A Comparison Of The Resource Requirements Of Snort And Bro In Production Networks
- Barnett, Richard J, Irwin, Barry V W
- Authors: Barnett, Richard J , Irwin, Barry V W
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430040 , vital:72661 , https://www.iadisportal.org/applied-computing-2009-proceedings
- Description: Intrusion Detection is essential in modern networking. However, with the increas-ing load on modern networks, the resource requirements of NIDS are significant. This paper explores and compares the requirements of Snort and Bro, and finds that Snort is more efficient at processing network traffic than Bro. It also finds that both systems are capable of analysing current network loads on commodity hardware, but may be unable to do so for higher bandwidth networks. This is ben-eficial in a South African context due to the increasing international bandwidth that will come online with the launch of the SEACOM Cable, and local projects such as SANREN.
- Full Text:
- Date Issued: 2009
- Authors: Barnett, Richard J , Irwin, Barry V W
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430040 , vital:72661 , https://www.iadisportal.org/applied-computing-2009-proceedings
- Description: Intrusion Detection is essential in modern networking. However, with the increas-ing load on modern networks, the resource requirements of NIDS are significant. This paper explores and compares the requirements of Snort and Bro, and finds that Snort is more efficient at processing network traffic than Bro. It also finds that both systems are capable of analysing current network loads on commodity hardware, but may be unable to do so for higher bandwidth networks. This is ben-eficial in a South African context due to the increasing international bandwidth that will come online with the launch of the SEACOM Cable, and local projects such as SANREN.
- Full Text:
- Date Issued: 2009
A method for automatically creating 3d animated scenes from annotated fiction text
- Glass, Kevin R, Bangay, Shaun D
- Authors: Glass, Kevin R , Bangay, Shaun D
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/432699 , vital:72893 , https://www.iadisportal.org/ijcsis/papers/2009110208.pdf
- Description: This paper describes a strategy for automatically converting fiction text into 3D animations. It assumes the existence of fiction text annotated with avatar, object, setting, transition and relation annotations, and presents a transformation process that converts annotated text into quantified constraint systems, the solutions to which are used in the population of 3D environments. Constraint solutions are valid over temporal intervals, ensuring that consistent dynamic behaviour is produced. A substantial level of automation is achieved, while providing opportunities for creative manual intervention in animation process. The process is demonstrated using annotated examples drawn from popular fiction text that are converted into animation sequences, confirming that the desired results can be achieved with only high-level human direction.
- Full Text:
- Date Issued: 2009
- Authors: Glass, Kevin R , Bangay, Shaun D
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/432699 , vital:72893 , https://www.iadisportal.org/ijcsis/papers/2009110208.pdf
- Description: This paper describes a strategy for automatically converting fiction text into 3D animations. It assumes the existence of fiction text annotated with avatar, object, setting, transition and relation annotations, and presents a transformation process that converts annotated text into quantified constraint systems, the solutions to which are used in the population of 3D environments. Constraint solutions are valid over temporal intervals, ensuring that consistent dynamic behaviour is produced. A substantial level of automation is achieved, while providing opportunities for creative manual intervention in animation process. The process is demonstrated using annotated examples drawn from popular fiction text that are converted into animation sequences, confirming that the desired results can be achieved with only high-level human direction.
- Full Text:
- Date Issued: 2009
A re-evaluation of morphological differences in the Karoo Thrush Turdus smithi–Olive Thrush Turdus olivaceus species complex
- Wilson, J W, Symes, C T, Brown, M, Bonnevie, Bo T, de Swardt, D H, Hanmer, D
- Authors: Wilson, J W , Symes, C T , Brown, M , Bonnevie, Bo T , de Swardt, D H , Hanmer, D
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/447680 , vital:74666 , https://doi.org/10.2989/OSTRICH.2009.80.3.7.970
- Description: There is confusion in the literature concerning the taxonomic status of the Turdus smithi—T. olivaceus species complex. Here we attempt to clarify morphological differences within this complex. In addition, we attempt to clarify identification of the respective taxa. Although mean measurements of morphometric features differed significantly between species and subspecies, these features are not useful in separating species or subspecies due to considerable overlap in measurements. Furthermore, there were often larger differences between subspecies of T. olivaceus (particularly the geographically isolated T. o. swynnertoni) than between T. olivaceus and T. smithi. We therefore suggest that further work investigates the elevation of T. o. swynnertoni to full species status. Plumage characteristics proved more useful in separating T. olivaceus and T. smithi in the field, except in regions where the distributions overlap (potential hybridisation zones). We highlight the importance of clarifying the delineation of separate species particularly with respect to bird census data (e.g. Southern African Bird Atlas Project 2) and studies related to these species.
- Full Text:
- Date Issued: 2009
- Authors: Wilson, J W , Symes, C T , Brown, M , Bonnevie, Bo T , de Swardt, D H , Hanmer, D
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/447680 , vital:74666 , https://doi.org/10.2989/OSTRICH.2009.80.3.7.970
- Description: There is confusion in the literature concerning the taxonomic status of the Turdus smithi—T. olivaceus species complex. Here we attempt to clarify morphological differences within this complex. In addition, we attempt to clarify identification of the respective taxa. Although mean measurements of morphometric features differed significantly between species and subspecies, these features are not useful in separating species or subspecies due to considerable overlap in measurements. Furthermore, there were often larger differences between subspecies of T. olivaceus (particularly the geographically isolated T. o. swynnertoni) than between T. olivaceus and T. smithi. We therefore suggest that further work investigates the elevation of T. o. swynnertoni to full species status. Plumage characteristics proved more useful in separating T. olivaceus and T. smithi in the field, except in regions where the distributions overlap (potential hybridisation zones). We highlight the importance of clarifying the delineation of separate species particularly with respect to bird census data (e.g. Southern African Bird Atlas Project 2) and studies related to these species.
- Full Text:
- Date Issued: 2009
A tropical/subtropical biogeographic disjunction in southeastern Africa separates two evolutionarily significant units of an estuarine prawn
- Teske, Peter R, Winker, A Henning, McQuaid, Christopher D, Barker, Nigel P
- Authors: Teske, Peter R , Winker, A Henning , McQuaid, Christopher D , Barker, Nigel P
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/445407 , vital:74383 , https://doi.org/10.1007/s00227-009-1168-3
- Description: Recent phylogeographic research has indicated that biodiversity in the sea may be considerably greater than previously thought. However, the majority of phylogeographic studies on marine invertebrates have exclusively used a single locus (mitochondrial DNA), and it is questionable whether the phylogroups identified can be considered distinct species. We tested whether the mtDNA phylogroups of the southern African sandprawn Callianassa kraussi Stebbing (Decapoda: Thalassinidea) are also recovered using nuclear sequence data. Four mtDNA phylogroups were recovered that were each associated with one of South Africa’s four major biogeographic provinces. Three of these were poorly differentiated, but the fourth (tropical) group was highly distinct. The nuclear phylogeny recovered two major clades, one present in the tropical region and the other in the remainder of South Africa. Congruence between mitochondrial and nuclear DNA indicates that the species comprises two Evolutionarily Significant Units sensu Moritz (1994). In conjunction with physiological data from C. kraussi and morphological, ecological and physiological data from other species, this result supports the notion that at least some of the mtDNA phylogroups of coastal invertebrates whose distributions are limited.
- Full Text:
- Date Issued: 2009
- Authors: Teske, Peter R , Winker, A Henning , McQuaid, Christopher D , Barker, Nigel P
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/445407 , vital:74383 , https://doi.org/10.1007/s00227-009-1168-3
- Description: Recent phylogeographic research has indicated that biodiversity in the sea may be considerably greater than previously thought. However, the majority of phylogeographic studies on marine invertebrates have exclusively used a single locus (mitochondrial DNA), and it is questionable whether the phylogroups identified can be considered distinct species. We tested whether the mtDNA phylogroups of the southern African sandprawn Callianassa kraussi Stebbing (Decapoda: Thalassinidea) are also recovered using nuclear sequence data. Four mtDNA phylogroups were recovered that were each associated with one of South Africa’s four major biogeographic provinces. Three of these were poorly differentiated, but the fourth (tropical) group was highly distinct. The nuclear phylogeny recovered two major clades, one present in the tropical region and the other in the remainder of South Africa. Congruence between mitochondrial and nuclear DNA indicates that the species comprises two Evolutionarily Significant Units sensu Moritz (1994). In conjunction with physiological data from C. kraussi and morphological, ecological and physiological data from other species, this result supports the notion that at least some of the mtDNA phylogroups of coastal invertebrates whose distributions are limited.
- Full Text:
- Date Issued: 2009
Archetypal hero or living saint? The veneration of Nelson Mandela
- Authors: Maylam, Paul
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/450030 , vital:74877 , https://www.scielo.org.za/pdf/hist/v54n2/04.pdf
- Description: It is now a commonplace that Nelson Mandela–Madiba–has become the most venerated, iconic political figure of the late twentieth and early twenty-first century. Accolades and awards have been heaped upon him. In the words of Kofi Annan, the former UN Secretary-General,“To this day, Madiba remains probably the single most admired, most respected international figure in the entire world”. 1 “In these times of global warfare and strife,” remarks Desmond Tutu,“… Nelson Mandela stands out as a global icon for peace, love, reconciliation and magnanimity.” 2 In the international media, Mandela has been variously described as the only living saint, 3 and as “a moral colossus” towering over the world. 4 Nadine Gordimer views Gandhi and Mandela as “the two indisputably magnificent great people of the last millennium.” 5 The former Mayor of London, Ken Livingstone, was determined, when still in office, that a statue of Mandela be built in Trafalgar Square “so Nelson on his column and Nelson Mandela on his pedestal would in a sense encapsulate the beginning and the end of the British Empire.” 6 There are actual plans afoot to construct a massive statue of Mandela, along the lines of the Statue of Liberty, overlooking the harbour in Port Elizabeth.
- Full Text:
- Date Issued: 2009
- Authors: Maylam, Paul
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/450030 , vital:74877 , https://www.scielo.org.za/pdf/hist/v54n2/04.pdf
- Description: It is now a commonplace that Nelson Mandela–Madiba–has become the most venerated, iconic political figure of the late twentieth and early twenty-first century. Accolades and awards have been heaped upon him. In the words of Kofi Annan, the former UN Secretary-General,“To this day, Madiba remains probably the single most admired, most respected international figure in the entire world”. 1 “In these times of global warfare and strife,” remarks Desmond Tutu,“… Nelson Mandela stands out as a global icon for peace, love, reconciliation and magnanimity.” 2 In the international media, Mandela has been variously described as the only living saint, 3 and as “a moral colossus” towering over the world. 4 Nadine Gordimer views Gandhi and Mandela as “the two indisputably magnificent great people of the last millennium.” 5 The former Mayor of London, Ken Livingstone, was determined, when still in office, that a statue of Mandela be built in Trafalgar Square “so Nelson on his column and Nelson Mandela on his pedestal would in a sense encapsulate the beginning and the end of the British Empire.” 6 There are actual plans afoot to construct a massive statue of Mandela, along the lines of the Statue of Liberty, overlooking the harbour in Port Elizabeth.
- Full Text:
- Date Issued: 2009
Arthropod Fauna of the UAE, Vol. 2, A. van Harten (Ed.): book review
- Authors: Villet, Martin H
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/451625 , vital:75065 , https://hdl.handle.net/10520/EJC32810
- Description: This volume extends the UAE's catalogue of arthropods from 1400 species to 1790 species, and describes 83 new species, four new genera and even a new tribe. The chapters include about two arachnid taxa (pseudoscorpions and cunaxid mites), and cover a total of 63 families, 26 of them previously not recorded from the country. Three chapters deal with entomobryomorph springtails, earwigs and barklice, respectively, and the rest are focused on families in the 'megadiverse' orders Coleoptera, Hymenoptera, Lepidoptera and Diptera.
- Full Text:
- Date Issued: 2009
- Authors: Villet, Martin H
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/451625 , vital:75065 , https://hdl.handle.net/10520/EJC32810
- Description: This volume extends the UAE's catalogue of arthropods from 1400 species to 1790 species, and describes 83 new species, four new genera and even a new tribe. The chapters include about two arachnid taxa (pseudoscorpions and cunaxid mites), and cover a total of 63 families, 26 of them previously not recorded from the country. Three chapters deal with entomobryomorph springtails, earwigs and barklice, respectively, and the rest are focused on families in the 'megadiverse' orders Coleoptera, Hymenoptera, Lepidoptera and Diptera.
- Full Text:
- Date Issued: 2009
As safe as houses, not: The global financial crisis
- Authors: Rumney, Reg
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/454203 , vital:75327 , https://hdl.handle.net/10520/EJC139943
- Description: Property journalism helped foster an unshakeable, irrational and ultimately incorrect faith in the ever-increasing value of homes, undoubtedly one of the precipitators of the global financial crisis, writes Reg Rumney.
- Full Text:
- Date Issued: 2009
- Authors: Rumney, Reg
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/454203 , vital:75327 , https://hdl.handle.net/10520/EJC139943
- Description: Property journalism helped foster an unshakeable, irrational and ultimately incorrect faith in the ever-increasing value of homes, undoubtedly one of the precipitators of the global financial crisis, writes Reg Rumney.
- Full Text:
- Date Issued: 2009
Beyond just research: Experiences from Southern Africa in developing social learning partnerships for resource conservation initiatives
- Shackleton, Charlie M, Cundill, Georgina, Knight, Andrew T
- Authors: Shackleton, Charlie M , Cundill, Georgina , Knight, Andrew T
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181157 , vital:43703 , xlink:href="https://doi.org/10.1111/j.1744-7429.2009.00559.x"
- Description: There is a well-acknowledged communication or knowledge gap between scientists and decision-makers. Many scientists who take on the challenge of narrowing this gap operate on the understanding that their role is to communicate their findings in a one-way flow of information: from science to decision-makers. However, to be effective scientists must engage in an ongoing social learning process with decision-makers, and regard themselves as facilitators, and also as one among many stakeholders who have valid and important ecological knowledge. The developing world poses some particular challenges in this regard, specifically in terms of the large number of local level subsistence resources users who are important de facto decision-makers. We examine four natural resource management case studies from South Africa that differ in spatial scale and complexity, ranging from a single village to a whole biome. We distil seven lessons to help guide development of social learning processes and organizations in similar situations relating to natural resource planning and management. The lessons pertain to: maintaining ‘key individuals’ within social learning processes; the role of researchers; the formulation of research questions that social learning processes require adaptive long-term funding and capacity support; that local resource users are key decision-makers in developing countries; some perspectives on knowledge; and the need to measure research success.
- Full Text:
- Date Issued: 2009
- Authors: Shackleton, Charlie M , Cundill, Georgina , Knight, Andrew T
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181157 , vital:43703 , xlink:href="https://doi.org/10.1111/j.1744-7429.2009.00559.x"
- Description: There is a well-acknowledged communication or knowledge gap between scientists and decision-makers. Many scientists who take on the challenge of narrowing this gap operate on the understanding that their role is to communicate their findings in a one-way flow of information: from science to decision-makers. However, to be effective scientists must engage in an ongoing social learning process with decision-makers, and regard themselves as facilitators, and also as one among many stakeholders who have valid and important ecological knowledge. The developing world poses some particular challenges in this regard, specifically in terms of the large number of local level subsistence resources users who are important de facto decision-makers. We examine four natural resource management case studies from South Africa that differ in spatial scale and complexity, ranging from a single village to a whole biome. We distil seven lessons to help guide development of social learning processes and organizations in similar situations relating to natural resource planning and management. The lessons pertain to: maintaining ‘key individuals’ within social learning processes; the role of researchers; the formulation of research questions that social learning processes require adaptive long-term funding and capacity support; that local resource users are key decision-makers in developing countries; some perspectives on knowledge; and the need to measure research success.
- Full Text:
- Date Issued: 2009
Can eyeflecks be used to sex African Black Oystercatchers Haematopus moquini in the field?
- Kohler, Sophie, Bonnevie, Bo T, Dano, Stéphanie
- Authors: Kohler, Sophie , Bonnevie, Bo T , Dano, Stéphanie
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/448070 , vital:74695 , https://doi.org/10.2989/OSTRICH.2009.80.2.8.835
- Description: Morphometric differences between males and females are a common feature among oystercatcher species (Hockey 1996), although breeding partners often appear similar when observed from a distance. Combinations of different biometric parameters such as bill size and shape, body mass, wing and tarsus lengths have been used to discriminate males and females in the field in European Oystercatchers Haematopus ostralegus (Zwarts et al. 1996), American Black Oystercatchers Haematopus bachmani (Guzzetti et al. 2008) and the three oystercatcher species present in New Zealand (Baker 1973). Sexual dimorphism also occurs in the African Black Oystercatcher Haematopus moquini, an endemic species living on the coasts of Namibia and South Africa. In this species, females tend to have longer and sharper bills than males (Hockey 1981, Hockey 2005).
- Full Text:
- Date Issued: 2009
- Authors: Kohler, Sophie , Bonnevie, Bo T , Dano, Stéphanie
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/448070 , vital:74695 , https://doi.org/10.2989/OSTRICH.2009.80.2.8.835
- Description: Morphometric differences between males and females are a common feature among oystercatcher species (Hockey 1996), although breeding partners often appear similar when observed from a distance. Combinations of different biometric parameters such as bill size and shape, body mass, wing and tarsus lengths have been used to discriminate males and females in the field in European Oystercatchers Haematopus ostralegus (Zwarts et al. 1996), American Black Oystercatchers Haematopus bachmani (Guzzetti et al. 2008) and the three oystercatcher species present in New Zealand (Baker 1973). Sexual dimorphism also occurs in the African Black Oystercatcher Haematopus moquini, an endemic species living on the coasts of Namibia and South Africa. In this species, females tend to have longer and sharper bills than males (Hockey 1981, Hockey 2005).
- Full Text:
- Date Issued: 2009
Caught in a blamestorm: the global financial crisis
- Authors: Rumney, Reg
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/454216 , vital:75328 , https://hdl.handle.net/10520/EJC139951
- Description: The outpouring of negativity towards financial journalists has been sur-prising, symbolised by TV satirist Jon Stewart's excoriation of CNBC financial commentator Jim Cramer on the Daily Show. Journalists were no more to blame for the crisis than anyone else involved in the markets. In the subsequent ''blamestorm'', however, fingers have also been pointed at economists, analysts, bankers, quants, credit rating agencies, regulators, governments, and Alan Greenspan, to name a few.
- Full Text:
- Date Issued: 2009
- Authors: Rumney, Reg
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/454216 , vital:75328 , https://hdl.handle.net/10520/EJC139951
- Description: The outpouring of negativity towards financial journalists has been sur-prising, symbolised by TV satirist Jon Stewart's excoriation of CNBC financial commentator Jim Cramer on the Daily Show. Journalists were no more to blame for the crisis than anyone else involved in the markets. In the subsequent ''blamestorm'', however, fingers have also been pointed at economists, analysts, bankers, quants, credit rating agencies, regulators, governments, and Alan Greenspan, to name a few.
- Full Text:
- Date Issued: 2009
Characterization of manganese tetraarylthiosubstituted phthalocyanines self assembled monolayers
- Matemadombo, Fungisai, Durmus, Mahmut, Togo, Chamunorwa, Limson, Janice L, Nyokong, Tebello
- Authors: Matemadombo, Fungisai , Durmus, Mahmut , Togo, Chamunorwa , Limson, Janice L , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263364 , vital:53621 , xlink:href="https://doi.org/10.1016/j.electacta.2009.04.059"
- Description: Manganese tetraarylthiosubstituted phthalocyanines (complexes 1–5) have been deposited on Au electrode surfaces through the self assembled monolayer (SAM) technique. SAM characteristics reported in this work are: ion barrier factor (∼1); interfacial capacitance (303–539 μF cm−2) and surface coverage (1.06 × 10−10–2.80 × 10−10 mol cm−2). Atomic force microscopy was employed in characterizing a SAM. SAMs of complexes 1–5 were employed to detect L-cysteine (with limit of detection ranging from 2.83 × 10−7 to 3.14 × 10−7 M at potentials of 0.68–0.75 V vs. Ag|AgCl) and nitrite (limit of detection ranging from 1.78 × 10−7 to 3.02 × 10−7 M at potentials of 0.69–0.76 V vs. Ag|AgCl).
- Full Text:
- Date Issued: 2009
- Authors: Matemadombo, Fungisai , Durmus, Mahmut , Togo, Chamunorwa , Limson, Janice L , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263364 , vital:53621 , xlink:href="https://doi.org/10.1016/j.electacta.2009.04.059"
- Description: Manganese tetraarylthiosubstituted phthalocyanines (complexes 1–5) have been deposited on Au electrode surfaces through the self assembled monolayer (SAM) technique. SAM characteristics reported in this work are: ion barrier factor (∼1); interfacial capacitance (303–539 μF cm−2) and surface coverage (1.06 × 10−10–2.80 × 10−10 mol cm−2). Atomic force microscopy was employed in characterizing a SAM. SAMs of complexes 1–5 were employed to detect L-cysteine (with limit of detection ranging from 2.83 × 10−7 to 3.14 × 10−7 M at potentials of 0.68–0.75 V vs. Ag|AgCl) and nitrite (limit of detection ranging from 1.78 × 10−7 to 3.02 × 10−7 M at potentials of 0.69–0.76 V vs. Ag|AgCl).
- Full Text:
- Date Issued: 2009
Characterization of nickel tetrahydroxy phthalocyanine complexes and the electrocatalytic oxidation of 4-chlorophenol
- Khene, Samson M, Lobb, Kevin A, Nyokong, Tebello
- Authors: Khene, Samson M , Lobb, Kevin A , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263308 , vital:53616 , xlink:href="https://doi.org/10.1016/j.ica.2009.08.019"
- Description: This work reports on the use of nickel(II) tetrahydroxy (NiPc(OH)4) and (poly-Ni(OH)Pc(OH)4) phthalocyanine complexes as films on ordinary poly graphite electrode (OPGE) for the electrochemical oxidation of 4-chlorophenol (4-CP). The NiPc(OH)4 film was electrotransformed to Ni(OH)Pc(OH)4 film in aqueous 0.1 M NaOH solution to the ‘O–Ni–O oxo’ bridge form. The result showed that the Ni(OH)Pc(OH)4 film on OPGE was more electroactive in terms of increase in current and less catalytic in terms of potential compared to the adsorbed NiPc(OH)4 on OPGE. The reactivity of the two molecules was explained by theoretical calculations. The energies of the frontier orbitals of NiPc(OH)4, Ni(OH)Pc(OH)4 and 4-chlorophenol were calculated using density functional theory (DFT) method. The inter molecular hardness (η) and donor–acceptor hardness (ηDA) of Ni(OH)Pc(OH)4, NiPc(OH)4, Ni(OH)Pc(OH)4/4-chlorophenol and NiPc(OH)4/4-chlorophenol were estimated. The Ni(OH)Pc(OH)4, showed stronger interaction with 4-chlorophenol than NiPc(OH)4. DFT method was also used to model IR and Raman spectrum of H2Pc(OH)4 and NiPc(OH)4.
- Full Text:
- Date Issued: 2009
- Authors: Khene, Samson M , Lobb, Kevin A , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263308 , vital:53616 , xlink:href="https://doi.org/10.1016/j.ica.2009.08.019"
- Description: This work reports on the use of nickel(II) tetrahydroxy (NiPc(OH)4) and (poly-Ni(OH)Pc(OH)4) phthalocyanine complexes as films on ordinary poly graphite electrode (OPGE) for the electrochemical oxidation of 4-chlorophenol (4-CP). The NiPc(OH)4 film was electrotransformed to Ni(OH)Pc(OH)4 film in aqueous 0.1 M NaOH solution to the ‘O–Ni–O oxo’ bridge form. The result showed that the Ni(OH)Pc(OH)4 film on OPGE was more electroactive in terms of increase in current and less catalytic in terms of potential compared to the adsorbed NiPc(OH)4 on OPGE. The reactivity of the two molecules was explained by theoretical calculations. The energies of the frontier orbitals of NiPc(OH)4, Ni(OH)Pc(OH)4 and 4-chlorophenol were calculated using density functional theory (DFT) method. The inter molecular hardness (η) and donor–acceptor hardness (ηDA) of Ni(OH)Pc(OH)4, NiPc(OH)4, Ni(OH)Pc(OH)4/4-chlorophenol and NiPc(OH)4/4-chlorophenol were estimated. The Ni(OH)Pc(OH)4, showed stronger interaction with 4-chlorophenol than NiPc(OH)4. DFT method was also used to model IR and Raman spectrum of H2Pc(OH)4 and NiPc(OH)4.
- Full Text:
- Date Issued: 2009
Characterization of polymeric film of a new manganese phthalocyanine complex octa-substituted with 2-diethylaminoethanethiol, and its use for the electrochemical detection of bentazon
- Akinbulu, Isaac A, Nyokong, Tebello
- Authors: Akinbulu, Isaac A , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262568 , vital:53534 , xlink:href="https://doi.org/10.1016/j.electacta.2009.07.074"
- Description: Manganese acetate octakis-(2-diethyaminoethanethiol) phthalocyanine (AcMnODEAETPc) was newly synthesized and characterized by spectroscopic and electrochemical methods. Solution electrochemistry of the complex showed three redox processes assigned to MnIIIPc−1/MnIIIPc−2, MnIIIPc−2/MnIIPc−2 and MnIIPc−2/MnIIPc−3 species. The new molecule was polymerized onto a glassy carbon electrode (GCE) to form thin films of different thickness, giving poly-10-AcMnODEAETPc-GCE, poly-20-AcMnODEAETPc-GCE and poly-30-AcMnODEAETPc-GCE, where 10, 20 and 30 represent the number of voltammetry scans during polymerization. Three distinct redox processes were observed on the modified electrode in 0.1 M phosphate buffer solution, pH 5, which confirmed the formation of the polymer. The current signal due to the herbicide, bentazon, was dependent on film thickness; the best signal was obtained on poly-20-AcMnODEAETPc-GCE while poly-10-AcMnODEAETPc-GCE gave the least signal. However, the signals due to the herbicide were better on the different films compared to the bare electrode. Electrochemical impedance spectroscopy (EIS) technique revealed that differences in film thickness offered different charge transfer resistances, Rct, hence difference in current signals for bentazon oxidation were observed on these films. A Tafel slope of 77 mV/decade, obtained for the herbicide on poly-20-AcMnODEAETPc-GCE, denotes a fast one electron transfer followed by a slow chemical step in the electro-oxidation of bentazon. The voltammetry signals of the herbicide on the films indicated the likely involvement of ring-based redox processes in the detection of the herbicide. A plot of background corrected current response, on this film, versus the concentration of bentazon was linear within the range 50–750 μM with a detection limit of 2.48 × 10−7 M.
- Full Text:
- Date Issued: 2009
- Authors: Akinbulu, Isaac A , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262568 , vital:53534 , xlink:href="https://doi.org/10.1016/j.electacta.2009.07.074"
- Description: Manganese acetate octakis-(2-diethyaminoethanethiol) phthalocyanine (AcMnODEAETPc) was newly synthesized and characterized by spectroscopic and electrochemical methods. Solution electrochemistry of the complex showed three redox processes assigned to MnIIIPc−1/MnIIIPc−2, MnIIIPc−2/MnIIPc−2 and MnIIPc−2/MnIIPc−3 species. The new molecule was polymerized onto a glassy carbon electrode (GCE) to form thin films of different thickness, giving poly-10-AcMnODEAETPc-GCE, poly-20-AcMnODEAETPc-GCE and poly-30-AcMnODEAETPc-GCE, where 10, 20 and 30 represent the number of voltammetry scans during polymerization. Three distinct redox processes were observed on the modified electrode in 0.1 M phosphate buffer solution, pH 5, which confirmed the formation of the polymer. The current signal due to the herbicide, bentazon, was dependent on film thickness; the best signal was obtained on poly-20-AcMnODEAETPc-GCE while poly-10-AcMnODEAETPc-GCE gave the least signal. However, the signals due to the herbicide were better on the different films compared to the bare electrode. Electrochemical impedance spectroscopy (EIS) technique revealed that differences in film thickness offered different charge transfer resistances, Rct, hence difference in current signals for bentazon oxidation were observed on these films. A Tafel slope of 77 mV/decade, obtained for the herbicide on poly-20-AcMnODEAETPc-GCE, denotes a fast one electron transfer followed by a slow chemical step in the electro-oxidation of bentazon. The voltammetry signals of the herbicide on the films indicated the likely involvement of ring-based redox processes in the detection of the herbicide. A plot of background corrected current response, on this film, versus the concentration of bentazon was linear within the range 50–750 μM with a detection limit of 2.48 × 10−7 M.
- Full Text:
- Date Issued: 2009
Children navigating rural poverty: Rural children's use of wild resources to counteract food insecurity in the Eastern Cape, South Africa
- McGarry, Dylan K, Shackleton, Charlie M
- Authors: McGarry, Dylan K , Shackleton, Charlie M
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181191 , vital:43706 , xlink:href="https://doi.org/10.1080/10796120802677594"
- Description: This paper analyzes the role of natural resources in the lives of rural children experiencing heightened vulnerability to poverty and the impact of HIV/AIDS, a subject that previously has been unexplored. The authors highlight wild-food use by rural children as a regular activity that supplements their domestic diets. Over the course of 18 months in the Eastern Cape of South Africa, the authors used a broad quantitative and qualitative methodology to explore the food acquisition and consumption patterns for 850 children. They found that the quality of children's domestic diets was, on average, 60% lower than the Food and Agricultural Organization (FAO) guidelines. This occurred in a population where 62% of the children surveyed were supplementing their diets with wild foods; and 30% with over half their diet supplemented in this way. Significantly, dietary diversity increased by 13% when wild food supplementation occurred. Another result was the commercialization of wild foods (observed among 47% of the children), wherein significantly more vulnerable children sold these foods. Considering the heightened nutritional and energy needs of children, combined with the impact of poverty and HIV/AIDS on household food access, wild foods represent the last freely attainable food sources available to them.
- Full Text:
- Date Issued: 2009
- Authors: McGarry, Dylan K , Shackleton, Charlie M
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181191 , vital:43706 , xlink:href="https://doi.org/10.1080/10796120802677594"
- Description: This paper analyzes the role of natural resources in the lives of rural children experiencing heightened vulnerability to poverty and the impact of HIV/AIDS, a subject that previously has been unexplored. The authors highlight wild-food use by rural children as a regular activity that supplements their domestic diets. Over the course of 18 months in the Eastern Cape of South Africa, the authors used a broad quantitative and qualitative methodology to explore the food acquisition and consumption patterns for 850 children. They found that the quality of children's domestic diets was, on average, 60% lower than the Food and Agricultural Organization (FAO) guidelines. This occurred in a population where 62% of the children surveyed were supplementing their diets with wild foods; and 30% with over half their diet supplemented in this way. Significantly, dietary diversity increased by 13% when wild food supplementation occurred. Another result was the commercialization of wild foods (observed among 47% of the children), wherein significantly more vulnerable children sold these foods. Considering the heightened nutritional and energy needs of children, combined with the impact of poverty and HIV/AIDS on household food access, wild foods represent the last freely attainable food sources available to them.
- Full Text:
- Date Issued: 2009
China in the African mediascape: doing better journalism
- Authors: Banda, Fackson
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/454561 , vital:75355 , https://hdl.handle.net/10520/EJC139919
- Description: Chinese assistance to African media is not new. What is different now is that it is being administered in the post-Cold War era with a greater degree of openness, says Fackson Banda.
- Full Text:
- Date Issued: 2009
- Authors: Banda, Fackson
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/454561 , vital:75355 , https://hdl.handle.net/10520/EJC139919
- Description: Chinese assistance to African media is not new. What is different now is that it is being administered in the post-Cold War era with a greater degree of openness, says Fackson Banda.
- Full Text:
- Date Issued: 2009
Chromone Studies. Part 17. Tricyclic Scaffolds from Reactions of chromone-3-carbaldehydes and methyl vinyl ketone under Baylis–Hillman conditions
- Ganto, Mlungiseleli M, Molefe, Duduzile M, Lobb, Kevin A, Kaye, Perry T
- Authors: Ganto, Mlungiseleli M , Molefe, Duduzile M , Lobb, Kevin A , Kaye, Perry T
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/449321 , vital:74811 , xlink:href="https://doi.org/10.3184/030823409X4652"
- Description: Reaction of a series of chromone-3-carbaldehydes with methyl vinyl ketone under Baylis–Hillman conditions, using 3-hydroxyquinuclidine in chloroform or DABCO in 1-methyl-2-pyrrolidinone, affords unprecedented tricylic chromone derivatives which, depending on the conditions, may be accompanied by the normal Baylis–Hillman products or their respective tricyclic dimers.
- Full Text:
- Date Issued: 2009
- Authors: Ganto, Mlungiseleli M , Molefe, Duduzile M , Lobb, Kevin A , Kaye, Perry T
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/449321 , vital:74811 , xlink:href="https://doi.org/10.3184/030823409X4652"
- Description: Reaction of a series of chromone-3-carbaldehydes with methyl vinyl ketone under Baylis–Hillman conditions, using 3-hydroxyquinuclidine in chloroform or DABCO in 1-methyl-2-pyrrolidinone, affords unprecedented tricylic chromone derivatives which, depending on the conditions, may be accompanied by the normal Baylis–Hillman products or their respective tricyclic dimers.
- Full Text:
- Date Issued: 2009
Comparative electrocatalytic behavior of self-assembled monolayer of thiol derivatised Co (II) phthalocyanines on gold disk, ultramicro cylinder and fiber electrodes
- Nombona, Nolwazi, Geraldo, Daniela A, Hakuzimana, Jean, Schwarz, Anne, Westbroek, Philippe, Nyokong, Tebello
- Authors: Nombona, Nolwazi , Geraldo, Daniela A , Hakuzimana, Jean , Schwarz, Anne , Westbroek, Philippe , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263488 , vital:53632 , xlink:href="https://doi.org/10.1007/s10800-008-9716-y"
- Description: This paper reports on the use of thiol derivatised cobalt phthalocyanines as self assembled monolayers (SAMs) on gold disk electrode, gold ultramicro-cylinder electrode (UMCE) and on gold coated fiber for the detection of L-cysteine. The complexes are peripherally and non-peripherally substituted with phenylthio substituents. The SAM modified electrodes showed enhancement of catalytic currents and overpotential reduction occurred on the gold modified electrodes with different geometries. Electrocatalytic oxidation of L-cysteine on SAM modified gold coated fiber was reported for the first time. The gold coated fiber and ultramicro cylinder electrode were less stable towards the electrocatalytic oxidation of cysteine compared to its oxidation on the gold disk. The gold disk electrode gave better catalytic performance in terms of stability and reduction of overpotential.
- Full Text:
- Date Issued: 2009
- Authors: Nombona, Nolwazi , Geraldo, Daniela A , Hakuzimana, Jean , Schwarz, Anne , Westbroek, Philippe , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263488 , vital:53632 , xlink:href="https://doi.org/10.1007/s10800-008-9716-y"
- Description: This paper reports on the use of thiol derivatised cobalt phthalocyanines as self assembled monolayers (SAMs) on gold disk electrode, gold ultramicro-cylinder electrode (UMCE) and on gold coated fiber for the detection of L-cysteine. The complexes are peripherally and non-peripherally substituted with phenylthio substituents. The SAM modified electrodes showed enhancement of catalytic currents and overpotential reduction occurred on the gold modified electrodes with different geometries. Electrocatalytic oxidation of L-cysteine on SAM modified gold coated fiber was reported for the first time. The gold coated fiber and ultramicro cylinder electrode were less stable towards the electrocatalytic oxidation of cysteine compared to its oxidation on the gold disk. The gold disk electrode gave better catalytic performance in terms of stability and reduction of overpotential.
- Full Text:
- Date Issued: 2009
Conservation, commercialisation and confusion: Harvesting of Ischyrolepis in a coastal forest, South Africa
- Shackleton, Charlie M, Parkin, Fiona, Chauke, Maphambe I, Downsborough, Linda, Olsen, Ashleigh, Brill, Greg, Weideman, Craig I
- Authors: Shackleton, Charlie M , Parkin, Fiona , Chauke, Maphambe I , Downsborough, Linda , Olsen, Ashleigh , Brill, Greg , Weideman, Craig I
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181169 , vital:43704 , xlink:href="https://doi.org/10.1007/s10668-007-9106-3"
- Description: Harvesting of non-timber forest products is an integral component of rural livelihoods throughout the developing world. At times this is at odds with conservation objectives. Reconciliation of the two requires examination of local level contexts and needs. This paper reports on the harvesting needs for Ischyrolepis by a rural community in South Africa, against the setting that they had recently been prohibited from harvesting by the local conservation officials. Interviews were conducted with conservation officials to understand the reasoning for the prohibition. Local demand for Ischyrolepis was assessed by household surveys, as well as in-depth interviews with traders. The density and size class distribution of Ischyrolepis was determined using transects. The total annual demand for Ischyrolepis was determined to be approximately only 2.7% of the standing crop. The bulk of the annual demand was for small-scale trade, the income from which was a primary source of income for the few harvesters. Very little evidence could be found indicating that harvesting was damaging the resource or its habitat, and local knowledge suggested that the abundance of the species was stimulated by harvesting. Even if market demand were to increase, the size of the shoots required means that less than 20% of the standing crop could be harvested annually. Current regulations around harvesting are in a state of revision, and hence confusion prevails regarding if harvesting is permissible, and if so, under what conditions, which is detrimental to both conservation and livelihoods.
- Full Text:
- Date Issued: 2009
- Authors: Shackleton, Charlie M , Parkin, Fiona , Chauke, Maphambe I , Downsborough, Linda , Olsen, Ashleigh , Brill, Greg , Weideman, Craig I
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181169 , vital:43704 , xlink:href="https://doi.org/10.1007/s10668-007-9106-3"
- Description: Harvesting of non-timber forest products is an integral component of rural livelihoods throughout the developing world. At times this is at odds with conservation objectives. Reconciliation of the two requires examination of local level contexts and needs. This paper reports on the harvesting needs for Ischyrolepis by a rural community in South Africa, against the setting that they had recently been prohibited from harvesting by the local conservation officials. Interviews were conducted with conservation officials to understand the reasoning for the prohibition. Local demand for Ischyrolepis was assessed by household surveys, as well as in-depth interviews with traders. The density and size class distribution of Ischyrolepis was determined using transects. The total annual demand for Ischyrolepis was determined to be approximately only 2.7% of the standing crop. The bulk of the annual demand was for small-scale trade, the income from which was a primary source of income for the few harvesters. Very little evidence could be found indicating that harvesting was damaging the resource or its habitat, and local knowledge suggested that the abundance of the species was stimulated by harvesting. Even if market demand were to increase, the size of the shoots required means that less than 20% of the standing crop could be harvested annually. Current regulations around harvesting are in a state of revision, and hence confusion prevails regarding if harvesting is permissible, and if so, under what conditions, which is detrimental to both conservation and livelihoods.
- Full Text:
- Date Issued: 2009
Creating a virtual classroom: evaluating the use of online discussion forums to increase teaching and learning activities
- Authors: Bezuidenhout, L Peta
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: Conference paper
- Identifier: vital:6070 , http://hdl.handle.net/10962/d1004635
- Description: In teaching large classes, the educationally beneficial informal interaction between students and between lecturer and students is generally reduced, while effective use of both students’ and lecturer’s time is often a challenge. During student consultations, especially over the already stressful test and examination periods, many of the questions asked by the students are the same or similar. The lecturer needs to respond to each query by providing the same detailed explanation for the problem, resulting in ineffective use of time for the lecturer, while students waste time waiting for an appointment, or more often, simply don’t bother to follow up on any queries they may have. Having a social presence is important for students’ cognitive development, but in a large class posing questions or interrogating issues during a lecture appears to be challenging for many students. It is often not easy for students to initiate discussions or establish relationships with peers or the lecturer due to feelings of vulnerability and due to the size and impersonal atmosphere of the lecture theatre. This paper deals with the introduction of online discussion forums in an introductory accounting course and the benefits and problems experienced by the students, tutors and lecturer as a result thereof. Feedback received from these participants is discussed. The introduction and use of these forums resulted in a virtual classroom being created, where significantly more teaching and learning activities took place, to the benefit of all participants. Participation could have been peripheral -in the form of simply reading discussions; or active – through posting questions, or responding to questions.
- Full Text:
- Date Issued: 2009
- Authors: Bezuidenhout, L Peta
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: Conference paper
- Identifier: vital:6070 , http://hdl.handle.net/10962/d1004635
- Description: In teaching large classes, the educationally beneficial informal interaction between students and between lecturer and students is generally reduced, while effective use of both students’ and lecturer’s time is often a challenge. During student consultations, especially over the already stressful test and examination periods, many of the questions asked by the students are the same or similar. The lecturer needs to respond to each query by providing the same detailed explanation for the problem, resulting in ineffective use of time for the lecturer, while students waste time waiting for an appointment, or more often, simply don’t bother to follow up on any queries they may have. Having a social presence is important for students’ cognitive development, but in a large class posing questions or interrogating issues during a lecture appears to be challenging for many students. It is often not easy for students to initiate discussions or establish relationships with peers or the lecturer due to feelings of vulnerability and due to the size and impersonal atmosphere of the lecture theatre. This paper deals with the introduction of online discussion forums in an introductory accounting course and the benefits and problems experienced by the students, tutors and lecturer as a result thereof. Feedback received from these participants is discussed. The introduction and use of these forums resulted in a virtual classroom being created, where significantly more teaching and learning activities took place, to the benefit of all participants. Participation could have been peripheral -in the form of simply reading discussions; or active – through posting questions, or responding to questions.
- Full Text:
- Date Issued: 2009
Cultural historical activity theory, expansive learning and agency in permaculture workplaces
- Authors: Mukute, Mutizwa
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386474 , vital:68145 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122818"
- Description: This paper reports on how Cultural Historical Activity Theory was used to identify and analyse contradictions; model and implement solutions in the learning and practice of permaculture at one school and its community in Zimbabwe. This is one of three sustainable agriculture workplace learning sites being examined in a wider study on change-oriented learning and sustainability practices (Mukute, 2009). It gives a brief background to permaculture and the School and Colleges Permaculture Programme (SCOPE) in Zimbabwe. The paper focuses on how contradictions were used as sources of learning and development leading to ‘real life expansions’. This demonstrates and reflects on the value of an interventionist research theory and methodology employed in the study to enhance participants’ agency in sustainable agriculture workplaces.
- Full Text:
- Date Issued: 2009
- Authors: Mukute, Mutizwa
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386474 , vital:68145 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122818"
- Description: This paper reports on how Cultural Historical Activity Theory was used to identify and analyse contradictions; model and implement solutions in the learning and practice of permaculture at one school and its community in Zimbabwe. This is one of three sustainable agriculture workplace learning sites being examined in a wider study on change-oriented learning and sustainability practices (Mukute, 2009). It gives a brief background to permaculture and the School and Colleges Permaculture Programme (SCOPE) in Zimbabwe. The paper focuses on how contradictions were used as sources of learning and development leading to ‘real life expansions’. This demonstrates and reflects on the value of an interventionist research theory and methodology employed in the study to enhance participants’ agency in sustainable agriculture workplaces.
- Full Text:
- Date Issued: 2009