matabane in Isidingo, may be more sustainable role models as their message can be scientifically-based and well-researched. Realistic characters serve as role models whose behaviour is to be emulated. Soap operas appeal to a wide audience and so storylines can be tailor-made according to the times and the needs in terms of health issues and messaging. Thus, soap operas are not a single platform but rather one which can be exploited to maximum advantage for public health messaging.
- Full Text:
- Date Issued: 2015
"Soliloquy: the untold story of Sleeping Beauty's dreams"; a re-vision of Charles Perrault's "The sleeping beauty in the woods."
- Authors: Ledwick, Lisa-Mari
- Date: 2015
- Subjects: Perrault, Charles, 1628-1703 , Symbolism in fairy tales , Sleeping Beauty (Tale) in literature
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: http://hdl.handle.net/10948/3155 , vital:20405
- Description: Taken as a whole, the purpose of the practical and theoretical components of this research aims to contextualise and present a contemporary fairy tale heroine who recuperates and re-values traditional aspects of femininity within a feminist context.
- Full Text:
- Date Issued: 2015
- Authors: Ledwick, Lisa-Mari
- Date: 2015
- Subjects: Perrault, Charles, 1628-1703 , Symbolism in fairy tales , Sleeping Beauty (Tale) in literature
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: http://hdl.handle.net/10948/3155 , vital:20405
- Description: Taken as a whole, the purpose of the practical and theoretical components of this research aims to contextualise and present a contemporary fairy tale heroine who recuperates and re-values traditional aspects of femininity within a feminist context.
- Full Text:
- Date Issued: 2015
"Why Persephone?" investigating the unique position of Persephone as a dying god(dess) offering hope for the afterlife
- Authors: Goodwin, Grant
- Date: 2015
- Subjects: Mythology, Greek , Gods, Greek , Future life , Greece -- Religious life and customs , Persephone -- (Greek deity)
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3655 , http://hdl.handle.net/10962/d1017896
- Description: Persephone’s myth is unique, as it was the central narrative of one of the most prominent ancient mystery religions, and remains one of the few (certainly the most prominent) ancient Greek myths to focus on the relationship of a mother and her daughter. This unique focus must have offered her worshippers something important that they perhaps could not find elsewhere, especially as a complex and elaborate cult grew around it, transforming the divine allegory of the changing seasons or the storage of the grain beneath the earth, into a narrative offering hope for a better place in the afterlife. To understand the appeal of this myth, two aspects of her worship and mythic significance require study: the expectations of her worshippers for their own lives, to which the goddess may have been seen as a forerunner; and the mythic frameworks operating which would characterise the goddess for her worshippers. The myth, as described in The Hymn to Demeter, is initially interpreted for its literary meaning, and then set within its cultural milieu to uncover what meaning it may have had for Persephone’s worshippers, particularly in terms of marriage and death, which form the initial motivating action of the myth. From this socio-anthropological study we turn to the mythic patterns and motifs the story offers, particularly the figure of the goddess of the Underworld (primarily in the influential Mesopotamian literature), and the Dying-Rising God figure (similarly derived from the Near East). These figures, when compared to the Greek goddess, may both reveal her unique appeal, and highlight the common attractions that lie in the figures generally. By this two-part investigation, on the particular culture’s expectations and the general mythic framework she exists in, Persephone’s meaning in her native land may be uncovered and understood.
- Full Text:
- Date Issued: 2015
- Authors: Goodwin, Grant
- Date: 2015
- Subjects: Mythology, Greek , Gods, Greek , Future life , Greece -- Religious life and customs , Persephone -- (Greek deity)
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3655 , http://hdl.handle.net/10962/d1017896
- Description: Persephone’s myth is unique, as it was the central narrative of one of the most prominent ancient mystery religions, and remains one of the few (certainly the most prominent) ancient Greek myths to focus on the relationship of a mother and her daughter. This unique focus must have offered her worshippers something important that they perhaps could not find elsewhere, especially as a complex and elaborate cult grew around it, transforming the divine allegory of the changing seasons or the storage of the grain beneath the earth, into a narrative offering hope for a better place in the afterlife. To understand the appeal of this myth, two aspects of her worship and mythic significance require study: the expectations of her worshippers for their own lives, to which the goddess may have been seen as a forerunner; and the mythic frameworks operating which would characterise the goddess for her worshippers. The myth, as described in The Hymn to Demeter, is initially interpreted for its literary meaning, and then set within its cultural milieu to uncover what meaning it may have had for Persephone’s worshippers, particularly in terms of marriage and death, which form the initial motivating action of the myth. From this socio-anthropological study we turn to the mythic patterns and motifs the story offers, particularly the figure of the goddess of the Underworld (primarily in the influential Mesopotamian literature), and the Dying-Rising God figure (similarly derived from the Near East). These figures, when compared to the Greek goddess, may both reveal her unique appeal, and highlight the common attractions that lie in the figures generally. By this two-part investigation, on the particular culture’s expectations and the general mythic framework she exists in, Persephone’s meaning in her native land may be uncovered and understood.
- Full Text:
- Date Issued: 2015
'Becoming animal': motifs of hybridity and liminality in fairy tales and selected contemporary artworks
- Authors: Wasserman, Minke
- Date: 2015
- Subjects: Fairy tales -- History and criticism , Liminality in literature , Cultural fusion in literature , Cultural fusion and the arts , Art, Modern -- 21st century -- Themes, motives , Art, Modern -- 21st century -- Exhibitions , Human-animal relationships in art , Human-animal relationships in literature
- Language: English
- Type: Thesis , Masters , MFA
- Identifier: vital:2512 , http://hdl.handle.net/10962/d1019759
- Description: ‘Becoming Animal’: Motifs of Hybridity and Liminality in Fairy Tales and Selected Contemporary Artworks serves as a theoretical examination of the concept of the hybrid. My research unpacks the liminal aspect of hybridity, locating the hybrid in the imaginative world of popular fairy tales, folk lore and mythology. In my accompanying MFA exhibition, Becoming(s), I explore these motifs through an installation of mixed-media sculptures which are based on the hybrid creatures that populated the fantasy world of my childhood. The written component of my MFA submission will relate directly to my professional art practise, developing it further and situating it within a relevant context. In my mini-thesis I will consider the liminal in relation to the ‘animal turn’ in contemporary art, with a particular focus on relevant artists working with the motifs of hybridity, such as Nandipha Mntambo, Jane Alexander and Kiki Smith. The ‘animal turn’ is a term used by Kari Weil (2010: 3) to describe a contemporary interest in issues of the nonhuman, and in the ways that the relationship between humans and nonhumans is marked by “difference, otherness and power”. Of key concern to my research will be Giles Deleuze and Felix Guattari’s concept of ‘becoming animal’. Rather than describing a transition from one stable state to another, ‘becoming animal’ suggests a radical dissolution of boundaries – not just between species (such as ‘human’ and ‘animal’) but between any essentialising binaries. As such, ‘becoming animal’ suggests a conception of identity as being fluid and mutable, rather than stable and fixed.
- Full Text:
- Date Issued: 2015
- Authors: Wasserman, Minke
- Date: 2015
- Subjects: Fairy tales -- History and criticism , Liminality in literature , Cultural fusion in literature , Cultural fusion and the arts , Art, Modern -- 21st century -- Themes, motives , Art, Modern -- 21st century -- Exhibitions , Human-animal relationships in art , Human-animal relationships in literature
- Language: English
- Type: Thesis , Masters , MFA
- Identifier: vital:2512 , http://hdl.handle.net/10962/d1019759
- Description: ‘Becoming Animal’: Motifs of Hybridity and Liminality in Fairy Tales and Selected Contemporary Artworks serves as a theoretical examination of the concept of the hybrid. My research unpacks the liminal aspect of hybridity, locating the hybrid in the imaginative world of popular fairy tales, folk lore and mythology. In my accompanying MFA exhibition, Becoming(s), I explore these motifs through an installation of mixed-media sculptures which are based on the hybrid creatures that populated the fantasy world of my childhood. The written component of my MFA submission will relate directly to my professional art practise, developing it further and situating it within a relevant context. In my mini-thesis I will consider the liminal in relation to the ‘animal turn’ in contemporary art, with a particular focus on relevant artists working with the motifs of hybridity, such as Nandipha Mntambo, Jane Alexander and Kiki Smith. The ‘animal turn’ is a term used by Kari Weil (2010: 3) to describe a contemporary interest in issues of the nonhuman, and in the ways that the relationship between humans and nonhumans is marked by “difference, otherness and power”. Of key concern to my research will be Giles Deleuze and Felix Guattari’s concept of ‘becoming animal’. Rather than describing a transition from one stable state to another, ‘becoming animal’ suggests a radical dissolution of boundaries – not just between species (such as ‘human’ and ‘animal’) but between any essentialising binaries. As such, ‘becoming animal’ suggests a conception of identity as being fluid and mutable, rather than stable and fixed.
- Full Text:
- Date Issued: 2015
(Ferrocenylpyrazolyl) zinc (II) benzoates as catalysts for the ring opening polymerization of ε-caprolactone
- Obuah, Collins, Lochee, Yemanlall, Jordaan, Johan H L, Otto, Daniel P, Nyokong, Tebello, Darkwa, James
- Authors: Obuah, Collins , Lochee, Yemanlall , Jordaan, Johan H L , Otto, Daniel P , Nyokong, Tebello , Darkwa, James
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189515 , vital:44853 , xlink:href="https://doi.org/10.1016/j.poly.2015.02.007"
- Description: The reaction of Zn(OAc)2 and C6H5COOH or 3,5-NO2-C6H3COOH with 3-ferrocenylpyrazolyl-methylenepyridine (L1), 3-ferrocenyl-5-methylpyrazolyl-methylenepyridine (L2), 3-ferrocenylpyrazolyl-ethylamine (L3) and 3-ferrocenyl-5-pyrazolyl-ethylamine (L4) afford the corresponding complexes [Zn(C6H5COO)2(L1)] (1), [Zn(C6H5COO)2(L2)] (2), [Zn(3,5-NO2-C6H3COO)2(L1)] (3), [Zn(3,5-NO2-C6H3 COO)2(L2)] (4), [Zn(C6H5COO)2(L3)] (5), [Zn(C6H5COO)2(L4)] (6), [Zn(3,5-NO2-C6H3COO)2(L3)] (7) and [Zn(3,5-NO2-C6H3COO)2(L4)] (8). These complexes behave as catalysts for the ring opening polymerization of e-caprolactone to produce polymers with molecular weight that range from 1480 to 7080 g mol1 and exhibited moderate to broad PDIs. Evidence of these complexes acting as catalysts was obtained from both the polymerization data and kinetic studies. The polymerization data show that variation of the [CL]/[C] from 100 to 800 produced PCL with relatively the same molecular weight indicative of a catalyst behavior. The appearance of induction period in kinetic plots strengthens the fact that these complexes are catalysts rather than initiators. MALDI-TOF MS and 1 H NMR data show di-hydroxy end groups, which support the coordination mechanism rather than insertion mechanism. To understand the broad PDIs obtained for some of the polymer, the electronic properties of the zinc complexes were investigated using cyclic voltammetry. The results show that the zinc complexes containing amine based ligands are highly electrophilic therefore making them unstable, hence the broad PDIs observed for zinc complexes containing amine based ligands. Among the eight complexes investigated, complex 7 is the most active catalyst with kp value of 1.18 107 h1 mol1 at 110 C.
- Full Text:
- Date Issued: 2015
- Authors: Obuah, Collins , Lochee, Yemanlall , Jordaan, Johan H L , Otto, Daniel P , Nyokong, Tebello , Darkwa, James
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189515 , vital:44853 , xlink:href="https://doi.org/10.1016/j.poly.2015.02.007"
- Description: The reaction of Zn(OAc)2 and C6H5COOH or 3,5-NO2-C6H3COOH with 3-ferrocenylpyrazolyl-methylenepyridine (L1), 3-ferrocenyl-5-methylpyrazolyl-methylenepyridine (L2), 3-ferrocenylpyrazolyl-ethylamine (L3) and 3-ferrocenyl-5-pyrazolyl-ethylamine (L4) afford the corresponding complexes [Zn(C6H5COO)2(L1)] (1), [Zn(C6H5COO)2(L2)] (2), [Zn(3,5-NO2-C6H3COO)2(L1)] (3), [Zn(3,5-NO2-C6H3 COO)2(L2)] (4), [Zn(C6H5COO)2(L3)] (5), [Zn(C6H5COO)2(L4)] (6), [Zn(3,5-NO2-C6H3COO)2(L3)] (7) and [Zn(3,5-NO2-C6H3COO)2(L4)] (8). These complexes behave as catalysts for the ring opening polymerization of e-caprolactone to produce polymers with molecular weight that range from 1480 to 7080 g mol1 and exhibited moderate to broad PDIs. Evidence of these complexes acting as catalysts was obtained from both the polymerization data and kinetic studies. The polymerization data show that variation of the [CL]/[C] from 100 to 800 produced PCL with relatively the same molecular weight indicative of a catalyst behavior. The appearance of induction period in kinetic plots strengthens the fact that these complexes are catalysts rather than initiators. MALDI-TOF MS and 1 H NMR data show di-hydroxy end groups, which support the coordination mechanism rather than insertion mechanism. To understand the broad PDIs obtained for some of the polymer, the electronic properties of the zinc complexes were investigated using cyclic voltammetry. The results show that the zinc complexes containing amine based ligands are highly electrophilic therefore making them unstable, hence the broad PDIs observed for zinc complexes containing amine based ligands. Among the eight complexes investigated, complex 7 is the most active catalyst with kp value of 1.18 107 h1 mol1 at 110 C.
- Full Text:
- Date Issued: 2015
(Un)stable architecture as deconstructed meaning
- Authors: Lombard, Lindi
- Date: 2015
- Subjects: Art and architecture , Architecture in art , Proportion (Art) , Vertigo in art , Deconstructivism (Architecture)
- Language: English
- Type: Thesis , Masters , MFA
- Identifier: http://hdl.handle.net/10962/5825 , vital:20980
- Description: How often do we notice the buildings that we work in, play in and live in? The architecture that we construct is specially geared to our human proportions, and shelters and accommodates us. It can be seen as a metaphor for the body, the self, and systems of social control that we have created. When the structure of this architecture is compromised, either literally or metaphorically, we experience instability and vertigo. My practical submission, Vertigo is concerned with architecture, perspective, deconstruction, instability, vertigo, scale and the body. Vertigo consists of paintings, ranging in scale from the size of a brick to the height of a single storey house. Utilizing a highly representational style as well as working with abstract sign systems and technical plan drawings, I destabilize firstly, our sense of certainty in the architecture that surrounds us, and secondly, prompts us to question the assumed fixity of ourselves and our social systems, through the convergence and collision of architecture and painting. This supporting document, (Un)stable Architecture as Deconstructed Meaning, considers the key conceptual concerns informing my practical submission. In chapter one of this mini-thesis: Deconstructivist Architecture, Instability and Impermanence I look at Deconstructivist Architecture which challenges traditional values of order, stability, harmony and unity of architecture. I position my work in relation to architecture projects on the Deconstructivist Architecture show in relation to their intent of undoing, shifting and destabilizing structure and what architecture is traditionally valued for. I also look at the shifting meaning and symbolism of architecture and skyscrapers. In the second chapter: Vertiginous Point of View and Shifted Perspectives I engage with vertigo, perspective, scale and the bodily analogy in architecture. I look at how Julie Mehretu destabilises built space and architecture in a painterly way, depicting multiple perspectives which are subjected to multiple interpretations. In chapter Three: Painting a Building and Building a Painting: Process, Scale and the Body, I discuss and engage with my practical submission, Vertigo, in relation to my process, scale, the body, vertigo, deconstruction, instability and perspective.
- Full Text:
- Date Issued: 2015
- Authors: Lombard, Lindi
- Date: 2015
- Subjects: Art and architecture , Architecture in art , Proportion (Art) , Vertigo in art , Deconstructivism (Architecture)
- Language: English
- Type: Thesis , Masters , MFA
- Identifier: http://hdl.handle.net/10962/5825 , vital:20980
- Description: How often do we notice the buildings that we work in, play in and live in? The architecture that we construct is specially geared to our human proportions, and shelters and accommodates us. It can be seen as a metaphor for the body, the self, and systems of social control that we have created. When the structure of this architecture is compromised, either literally or metaphorically, we experience instability and vertigo. My practical submission, Vertigo is concerned with architecture, perspective, deconstruction, instability, vertigo, scale and the body. Vertigo consists of paintings, ranging in scale from the size of a brick to the height of a single storey house. Utilizing a highly representational style as well as working with abstract sign systems and technical plan drawings, I destabilize firstly, our sense of certainty in the architecture that surrounds us, and secondly, prompts us to question the assumed fixity of ourselves and our social systems, through the convergence and collision of architecture and painting. This supporting document, (Un)stable Architecture as Deconstructed Meaning, considers the key conceptual concerns informing my practical submission. In chapter one of this mini-thesis: Deconstructivist Architecture, Instability and Impermanence I look at Deconstructivist Architecture which challenges traditional values of order, stability, harmony and unity of architecture. I position my work in relation to architecture projects on the Deconstructivist Architecture show in relation to their intent of undoing, shifting and destabilizing structure and what architecture is traditionally valued for. I also look at the shifting meaning and symbolism of architecture and skyscrapers. In the second chapter: Vertiginous Point of View and Shifted Perspectives I engage with vertigo, perspective, scale and the bodily analogy in architecture. I look at how Julie Mehretu destabilises built space and architecture in a painterly way, depicting multiple perspectives which are subjected to multiple interpretations. In chapter Three: Painting a Building and Building a Painting: Process, Scale and the Body, I discuss and engage with my practical submission, Vertigo, in relation to my process, scale, the body, vertigo, deconstruction, instability and perspective.
- Full Text:
- Date Issued: 2015
A best practice guideline for evidence based teaching strategies for nurse educators
- Authors: Breytenbach, Cecile
- Date: 2015
- Subjects: Nursing -- Study and teaching -- Great Britain , Nurse educators , Evidence-based nursing
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/4831 , vital:20699
- Description: Evidence based practice (EBP) is a worldwide phenomena defined as the “conscientious explicit and judicious use of current best evidence in making decisions about the patient’s care”. The evidence based practice concept’s aim is to effectively guide health care professionals to build knowledge that will be supported by evidence. Evidence based practice must be supported by evidence based teaching. Nurse educators must be up to date with evidence based teaching as well as the latest evidence based teaching strategies, in order to teach the new millennial nursing students and for the new qualifications structure. Teaching the concept of evidence based practice by implementing evidence based teaching to nursing students will enable them to transform the future of healthcare by delivering high quality care practice. A paucity of evidence is available on evidence based teaching and teaching strategies in the South African context. Therefore the researcher used a systematic review methodology to explore and describe the best available evidence based teaching strategies and to develop a guideline on evidence based teaching strategies for nurse educators. The data bases searched included: MEDLINE, CINAHL, PubMed and Google Scholar. Manual searches were done and completed with the assistance of librarians. A total number of n=50 studies were identified as potentially relevant to the study. The number or articles included for critical appraisal were 20. On completion of the critical appraisal n=17 articles were identified for the review. The included studies for the review were n=7 Level 1, systematic reviews and n=10 Level 2, quasi-experimental studies. Three studies were excluded after critical appraisal from two reviewers, appraisal was done independently, and consensuses were reached between the two reviewers. The Joanna Briggs Institutes critical appraisal and data extraction instruments were used for the study. The descriptive data synthesis was done of the included studies as well as a comparison of teaching strategies to determine which one to better than the other one. Although n = 4 of the teaching strategies (concept mapping, internet-based learning, evidence based interactive strategy and cultural competence) significantly increased knowledge, the overall results found that a variety of teaching strategies to be implemented to increase the knowledge outcomes of the nursing students. The different teaching strategies found were: e-learning, concept mapping, internet-based learning, web-based learning, gaming, problem-based learning, and case studies, evidence based learning and cultural competence. However, more research is needed to investigate the best use of the different teaching strategies and compare the impact of a variety of teaching strategies on increasing knowledge of the nursing student.
- Full Text:
- Date Issued: 2015
- Authors: Breytenbach, Cecile
- Date: 2015
- Subjects: Nursing -- Study and teaching -- Great Britain , Nurse educators , Evidence-based nursing
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/4831 , vital:20699
- Description: Evidence based practice (EBP) is a worldwide phenomena defined as the “conscientious explicit and judicious use of current best evidence in making decisions about the patient’s care”. The evidence based practice concept’s aim is to effectively guide health care professionals to build knowledge that will be supported by evidence. Evidence based practice must be supported by evidence based teaching. Nurse educators must be up to date with evidence based teaching as well as the latest evidence based teaching strategies, in order to teach the new millennial nursing students and for the new qualifications structure. Teaching the concept of evidence based practice by implementing evidence based teaching to nursing students will enable them to transform the future of healthcare by delivering high quality care practice. A paucity of evidence is available on evidence based teaching and teaching strategies in the South African context. Therefore the researcher used a systematic review methodology to explore and describe the best available evidence based teaching strategies and to develop a guideline on evidence based teaching strategies for nurse educators. The data bases searched included: MEDLINE, CINAHL, PubMed and Google Scholar. Manual searches were done and completed with the assistance of librarians. A total number of n=50 studies were identified as potentially relevant to the study. The number or articles included for critical appraisal were 20. On completion of the critical appraisal n=17 articles were identified for the review. The included studies for the review were n=7 Level 1, systematic reviews and n=10 Level 2, quasi-experimental studies. Three studies were excluded after critical appraisal from two reviewers, appraisal was done independently, and consensuses were reached between the two reviewers. The Joanna Briggs Institutes critical appraisal and data extraction instruments were used for the study. The descriptive data synthesis was done of the included studies as well as a comparison of teaching strategies to determine which one to better than the other one. Although n = 4 of the teaching strategies (concept mapping, internet-based learning, evidence based interactive strategy and cultural competence) significantly increased knowledge, the overall results found that a variety of teaching strategies to be implemented to increase the knowledge outcomes of the nursing students. The different teaching strategies found were: e-learning, concept mapping, internet-based learning, web-based learning, gaming, problem-based learning, and case studies, evidence based learning and cultural competence. However, more research is needed to investigate the best use of the different teaching strategies and compare the impact of a variety of teaching strategies on increasing knowledge of the nursing student.
- Full Text:
- Date Issued: 2015
A business model for medical subspecialty training in South Africa
- Dalmeyer, Johannes Paulus Franciscus
- Authors: Dalmeyer, Johannes Paulus Franciscus
- Date: 2015
- Subjects: Health care teams -- Training of -- South Africa , Medical care -- Needs assessment -- South Africa , Evidence-based medicine -- South Africa
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/3508 , vital:20437
- Description: The shortage of healthcare workers and doctors in the developing world compared to the developed world is a problem, and will continue to be so, due to the continual migration of qualified professionals and the inability of the state to remedy these shortfalls. A shortage of healthcare workers and specialist doctors will seriously hamper the Government’s National Health Insurance (NHI) plan, as well as the sustainability of the private health care sector. In addition, the duration of medical training in South Africa is exceptionally long. The three major hospital groups and other private corporates have over the last number of years taken limited initiative to fund education projects in conjunction with the academic institutions. However, these projects have been poorly focused and have been managed in an unstructured and detached manner. There is a desire from the private sector to get involved in these projects on a much larger scale through more formalised structures. Given this background, the primary objective of this research is to develop a business model for medical subspecialty training to complement the current academic subspecialty training in South Africa. A trial model for training subspecialists in reproductive medicine was developed as a first attempt to address the threatening shortages and training duration. This trial programme is the basis of this research. A two-phased process was used in collecting data. In Phase 1 data was collected from stakeholder groups. The results of this survey assisted in generating variables to include in the measuring instrument for the survey in Phase 2. In Phase 2 the perceptions and expectations of sub-specialists (reproductive subspecialists and cardiologists) regarding sub-specialty training was collected. The results of the demographic variables confirm the aging profile of subspecialist and the need to ensure succession. The results further showed that cardiologists and reproductive subspecialist expectations of the training of subspecialists are very similar except for their expectations on the training duration. Reproductive subspecialist respondents agreed more than cardiology subspecialist respondents that the training duration is too long. The biggest gap between perceptions and expectations is also with the factor training. The results showed that the expectations of subspecialists are not met for training. From these results a business model for the training of medical subspecialists is proposed. This proposed business model can play a complementary role to the existing state controlled system and form the bases of Public Private Partnerships (PPP) in medical training. This proposed business model will fit a developing country were the focus is on primary healthcare, with financial and capacity constraints. The proposed model would require role players to bring about change to accommodate a larger scale Public Private Partnership (PPP) to ensure the implementation of the model. The proposed decentralised business model for training subspecialists would allow the trainee subspecialist to practise as a specialist thus maintaining an acceptable income, and enable an expedited completion and lead to a wider dissemination of medical expertise that can be delivered in a wider national foot print. It further will provide for a structured Public Private Partnership.
- Full Text:
- Date Issued: 2015
- Authors: Dalmeyer, Johannes Paulus Franciscus
- Date: 2015
- Subjects: Health care teams -- Training of -- South Africa , Medical care -- Needs assessment -- South Africa , Evidence-based medicine -- South Africa
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/3508 , vital:20437
- Description: The shortage of healthcare workers and doctors in the developing world compared to the developed world is a problem, and will continue to be so, due to the continual migration of qualified professionals and the inability of the state to remedy these shortfalls. A shortage of healthcare workers and specialist doctors will seriously hamper the Government’s National Health Insurance (NHI) plan, as well as the sustainability of the private health care sector. In addition, the duration of medical training in South Africa is exceptionally long. The three major hospital groups and other private corporates have over the last number of years taken limited initiative to fund education projects in conjunction with the academic institutions. However, these projects have been poorly focused and have been managed in an unstructured and detached manner. There is a desire from the private sector to get involved in these projects on a much larger scale through more formalised structures. Given this background, the primary objective of this research is to develop a business model for medical subspecialty training to complement the current academic subspecialty training in South Africa. A trial model for training subspecialists in reproductive medicine was developed as a first attempt to address the threatening shortages and training duration. This trial programme is the basis of this research. A two-phased process was used in collecting data. In Phase 1 data was collected from stakeholder groups. The results of this survey assisted in generating variables to include in the measuring instrument for the survey in Phase 2. In Phase 2 the perceptions and expectations of sub-specialists (reproductive subspecialists and cardiologists) regarding sub-specialty training was collected. The results of the demographic variables confirm the aging profile of subspecialist and the need to ensure succession. The results further showed that cardiologists and reproductive subspecialist expectations of the training of subspecialists are very similar except for their expectations on the training duration. Reproductive subspecialist respondents agreed more than cardiology subspecialist respondents that the training duration is too long. The biggest gap between perceptions and expectations is also with the factor training. The results showed that the expectations of subspecialists are not met for training. From these results a business model for the training of medical subspecialists is proposed. This proposed business model can play a complementary role to the existing state controlled system and form the bases of Public Private Partnerships (PPP) in medical training. This proposed business model will fit a developing country were the focus is on primary healthcare, with financial and capacity constraints. The proposed model would require role players to bring about change to accommodate a larger scale Public Private Partnership (PPP) to ensure the implementation of the model. The proposed decentralised business model for training subspecialists would allow the trainee subspecialist to practise as a specialist thus maintaining an acceptable income, and enable an expedited completion and lead to a wider dissemination of medical expertise that can be delivered in a wider national foot print. It further will provide for a structured Public Private Partnership.
- Full Text:
- Date Issued: 2015
A case study of organisational change in an employee wellness company and its effects on job satisfaction and organisational climate
- Authors: Kassiem, Wahib
- Date: 2015
- Subjects: Organizational change -- South Africa -- Case studies
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:844 , http://hdl.handle.net/10962/d1016404
- Description: The modern era has brought the phenomenon of organisational change closer to the average person. With the recent financial crisis placing more strain on businesses, organisations are always under pressure to review their business models in order to deliver a sustainable operational model and as result, hopefully a sustainable competitive advantage. In order to remain competitive, the leadership team has to constantly seek ways of differentiating their organisations from others with similar product offerings. When these changes are initiated, there is no doubt that the leadership gave extensive thought prior to execution. However, their motives are not always clear to their most important constitution, their employees. Often when these changes are implemented, employees believe that they’ve been left out of the decision making process. Furthermore, post change review with employees are also not given enough thought and are often not done. This research used qualitative research methods to establish how employees experience job satisfaction and organisational climate subsequent to changes that transpired within their work environment. Semi-structured interviews and document analysis were used to collect data. The interviews were constructed by expanding upon well-documented quantitative dimensions of these behavioural variables. Questions were developed focusing on these dimensions in line with the changes experienced. The sample consisted of nine employees at an employee wellness organisation in Roodepoort, Gauteng. There is evidence to show that in this short period of two years (May 2012 to June 2014), by implementing various changes, the new leadership has improved the financial viability of the organisation. However, insights from the interviews point to a number of areas where the leadership and management structures have to exert more effort. Communication processes have to be reviewed, especially to lower levels. As there exists limited opportunities for promotion, investigations into expanding existing roles, again at the lower levels may assist in raising job satisfaction levels. Employees felt that support structures are severely lacking when significant changes affecting them are implemented. A climate for innovation and risk taking has to be considered which, if instituted, could aid the organisation in setting the pace for the organisational wellness industry. The structure adopted for this research consists of three sections. Section one follows the evaluation report format, with the literature review and research methodology sections following thereafter. By making use of established literature as a basis, the findings and recommendations are therefore not exclusively applicable to this organisation. Hence other organisations intending similar change initiatives could benefit from this research.
- Full Text:
- Date Issued: 2015
- Authors: Kassiem, Wahib
- Date: 2015
- Subjects: Organizational change -- South Africa -- Case studies
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:844 , http://hdl.handle.net/10962/d1016404
- Description: The modern era has brought the phenomenon of organisational change closer to the average person. With the recent financial crisis placing more strain on businesses, organisations are always under pressure to review their business models in order to deliver a sustainable operational model and as result, hopefully a sustainable competitive advantage. In order to remain competitive, the leadership team has to constantly seek ways of differentiating their organisations from others with similar product offerings. When these changes are initiated, there is no doubt that the leadership gave extensive thought prior to execution. However, their motives are not always clear to their most important constitution, their employees. Often when these changes are implemented, employees believe that they’ve been left out of the decision making process. Furthermore, post change review with employees are also not given enough thought and are often not done. This research used qualitative research methods to establish how employees experience job satisfaction and organisational climate subsequent to changes that transpired within their work environment. Semi-structured interviews and document analysis were used to collect data. The interviews were constructed by expanding upon well-documented quantitative dimensions of these behavioural variables. Questions were developed focusing on these dimensions in line with the changes experienced. The sample consisted of nine employees at an employee wellness organisation in Roodepoort, Gauteng. There is evidence to show that in this short period of two years (May 2012 to June 2014), by implementing various changes, the new leadership has improved the financial viability of the organisation. However, insights from the interviews point to a number of areas where the leadership and management structures have to exert more effort. Communication processes have to be reviewed, especially to lower levels. As there exists limited opportunities for promotion, investigations into expanding existing roles, again at the lower levels may assist in raising job satisfaction levels. Employees felt that support structures are severely lacking when significant changes affecting them are implemented. A climate for innovation and risk taking has to be considered which, if instituted, could aid the organisation in setting the pace for the organisational wellness industry. The structure adopted for this research consists of three sections. Section one follows the evaluation report format, with the literature review and research methodology sections following thereafter. By making use of established literature as a basis, the findings and recommendations are therefore not exclusively applicable to this organisation. Hence other organisations intending similar change initiatives could benefit from this research.
- Full Text:
- Date Issued: 2015
A Case study of students' first additional language reading and response in the faculty of education at the University of Fort Hare: Eastern Cape
- Authors: Linake, Manthekeleng A
- Date: 2015
- Subjects: Language and education Language and languages -- Study and teaching -- South Africa --Eastern Cape English language -- Study and teaching -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , Degree
- Identifier: http://hdl.handle.net/10353/5851 , vital:29402
- Description: Although reading ability alone cannot guarantee academic success, it is highly likely that a lack of reading can function as a key barrier to academic achievement. There are many other factors that are part of the causality. Of these, socio-economic status, teaching methods, parental involvement and lack of exposure to LoLT are probably the most important. Classroom teaching for reading instruction needs to be considered as the critical factor in preventing reading problems and must be the central focus for change. As such, teachers’ acquisition of the teaching skills necessary to bring about the development of literate language competency are critical especially in South Africa where many assumptions have been largely unquestioned about how to teach reading and writing, which languages to use and what counts as high quality practice in classrooms (Banda, 2000). The main aim of the study was to investigate principally reading with the use of English first additional language (FAL) in South African Universities. The objectives included enabling students to successfully learn reading in order to promote their’ reading to such a level that they can continue reading to learn and not learning to read. The researcher was particularly interested in exploring broader trends in reading strategies, instructions and training for students with the intention of contributing possible strategies to address the training of students for their role as literacy instructors in English as well as in multilingual education in South Africa. Methodologically, the study is premised within the interpretivist paradigm based on a qualitative research method. It is a case study design. It is a longitudinal study that covered a total of four years, the duration for a B Ed degree. The population comprises all forth year English teaching methods class and ten lecturers in the programme. The data collection tools included documents, participant observation, journal entry, assessments and focus groups. Interviews were granted to a purposively selected number of students (9) based on their academic performance over the years. There were three weak, three medium and three strong students that were interviewed. A total of 10 teachers were randomly selected from the Faculty to get their input about students’ reading. The ages of the respondents ranged from 18-60. The study concluded that students prefer to be taught in English although most see it as a barrier to learning. The findings showed that language learning can be easier if it is considered as social practice with academic purpose. The researcher recommends that there is need for a reduction of administrative duties from the lecturers to create more time for consultation. She or he also see a need for tutorials which can help to expose learners even more to interaction in EFAL.
- Full Text:
- Date Issued: 2015
- Authors: Linake, Manthekeleng A
- Date: 2015
- Subjects: Language and education Language and languages -- Study and teaching -- South Africa --Eastern Cape English language -- Study and teaching -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , Degree
- Identifier: http://hdl.handle.net/10353/5851 , vital:29402
- Description: Although reading ability alone cannot guarantee academic success, it is highly likely that a lack of reading can function as a key barrier to academic achievement. There are many other factors that are part of the causality. Of these, socio-economic status, teaching methods, parental involvement and lack of exposure to LoLT are probably the most important. Classroom teaching for reading instruction needs to be considered as the critical factor in preventing reading problems and must be the central focus for change. As such, teachers’ acquisition of the teaching skills necessary to bring about the development of literate language competency are critical especially in South Africa where many assumptions have been largely unquestioned about how to teach reading and writing, which languages to use and what counts as high quality practice in classrooms (Banda, 2000). The main aim of the study was to investigate principally reading with the use of English first additional language (FAL) in South African Universities. The objectives included enabling students to successfully learn reading in order to promote their’ reading to such a level that they can continue reading to learn and not learning to read. The researcher was particularly interested in exploring broader trends in reading strategies, instructions and training for students with the intention of contributing possible strategies to address the training of students for their role as literacy instructors in English as well as in multilingual education in South Africa. Methodologically, the study is premised within the interpretivist paradigm based on a qualitative research method. It is a case study design. It is a longitudinal study that covered a total of four years, the duration for a B Ed degree. The population comprises all forth year English teaching methods class and ten lecturers in the programme. The data collection tools included documents, participant observation, journal entry, assessments and focus groups. Interviews were granted to a purposively selected number of students (9) based on their academic performance over the years. There were three weak, three medium and three strong students that were interviewed. A total of 10 teachers were randomly selected from the Faculty to get their input about students’ reading. The ages of the respondents ranged from 18-60. The study concluded that students prefer to be taught in English although most see it as a barrier to learning. The findings showed that language learning can be easier if it is considered as social practice with academic purpose. The researcher recommends that there is need for a reduction of administrative duties from the lecturers to create more time for consultation. She or he also see a need for tutorials which can help to expose learners even more to interaction in EFAL.
- Full Text:
- Date Issued: 2015