Petrogenesis of the upper critical zone in the Western Bushveld Complex with emphasis on the UG1 Footwall and Bastard units
- Authors: De Klerk, William Johan
- Date: 1992
- Subjects: Petrogenesis -- South Africa Formations (Geology) -- South Africa Mineralogy -- South Africa Geochemistry -- South Africa Petrology -- Africa, Southern Rustenburg Platinum Mines
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4986 , http://hdl.handle.net/10962/d1005598
- Description: This study is an account of the stratigraphic sequence, the petrography, mineralogy (microprobe investigations of orthopyroxene, clinopyroxene, olivine and plagioclase feldspar), and whole-rock major- and traceelement geochemistry of the silicate cumulates of the Upper Critical Zone in the western Bushveld Complex. Two parts of the study - an investigation of a 350m column incorporating the MG3 and UGI Footwall Units, and a comparison of two additional Upper Critical Zone profiles with a previously compiled profile between the UGI and Bastard Units - are focused on RPM Union Section in the northwestern sector of the Complex. The third part is a detailed vertical and lateral investigation of the Bastard Unit at the top of the Critical Zone, which draws on sampling and data compilation from seventeen profiles in the western limb of the Complex. The MG3 Unit (45m) is made up of a lower chromitite layer overlain by a norite-pyroxenite-anorthosite sequence while the UGlFW Unit (295m) is composed of a related series of lower chromitite layers (MG4) overlain by a pyroxenite-norite-anorthosite sequence capped by the UGI chromitite layer. These mafic cumulates display a distinctive pattern of oscillating cryptic variation in whole-rock Mg/(Mg+Fe), FeO/Ti0₂, Cr/Co and Ni/V ratios through the sequence. Sympathetic oscillations are recorded for compositions of orthopyroxene and plagioclase feldspar and eight subcycles are recognised through the UGlFW Unit. The entire sequence is characterised by the presence of small, spheroidal, embayed and irregularly shaped plagioclase grains which are poikilitically enclosed in cumulus orthopyroxene grains of both pyroxenites and norites. This texture is indicative of partial resorption of pre-existing feldspar primocrysts within the melt prior to their being incorporated into the host orthopyroxene grains. Textural, geochemical and isotopic data suggest that this sequence was built up by periodic additions of fresh, relatively primitive liquid into fractionated resident liquid, and subsequent mixing within the magma chamber. The Bastard Unit sequence, described in Chapter 4, is the last and most complete cyclic unit (c. 60m) of the Critical Zone, and its upper contact defines the boundary between the Critical and Main Zones of the Complex. This Unit can conveniently be sub-divided into a lower part, where orthopyroxene occurs as a cumulus phase, and the upper part which is composed entirely of anorthosite (Giant Mottled Anorthosite). The basal part of the Unit (≤ 18m) comprises a thin chromitite layer < O.5cm) overlain by a pyroxenite-melanorite-norite-leuconorite sequence. The basal pyroxenite is orthocumulate in character and rapidly gives way to norites and leuconorites. A distinct threefold subdivision emerges within the Giant Mottled Anorthosite which is predominantly an adcumulate which becomes orthocumulate in character at its top. Apart from minor deviations in thicknesses these lithologies are recorded over the entire strike-length covered in this study. Profiles of cryptic variation are compiled for orthopyroxene, plagioclase and whole-rock data and show that the Bastard Unit displays a characteristic pattern which is maintained throughout the western Bushveld Complex. A minor yet distinctive reversal in cryptic variation is revealed at a level which is stratigraphically variable within the lower Giant Mottled Anorthosite, and results in a double cuspate pattern. A remarkable feature of the basal Bastard pyroxenites is that although the modal proportion of mafic to felsic constituents varies systematically away from the northwestern sector, the Mg/(Mg+Fe) ratio of orthopyroxenes remains constant at 0.804 over a lateral strike distance of 171km. Within the upper part of the Unit the orthopyroxene is markedly Fe-rich and it is here that inverted primary pigeonite appears for the first time as a cumulus phase. In addition, K-feldspar, oscillatory zoned plagioclase grains and high levels of incompatible trace elements are noted at this level. On the basis of the data presented it is concluded that the Bastard Unit represents the crystallisation of a final, relatively large influx of hotter primitive liquid, with upper Critical Zone affinities, and subsequent mixing with a column of cooler (less dense) supernatant liquid which had in part hybridized with the overlying Main Zone magma. It is hypothesised that this new liquid was emplaced as a basal flow beneath supernatant liquid and that it initiated the deposition of mafic cumulates at its base. The supernatant liquid is interpreted as representing the fractionated residuum produced by crystallisation of earlier cyclic units, with plagioclase on the liquidus, and that it contained an abundance of small plagioclase primocrysts in suspension. Development of the Unit can be viewed as a two-stage process. In the lower half of the unit, chemical and physical parameters typical of the new magma dominated the crystallisation process, and resulted in cumulates very similar to other relatively complete Upper Critical Zone units. In the upper, leucocratic sequence, above a minor reversal, crystallisation was from a liquid which was the product of mixing of a minor pulse of primitive liquid with the reservoir of hybridized supernatant liquid. Although the Bastard Unit is not continuous around the entire Western limb of the Complex, it is concluded that it developed in a single, or connected, magma chamber and that its irruptive feeder zone was located in the proximal northwestern facies of the Complex.
- Full Text:
- Authors: De Klerk, William Johan
- Date: 1992
- Subjects: Petrogenesis -- South Africa Formations (Geology) -- South Africa Mineralogy -- South Africa Geochemistry -- South Africa Petrology -- Africa, Southern Rustenburg Platinum Mines
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4986 , http://hdl.handle.net/10962/d1005598
- Description: This study is an account of the stratigraphic sequence, the petrography, mineralogy (microprobe investigations of orthopyroxene, clinopyroxene, olivine and plagioclase feldspar), and whole-rock major- and traceelement geochemistry of the silicate cumulates of the Upper Critical Zone in the western Bushveld Complex. Two parts of the study - an investigation of a 350m column incorporating the MG3 and UGI Footwall Units, and a comparison of two additional Upper Critical Zone profiles with a previously compiled profile between the UGI and Bastard Units - are focused on RPM Union Section in the northwestern sector of the Complex. The third part is a detailed vertical and lateral investigation of the Bastard Unit at the top of the Critical Zone, which draws on sampling and data compilation from seventeen profiles in the western limb of the Complex. The MG3 Unit (45m) is made up of a lower chromitite layer overlain by a norite-pyroxenite-anorthosite sequence while the UGlFW Unit (295m) is composed of a related series of lower chromitite layers (MG4) overlain by a pyroxenite-norite-anorthosite sequence capped by the UGI chromitite layer. These mafic cumulates display a distinctive pattern of oscillating cryptic variation in whole-rock Mg/(Mg+Fe), FeO/Ti0₂, Cr/Co and Ni/V ratios through the sequence. Sympathetic oscillations are recorded for compositions of orthopyroxene and plagioclase feldspar and eight subcycles are recognised through the UGlFW Unit. The entire sequence is characterised by the presence of small, spheroidal, embayed and irregularly shaped plagioclase grains which are poikilitically enclosed in cumulus orthopyroxene grains of both pyroxenites and norites. This texture is indicative of partial resorption of pre-existing feldspar primocrysts within the melt prior to their being incorporated into the host orthopyroxene grains. Textural, geochemical and isotopic data suggest that this sequence was built up by periodic additions of fresh, relatively primitive liquid into fractionated resident liquid, and subsequent mixing within the magma chamber. The Bastard Unit sequence, described in Chapter 4, is the last and most complete cyclic unit (c. 60m) of the Critical Zone, and its upper contact defines the boundary between the Critical and Main Zones of the Complex. This Unit can conveniently be sub-divided into a lower part, where orthopyroxene occurs as a cumulus phase, and the upper part which is composed entirely of anorthosite (Giant Mottled Anorthosite). The basal part of the Unit (≤ 18m) comprises a thin chromitite layer < O.5cm) overlain by a pyroxenite-melanorite-norite-leuconorite sequence. The basal pyroxenite is orthocumulate in character and rapidly gives way to norites and leuconorites. A distinct threefold subdivision emerges within the Giant Mottled Anorthosite which is predominantly an adcumulate which becomes orthocumulate in character at its top. Apart from minor deviations in thicknesses these lithologies are recorded over the entire strike-length covered in this study. Profiles of cryptic variation are compiled for orthopyroxene, plagioclase and whole-rock data and show that the Bastard Unit displays a characteristic pattern which is maintained throughout the western Bushveld Complex. A minor yet distinctive reversal in cryptic variation is revealed at a level which is stratigraphically variable within the lower Giant Mottled Anorthosite, and results in a double cuspate pattern. A remarkable feature of the basal Bastard pyroxenites is that although the modal proportion of mafic to felsic constituents varies systematically away from the northwestern sector, the Mg/(Mg+Fe) ratio of orthopyroxenes remains constant at 0.804 over a lateral strike distance of 171km. Within the upper part of the Unit the orthopyroxene is markedly Fe-rich and it is here that inverted primary pigeonite appears for the first time as a cumulus phase. In addition, K-feldspar, oscillatory zoned plagioclase grains and high levels of incompatible trace elements are noted at this level. On the basis of the data presented it is concluded that the Bastard Unit represents the crystallisation of a final, relatively large influx of hotter primitive liquid, with upper Critical Zone affinities, and subsequent mixing with a column of cooler (less dense) supernatant liquid which had in part hybridized with the overlying Main Zone magma. It is hypothesised that this new liquid was emplaced as a basal flow beneath supernatant liquid and that it initiated the deposition of mafic cumulates at its base. The supernatant liquid is interpreted as representing the fractionated residuum produced by crystallisation of earlier cyclic units, with plagioclase on the liquidus, and that it contained an abundance of small plagioclase primocrysts in suspension. Development of the Unit can be viewed as a two-stage process. In the lower half of the unit, chemical and physical parameters typical of the new magma dominated the crystallisation process, and resulted in cumulates very similar to other relatively complete Upper Critical Zone units. In the upper, leucocratic sequence, above a minor reversal, crystallisation was from a liquid which was the product of mixing of a minor pulse of primitive liquid with the reservoir of hybridized supernatant liquid. Although the Bastard Unit is not continuous around the entire Western limb of the Complex, it is concluded that it developed in a single, or connected, magma chamber and that its irruptive feeder zone was located in the proximal northwestern facies of the Complex.
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Mineralogy, petrology and geochemistry of the lower and lower critical zones, Northwestern Bushveld Complex
- Authors: Teigler, Bernd
- Date: 1991
- Subjects: Mineralogy -- South Africa -- North-Western Transvaal Petrology -- South Africa -- North-Western Transvaal Geochemistry -- South Africa -- North-Western Transvaal
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4978 , http://hdl.handle.net/10962/d1005590
- Description: This study of the lower part of the Rustenburg Layered Suite in the Western Bushveld Complex is based mainly on drill core samples from three localities, which are approximately 130 km apart. The NG-sequence, situated in the northwestern sector of the complex (Union Section, R.P.M.) extends from the floor of the complex to the base of the upper Critical Zone. The sequence is ca. 1800 m thick and it comprises mainly ultramafic cumulates, namely pyroxenites, olivine pyroxenites, harzburgites and dunites. Norites and anorthos ites are present only in minor proportion. Within the upper half of the NG-sequence ten prominent chromitite layers are correlated with the LGI MG4-interval. Correlation is also established between published sequences and the two other sequences studied, located 8 km and 55 km, respectively, east of Rustenburg. Whole-rock chemical data (major and trace elements), microprobe and Sr isotope data are presented. Petrographic studies provide modal analyses and measurements of grain size. All petrographic, mineralogical and other geochemical data point to an origin of the cumulates of the NG-sequence by crystallization from liquids of the U-type lineage and derivatives thereof. No evidence is found for the involvement of parental liquids with a distinctly different composition or crystallization order (A-liquids). However, subtle compositional variations of the parental liquids are evident in slight changes of the Cr content in orthopyroxene or in variations of Sr isotope ratio. The NG-sequence is characterized by intervals with reversed fractionation trends caused by repeated influxes of pristine magma (during periods of high magmatic activity) resulting in a high degree of rejuvenation. These intervals are overlain by others with a normal fractionation trend, interpreted as cumulates formed in periods with low or no magmatic activity, in which fractional crystallization controlled bulk composition of the evolving liquid. The Lower Zone in the NG-sequence is dominated by a progressive shift towards more primitive compositions, while in the Critical Zone fractionation was the major operating process in the magma chamber. However, during deposition of the pyroxenitic lower Critical Zone several replenishment events occurred, during which fresh Cr-rich magma was emplaced. Massive chromitite layers were deposited after mixing between the newly emplaced magma and the resident residual liquid shifted bulk compositions into the primary field of chrome-spinel. Cumulus plagioclase crystallized after bulk composition of the residual liquid was driven to the orthopyroxene plagioclase cotectic by continued fractional crystallization; this occurred once in the Lower Zone, yielding a single, thin norite layer, and again in the upper Critical Zone of the NG-sequence. A facies model is proposed based on the stratigraphic and compositional variations along strike in the Western Bushveld Complex. This model explains the variations by means of the position of the sequence with regard to a feeder system. The olivine- and orthopyroxene-rich, but plagioclase-poor NG-sequence represents the proximal facies, while the SF-sequence (poor in ferromagnesian phases, but plagioclase-rich) is developed as a distal facies, close to the Brits graben.
- Full Text:
- Authors: Teigler, Bernd
- Date: 1991
- Subjects: Mineralogy -- South Africa -- North-Western Transvaal Petrology -- South Africa -- North-Western Transvaal Geochemistry -- South Africa -- North-Western Transvaal
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4978 , http://hdl.handle.net/10962/d1005590
- Description: This study of the lower part of the Rustenburg Layered Suite in the Western Bushveld Complex is based mainly on drill core samples from three localities, which are approximately 130 km apart. The NG-sequence, situated in the northwestern sector of the complex (Union Section, R.P.M.) extends from the floor of the complex to the base of the upper Critical Zone. The sequence is ca. 1800 m thick and it comprises mainly ultramafic cumulates, namely pyroxenites, olivine pyroxenites, harzburgites and dunites. Norites and anorthos ites are present only in minor proportion. Within the upper half of the NG-sequence ten prominent chromitite layers are correlated with the LGI MG4-interval. Correlation is also established between published sequences and the two other sequences studied, located 8 km and 55 km, respectively, east of Rustenburg. Whole-rock chemical data (major and trace elements), microprobe and Sr isotope data are presented. Petrographic studies provide modal analyses and measurements of grain size. All petrographic, mineralogical and other geochemical data point to an origin of the cumulates of the NG-sequence by crystallization from liquids of the U-type lineage and derivatives thereof. No evidence is found for the involvement of parental liquids with a distinctly different composition or crystallization order (A-liquids). However, subtle compositional variations of the parental liquids are evident in slight changes of the Cr content in orthopyroxene or in variations of Sr isotope ratio. The NG-sequence is characterized by intervals with reversed fractionation trends caused by repeated influxes of pristine magma (during periods of high magmatic activity) resulting in a high degree of rejuvenation. These intervals are overlain by others with a normal fractionation trend, interpreted as cumulates formed in periods with low or no magmatic activity, in which fractional crystallization controlled bulk composition of the evolving liquid. The Lower Zone in the NG-sequence is dominated by a progressive shift towards more primitive compositions, while in the Critical Zone fractionation was the major operating process in the magma chamber. However, during deposition of the pyroxenitic lower Critical Zone several replenishment events occurred, during which fresh Cr-rich magma was emplaced. Massive chromitite layers were deposited after mixing between the newly emplaced magma and the resident residual liquid shifted bulk compositions into the primary field of chrome-spinel. Cumulus plagioclase crystallized after bulk composition of the residual liquid was driven to the orthopyroxene plagioclase cotectic by continued fractional crystallization; this occurred once in the Lower Zone, yielding a single, thin norite layer, and again in the upper Critical Zone of the NG-sequence. A facies model is proposed based on the stratigraphic and compositional variations along strike in the Western Bushveld Complex. This model explains the variations by means of the position of the sequence with regard to a feeder system. The olivine- and orthopyroxene-rich, but plagioclase-poor NG-sequence represents the proximal facies, while the SF-sequence (poor in ferromagnesian phases, but plagioclase-rich) is developed as a distal facies, close to the Brits graben.
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The petrology, mineralogy and geochemistry of the main zone of the Bushveld Complex at Rustenburg Platinum Mines, Union Section
- Authors: Mitchell, Andrew Alexander
- Date: 1988
- Subjects: Mineralogy -- South Africa Petrology -- South Africa Rustenburg Platinum Mines Geochemistry -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4903 , http://hdl.handle.net/10962/d1001563
- Description: Union Section of Rustenburg Patinum Mines is situated in the northwestern part of the Bushveld Complex, some twenty kilometres north of the Pilanesberg Alkaline Complex. The mining lease area covers a roughly triangular segment of Lower, Critical and Main Zone rocks, transgressed to the north and south by magnetite-bearing ferrogabbro of the Upper Zone. The Main Zone at Union Section is the focus of this study. The prime source of sample material for the study is the deep exploration borehole SK2, but additional, supplementary samples were collected on surface and underground, as well as from a second surface exploration borehole, SK4. In line with the recommendations of SACS (1980), the top of the Critical Zone, and therefore the base of the Main Zone, is taken to be the top of the Bastard Cyclic Unit. Sharpe (1985) suggested that the succession from the base of the Main is an isotopically separate entity Zone up to the Pyroxenite Marker from the rest of the Bushveld layered succession. This is not strictly true, as there is evidence that more than one parental magma was involved in the formation of this interval. It is, however, true that there are fundamental differences, particularly in isotopic makeup, between the Main Zone rocks below the pyroxenite Marker and those above (the latter having been assigned by Molyneux (1970) to subzone C of the Main Zone). Kruger et al. (1986, in press) suggested that the Pyroxenite Marker marks the base of the Upper Zone, and this convention is adhered to here. The implication of this is that the rocks which formerly constituted subzone C of the Main Zone are now considered part of the Upper Zone. The Main Zone rocks below the pyroxenite Marker were originally subdivided by Molyneux (1970) into two subzones, A and B. The results of the present study indicate that this subdivision is not justified. Instead, eight units have been distinguished in the Main Zone on geochemical, petrological and mineralogical bases. Each of these units is characterized by a coherent set, or progression, of chemical and petrological characteristics. The specific assignment of genetic connotations to these units has been deliberately avoided , at least until further studies of the Main Zone prove this to be justified. The demarcation of the eight units is illustrated in the composite diagram (Fig. 34) in the back pocket of this work, and the reasons for the subdivisions are listed in Table 6 (at the end of chapter 7 of this thesis). Until the late 1970's, it was thought that most layered cumulates formed by crystal settling (Wager and Brown, 1968). More recently, there has been a fundamental conceptual change, and many workers now believe that most cumulate rocks formed by in situ crystallization at the floor and walls of the magma chamber (McBirney and Noyes, 1979, Irvine, 1980a; Campbell, 1987). There is, however, some evidence for the physical separation of phases undergoing cotectic crystallization, particularly in the Upper Critical Zone and lower part of the Main Zone (Eales et al., 1986). This process, which has been alluded to in the past by various authors (Ferguson and Botha, 1963; Vermaak, 1976) involves the flotation of early-formed plagioclase crystals due to their positive bouyancy in tholeiitic liquids. The result is an apparent decoupling of the chemistry of pyroxene and plagioclase, as in unit IV of the Main Zone, where plagioclase becomes more anorthitic upwards, whilst pyroxene becomes more iron-rich. There is some substantial evidence, particularly in reversals in the strontium isotope initial ratio and the orthopyroxene Mg/(Mg+Fe) ratio , for multiple intrusion in the Main Zone. Although the largest and most important magma influx in the Main Zone was a high-R₀ aluminous tholeiite, as suggested by Sharpe (1985), the intrusive history of the Main Zone is believed to be far more complex than Sharpe (op. cit.) suggested. Significantly, there is strong evidence for small influxes of Upper Zone-type (Fe-rich tholeiite) magma in the upper reaches of the Main Zone. These are believed to be precursors to the major influx of Upper Zone-type magma at the pyroxenite Marker (Kruger et al, 1986, in press). The fate of intercumulus liquids in cumulate rocks has recently recieved substantial attention (Sparks et al., 1985; Morse, 1986; Barnes, 1986: Campbell, 1987). It is believed that the migration, or at least redistribution, of intercumulus liquids has played a vital role in modifying fractionation trends in the Main Zone. More importantly, the accumulation of late-stage intercumulus liquids is believed to be responsible for the formation of the Fe-rich ultramafic pegmatite bodies that interrupt the layered cumulates in borehole SK2 , Adobe Acrobat 9.53 Paper Capture Plug-in
- Full Text:
- Authors: Mitchell, Andrew Alexander
- Date: 1988
- Subjects: Mineralogy -- South Africa Petrology -- South Africa Rustenburg Platinum Mines Geochemistry -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4903 , http://hdl.handle.net/10962/d1001563
- Description: Union Section of Rustenburg Patinum Mines is situated in the northwestern part of the Bushveld Complex, some twenty kilometres north of the Pilanesberg Alkaline Complex. The mining lease area covers a roughly triangular segment of Lower, Critical and Main Zone rocks, transgressed to the north and south by magnetite-bearing ferrogabbro of the Upper Zone. The Main Zone at Union Section is the focus of this study. The prime source of sample material for the study is the deep exploration borehole SK2, but additional, supplementary samples were collected on surface and underground, as well as from a second surface exploration borehole, SK4. In line with the recommendations of SACS (1980), the top of the Critical Zone, and therefore the base of the Main Zone, is taken to be the top of the Bastard Cyclic Unit. Sharpe (1985) suggested that the succession from the base of the Main is an isotopically separate entity Zone up to the Pyroxenite Marker from the rest of the Bushveld layered succession. This is not strictly true, as there is evidence that more than one parental magma was involved in the formation of this interval. It is, however, true that there are fundamental differences, particularly in isotopic makeup, between the Main Zone rocks below the pyroxenite Marker and those above (the latter having been assigned by Molyneux (1970) to subzone C of the Main Zone). Kruger et al. (1986, in press) suggested that the Pyroxenite Marker marks the base of the Upper Zone, and this convention is adhered to here. The implication of this is that the rocks which formerly constituted subzone C of the Main Zone are now considered part of the Upper Zone. The Main Zone rocks below the pyroxenite Marker were originally subdivided by Molyneux (1970) into two subzones, A and B. The results of the present study indicate that this subdivision is not justified. Instead, eight units have been distinguished in the Main Zone on geochemical, petrological and mineralogical bases. Each of these units is characterized by a coherent set, or progression, of chemical and petrological characteristics. The specific assignment of genetic connotations to these units has been deliberately avoided , at least until further studies of the Main Zone prove this to be justified. The demarcation of the eight units is illustrated in the composite diagram (Fig. 34) in the back pocket of this work, and the reasons for the subdivisions are listed in Table 6 (at the end of chapter 7 of this thesis). Until the late 1970's, it was thought that most layered cumulates formed by crystal settling (Wager and Brown, 1968). More recently, there has been a fundamental conceptual change, and many workers now believe that most cumulate rocks formed by in situ crystallization at the floor and walls of the magma chamber (McBirney and Noyes, 1979, Irvine, 1980a; Campbell, 1987). There is, however, some evidence for the physical separation of phases undergoing cotectic crystallization, particularly in the Upper Critical Zone and lower part of the Main Zone (Eales et al., 1986). This process, which has been alluded to in the past by various authors (Ferguson and Botha, 1963; Vermaak, 1976) involves the flotation of early-formed plagioclase crystals due to their positive bouyancy in tholeiitic liquids. The result is an apparent decoupling of the chemistry of pyroxene and plagioclase, as in unit IV of the Main Zone, where plagioclase becomes more anorthitic upwards, whilst pyroxene becomes more iron-rich. There is some substantial evidence, particularly in reversals in the strontium isotope initial ratio and the orthopyroxene Mg/(Mg+Fe) ratio , for multiple intrusion in the Main Zone. Although the largest and most important magma influx in the Main Zone was a high-R₀ aluminous tholeiite, as suggested by Sharpe (1985), the intrusive history of the Main Zone is believed to be far more complex than Sharpe (op. cit.) suggested. Significantly, there is strong evidence for small influxes of Upper Zone-type (Fe-rich tholeiite) magma in the upper reaches of the Main Zone. These are believed to be precursors to the major influx of Upper Zone-type magma at the pyroxenite Marker (Kruger et al, 1986, in press). The fate of intercumulus liquids in cumulate rocks has recently recieved substantial attention (Sparks et al., 1985; Morse, 1986; Barnes, 1986: Campbell, 1987). It is believed that the migration, or at least redistribution, of intercumulus liquids has played a vital role in modifying fractionation trends in the Main Zone. More importantly, the accumulation of late-stage intercumulus liquids is believed to be responsible for the formation of the Fe-rich ultramafic pegmatite bodies that interrupt the layered cumulates in borehole SK2 , Adobe Acrobat 9.53 Paper Capture Plug-in
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The petrogenesis of the volcanic rocks of the Witwatersrand triad in the Klerksdorp area, Transvaal
- Authors: Bowen, Michael Peter
- Date: 1985
- Subjects: Volcanic rocks , Witwatersrand triad , Klerksdorp , Transvaal , Northwest Province , South Africa , Chemical analysis , Magma , Geology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4909 , http://hdl.handle.net/10962/d1001569
- Description: Several hundred chemical analyses of early Proterozoic lavas of the Witwatersrand triad (incorporating the Dominion Group, Witwatersrand Supergroup and Ventersdorp Supergroup) in the Klerksdorp area, have revealed the presence of various distinct magma types. These essentially correspond to formally defined lithostratigraphic units, but several inconsistencies have necessitated the use of informal nomenclature. The lavas have been regionally metamorphosed to low-grade, greenschist facies assemblages. Original igneous textures are preserved, despite a metamorphic overprint. Metamorphism has resulted in a certain degree of random chemical remobilization. Ba, Sr, Rb, K₂0, Na₂0 and CaO have been highly mobile, and their usefulness in petrogenetic modelling is extremely limited. In contrast, Zr, Nb, Y, LREE's, Cr, Ni, Ti0₂ P₂0₅ and Al₂0₃ have remained immobile. Ti/Zr and Ti/P ratios together constitute efficient discriminating variables for characterizing the different magma types. Lava compositions range from primitive Mg-rich tholeiites to rhyolites, the bulk being tholeiitic andesites. Al₂0₃ contents do not exceed 15%, a feature which reflects the tholeiitic, as opposed to calcalkaline, character of these lavas. Two magma-types are present within the Dominion Group, which is a typical example of bimodal volcanism. The Dominion basic lavas are overlain by the Dominion acid porphyries, with a limited amount of interfingering. The basic lava suite is highly fractionated, with compositions ranging from Mg-, Cr- and Ni-rich tholeiites (close to primary mantle melts) to evolved tholeiitic andesites. The most primitive liquids evolved by 45% fractional crystallization of hornblende, followed by a further 70% crystallization of an orthopyroxene-plagioclase assemblage containing up to 3% sulphides. The Dominion porphyries are rhyolitic, display very limited compositional variation, and probably represent a crustal melt related to the same magmatic event which produced the basic lavas. The only lavas from the Witwatersrand Supergroup present in the Klerksdorp area are those of the Crown Formation (Jeppestown amygdaloid). These are tholeiitic dacites which display extremely limited compositional variation, and are unrelated to any of the other magmas of the Witwatersrand triad. The Ventersdorp Supergroup comprises 4 magma-types: The Kliprivierberg Group lavas at the base are subdivisible into 3 sub-types on the basis of Zr contents. (Zr>11Oppm) are the most evolved. They are tholeiitic andesites which display fairly limited compositional variation. It is likely that more evolved compositions are present in other areas where the porphyritic lavas which characterize this unit are better developed. The overlying Orkney lavas are characterized by 110ppm>Zr>90ppm. They are tholeiitic andesites of similar composition to the Alberton lavas, but have lower incompatible element levels, higher siderophile element levels, and are of extremely uniform composition. The uppermost Loraine/Edenville lavas range from magnesian tholeiites to tholeiitic andesites. They are distinguished by Zr< 90ppm, and contain the most primitive magmas af the Witwatersrand triad, with up to 17,5% MgO, 2600ppm Cr, 600ppm Ni and M-values up to 77. The most primitive liquids evolved by 38% fractional crystallization of orthopyroxene ∓ chromite, followed by 35% fractional crystallization of an extract containing clinopyroxene and plagioclase. The absence of olivine precipitation is a result of the inherently high Si0₂ content of the magma. The Loraine/Edenville, Orkney and Alberton lavas do not lie on a common liquid line of descent, but are probably consanguinous. The Platberg Group overlies the Kliprivierberg Group, and has a coarse-clastic sedimentary unit, the Kameeldoorns Formation, at the base. Three petrographically distinct porphyritic lava sequences overlie the Kameeldoorns Formation, namely the informal "Goedgenoeg formation", the Makwassie quartz-feldspar porphyries and the Rietgat Formation. Despite petrographic differences, the Goedgenoeg and Rietgat lavas are chemically indistinguishable and thus form a single magma-type. The Makwassie porphyries are dacitic in composition with a high proportion of feldspar and quartz phenocrysts. Rational variation trends are attributed to a nett loss of Si0₂ during secondary alteration. The porphyries are probably of crustal origin. The Goedgenoeg/Rietgat lavas display unusual chemistry and a broad, irrational compositional spectrum. They contain very high incompatible element levels, high nonnative quartz, as well as high MgO, M-values, Cr and Ni relative to the other tholeiitic andesites of the Witwatersrand triad. It is tentatively suggested that they are hybrid magmas containing both crust and mantle components, the former possibly represented by the Makwassie porphyries. Field evidence suggests that Platberg volcanism commenced directly after Klipriviersberg volcanism ceased, and was accompanied by a period of enhanced tectonic activity. The Platberg lavas thus probably reflect a crustal melting cycle associated with the Klipriviersberg magmatic event. The Allanridge lavas are the youngest rocks of the Witwatersrand triad. They are separated from the Platberg Group by a unit of flat-lying sediments, the Bothaville Formation, which was deposited after an extended period of peneplanation. The Allanridge lavas form a separate magma-type. They are tholeiitic andesites of similar composition to the Alberton lavas, but have higher incompatible element levels and are not consanguinous. The compositional similarities amongst the basic magma-types of the Witwatersrand triad suggests that all were generated in an hydrous mantle. Interelement ratio differences between the various magma-types nevertheless support the concept that the mantle was chemically heterogeneous during the early Proterozoic.
- Full Text:
- Authors: Bowen, Michael Peter
- Date: 1985
- Subjects: Volcanic rocks , Witwatersrand triad , Klerksdorp , Transvaal , Northwest Province , South Africa , Chemical analysis , Magma , Geology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4909 , http://hdl.handle.net/10962/d1001569
- Description: Several hundred chemical analyses of early Proterozoic lavas of the Witwatersrand triad (incorporating the Dominion Group, Witwatersrand Supergroup and Ventersdorp Supergroup) in the Klerksdorp area, have revealed the presence of various distinct magma types. These essentially correspond to formally defined lithostratigraphic units, but several inconsistencies have necessitated the use of informal nomenclature. The lavas have been regionally metamorphosed to low-grade, greenschist facies assemblages. Original igneous textures are preserved, despite a metamorphic overprint. Metamorphism has resulted in a certain degree of random chemical remobilization. Ba, Sr, Rb, K₂0, Na₂0 and CaO have been highly mobile, and their usefulness in petrogenetic modelling is extremely limited. In contrast, Zr, Nb, Y, LREE's, Cr, Ni, Ti0₂ P₂0₅ and Al₂0₃ have remained immobile. Ti/Zr and Ti/P ratios together constitute efficient discriminating variables for characterizing the different magma types. Lava compositions range from primitive Mg-rich tholeiites to rhyolites, the bulk being tholeiitic andesites. Al₂0₃ contents do not exceed 15%, a feature which reflects the tholeiitic, as opposed to calcalkaline, character of these lavas. Two magma-types are present within the Dominion Group, which is a typical example of bimodal volcanism. The Dominion basic lavas are overlain by the Dominion acid porphyries, with a limited amount of interfingering. The basic lava suite is highly fractionated, with compositions ranging from Mg-, Cr- and Ni-rich tholeiites (close to primary mantle melts) to evolved tholeiitic andesites. The most primitive liquids evolved by 45% fractional crystallization of hornblende, followed by a further 70% crystallization of an orthopyroxene-plagioclase assemblage containing up to 3% sulphides. The Dominion porphyries are rhyolitic, display very limited compositional variation, and probably represent a crustal melt related to the same magmatic event which produced the basic lavas. The only lavas from the Witwatersrand Supergroup present in the Klerksdorp area are those of the Crown Formation (Jeppestown amygdaloid). These are tholeiitic dacites which display extremely limited compositional variation, and are unrelated to any of the other magmas of the Witwatersrand triad. The Ventersdorp Supergroup comprises 4 magma-types: The Kliprivierberg Group lavas at the base are subdivisible into 3 sub-types on the basis of Zr contents. (Zr>11Oppm) are the most evolved. They are tholeiitic andesites which display fairly limited compositional variation. It is likely that more evolved compositions are present in other areas where the porphyritic lavas which characterize this unit are better developed. The overlying Orkney lavas are characterized by 110ppm>Zr>90ppm. They are tholeiitic andesites of similar composition to the Alberton lavas, but have lower incompatible element levels, higher siderophile element levels, and are of extremely uniform composition. The uppermost Loraine/Edenville lavas range from magnesian tholeiites to tholeiitic andesites. They are distinguished by Zr< 90ppm, and contain the most primitive magmas af the Witwatersrand triad, with up to 17,5% MgO, 2600ppm Cr, 600ppm Ni and M-values up to 77. The most primitive liquids evolved by 38% fractional crystallization of orthopyroxene ∓ chromite, followed by 35% fractional crystallization of an extract containing clinopyroxene and plagioclase. The absence of olivine precipitation is a result of the inherently high Si0₂ content of the magma. The Loraine/Edenville, Orkney and Alberton lavas do not lie on a common liquid line of descent, but are probably consanguinous. The Platberg Group overlies the Kliprivierberg Group, and has a coarse-clastic sedimentary unit, the Kameeldoorns Formation, at the base. Three petrographically distinct porphyritic lava sequences overlie the Kameeldoorns Formation, namely the informal "Goedgenoeg formation", the Makwassie quartz-feldspar porphyries and the Rietgat Formation. Despite petrographic differences, the Goedgenoeg and Rietgat lavas are chemically indistinguishable and thus form a single magma-type. The Makwassie porphyries are dacitic in composition with a high proportion of feldspar and quartz phenocrysts. Rational variation trends are attributed to a nett loss of Si0₂ during secondary alteration. The porphyries are probably of crustal origin. The Goedgenoeg/Rietgat lavas display unusual chemistry and a broad, irrational compositional spectrum. They contain very high incompatible element levels, high nonnative quartz, as well as high MgO, M-values, Cr and Ni relative to the other tholeiitic andesites of the Witwatersrand triad. It is tentatively suggested that they are hybrid magmas containing both crust and mantle components, the former possibly represented by the Makwassie porphyries. Field evidence suggests that Platberg volcanism commenced directly after Klipriviersberg volcanism ceased, and was accompanied by a period of enhanced tectonic activity. The Platberg lavas thus probably reflect a crustal melting cycle associated with the Klipriviersberg magmatic event. The Allanridge lavas are the youngest rocks of the Witwatersrand triad. They are separated from the Platberg Group by a unit of flat-lying sediments, the Bothaville Formation, which was deposited after an extended period of peneplanation. The Allanridge lavas form a separate magma-type. They are tholeiitic andesites of similar composition to the Alberton lavas, but have higher incompatible element levels and are not consanguinous. The compositional similarities amongst the basic magma-types of the Witwatersrand triad suggests that all were generated in an hydrous mantle. Interelement ratio differences between the various magma-types nevertheless support the concept that the mantle was chemically heterogeneous during the early Proterozoic.
- Full Text:
The extrusive and intrusive basaltic rocks of the Molteno-Jamestown area
- Authors: Mitchell, Andrew Alexander
- Date: 1980
- Subjects: Basalt -- South Africa -- Cape of Good Hope
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4900 , http://hdl.handle.net/10962/d1001559
- Description: The Karoo basalt outliers between Molteno and Jamestown in the north-eastern Cape Province are associated with two central volcanic vent complexes, referred to in the text as the Brosterlea and the Modderfontein complexes. The basalts, particularly those associated with the Brosterlea complex, show geochemical variations throughout the sequence, a factor which has facilitated the subdivision of the Brosterlea basalts into a series of discrete units, each having its own chemical characteristics. Most of the basalt units at Brosterlea can be correlated with units identified in the Barkly East basalt suite. As is the case around Barkly East, the Brosterlea basalt units cannot be related to one another by any simple crystal fractionation or partial melting process, and the most feasible alternative explanation lies in the existence of inhomogeneities in the upper mantle at the time of generation of the magmas. New electron microprobe data are presented for the silicate phases in the Karoo basalts. Analyses of augites from a limited number of slides indicate that pyroxenes from different basalt units define different trends on the Ca - Mg - Fe triangular diagram. The plagioclases in the Brosterlea basalts are fairly Ca-rich (average 70% An), and the K-content of the plagioclases is shown to vary with the K-content of the parent basalt. A comparison of the Karoo Central Province with the younger Columbia River and Deccan Trap Provinces shows many similarities in the evolutionary history of the three provinces. The Karoo Province, however, is distinct from the other two provinces in some aspects of the geochemistry. Broadly speaking, the Karoo basalts are depleted in the incompatible elements relative to the Columbia River and Deccan basalts, and often enriched in the transition metals, most specifically Cr
- Full Text:
- Authors: Mitchell, Andrew Alexander
- Date: 1980
- Subjects: Basalt -- South Africa -- Cape of Good Hope
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4900 , http://hdl.handle.net/10962/d1001559
- Description: The Karoo basalt outliers between Molteno and Jamestown in the north-eastern Cape Province are associated with two central volcanic vent complexes, referred to in the text as the Brosterlea and the Modderfontein complexes. The basalts, particularly those associated with the Brosterlea complex, show geochemical variations throughout the sequence, a factor which has facilitated the subdivision of the Brosterlea basalts into a series of discrete units, each having its own chemical characteristics. Most of the basalt units at Brosterlea can be correlated with units identified in the Barkly East basalt suite. As is the case around Barkly East, the Brosterlea basalt units cannot be related to one another by any simple crystal fractionation or partial melting process, and the most feasible alternative explanation lies in the existence of inhomogeneities in the upper mantle at the time of generation of the magmas. New electron microprobe data are presented for the silicate phases in the Karoo basalts. Analyses of augites from a limited number of slides indicate that pyroxenes from different basalt units define different trends on the Ca - Mg - Fe triangular diagram. The plagioclases in the Brosterlea basalts are fairly Ca-rich (average 70% An), and the K-content of the plagioclases is shown to vary with the K-content of the parent basalt. A comparison of the Karoo Central Province with the younger Columbia River and Deccan Trap Provinces shows many similarities in the evolutionary history of the three provinces. The Karoo Province, however, is distinct from the other two provinces in some aspects of the geochemistry. Broadly speaking, the Karoo basalts are depleted in the incompatible elements relative to the Columbia River and Deccan basalts, and often enriched in the transition metals, most specifically Cr
- Full Text:
A mineralogical investigation of co-existing iron-titanium oxides from various igneous rocks with special reference to some South African titaniferous iron ores
- Authors: Reynolds, Ivan Melvin
- Date: 1979
- Subjects: Igneous rocks Mineralogy
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4926 , http://hdl.handle.net/10962/d1004589
- Description: Part I consists of a detailied review of the available literature on the Fe- Ti oxides and their solid solution relationships. Particular attention is glven to the microstructures exhibited by these oxides and the hypotheses put forward to explain them. These data are synthesised and models are presented in which the microstructural developments in titaniferous magnetites amd ilmenites are explained in terms of current ideas on the influence of oxygen fugacity, exsolution mechanisms and crystal chemistry. These models have direct application to the microintergrowths observed in the naturally occurring Fe-Ti oxides from a wide range of igneous rocks. The available data on the minor and trace element chemistry of the Fe-Ti oxides are reviewed with particular reference to their variation in these minerals from different host rocks. The behaviour of the Fe-Ti oxides during secondary oxidation is discussed with particular reference to the oxidation of titaniferous magnetite and the weathering of ilmenite. The results of a mineralogical investigation into the co-existing Fe-Ti oxides from a range of igneous rocks including kimberlites, gabbros, dolerites, diabases, syenites, granophyres, granites and pegmatites are presented in Part 2 together with data on the ilmenites present in certain Eastern Cape beach sands. The kimberlite ilmenites are chemically distinct and can be readily distinguished on the basis of their relatively high MgO, Fe₂0₃ and Cr₂O₃ contents. They can also be distinguished from ilmenites from other igneous rocks on the basis of unit cell dimensions, d-spacings, reflectivities and micro-indentation hardness. The ilmenites from a wide range of basic to granitic igneous rocks exhibit a limited compositional range in which the MnO content appears to increase with increasing Si0₂ content. Relatively insensitive indirectly determined parameters such as unit cell dimensions, reflectivities and micro-indentation hardnesses cannot be used to distinguish between the ilmenites from the different rock types in these classes. The titaniferous magnetites exhibit progressively decreasing Ti0₂ contents from a maximum in the basic igneous rocks to a minimum in the granitic types. The titaniferous magnetite typically exhibits varying degrees of deuteric alteration, while the microstructures developed can be interpreted 1n terms of the models presented in Part 1. Part 3 represents an extension of Part 2 and deals with a mineralogical investigation of the titaniferous iron ores in five South African basic intrusions. The Bushveld and Kaffirskraal ores consist of multi-phase titaniferous magnetite grains containing crystallographically oriented ilmenite, ulvospinel and pleonaste microintergrowths. Minor coarser-grained ilmenite is also present. The Usushwana ores are texturally similar but contain abundant lamellar ilmenite in place of the ulvospinel. The primary features are well preserved in the unmetamorphosed Bushveld and Kaffirskraal ores. The Usushwana ores have been slightly metamorphosed resulting in the extensive replacement of the titaniferous magnetites by sphene and chlorite aggregates. The ores from these three complexes cannot be beneficiated by conventional ore-dressing techniques and require direct metallurgical treatment for the recovery of Fe, Ti0₂ and V₂O₅. The metamorphosed Mambula and Rooiwater ores have been recrystallised to a varying degrees and consist of multi-phase titaniferous magnetite grains containing modified ilmenite and pleonaste microintergrowths. These modified microstructures differ from those encountered in titaniferous magnetites from unmetnmorphosed basic rocks and their degree of modification can be related to the degree of met amorphism. Variable amounts of coarse granular ilmenite are also present and their development is related to the metamorphic grade and degree of recrystallisation. These ores can be partially beneficiated to yield ilmenite- and lower-Ti0₂ magnetite concentrates in which V₂O₅ contents of the magnetic fractions are higher than those of the original ores. The Trompsburg ores differ from those of the other complexes in that they are Mg-rich and are characterised by the presence of abundant olivine. The titaniferous magnetites typically exhibit well-defined ulvospinel cloth textures and are often surrounded by small amounts of graphite. They show evidence of a variety of extensive late-stage alteration features. The ores from the five investigated complexes are compared with similar ores from the Bushveld Complex. The ores from each complex can be readily distinguished on the basis of their chemical compositions and textural relationships. These features can be related to their crystallisation his tories and, in some cases, to post-crystallisation processes. The microstructural evolution of the ores from each complex is interpreted in terms of the models developed in Part I.
- Full Text:
- Authors: Reynolds, Ivan Melvin
- Date: 1979
- Subjects: Igneous rocks Mineralogy
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4926 , http://hdl.handle.net/10962/d1004589
- Description: Part I consists of a detailied review of the available literature on the Fe- Ti oxides and their solid solution relationships. Particular attention is glven to the microstructures exhibited by these oxides and the hypotheses put forward to explain them. These data are synthesised and models are presented in which the microstructural developments in titaniferous magnetites amd ilmenites are explained in terms of current ideas on the influence of oxygen fugacity, exsolution mechanisms and crystal chemistry. These models have direct application to the microintergrowths observed in the naturally occurring Fe-Ti oxides from a wide range of igneous rocks. The available data on the minor and trace element chemistry of the Fe-Ti oxides are reviewed with particular reference to their variation in these minerals from different host rocks. The behaviour of the Fe-Ti oxides during secondary oxidation is discussed with particular reference to the oxidation of titaniferous magnetite and the weathering of ilmenite. The results of a mineralogical investigation into the co-existing Fe-Ti oxides from a range of igneous rocks including kimberlites, gabbros, dolerites, diabases, syenites, granophyres, granites and pegmatites are presented in Part 2 together with data on the ilmenites present in certain Eastern Cape beach sands. The kimberlite ilmenites are chemically distinct and can be readily distinguished on the basis of their relatively high MgO, Fe₂0₃ and Cr₂O₃ contents. They can also be distinguished from ilmenites from other igneous rocks on the basis of unit cell dimensions, d-spacings, reflectivities and micro-indentation hardness. The ilmenites from a wide range of basic to granitic igneous rocks exhibit a limited compositional range in which the MnO content appears to increase with increasing Si0₂ content. Relatively insensitive indirectly determined parameters such as unit cell dimensions, reflectivities and micro-indentation hardnesses cannot be used to distinguish between the ilmenites from the different rock types in these classes. The titaniferous magnetites exhibit progressively decreasing Ti0₂ contents from a maximum in the basic igneous rocks to a minimum in the granitic types. The titaniferous magnetite typically exhibits varying degrees of deuteric alteration, while the microstructures developed can be interpreted 1n terms of the models presented in Part 1. Part 3 represents an extension of Part 2 and deals with a mineralogical investigation of the titaniferous iron ores in five South African basic intrusions. The Bushveld and Kaffirskraal ores consist of multi-phase titaniferous magnetite grains containing crystallographically oriented ilmenite, ulvospinel and pleonaste microintergrowths. Minor coarser-grained ilmenite is also present. The Usushwana ores are texturally similar but contain abundant lamellar ilmenite in place of the ulvospinel. The primary features are well preserved in the unmetamorphosed Bushveld and Kaffirskraal ores. The Usushwana ores have been slightly metamorphosed resulting in the extensive replacement of the titaniferous magnetites by sphene and chlorite aggregates. The ores from these three complexes cannot be beneficiated by conventional ore-dressing techniques and require direct metallurgical treatment for the recovery of Fe, Ti0₂ and V₂O₅. The metamorphosed Mambula and Rooiwater ores have been recrystallised to a varying degrees and consist of multi-phase titaniferous magnetite grains containing modified ilmenite and pleonaste microintergrowths. These modified microstructures differ from those encountered in titaniferous magnetites from unmetnmorphosed basic rocks and their degree of modification can be related to the degree of met amorphism. Variable amounts of coarse granular ilmenite are also present and their development is related to the metamorphic grade and degree of recrystallisation. These ores can be partially beneficiated to yield ilmenite- and lower-Ti0₂ magnetite concentrates in which V₂O₅ contents of the magnetic fractions are higher than those of the original ores. The Trompsburg ores differ from those of the other complexes in that they are Mg-rich and are characterised by the presence of abundant olivine. The titaniferous magnetites typically exhibit well-defined ulvospinel cloth textures and are often surrounded by small amounts of graphite. They show evidence of a variety of extensive late-stage alteration features. The ores from the five investigated complexes are compared with similar ores from the Bushveld Complex. The ores from each complex can be readily distinguished on the basis of their chemical compositions and textural relationships. These features can be related to their crystallisation his tories and, in some cases, to post-crystallisation processes. The microstructural evolution of the ores from each complex is interpreted in terms of the models developed in Part I.
- Full Text:
The Aapiesboomen magnesite deposit, Burgersfort, Transvaal
- Authors: Taylor, N C
- Date: 1974
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:21130 , http://hdl.handle.net/10962/6505
- Description: The published literature on magnesite is extensively reviewed as regards the properties, uses, production, occurrence and genesis of the mineral. Despite opposition from the producers of sea water magnesia in recent years, magnesite still finds a ready market for the manufacture of refractory materials, particularly in the steel industry. Less important uses include the manufacture of magnesium metal, carbonic acid gas, Sorel cement, paper, pharmaceuticals and fertilizers. Large bodies of cryptocrystalline magnesite occur in Greece, Yugoslavia, Turkey and India, while the deposits in Austria, Czechoslovakia, Russia and China produce most of the world supply of crystalline material. Four types of magnesite bodies may be distinguished: quartz-magnesite deposits, talc-magnesite occurrences, magnesite associated with sedimentary rocks and sagvandite, a magnesite-bronzite rock. Most South African deposits, including the Aapiesboomen body, belong to the first type. Experimental, field and textural evidence indicates that the quartz-magnesite deposits may form from serpentine under a wide range of hydrothermal and supergene conditions below about 400°C and between very low and very high concentrations of co2 in the fluid phase. Above 400°C talc is produced at the expense of quartz. Sedimentary magnesite has been observed t o form in present day saline lakes, but the large size of the older crystalline deposits associated with limestones and dolomites has been used as an argument against the use of the same principle to explain the genesis of the latter bodies : much controversy still surrounds the sedimentary-hydrothermal debate concerning their origin. It seems probable thet sagvandites are produced by a process of CO2- metasomatism.
- Full Text:
- Authors: Taylor, N C
- Date: 1974
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:21130 , http://hdl.handle.net/10962/6505
- Description: The published literature on magnesite is extensively reviewed as regards the properties, uses, production, occurrence and genesis of the mineral. Despite opposition from the producers of sea water magnesia in recent years, magnesite still finds a ready market for the manufacture of refractory materials, particularly in the steel industry. Less important uses include the manufacture of magnesium metal, carbonic acid gas, Sorel cement, paper, pharmaceuticals and fertilizers. Large bodies of cryptocrystalline magnesite occur in Greece, Yugoslavia, Turkey and India, while the deposits in Austria, Czechoslovakia, Russia and China produce most of the world supply of crystalline material. Four types of magnesite bodies may be distinguished: quartz-magnesite deposits, talc-magnesite occurrences, magnesite associated with sedimentary rocks and sagvandite, a magnesite-bronzite rock. Most South African deposits, including the Aapiesboomen body, belong to the first type. Experimental, field and textural evidence indicates that the quartz-magnesite deposits may form from serpentine under a wide range of hydrothermal and supergene conditions below about 400°C and between very low and very high concentrations of co2 in the fluid phase. Above 400°C talc is produced at the expense of quartz. Sedimentary magnesite has been observed t o form in present day saline lakes, but the large size of the older crystalline deposits associated with limestones and dolomites has been used as an argument against the use of the same principle to explain the genesis of the latter bodies : much controversy still surrounds the sedimentary-hydrothermal debate concerning their origin. It seems probable thet sagvandites are produced by a process of CO2- metasomatism.
- Full Text:
The geology of a portion of the country between Witvlei and Omitara, South West Africa
- Fey, P
- Authors: Fey, P
- Date: 1972
- Subjects: Petrology -- Namibia , Stratigraphy -- Namibia , Mineralogy -- Namibia , Geology -- Namibia
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5052 , http://hdl.handle.net/10962/d1011821
- Description: A brief account of the location and physical aspects of the region is followed by descriptions of mapping and laboratory techniques employed. Recent ideas on regional stratigraphical correlation in South West Africa are critically reviewed. Strata lying southeast of the farm Losberg 105 have, on the basis of lithology and copper mineralisation, been correlated with the Tsumis Formation. The Hasib Formation, of predominantly marine character, has on structural grounds been excluded from the Damara System. The latter here has a greater thickness than elsewhere in South West Africa, unless isoclinal folding is much more prevalent than has been assumed. The occurrence on Eintracht 118 of a pebble conglomerate, tentatively equated with the Chuos Tillite, makes possible a subdivision of the Damara strata into the various series established in the literature. It has been found possible to differentiate between Kamtsas and Damara quartzites on petrological grounds. Further, it is concluded that the bulk of Hakos carbonate rocks originated as dolomites and have subsequently been dedolomitized to a greater or lesser extent. The area contains both ortho- and para-amphibolites, as well as one occurrence of intrusive granite. Evidence is given for at least three periods of deformation. It is oonsidered that, if the Hosib Formation was involved in a pre-Damara orogenic episode, later folding must have been co-axial with this. Sedimentation and metamorphism are treated in broad outline. There appears to have been a deepening of the basin of deposition from Hasib to Damara times. Cyclicity in sedimentation is evidenced by lithological associations in the Damara strata. The entire area falls into the greenschist facies of regional metamorphism. Superficial deposits include river gravel and, silt, quartzite- and vein quartz-rubble, calcrete and Kalahari sand. The economic geology is described with special reference to the widespread copper mineralisation.
- Full Text:
- Authors: Fey, P
- Date: 1972
- Subjects: Petrology -- Namibia , Stratigraphy -- Namibia , Mineralogy -- Namibia , Geology -- Namibia
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5052 , http://hdl.handle.net/10962/d1011821
- Description: A brief account of the location and physical aspects of the region is followed by descriptions of mapping and laboratory techniques employed. Recent ideas on regional stratigraphical correlation in South West Africa are critically reviewed. Strata lying southeast of the farm Losberg 105 have, on the basis of lithology and copper mineralisation, been correlated with the Tsumis Formation. The Hasib Formation, of predominantly marine character, has on structural grounds been excluded from the Damara System. The latter here has a greater thickness than elsewhere in South West Africa, unless isoclinal folding is much more prevalent than has been assumed. The occurrence on Eintracht 118 of a pebble conglomerate, tentatively equated with the Chuos Tillite, makes possible a subdivision of the Damara strata into the various series established in the literature. It has been found possible to differentiate between Kamtsas and Damara quartzites on petrological grounds. Further, it is concluded that the bulk of Hakos carbonate rocks originated as dolomites and have subsequently been dedolomitized to a greater or lesser extent. The area contains both ortho- and para-amphibolites, as well as one occurrence of intrusive granite. Evidence is given for at least three periods of deformation. It is oonsidered that, if the Hosib Formation was involved in a pre-Damara orogenic episode, later folding must have been co-axial with this. Sedimentation and metamorphism are treated in broad outline. There appears to have been a deepening of the basin of deposition from Hasib to Damara times. Cyclicity in sedimentation is evidenced by lithological associations in the Damara strata. The entire area falls into the greenschist facies of regional metamorphism. Superficial deposits include river gravel and, silt, quartzite- and vein quartz-rubble, calcrete and Kalahari sand. The economic geology is described with special reference to the widespread copper mineralisation.
- Full Text:
The Birds' River dolerite complex
- Authors: Booth, P W K
- Date: 1971
- Subjects: Diabase , Diabase -- South Africa -- Cape of Good Hope -- Dordrecht. , Igneous rocks -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5043 , http://hdl.handle.net/10962/d1007664 , Diabase , Diabase -- South Africa -- Cape of Good Hope -- Dordrecht. , Igneous rocks -- South Africa
- Description: A plug-like intrusion of Karroo dolerite, near Dordrecht in the Eastern Cape of the Republic, is described. Field mapping with the, aid of aerial photographs has revealed that the contact of the intrusion, for the most part, dips very steeply outwards. In the south- eastern and eastern areas, however, sheet- or sill-like forms appear to be given off from the main intrusion. In plan view the intrusion is roughly oval shaped, its longer axis being aligned in a north-westerly direction. Its surface area measures approximately 60 square kilometres (24 square miles). A large number of xenoliths composed exclusively of Stormberg sediments, pyroclastic rocks and minor lavas, are to be found cropping out within the dolerite intrusion. These xenoliths, many of which occur in positions far above or below their normal stratigraphic elevation, are extremely variable in size - the largest having an area of approximately 15 square kilometres (6 square miles). The xenoliths represent fragments of the original "roof" of sediments and pyroclastics which have collapsed into and been engulfed by the dolerite magma. This type of dolerite intrusion is known as a "belljar" intrusion. A superficial classification of the dolerites, based chiefly on textural and certain mineralogical features, is presented. In the area surrounding the main intrusion are a number of dolerite dikes and sheets. The youngest phase of igneous activity is represented by the Dragon's Back dike, which cuts across the complex in a north-westerly direction. Several veining phenomena, as well as an interesting variety of metamorphic and metasomatic rocks, are associated with the main dolerite intrusion. Six diatremes are situated in the vicinity of the intrusion. Pyroclastic rocks are represented by a variety of types, and are to be found outside the area of the intrusion, and as xenoliths within it. A tentative interpretation of the mechanism of formation of the intrusion, which appears to be related to volcanic activity and cauldron subsidence, is presented.
- Full Text:
- Authors: Booth, P W K
- Date: 1971
- Subjects: Diabase , Diabase -- South Africa -- Cape of Good Hope -- Dordrecht. , Igneous rocks -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5043 , http://hdl.handle.net/10962/d1007664 , Diabase , Diabase -- South Africa -- Cape of Good Hope -- Dordrecht. , Igneous rocks -- South Africa
- Description: A plug-like intrusion of Karroo dolerite, near Dordrecht in the Eastern Cape of the Republic, is described. Field mapping with the, aid of aerial photographs has revealed that the contact of the intrusion, for the most part, dips very steeply outwards. In the south- eastern and eastern areas, however, sheet- or sill-like forms appear to be given off from the main intrusion. In plan view the intrusion is roughly oval shaped, its longer axis being aligned in a north-westerly direction. Its surface area measures approximately 60 square kilometres (24 square miles). A large number of xenoliths composed exclusively of Stormberg sediments, pyroclastic rocks and minor lavas, are to be found cropping out within the dolerite intrusion. These xenoliths, many of which occur in positions far above or below their normal stratigraphic elevation, are extremely variable in size - the largest having an area of approximately 15 square kilometres (6 square miles). The xenoliths represent fragments of the original "roof" of sediments and pyroclastics which have collapsed into and been engulfed by the dolerite magma. This type of dolerite intrusion is known as a "belljar" intrusion. A superficial classification of the dolerites, based chiefly on textural and certain mineralogical features, is presented. In the area surrounding the main intrusion are a number of dolerite dikes and sheets. The youngest phase of igneous activity is represented by the Dragon's Back dike, which cuts across the complex in a north-westerly direction. Several veining phenomena, as well as an interesting variety of metamorphic and metasomatic rocks, are associated with the main dolerite intrusion. Six diatremes are situated in the vicinity of the intrusion. Pyroclastic rocks are represented by a variety of types, and are to be found outside the area of the intrusion, and as xenoliths within it. A tentative interpretation of the mechanism of formation of the intrusion, which appears to be related to volcanic activity and cauldron subsidence, is presented.
- Full Text:
The geology of a portion of north-western Albany
- Authors: Wright, Alexander Ross
- Date: 1969
- Subjects: Geology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5068 , http://hdl.handle.net/10962/d1013440
- Description: [Introduction] During 1965 the author, in looking for a project for a thesis to be submitted for the degree of Master of Science in Geology, decided to map a suitable region in order to gain experience in geological field work. The exact nature of the region itself was of no great importance, but since this study was to be conducted through Rhodes University, it was decided that an area, as near to Grahamstown as possible, would be the most suitable. With this in view, the geologist in charge of the Grahamstown Office of the Geological Survey was invited to suggest an area suitable for study, and if possible, to obtain financial assistance. He indicated the region which has been mapped and which will eventually form part of the proposed sheet 143. It is immediately adjacent to, and to the west of the 1:125,000 sheet 136 of Grahamstown completed by Mountain in 1940.
- Full Text:
- Authors: Wright, Alexander Ross
- Date: 1969
- Subjects: Geology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5068 , http://hdl.handle.net/10962/d1013440
- Description: [Introduction] During 1965 the author, in looking for a project for a thesis to be submitted for the degree of Master of Science in Geology, decided to map a suitable region in order to gain experience in geological field work. The exact nature of the region itself was of no great importance, but since this study was to be conducted through Rhodes University, it was decided that an area, as near to Grahamstown as possible, would be the most suitable. With this in view, the geologist in charge of the Grahamstown Office of the Geological Survey was invited to suggest an area suitable for study, and if possible, to obtain financial assistance. He indicated the region which has been mapped and which will eventually form part of the proposed sheet 143. It is immediately adjacent to, and to the west of the 1:125,000 sheet 136 of Grahamstown completed by Mountain in 1940.
- Full Text:
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