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The utilization of tilting-filter photometry in airglow and auroral research

  • Authors: Dore, Ian Stuart
  • Date: 1992
  • Subjects: Photometry -- Research , Airglow -- Research , Auroras -- Research , Auroral photography -- Research
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5494 , http://hdl.handle.net/10962/d1005280 , Photometry -- Research , Airglow -- Research , Auroras -- Research , Auroral photography -- Research
  • Description: This thesis describes the application of tilting-filter photometry to the study of the airglow and aurora. Previous South African photometric research is reviewed. Optical instrumentation and techniques used in airglow and auroral research are reviewed. The transmission characteristics of narrowband interference filters are discussed. The analogue meridian-scanning tilting-filter photometry system used at Sanae, Antarctica is described. Shortcomings of this system have been identified, and modifications have been made to improve its spatial and temporal resolution. Details are given of the computer-controlled digital photometry system which replaced the analogue system. Equations are derived for the conversion of raw photometric data (analogue chart deflections or digital photon counts) to absolute emission intensities. The accuracy of the intensities obtained depends on the absolute calibration of the photometer, the transmission characteristics of the filter used to isolate the spectral feature of interest, and the effects of atmospheric extinction and scattering. The influence of these factors on observed emission intensities is discussed. Various models used to determine atmospheric correction factors are reviewed. It is shown that atmospheric correction factors can have a significant effect on both emission intensities and intensity ratios. The procedure used to determine the transmission characteristics of interference filters is described, as is the procedure used to cross-calibrate secondary light sources. The transmission characteristics of the filters and the brightnesses of the light sources were both found to have changed appreciably with age. The observation of a magnetospheric substorm at Sanae (L ≃ 4) is used to illustrate the use of a meridian-scanning tilting-filter photometer system in auroral research. The ratio I(557.7)/ I(391.4) observed at Sanae was found to be lower than expected, as were the OJ airglow emission intensities. A prototype digital photometer system was used aboard a ship, to observe the airglow in the region of the South Atlantic Anomaly. Significant N₂⁺ lNG emissions at 391.4 nm were measured, confirming the presence of discernable particle precipitation in the region. The 0I557.7 and 630.0 nm intensities measured from the ship were found to be lower than expected. This, combined with low airglow and auroral intensities measured at Sanae, is a cause for concern. It is recommended that further checks be made regarding the brightness of the calibration sources.
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  • Date Issued: 1992

Computer control of a barry research chirpsounder

  • Authors: Evans, Geoffrey Philip
  • Date: 1985
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5507 , http://hdl.handle.net/10962/d1007495
  • Description: This thesis describes the design and development of a computer-based controller together with additional hardware that greatly extends the capabilities of a Barry Research VOS-1 Chirpsounder. The measurement of the virtual height of the ionosphere as a function of frequency using pulse- and frequency-modulated carrier wave (FMCW techniques is described and the concept of the so called "digital" ionosonde is introduced. The modifications required for the standard Chirpsounder to perform as a versatile digital chirp ionosonde are discussed. Simplified block diagrams are used to describe the Controller hardware which is fully described in two comprehensive service manuals which have been included as appendices. Important aspects of the Controller software and data storage formats are described in detail. The emphasis is then placed on system capabilities. An operators' software manual which describes system initialization and operation in terms of system commands is included as an appendix. Results of tests at both Grahamstown, South Africa , and at the SANAE base in the Antarctic are presented.
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  • Date Issued: 1985

Advanced ionospheric chirpsounding

  • Authors: Poole, Allon William Victor
  • Date: 1984
  • Subjects: Ionospheric sounds Ionosphere -- Research
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:5446 , http://hdl.handle.net/10962/d1001999
  • Description: This dissertation reports research into the theory and practical application of linear frequency modulated ionospheric sounding, as an alternative to the more usual technique of pulse modulation. A comparison of this technique with that of conventional pulse sounders is given, based on the concepts of matched filters and ambiguity functions for both modulations. A theory is developed to relate the group range and phase velocity of the ionospheric target to the phase and frequency of the difference signal at the receiver output. A method is then described whereby the group range and phase velocity of the reflection point as well as the amplitude, arrival angle and polarisation mode of the reflected energy can be measured. A description of the implementation of the technique is given together with some initial results. Finally, some suggestions for improvements are given
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  • Date Issued: 1984

A real time Fast Fourier Transform analyser

  • Authors: Fisher, John Stanley
  • Date: 1980
  • Subjects: Fourier transformations Ionosondes Algorithms Computer simulation
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5439 , http://hdl.handle.net/10962/d1001992
  • Description: From the requirements of the Ionosonde digitisation project, undertaken by Rhodes University Antarctic Research Group, it was decided to use the Fast Fourier Transform to compute the spectrum analysis. Several FFT algorithms are reviewed and properties discussed, and the Ccoley Tukey algorithm chosen for utilization. The hardware implementation of this algorithm, and the microprogram control of the whole system are discussed in detail, and such design aspects that required computer simulation are also treated in detail. The final testing of the analyser is shown, and includes a test using data from an ionosonde sounding. The conclusions contain details of extensions to the analysers present operation, required by plans to place the whole Chirpsounder under microprocessor control
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  • Date Issued: 1980

Oblique incidence investigations of the ionosphere over the Southern Ocean

  • Authors: Rash, Jonathan Paul Stuart
  • Date: 1979
  • Subjects: Ionosphere Ionosphere -- Antartctic Ocean
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:5438 , http://hdl.handle.net/10962/d1001991
  • Description: The region of the South Atlantic and Southern Oceans ... is of considerable interest in ionospheric and aeronomic research owing to the presence of several 'anomalies'. The most notable of these is the South Atlantic (or Brazilian) Anomaly associated with the global minimum of magnetic field intensity off the coast of Brazil (Introduction, p. 1)
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  • Date Issued: 1979

The development of an improved coded-pulse, vertical-incidence ionosonde

  • Authors: Cretchley, Brian Brind
  • Date: 1979
  • Subjects: Ionosondes Ionospheric sounds Computer simulation
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5436 , http://hdl.handle.net/10962/d1001989
  • Description: This thesis describes the theoretical development of a new ionospheric sounding system. The different types of ionosonde, their prime objectives, and their relative merits and demerits are discussed. The various types of code and their correlation functions are described. The essential requirements of the new system are listed, and suitable codes are found for it. Computer calculations and mathematical derivations demonstrate the (theoretical) suitability of these codes under all conditions. Essentials of the mode of operation of the system and details of its design are specified, and computer simulations are used to examine relevant aspects of its operation. Finally, since the construction of the system is not complete and results cannot therefore be presented, the present state of construction of the system is described
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  • Date Issued: 1979

Some properties of magnetospheric electrons observed west of Sanae

  • Authors: Greener, James G
  • Date: 1973
  • Subjects: Magnetosphere
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5523 , http://hdl.handle.net/10962/d1012091 , Magnetosphere
  • Description: The southern hemisphere has always been the neglected twin in the field ot geophysical research. The reasons for this are certainly not in the realm of science but in the history of man and his development in the northern half of the globe. Geophysically, however, our southern half provides a wealth of interesting problems and anomalies. Roederer (1966) explains the use of this word 'anomaly' by showing what some of the oddities of the southern hemisphere are, and by contrasting them with the corresponding regions of the earth across the equator. The principal feature is of course the geomagnetic surface field strength minimum at a point in the South Atlantic ocean very near the coast of Brazil. Intro., p. 1.
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  • Date Issued: 1973

A new model of the IO-Controlled Jovian decametric radiation

  • Authors: Goertz, Christoph K
  • Date: 1972
  • Subjects: Jupiter (Planet) Radiation Magnetosphere Ionosphere
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:5521 , http://hdl.handle.net/10962/d1012043
  • Description: Jupiter, the largest planet in the solar system, is not only an emitter of thermal radiation like any other planet. Jupiter also emits relatively high-intensity non-thermal radiation in two bands, the decimetre wavelength range and the decametre wavelength range (5 MHz< f < 40 MHz). The decimetric radiation is believed to be due to synchrotron radiation of electrons trapped in a kind of Jovian "Van Allen belt". This thesis deals almost exclusively with the decametric radiation. Although the decametric radiation has been observed for 15 years since its discovery by Burke and Franklin in 1955, there is no generally accepted theoretical model of its generation to be found in the literature as yet. This is not surprising, as there are many complex and confusing aspects of the radiation. And since our knowledge of the Jovian ionosphere, magnetosphere and magnetic field is very limited indeed, every theoretical model must be based on some more or less well justified assumptions. It is, however, possible to draw some conclusions from the observed properties of the decimetric and decametric radiation. The radiation in both bands is polarized. It has been shown that at least part of the polarization is an intrinsic property of the radiation source at Jupiter, This indicates the existence of a Jovian magnetic field. The magnitude and shape of the magnetic field, however, is open to discussion, although a dipole field does seem to be a good approximation at least for large distances from Jupiter. Intro. p. 1-2.
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  • Date Issued: 1972

Diurnal and seasonal variations of the F2 region of the Antarctic ionosphere

  • Authors: Williams, Morgan Howard
  • Date: 1972
  • Subjects: Harmonic analysis , Ionosphere -- Antarctic Ocean
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:5548 , http://hdl.handle.net/10962/d1013459
  • Description: [From Introduction, p. 2] The first chapter of this thesis deals with an analysis of F2 critical frequency data first for SANAE and then for eleven other Antarctic and sub-Antarctic stations covering the period 1957 to 1969. This shows certain aspects of the F2 behaviour. Some of the results of this chapter have been reported in a paper by Gledhill and Williams. The two most important mechanisms thought to be responsible for the Antarctic f₀F2 behaviour are incoming corpuscular radiation and horizontal neutral winds. These two mechanisms together with two others (the temperature theory of Torr and Torr and the semi-annual variation of neutral atmospheric density) are discussed in detail in part 2 (Chapters 2 to 4) with a view to discovering which aspects of the f₀F2 behaviour over Antarctica can be explained by each theory. An attempt is made in Part 3 (Chapters 5 and 6) to explain the observed behaviour by solving the continuity equation of the ionosphere for high-latitude stations. Finally, besides the critical frequency, another parameter of importance in explaining the behaviour in the F2 region is the height at which the F2 maximum occurs. This quantity cannot be read directly from an ionogram and it is not an easy quantity to determine. In fact the way in which it is usually obtained is by "scaling" the ionogram in question and converting the virtual heights obtained into real heights. In Part 4 (Chapter 7 and 8) an outline is given of the two computer programs which were written to perform this conversion.
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  • Date Issued: 1972

Theoretical aspects of the generation of radio noise by the planet Jupiter

  • Authors: Deift, Percy A
  • Date: 1972
  • Subjects: Jupiter (Planet) , Radio astronomy , Radio noise
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5516 , http://hdl.handle.net/10962/d1011051 , Jupiter (Planet) , Radio astronomy , Radio noise
  • Description: Decameter radiation was first observed from Jupiter by Burke and Franklin (JGR 60, 213, 1955). In 1964 Bigg (Nature, 203, 1008, (1964)) found that 1o exerted a profound effect on the radiation. The majority of the early theories to explain the origin of the decameter emissions, attributed the radiation to an emission process occurring at or near the electron gyrofrequency or the plasma frequency. Intro., p. 1. The majority of the early theories to explain the origin of the decameter emissions, attributed the radiation to an emission process occurring at or near the electron gyrofrequency or the plasma frequency (for a review see eg. Warwick, Space Sci. Rev. &" 841 (1967)). More recent work centred around the question of how 10 modulates the emission (see the article of Carr and Gulkis (Annual Review of Astronomy and Astrophysics Vol 8 (1970)) for a detailed review).
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  • Date Issued: 1972

A critical analysis of the teaching of fundamental physical concepts and principles, with particular reference to South African schools

  • Authors: Helm, Hugh
  • Date: 1970
  • Subjects: Physics -- Study and teaching -- South Africa
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:5541 , http://hdl.handle.net/10962/d1013345
  • Description: From introduction: The main purpose of the present study is to give a detailed critical survey of possible teaching approaches to fundamental physical ooncepts and principles which could reasonably be taught at sohool, and to consider the implications of this survey for the teaching of physical science in South Africa
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  • Date Issued: 1970

An investigation into the decametric radio emission by the planet Jupiter

  • Authors: Gruber, Georg M
  • Date: 1967
  • Subjects: Jupiter (Planet) , Radio astronomy , Radio sources (Astronomy)
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:5545 , http://hdl.handle.net/10962/d1013410
  • Description: From introduction: Jupiter is the largest planet in the solar system. Its distance from the Sun is five times that of the Earth and its mass is nearly two and a half times that of all the other planets added together. Jupiter turns about its own axis rather rapidly, once in just under ten hours, and it completes one revolution about the Sun in just under twelve years. Thus Earth has to pass almost directly between the Sun and Jupiter once every thirteen months. When this happens Jupiter is said to be in "opposition", as its position is then opposite to that of the Sun, when viewed from Earth. Around this time the planet will be most favourably placed for observations, as it is at its closest to Earth and up in the sky for a large part of the night. During the day observations on radio frequencies are more difficult, as the Sun is a source of great interference. Besides being an emitter of thermal electromagnetic radiation, as one would expect, Jupiter also emits two kinds of non-thermal radiation, one in the decimetre wavelength range and the other in the decametre wavelength range. A large number of scientists have worked on the problems of decimetre and decametre radiation. This thesis deals with some aspects of decametre radiation.
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  • Date Issued: 1967

Ultraviolet specular reflectance, electronic absorption and the excitation of fluorescence in single crystals of anthracene

  • Authors: Wright, W H
  • Date: 1966
  • Subjects: Anthracene crystals -- Fluorescence , Ultraviolet spectroscopy -- Absorption , Reflectance
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:5544 , http://hdl.handle.net/10962/d1013366
  • Description: From introduction: The Fluorescence Excitation Spectrum or anthracene is known to vary considerably with the age and condition or the crystal. This thesis represents an attempt to improve the understanding of these variations. To put the problem on a quantitative basis it was found necessary to know both the ultraviolet reflection and absorption spectra. Reports of the reflection spectrum appear to have been confined to the case of polarised incident light. In addition the reflectivity measurements are always reported for a freshly cleaved surface. For these reasons the reflectivity of anthracene for various conditions of the reflecting surface was measured with unpolarised light. These varying reflectivities were used to further knowledge of the chemical processes at the crystal surface, as well as being used directly in the calculation of fluorescence excitation spectra. Reflection spectra with a- and b- crystallographic axis polarisations were also obtained. Since such spectra are reported in the literature it was possible, by comparison, to conclude that the experimental methods used in this thesis yielded valid results. The polarised measurements were used to obtain optical constants for the crystal. In the interests of readability most of the complicated process of converting the reflectivities to optical constants is dealt with in three appendices to the thesis.
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  • Date Issued: 1966

Some ionospheric effects observed at sunrise

  • Authors: Baker, D C
  • Date: 1964
  • Subjects: Sun -- Rising and setting , Ionosphere -- Research
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5513 , http://hdl.handle.net/10962/d1009496 , Sun -- Rising and setting , Ionosphere -- Research
  • Description: The study of the ionosphere over the sunrise period is necessary for an understanding of the vtiriations in layer structure with time and has been a topic of research of many workers. On the whole these investigations have been restricted to a study of critical frequency variations with relatively short intervals of a few minutes between successive records, of N-h curves deduced from ionograms with long intervals (15 minutes or so) between successive N-h curves or of continuously monitored single frequency reflections. Not one of the three techniques is entirely satisfactory for a detailed study of ionospheric behaviour over sunrise. The first two do not give a sufficiently clear indication of what happens in the initial stages of layer development, while from the third incomplete data is obtained as to what is happening at a specific electron-density level. For this reason a preliminary investigation of the ionosphere over sunrise was made at Rhodes University during August, 1959. The records were obtained at four-and-a-half minute intervals and scaled by the method of KELSO (1952 ). "Many of t he results were inconclusive but it appeared that records would have to be taken at approximately one minute intervals and reduced to N-h curves by a scaling technique which made full allowance for low-level ionization if useful results were to be obtained. An attempt has been made in this thesis to investigate the behaviour of the ionosphere over sunrise more fully than can be done by the three techniques referred to. A number of observed phenomena are also examined. Part I deals with the theoretical background to ionosphere physics in general and describes the equipment, equipment modifications and experimental procedure. Part II presents the results obtained. The records for a largescale travelling disturbance are analysed. Various observed phenomena are described and discussed. A simple method of obtaining production rates from experimental data is described. The implications of the observed variations of production rates with height and time are discussed. Suggestions for further research and improvement of the methods used arc made in Charter 9.
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  • Date Issued: 1964

The South Atlantic radiation anomaly

  • Authors: Van Rooyen, H O
  • Date: 1964
  • Subjects: Terrestrial radiation , Atmospheric radiation , Geomagnetism , Electron precipitation , South Atlantic Ocean -- Radiation
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5546 , http://hdl.handle.net/10962/d1013427
  • Description: Part I. (1) An elementary treatment of the motion of charged particles in a magnetic field is presented. The concept of guiding centre motion is introduced, and is used in outlining the theory of particle drifts. (2 ) The motion of charged particles in the geomagnetic field is discussed, and the concept of adiabatic invariance introduced. (3) Mc Iliwains coordinates for mapping the distribution of charged particles trapped in the geometric field are defined and briefly discussed. (4) A survey of present knowledge of the Van Allen radiation zones is made. Particular attention is given to the distribution, characteristics, and variability of the trapped radiation. (5) The Cape Town magnetic anomaly, the Brazil radiation anomaly and the South Atlantic radiation anomaly are discussed. The electrons entering the South Atlantic radiation anomaly are shown to be those monitored over Iowa by the US satellite Injun I. Part 11. (1) It is shown how the geomagnetic field can, at high altitudes and over relatively short distances, be approximated by the field of a monopole. A new method is developed which enables one to plot the energy absorbed from an electron (which moves in a monopole field in the atmosphere) against altitude, given the initial energy and pitch angle of the electron. Some numerical computations using this method are described, and the results discussed. These results are used, in conjunction with US satellite Injun I for the Iowa region, to estimate the energy inout to the atmosphere in the South Atlantic radiation anomaly. The main approximations and simplifying assumptions made in this treatment, are discussed. (2) Geophysical effects generally recognized to be connected with the precipitation of charged particles are discussed. In the course of this discussion the two main theories of the connection between the radiation zones and the auroras are examined. (3) A preliminary discussion, based on the work summarized in point (1) of detectable geophysical events associated with the precipitation of electrons into the South Atlantic radiation anomaly is given. It is concluded that auroral emission, X-ray bursts, and ionospheric ionization in the E region should be more frequent and pronounced in the South Atlantic radiation anomaly than in any other region of comparable invariant latitudes and that the effects of atmospheric heating by precipitated electrons should be detectable over the anomaly. (4) An assessment is made of the value of the method referred to in point (1). Suggestions for its modification and extension are put forward. It is suggested that if more extensive rocket and satellite data on the low energy component of the electron flux become available, this method can be employed in a rigorous theoretical investigation of the South Atlantic radiation anomaly. Summary, p. 98-100.
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  • Date Issued: 1964

Some properties of a model F1 layer of the ionosphere

  • Authors: De Jager, Gerhard
  • Date: 1963
  • Subjects: Ionosphere , Ionospheric electron density
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5515 , http://hdl.handle.net/10962/d1011046 , Ionosphere , Ionospheric electron density
  • Description: The present work was initially aimed at providing an explanation for some of the phenomena that occur in the ionosphere at sunrise. The approach that was taken was to determine the changes that take place on a theoretical model of the ionosphere and then to compare these with observations. A prerequisite for this approach was a theoretical model that would show, among other things, a bifurcation of the F layer during daytime without making unjustified arbitrary assumptions. The absence of such a model, particularly as far as non-equilibrium conditions are concerned, resulted in the present attempt to provide such a model for the F1 region.
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  • Date Issued: 1963

Construction of a wide-frequency range double heterodyne conductance bridge and its use in the investigation of polarisation errors in conductance measurements

  • Authors: Govinden, Herby Silvester
  • Date: 1961
  • Subjects: Electrodynamics Electrolytes -- Conductivity
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:5522 , http://hdl.handle.net/10962/d1012074
  • Description: (1) Developments in a.c. conductance techniques during the past ninety years have been reviewed, and a brief outline is given of the older theories regarding electrolytic polarisation. (2) A conductance bridge - incorporating the double heterodyne principle - has been constructed, capable of giving resistance readings to an accuracy of 0.01% over a range of frequencies covering the best part of 100 kc/s. It has also been found possible to calibrate the oscillator so that frequency settings can be guaranteed to an accuracy of , at least, 0.1% in the range: 2 kc/S to 50 kc/S. (3) The Wheatstone Bridge Network has been slightly modified to enable measurements at the high frequencies. (4) Resistances in the measuring arm of the bridge have been calibrated 'in situ' by the method of intercomparison. (5) A brief description is given of the modern theories regarding electrode processes and modern methods of eliminating electrode effects. (6) Two types of conductance cells, with bright Pt electrodes, have been used to carry out measurements on potassium chloride solutions: (a) Thomas- Gledhill Cell (b) Nichol-Fuoss Cell. The latter incorporates concentric, cylindrical electrodes with the lead to the outer electrode acting as an electrical shield for the lead to the inner electrode. This cell was constructed and used for the first time in this laboratory. (7) From resistance-frequency graphs plotted, it is shown that the Jones and Christian extrapolation procedure cannot be applied (with any degree of confidence) to obtain the true resistance, when measurements are effected over an extended range of frequencies. (8) The method of resistance-reactance diagrams is discussed and applied to various networks of resistances and capacitances. (9) By drawing resistance-reactance diagrams for the experimental readings obtained, equivalent circuits have been derived - for all the solutions investigated in the N-F cell, and for the approx. O.OlD solution in the T-G cell - which approximate to cell behaviour in the range: 500 c/s to 75 kc/s. The less concentrated solutions in the T-G cell show peculiar behaviour at the high frequencies. (10) Probable reasons are advanced for deviations from linearity on resistance-frequency graphs. (11) A new method is proposed for determining the true resistance of solutions measured in cells of the N-F type. Summary, p. 166-167.
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  • Date Issued: 1961

Ionospheric studies of the solar eclipse 25 December, 1954

  • Authors: McElhinny, M W
  • Date: 1959
  • Subjects: Ionosphere -- Research , Solar eclipses
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:5531 , http://hdl.handle.net/10962/d1012869
  • Description: Since the Kennelly- Heaviside hypothesis in 1902 of the existence of a partially conducting layer in the upper atmosphere was proved to be true by the experiments of APPLETON and BARNETT (1925) and BREIT and TUVE (1926), this region has become known as the ionosphere. The ionosphere was soon discovered to consist of, not one but several layers (Fig. 1) (i) A layer at a height of just over 100 km. called the E layer. (ii) A layer at a height of approximately 300km. called the F₂ layer. (iii) A layer at a height of approximately 200 km. called the F₁ layer; this layer differs from the other two in that it is only present during the day time in Summer. (iv) Occasional intense reflections from a height of about 100 km. are found - these cannot be attributed to the normal E layer and have received the name "Sporadic E". The presence of two E layers (E₁ and E₂) has been suggested by HALLIDAY (1936) and BEST and RATCLIFFE (l978) but until recently most workers still seem to attribute these reflections to Sporadic E. Recent measurement by rockets of the electron density at E layer heights still do not confirm whether such bifurcation exists in the E region. The diurnal and seasonal variations of the first three layers indicate that the sun is the chief agent in their production. It is generally agreed that these layers consist of ionised molecules or atoms and free electrons produced by radiation from the sun. The origin of Sporadic E ionisation is still obscure, but it is thought that these sudden increases in ionisation which occur in E layer heights are due to passing meteors. Recently it has also been suggested by SEDDON, PICKAR and JACKSON (1954) from rocket measurements that Sporadic E might be due to a steep electron density gradient above the B layer.
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  • Date Issued: 1959

A conductimetric investigation of phenomena in extremely dilute aqueous solutions

  • Authors: Faure, Pierre Knobel
  • Date: 1957
  • Subjects: Adsorption , Solution (Chemistry)
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:4524 , http://hdl.handle.net/10962/d1014891
  • Description: 1. The apparatus used in this investigation is fully described, and a new method is outlined for the calibration of bridge resistances "in situ". 2. A chart is given for the accurate correction of weights in air to weights in vacuum for a range of temperatures extending from 10° to 28°C, and for pressures from 690 to 730 mm. 3. An automatic recycling still has been designed for the continuous production of "ultra-pure" water. This still is capable of delivering daily, in routine operation, 16 l. of water of conductivity less than 100 nm/cm after aeration with "C0₂- and NH₃-free" air. 4. A very soluble layer appears to form on the surface of' glass when it is dried; this layer is readily removed on contact with water. 5. The removal of carbon dioxide and of ammonia from aqueous solution by aeration with an indifferent gas has been fully investigated, and it has been shown that these gases can be completely eliminated by such a process. Whereas the carbon dioxide is removed fairly rapidly, however, the ammonia, whether present alone or together with carbon dioxide, only goes out of solution rather slowly. 6. It has been shown that ammonia is adsorbed from aqueous solution on the glass walls of the cell. 7. There does not appear to be any ammonium bicarbonate in the residual impurity left in the "ultra-pure" water obtained from the still; the impurity can, in fact, be regarded as neutral salt with sufficient accuracy for most purposes. 8. The resistance change which accompanies any variation in the rate of bubbling of the stirring gas through the water has been investigated, but no solution has been found as to the cause of this change. 9. A comparison has been made of the efficiency of different gases for stirring purposes, and it seems that, for general work, nitrogen is by far the most suitable of the common gases. 10. The extrapolation to be used for converting resistances to their values at infinite frequency appears ...
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  • Date Issued: 1957

Measurements of the solubilities of some silver halides in water by electrical methods

  • Authors: Malan, George McPherson
  • Date: 1955
  • Subjects: Silver halides -- Solubility , Silver halides -- Analysis , Conductometric analysis , Potentiometry , Silver halides
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:4515 , http://hdl.handle.net/10962/d1013502
  • Description: [Introduction, p. 3] The solubilities of the silver halides cannot be determined by the conventional methods of analytical chemistry because they are too sparingly soluble (of the order 1 x 10⁻⁵ to 1 x 10⁻⁶ g . equiv./1. at 25°C.) However, electrical, and to a lesser extent optical methods, are admirably suited because of their greater sensitivity. The conductometric and potentiometric methods are the two most important electrical techniques for the measurement of the solubilities of sparingly soluble salts, and are the ones employed in this research. There are large discrepancies between the published values for the solubility of silver chloride. Results obtained by the conductometric and potentiometric methods disagree. In addition, figures quoted by independent authors using the same method differ by as much as 15%.
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  • Date Issued: 1955
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