Geochemical exploration in tropical terrains with special reference to base metals
- Authors: Chiconela, Domingos Rubão
- Date: 1996
- Subjects: Geochemical prospecting -- Research -- Tropics , Geological mapping -- Research -- Tropics , Weathering -- Research -- Tropics , Geochemistry -- Research
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4953 , http://hdl.handle.net/10962/d1005565 , Geochemical prospecting -- Research -- Tropics , Geological mapping -- Research -- Tropics , Weathering -- Research -- Tropics , Geochemistry -- Research
- Description: In tropical areas, the high rainfall induces severe-and pervasive weathering, producing a thick soil cover. The lithologies underneath may b~ recognised using geochemical mapping, which is based on certain elements that have the ability to differentiate between various lithologic units. Elements that are independent of the weathering process are normally selected for this purpose. The chemistry of mobility of base metals is an important factor to take into account when evaluating the mobility and distribution of these elements in a soil profile. Factors such as pH, Eh, organic material, clay minerals, Fe and Mn oxides are normally key aspects to be considered. When iron-rich rocks undergo deep weathering, lateritic profiles are developed. These are widespread in a belt bordering the equatorial zone, including the Brazilian shield, West and East Africa, parts of India and Northern Australia. In these profiles, the high rainfall promotes intense leaching of the different horizons. Where the pre-existing profiles are mostly preserved, the base metals are distributed throughout the profile: in the upper ferruginous horizon, goethite and hematite can adsorb large amounts of Mo, resulting in large dispersion halo. Other base metals such as Cu and Zn are less resistant in these freely-drained profiles and, therefore, they may be partly leached from the profile. In the lower horizons, Cu, ,zn, Ni and Co are retained, hosted in kaolinite and smectite, and thus, a high geochemical contrast will be identified in this horizon at the expense of a decline in the size of the dispersion haloes. The pre-existing profiles can be truncated, with a thin stone line developing at the contact between the lateritic profile and the recent soil. The conditions in these environments favour the retention of most of the pathfinder and target elements in all soil horizons, with the B horizon showing the highest contrast. If the primary rock is rich in AI, a bauxitic profile will be developed. The world distribution of bauxites closely resembles that of laterites. The behaviour of Co and Ni is very similar to that of iron during the bauxitization. Furthermore, the factors that induce residual enrichment of Al with removal of Fe in the soil profile will cause significant depletion of Co and Ni in these profiles. These metals are then concentrated at the base of the profile because of precipitation from downward percolating solutions. Many karst bauxite deposits in Southern Europe are enriched with Ni and Co in the basal horizon. Such horizon is mined as nickel ore in the bauxites of the Lokris region in Greece. Copper and molybdenum are strongly enriched.in bauxitic profiles. Concentration ratios are 8 and 3.2 for Cu and Mo respectively. Molybdenum is closely related to goethite and hematite, and therefore, the high concentration of Mo in a bauxitic profile will be consistent with the horizon where iron is concentrated. Copper concentrates at the base of the iron rich-horizon but also appears enriched in the saprolite together with Co. When sulphide bodies occur, in this environment, deep and penetrative weathering has resulted in considerable near-surface mobilization of iron and silica. The supergene alteration commonly obscures the identity of the primary sulphides at the surface. In this case, geochemical assessment of the resulting gossan has proved to be crucial in mineral exploration. A search in the secondary mineral assemblage, volatile and precious metals may lead to the information on the composition of the primary sulphide assemblage. The conclusion that will be reached is that if the geochemical properties (mobility, affinities with Fe or Mn oxides and/or clay minerals) of each of the base metals are understood, an appropriate sampling (optimum size-depth combination) will then be done. In such cases, a subdued, weak, but significant, geochemical response will be identified in the surface horizon.
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- Date Issued: 1996
The metallogeny of the Upington and Kenhardt area, northern Cape
- Authors: Boelema, Robert
- Date: 1995
- Subjects: Metallogeny -- South Africa , Metallogeny -- South Africa -- Northern Cape , Plate tectonics -- South Africa -- Northern Cape , Geology, Structural -- South Africa -- Northern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4975 , http://hdl.handle.net/10962/d1005587 , Metallogeny -- South Africa , Metallogeny -- South Africa -- Northern Cape , Plate tectonics -- South Africa -- Northern Cape , Geology, Structural -- South Africa -- Northern Cape
- Description: In the Upington region, there are three major- tectonic crustal provinces; namely the Kaapvaal Craton, Kheis and Namaqua tectonic provinces. The Eburnian-aged (early Proterozoic) Kheis Province developed along the western flank of the Archaean Kaapvaal Craton while the Kibaran-aged (middle Proterozoic) Namaqua Metamorphic Province, superimposed on the Eburnian-aged basement, developed to the east of the Kheis Province. The Namaqua Metamorphic Province is divided into the Gordonia and Bushmanland Subprovinces, the former being further subdivided into various tectonostratigraphic terranes. These are termed, from west to east, the Kakamas, Areachap, and Upington Terranes. The Upington Terrane includes fault bounded grabens with accompanied bimodal volcanism and sedimentation of the Wilgenhoutsdrif and Koras Groups. The Areachap Terrane consists predominantly of amphibolites generated in an island arc environment while the Kakamas Terrane is characterised by volcano-sedimentary sequences which have been extensively intruded by syn to late-tectonic predominantly I-type Keimoes Suite granitoids. The main styles of mineralisation correlate well with the various tectonostratigraphic terranes. Sedimentary exhalative massive sulphide deposits are characteristic of the Bushmanland Subprovince and are thought to be associated with the deposits at Aggeneys and Putsberg to the west of the area under investigation. These deposits are considered to have been deposited in an east-west-elongated intracontinental basin. The Kakamas Terrane is typified by granite-related mineralisation. In the eastern portion of the Kakamas Terrane, Sn-Wand base metal-bearing veins occur while pegmatites are developed in the western portion. These two styles of granite-related mineralisation is considered to reflect differing depths of formation due mainly to varying degrees of thrusting. The Areachap Terrane consists of volcanogenic massive sulphide deposits of the Besshi-type and is considered to have formed in a back-arc environment. In the Upington Terrane, the Wilgenhoutsdrif and Koras Groups consists essentially of minor Cu occurrences mainly disseminated within basalts and in structural trap sites. The possibility for sediment-hosted Cu deposits is not ruled out. More recent surface processes have led to uranium and gypsum deposits in pans, river beds and calcretes. Eburnian aged tectonic setting remains enigmatic. Kibaran-aged tectonics which best fits the metallogeny of the area under investigation is considered to be of a subduction zone from west to east formed by the collision of the Bushmanland "microcontinent" against the Kaapvaal Craton. Subduction fbrmed an island arc setting in which the massive sulphide deposits were formed in the Areachap Terrane while the Wilgenhoutsdrif Groups developed in a marginal basin. Further convergence led to collision of the two continents and underriding of the Bushmanland "microcontinent" which generated predominantly I-type granitoids represented by the Keimoes Suite. The level of emplacement of these granitoids is a reflection of the degree of foreland thrusting and produced shallower level Sn-W and base metal vein-type mineralisation closer to the suture zone and deeper level pegmatites further from the suture zone to the west. The final period of deformation is represented by northward lateral movement which created "pull apart" fault-bounded basins into which the Koras Group was deposited.
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- Date Issued: 1995
Granitic series and their economic geology
- Authors: Kerber, Paulo Augusto
- Date: 1993
- Subjects: Granite , Geology, Economic
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4969 , http://hdl.handle.net/10962/d1005581 , Granite , Geology, Economic
- Description: The granitic rocks are subdivided into four series: tholeiitic, alkaline, calc-alkaline and mobilizates. These series can be formed from melting of mantle material (M-type granites) or from crustal rocks. There are granitic rocks formed from the mixing of these two magmas types. The rocks formed from crustal anatexis are subdivided into those formed from igneous rocks (I-type granites) and those formed from meta-sedimentary rocks (S-type granites). The former has similar characteristics to the mantle-derived granitoids. The mineral deposits related to igneous or mantle derived magma usually are Cu-Au, CUI Cu-Mo, Mo porphyries and have high oxygen fugacity and magnetic susceptibility (magnetite series). The Sn-W deposits usually are related to magma derived from meta-sedimentary or igneous rocks derived magma with low oxygen fugacity and magnetic susceptibility (ilmenite series). According to the tectonic setting, the granitoids rocks are classified as: Andino type, West Pacific type, Hercyno type, Caledonian type and Anorogenic (A-type granites).
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- Date Issued: 1993
Genetic models for epithermal gold deposits and applications to exploration
- Authors: Veselinović, Milica
- Date: 1992
- Subjects: Gold ores -- Geology , Hydrothermal deposits
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4950 , http://hdl.handle.net/10962/d1005562 , Gold ores -- Geology , Hydrothermal deposits
- Description: Epithermal gold deposits are the product of large-scale hydrothermal systems in tectonically active regions. They form at shallow crustal levels where the physico-chemical conditions change abruptly. Two major groups of epithermal gold deposits can be distinguished based on their genetic connection with: A) Copper-molybdenum porphyry systems and B) Geothermal systems related to volcanic centres and calderas. Epithermal gold deposits connected with geothermal systems encompass three major types: adularia-sericite, acid-sulphate and disseminated replacement (the Carlin-type). Their essential ingredients are: high heat source which leads to convection of groundwater in the upper crust; source of hydrothermal fluid, metals and reduced sulphur; and high-permeability structures which allow fluid convection and metal deposition. Mixing of these ingredients leads to the formation of epithermal gold deposits throughout crustal history, without any restriction on age. The ores were deposited from near-neutral (adularia-sericite type and some of the Carlin-type) to acidic (acid-sulphate type and porphyry-related epithermal gold deposits), low-salinity, high C0₂ and high H₂S fluids, which were predominantly meteoritic in origin. The transport capability of deep fluids in epithermal hydrothermal systems may be shown to be dependent largely on their H₂S content and, through a series of fluid mineral equilibria, on temperature and on C0₂ content. The most common mechanisms of ore deposition are boiling (phase separation), mixing of fluids of different temperatures and salinities, reaction between them and wall rocks, dilution and cooling. An understanding of genetic models for epithermal gold deposits provides the basis for the selection of favourable areas for regional to prospect-scale exploration.
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- Date Issued: 1992