Studies in chromium complexes
- Authors: Friend, Maurice Temple
- Date: 1953
- Subjects: Complex ions , Chromium
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4474 , http://hdl.handle.net/10962/d1011892 , Complex ions , Chromium
- Description: In this work physical and analytical methods have been used to investigate the potassium salts of certain dioxalato chromium (III) complexes. The solid potassium salts of the trioxalatochromiate and the cis and trans dioxalatodiaquochromiates together with a salt corresponding to potassium dioxalatosulphatoaquochromiate were prepared. The mono- and dihydroxo derivatives of the cis and trans dioxalatochromiates were also obtained in aqueous solution. The methods of preparation and analysis used are described. Spectrophotometric absorption curves obtained on solutions of these salts using a Beckman Spectrophotometer are in agreement with results of previous workers, and the new absorption curve obtained from a solution of the solid cis dioxalatodiaquochromia salt shows that it is pure and gives additional proof of the completeness of the trans - cis isomerisation. Summary, p. i.
- Full Text:
- Date Issued: 1953
- Authors: Friend, Maurice Temple
- Date: 1953
- Subjects: Complex ions , Chromium
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4474 , http://hdl.handle.net/10962/d1011892 , Complex ions , Chromium
- Description: In this work physical and analytical methods have been used to investigate the potassium salts of certain dioxalato chromium (III) complexes. The solid potassium salts of the trioxalatochromiate and the cis and trans dioxalatodiaquochromiates together with a salt corresponding to potassium dioxalatosulphatoaquochromiate were prepared. The mono- and dihydroxo derivatives of the cis and trans dioxalatochromiates were also obtained in aqueous solution. The methods of preparation and analysis used are described. Spectrophotometric absorption curves obtained on solutions of these salts using a Beckman Spectrophotometer are in agreement with results of previous workers, and the new absorption curve obtained from a solution of the solid cis dioxalatodiaquochromia salt shows that it is pure and gives additional proof of the completeness of the trans - cis isomerisation. Summary, p. i.
- Full Text:
- Date Issued: 1953
Studies in chromium complexes
- Authors: Cooper, Desmond Rudolph
- Date: 1953
- Subjects: Chromium , Complex ions
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4523 , http://hdl.handle.net/10962/d1014707
- Description: The chemistry of co-ordination compounds in general has played an important role in the development of the modern theory of valency, but the properties of complex salts between chromium and organic compounds containing carboxyl and amino- groups are of additional interest because of their bearing on the theory of certain technological processes such as chromium plating and, in particular, chrome-tanning. Owing to the rapid development of valence theory over the last two decades the technological chemist finds himself at a disadvantage vis-a-vis his academic counterpart in attempting to interpret the results of researches relating to these compounds as he must rely on the less powerful "classical" approach to his problems. Hence the need was felt for a brief survey of modern concepts of valency in terms of wave mechanics. For a more extended study the reader may consult the appropriate references and text books.
- Full Text:
- Date Issued: 1953
- Authors: Cooper, Desmond Rudolph
- Date: 1953
- Subjects: Chromium , Complex ions
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4523 , http://hdl.handle.net/10962/d1014707
- Description: The chemistry of co-ordination compounds in general has played an important role in the development of the modern theory of valency, but the properties of complex salts between chromium and organic compounds containing carboxyl and amino- groups are of additional interest because of their bearing on the theory of certain technological processes such as chromium plating and, in particular, chrome-tanning. Owing to the rapid development of valence theory over the last two decades the technological chemist finds himself at a disadvantage vis-a-vis his academic counterpart in attempting to interpret the results of researches relating to these compounds as he must rely on the less powerful "classical" approach to his problems. Hence the need was felt for a brief survey of modern concepts of valency in terms of wave mechanics. For a more extended study the reader may consult the appropriate references and text books.
- Full Text:
- Date Issued: 1953
An investigation of certain complex ions of trivalent chromium by spectrophotometric and other physical methods
- Authors: Burley, Ralph Walter
- Date: 1950
- Subjects: Chromium
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4521 , http://hdl.handle.net/10962/d1014675
- Description: Although chromium coordination compounds are of considerable technological importance, they have been subjected to few thorough investigations since Werner's original experlments, in spite of the fact that we now possess a number of accurate physical methods, not available in Werner's time for the study of coordination complexes, The object of the work described in this thesis was to obtain further information on the chemistry of complex chromium(III) ions with special reference to the dioxalato-diaquochromiate system, [Cr(C₂0₄)₂(H₂0)₂]. For this purpose; spectrophotometric and potentlometrlc measurements were combined to yield information on a number of topics, The spectrophotometric investigations consisted in measuring the absorption spectra of the potassium salts of the complexes under consideration and in observing the changes in light absorption which occur during their formatlon and decomposition. The instrument used was a Beckmann Quartz Spectrophotometer model du. More than than twelve new absorption spectra were measured in this work and in conjunction with the spectra of other chromium and cobalt complexes reported by earlier workers, these are used to review the position of spectrophotometry as a method of investigating chromium complexes. The reasons for the shapes of the absorption spectra are discussed and it is concluded that spectrophotometry is useful for observing the progress of reactions involving complex ions and for analysing solutions, but that more fundamental data cannot be expected from the absorption curves.
- Full Text:
- Date Issued: 1950
- Authors: Burley, Ralph Walter
- Date: 1950
- Subjects: Chromium
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4521 , http://hdl.handle.net/10962/d1014675
- Description: Although chromium coordination compounds are of considerable technological importance, they have been subjected to few thorough investigations since Werner's original experlments, in spite of the fact that we now possess a number of accurate physical methods, not available in Werner's time for the study of coordination complexes, The object of the work described in this thesis was to obtain further information on the chemistry of complex chromium(III) ions with special reference to the dioxalato-diaquochromiate system, [Cr(C₂0₄)₂(H₂0)₂]. For this purpose; spectrophotometric and potentlometrlc measurements were combined to yield information on a number of topics, The spectrophotometric investigations consisted in measuring the absorption spectra of the potassium salts of the complexes under consideration and in observing the changes in light absorption which occur during their formatlon and decomposition. The instrument used was a Beckmann Quartz Spectrophotometer model du. More than than twelve new absorption spectra were measured in this work and in conjunction with the spectra of other chromium and cobalt complexes reported by earlier workers, these are used to review the position of spectrophotometry as a method of investigating chromium complexes. The reasons for the shapes of the absorption spectra are discussed and it is concluded that spectrophotometry is useful for observing the progress of reactions involving complex ions and for analysing solutions, but that more fundamental data cannot be expected from the absorption curves.
- Full Text:
- Date Issued: 1950
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