The sorption of Hydrochloric Acid and Potassium Hydroxide by mohair and wool
- Authors: Bamford, Graeme Reginald Ernest
- Date: 1959
- Subjects: Hydrochloric acid -- Absorption and adsorption , Hydroxides -- Absorption and adsorption , Wool , Mohair
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4452 , http://hdl.handle.net/10962/d1009503
- Description: The main object of the present investigation has been to establish a titration curve for mohair keratin and to compare it with similar data for wool, to determine whether the differences in physical and chemical properties could be attributed in any way to the acidic and basic character of these fibres. As shown in subsequent discussion such measurements provide extremely useful information regarding the chemical structure of proteins in general, and in the technical fields involving processes such as wool scouring, carbonizing and dyeing. The study has been extended to include certain modified wools, i.e. photochemically damaged, and oxidized keratin. The most successful contribution to the titration data of wool keratin is the work of Steinhardt and Harris and subsequent authors have tended to adopt their procedures without modification. In the present study attempts have been made to obtain a clearer understanding of the fundamental processes. New techniques and analytical methods have been introduced to improve the accuracy of the measurements.
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- Date Issued: 1959
Synthetic ion exchange resins, incorporating asymmetric groups, as resolving agents
- Authors: O'Sullivan, Diarmid John
- Date: 1958
- Subjects: Ion exchange resins -- Synthesis
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4485 , http://hdl.handle.net/10962/d1012991
- Description: The object of this research is to further investigate the possiblitiy of resolving racemic bases on an optically active cation exchange resin. Any success in this direction would help to explain the reason for Bunnett and Mark's failure, since the general assumption that selective adsorption of one enantimorph of a racemic compound on an active exchanger should occur has been verified by Grubhofer and Schleith. The work can be conveniently divided into two sections. a) The preparation of optically active cation exchange resins and, b) the use of these as resolving agents. P. 8
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- Date Issued: 1958