List of Titles

Quick View

Determinism and reactive attitudes: reflections on our alleged unrenounceable commitments

- Kelland, Lindsay-Ann

Authors: Kelland, Lindsay-Ann
Date: 2009
Subjects: Free will and determinism Responsibility
Language: English
Type: Thesis , Masters , MA
Identifier: vital:2713 , http://hdl.handle.net/10962/d1002843
Description: There seems to exist a tension between our metaphysical and phenomenological commitments in the free will debate. On the one hand, I argue that at the metaphysical level we cannot coherently defend the belief that we are morally responsible in the sense that we deserve to be rewarded and punished for our actions, where desert-entailing moral responsibility is the primary understanding of moral responsibility presupposed in the free will debate. I argue that we are responsible for our actions but only in the weaker sense, termed ‘attributability’ by Gary Watson. On the other hand, we are allegedly unrenounceably committed at the phenomenological level to conceiving of, and treating, ourselves and one another as morally responsible beings in the desert-entailing sense. P. F. Strawson famously defends this claim in his seminal work, ‘Freedom and Resentment’. In my thesis I will set out this tension by exploring both commitments in turn. I then aim to show that the tension can be dissolved by arguing, contra P. F. Strawson, that our phenomenological commitment is not in fact unrenounceable. The dissolution of this tension entails, I argue, that we must examine our conception of self and other. We must explore the implications of adopting a position which denies that we are morally responsible beings for our life-hopes, personal feelings, inter-personal relationships and projects. Most importantly, I argue that we must renounce our current retributive condemnatory practices which are based on the unjustified belief that we are morally responsible beings.
Full Text:

Quick View

Developing an ionospheric map for South Africa

- Okoh, Daniel Izuikeninachi

Authors: Okoh, Daniel Izuikeninachi
Date: 2009
Subjects: Ionosphere -- South Africa , Shortwave radio , Ionospheric electron density -- South Africa
Language: English
Type: Thesis , Masters , MSc
Identifier: vital:5459 , http://hdl.handle.net/10962/d1005244 , Ionosphere -- South Africa , Shortwave radio , Ionospheric electron density -- South Africa
Description: This thesis describes the development of an ionospheric map for the South African region using the current available resources. The International Reference Ionosphere (IRI) model, the South African Bottomside Ionospheric Model (SABIM), and measurements from ionosondes in the South African Ionosonde Network, were incorporated into the map. An accurate ionospheric map depicting the foF2 and hmF2 parameters as well as electron density profiles at any location within South Africa is a useful tool for, amongst others, High Frequency (HF) communicators and space weather centers. A major product of the work is software, written in MATLAB, which produces spatial and temporal representations of the South African ionosphere. The map was validated and demonstrated for practical application, since a significant aim of the project was to make the map as applicable as possible. It is hoped that the map will find immense application in HF radio communication industries, research industries, aviation industries, and other industries that make use of Earth-Space systems. A potential user of the map is GrinTek Ewation (GEW) who is currently evaluating it for their purposes
Full Text:

Quick View

Development and validation of a stability-indicating method for the quantitation of paclitaxel in pharmaceutical dosage forms

- Mohammadi, Ali, Esimaeili, Farnaz, Dinarvand, Rasoul, Atyabi, Fatemeh, Walker, Roderick B

Authors: Mohammadi, Ali , Esimaeili, Farnaz , Dinarvand, Rasoul , Atyabi, Fatemeh , Walker, Roderick B
Date: 2009
Subjects: To be catalogued
Language: English
Type: text , article
Identifier: http://hdl.handle.net/10962/184278 , vital:44196 , xlink:href="https://doi.org/10.1093/chromsci/47.7.599"
Description: A simple, rapid stability-indicating isocratic assay has been developed and validated for the determination of Paclitaxel (PTX) in commercial injection formulations. The assay is performed using a Nucleosil RP-18 (5 µm, 250 × 4.0 mm i.d) column protected by a Nucleosil C18 precolumn (5 µm, 4.0 × 4.0 mm i.d.) with a mobile phase of methanol–water (80:20) and UV detection at 230 nm. The method was found to be specific for PTX in the presence of degradation products with an overall analytical run time of ~ 9 min. Accuracy reported as % bias was found to be 0.1–2.5% bias for all samples tested. Intra-assay precision (repeatability) was found to be 0.22–2.65% RSD, while inter-day precision (intermediate precision) was found to be 1.0–3.0% RSD for the samples studied. The calibration curve was found to be linear with the equation y = 29.78x + 7.65, and a linear regression coefficient of 0.9994 over the concentration range 0.05–20 µg/mL. The limits of quantitation and detection were 0.05 and 0.02 µg/mL, respectively. Taxol (30 mg/5 mL), a commercially available dosage form of PTX, was assayed and 100.6–103.6% of the label claim was recovered.
Full Text:

Quick View

Development of a neural network based model for predicting the occurrence of spread F within the Brazilian sector

- Paradza, Masimba Wellington

Authors: Paradza, Masimba Wellington
Date: 2009
Subjects: Neural networks (Computer science) , Ionosphere , F region
Language: English
Type: Thesis , Masters , MSc
Identifier: vital:5460 , http://hdl.handle.net/10962/d1005245 , Neural networks (Computer science) , Ionosphere , F region
Description: Spread F is a phenomenon of the ionosphere in which the pulses returned from the ionosphere are of a much greater duration than the transmitted ones. The occurrence of spread F can be predicted using the technique of Neural Networks (NNs). This thesis presents the development and evaluation of NN based models (two single station models and a regional model) for predicting the occurrence of spread F over selected stations within the Brazilian sector. The input space for the NNs included the day number (seasonal variation), hour (diurnal variation), sunspot number (measure of the solar activity), magnetic index (measure of the magnetic activity) and magnetic position (latitude, magnetic declination and inclination). Twelve years of spread F data measured during 1978 to 1989 inclusively at the equatorial site Fortaleza and low latitude site Cachoeira Paulista are used in the development of an input space and NN architecture for the NN models. Spread F data that is believed to be related to plasma bubble developments (range spread F) were used in the development of the models while those associated with narrow spectrum irregularities that occur near the F layer (frequency spread F) were excluded. The results of the models show the dependency of the probability of spread F as a function of local time, season and latitude. The models also illustrate some characteristics of spread F such as the onset and peak occurrence of spread F as a function of distance from the equator. Results from these models are presented in this thesis and compared to measured data and to modelled data obtained with an empirical model developed for the same purpose.
Full Text:

Quick View

Development of Thanatophilus micans (Fabricius 1794)(Coleoptera: Silphidae) at constant temperatures

- Midgley, John M, Villet, Martin H

Authors: Midgley, John M , Villet, Martin H
Date: 2009
Subjects: To be catalogued
Language: English
Type: text , article
Identifier: http://hdl.handle.net/10962/441904 , vital:73933 , https://doi.org/10.1007/s00414-008-0280-0
Description: Thanatophilus micans is capable of finding corpses at least as quickly as most fly species and, as the most widespread species of the Silphidae in Africa, offers a useful model for estimating post-mortem interval. Larvae were reared at ten constant temperatures from 15°C to 35°C and their length measured at 4, 8, or 12-h intervals depending on their instar. Length generally increased with increased rearing temperature, but decreased at extremely high temperatures. Note was made of the age at which individuals progressed past developmental milestones. Development took longer at lower temperatures. These results are presented as a combined isomegalen and isomorphen diagram. Developmental constants were generated for each milestone using major axis regression. Developmental threshold values did not differ significantly between milestones. Development took longer than in blow flies, but was faster than in Dermestidae. The three models presented here, therefore, cover an important time frame in estimating minimum PMI once fly larvae have matured to the point of leaving a corpse, and, therefore, provide a tool that was not previously available to forensic entomologists.
Full Text:

Quick View

Diffraction efficiency and I–V characteristics of metal-free phthalocyanine doped nematic liquid crystals

- Köysal, Oguz, Okutan, Mustafa, San, S Eren, Nyokong, Tebello, Durmus, Mahmut

Authors: Köysal, Oguz , Okutan, Mustafa , San, S Eren , Nyokong, Tebello , Durmus, Mahmut
Date: 2009
Subjects: To be catalogued
Language: English
Type: text , article
Identifier: http://hdl.handle.net/10962/263511 , vital:53634 , xlink:href="https://doi.org/10.1016/j.matchemphys.2008.10.056"
Description: The synthesis and characterization of the tetra-4-benzyloxyphenoxy substituted metal-free phthalocyanine (H2Pc) is reported for the first time. Formation of the photoinduced gratings has been experienced in a metal-free phthalocyanine doped nematic liquid crystal (LC) system and its I–V properties are characterized by electrical measurements. Four samples are prepared at different doping percentages and in homogenously aligned sandwiched geometry. We report the results of two set of experiments on these samples. One of them is the grating diffraction experiment for the analysis of optically induced reorientation process which is a basis for possible holographic applications. Accessible diffraction efficiency is found to be linearly increasing as the amount of the phthalocyanine doping rises. In the scope of the other set of measurements I–V peculiarity of the system is also found to be enhanced and linearly dependent on doping.
Full Text:

Quick View

Discourse and the oppression of nonhuman animals: a critical realist account

- Mitchell, Leslie Roy

Authors: Mitchell, Leslie Roy
Date: 2009
Subjects: Animal rights Animal welfare -- Moral and ethical aspects Critical realism Critical discourse analysis Animal industry -- Moral and ethical aspects Livestock -- Social aspects Human-animal relationships Agriculture -- Moral and ethical aspects
Language: English
Type: Thesis , Doctoral , PhD
Identifier: vital:1318 , http://hdl.handle.net/10962/d1003951
Description: This work examines the use of nonhuman animals in the farming industry and seeks to understand why this practice takes place and what supports its continuation. The research is approached from a critical realist perspective and after a description of past and current practices in the industry, it uses abduction and retroduction to determine the essential conditions for the continuation of the phenomenon of nonhuman animal farming. One essential condition is found to be the existence of negative discourses relating to nonhuman animals and this aspect is examined in more detail by analyzing a corpus of texts from a farming magazine using Critical Discourse Analysis. Major discourses which were found to be present were those of production, science and slavery which construct the nonhumans respectively as objects of scientific investigation, as production machines and as slaves. A minor discourse of achievement relating to the nonhumans was also present. Further analysis of linguistic features examined the way in which the nonhumans are socially constructed in the discourses. Drawing on work in experimental psychology by Millgram, Zimbardo and Bandura it was found that the effects of these discourses fulfil many of the conditions for bringing about moral disengagement in people thus explaining why billions of people are able to support animal farming in various ways even though what happens in the phenomenon is contrary to their basic ethical and moral beliefs.
Full Text:

Quick View

Discourses around abortion in a low-income community in the Western Cape

- Bowes, Tanya-Ann

Authors: Bowes, Tanya-Ann
Date: 2009
Subjects: Abortion -- Moral and ethical aspects , Abortion -- Religious aspects -- Christianity , Patriarchy -- South Africa , Abortion -- South Africa -- Western Cape , Male domination (Social structure)
Language: English
Type: text , Thesis , Masters , MSocSci
Identifier: vital:2939 , http://hdl.handle.net/10962/d1002448
Description: Since the introduction of the Choice on Termination of Pregnancy Act in 1996, research concerning abortion has primarily focused on public health issues or on the personal experience of women. The cultural and social context within which women experience a termination of pregnancy and in which services are offered has received less attention. The purpose of this study was to analyse public discourses around abortion in a low-income community in the Western Cape. Focus groups were used to gather data from three women’s and three men’s groups. The findings suggest that the agenda of pro-life discourses in this community is not always to defend the life of the fetus. Rather these discourses serve to protect, preserve and maintain the power of the traditional nuclear family, headed by the husband, over women’s reproduction and sexuality. Religious and moral arguments serve to disguise the gender issues at stake. However, instances also occurred where TOP was supported if the husband participated in the decision-making process. Therefore, his presence normalised abortion. Thus, the prevailing public discourses around abortion in this community either support or negate abortion in order to further the agenda of patriarchy.
Full Text:

Quick View

Disjunctions in the Diptera (Insecta) fauna of the Mediterranean Province and southern Africa and a discussion of biogeographical considerations : ecological overview article

- Kirk-Spriggs, A H, McGregor, Gillian K

Authors: Kirk-Spriggs, A H , McGregor, Gillian K
Date: 2009
Language: English
Type: text , Article
Identifier: vital:6880 , http://hdl.handle.net/10962/d1011636
Description: This paper explores disjunctions in the Diptera fauna of the Mediterranean Province and southern Africa, drawing from eight families of Diptera, the more ancient Psychodidae and Vermileonidae, and the more recent Acroceridae, Asilidae, Bombyliidae, Dolichopodidae, Pipunculidae and Sciomyzidae. Information from recent published revisions is geo-referenced and plotted onto maps using GIS software. These distribution patterns are interpreted and probable means and routes of dispersal between the two regions are discussed. The concept of an Afrotropical sub-Saharan boundary is outlined and it is argued that although the vast, arid and virtually abiotic Sahara acts as a barrier to dispersal today, relict floral and faunal populations of Mediterranean provincial origin still occur on the Hoggar and Tibesti Mountains of the central Sahara, indicating that the aridification of the Sahara is a very recent event. The presence of extensive palaeolakes formerly covering ca 10% of the present-day Sahara is regarded as evidence in support of this hypothesis. These lakes and their associated catchments, situated in basins between the central Saharan mountains, could clearly have acted as a humid route of dispersal as recently as 4000 BP, when these lakes began to recede, and this route is here regarded as a "central high Africa corridor"; a filter-bridge between the Mediterranean Province and southern Africa. Examples of Mediterranean provincial species of Ephydridae and the muscid genus Lispe Latreille, 1796, occurring as far south as the AÏr Massif in northern Niger are cited as examples of relict montane Diptera of Mediterranean provincial origin in the southern Hoggar Mountains; these groups being associated with the margins of standing water. Balinsky's (1962) concept of an "arid corridor" is also re-examined, using examples from the larger, less mobile Diptera, and it is concluded that such a pattern may not be the result of aridity, but represent an "eastern high Africa corridor", broadly corresponding to the "African Supers well". Other perceived distribution pathways between the Holarctic and Afrotropical Regions are mapped. Anemochore dispersal is considered, and the extent of the Afrotropical Region is discussed. Mediterranean tectonic evolution on both a globe of constant size and on a smaller Jurassic globe is also considered. It is concluded that if all the transitional zones between the zoogeographical regions are to be given more-or-less equivalent treatment, we must avoid setting boundaries based on earlier faunal distributions. For this reason the current boundary between the Palaearctic and Afrotropical Regions, arbitrary as it is, should be retained, despite evidence suggesting recent continuity between sub-Saharan Africa, North Africa and the Arabian Peninsula, corresponding broadly to the African and Arabian lithospheric plates.
Full Text:

Quick View

Dominant and non-dominant group's perceptions of the government-led economic transformation process in South Africa: report

- Dlamini, Thobile G. K

Authors: Dlamini, Thobile G. K
Date: 2009
Subjects: Group identity -- South Africa Post-apartheid era -- South Africa South Africa -- Ethnic relations Social change -- South Africa South Africa -- Social conditions -- 1994- South Africa -- Economic conditions -- 1991-
Language: English
Type: Thesis , Masters , MA
Identifier: vital:2963 , http://hdl.handle.net/10962/d1002472
Description: The enormous social, economic, and political government-led societal transformation South Africans have experienced over the past 15 years have brought about numerous societal and identity changes. The aim of the present study was to explore how dominant (White participants) and non-dominant (Black participants) groups experiencing the government-led societal transformation process deal with perceptions of intergroup differences based on Social Identity Theory (Tajfel & Turner, 1979, 1986) and related field research. Social Identity Theory predicts that in the presence of intergroup differences group members irrespective of their status position will apply identity management strategies to either improve or maintain their status position. The relationships between perceptions of intergroup relations and identity management strategies as proposed by Social Identity Theory were tested studying 170 second year Rhodes University psychology students. Sixty participants indicated themselves as Black South Africans (representing non-dominant group) and 110 participants identified themselves as White South Africans (dominant group). The results revealed that dominant and non-dominant groups differ systematically regarding the functional interaction between beliefs about the intergroup situation and identity management strategies. The results of the study indicate too, that ingroup identification differentiates between individual and collective strategies irrespective of the group’s status position.
Full Text:

Quick View

Drawing Lines in the Sand: AM v RM 2010 2 SA 223 (ECP)

- Kruuse, Helen

Authors: Kruuse, Helen
Date: 2009
Language: English
Type: Article , text
Identifier: http://hdl.handle.net/10962/54107 , vital:26391 , http://www.ufh.ac.za/speculumjuris/files/pdf/SpeculumJuris_2009_Part_2.pdf
Description: Judge Elna Revelas’s decision in the case of Mohamed v Mohamed 1 may be described as one of those run-of-the-mill applications in terms of rule 43 which are routinely heard on motion court days in any one of our high courts across the country. This case note suggests that her decision belies such a description. Instead, this note suggests that her decision marks a move away from existing jurisprudence on Muslim marriages in a way which may undermine, rather than promote, the recognition and respect for the marriage institutions of different religious systems and beliefs. I tentatively suggest that by granting the rule 43 application the court may have effectively imposed civil marriage obligations on a religious marriage even though the parties had not concluded a marriage in terms of the Marriage Act.2 As such, the decision has potentially radical consequences for parties in Muslim marriages and highlights the complex issues that courts have had to face in the last two decades without any guiding legislation. In order to understand the judgment properly, its context has to be considered. This context includes (1) the numerous judgments extending protection to women in Muslim marriages in the last two decades against the backdrop of the coming into effect of the Constitution of the Republic of South Africa, 1996; and (2) the application by the Women’s Legal Centre Trust (hereafter “WLCT”) to the Constitutional Court to force the President and Parliament to enact legislation to recognise and protect Muslim marriages.
Full Text:

Quick View

Drought, change and resilience in South Africa's arid and semi-arid rangelands

- Vetter, Susan M

Authors: Vetter, Susan M
Date: 2009
Language: English
Type: Article
Identifier: vital:6557 , http://hdl.handle.net/10962/d1006017
Description: Droughts can have serious ecological and economic consequences and will pose an increasing challenge to rangeiand users as the global climate is changing. Finding ways to reduce ecological and economic impacts of drought should thus be a major research thrust. Resilience, defined as the amount of perturbation a social or ecological system can absorb without shifting to a qualitatively different state, has emerged as a prominent concept in ecosystem ecology and more recently as a conceptual framework for understanding and managing complex social-ecological systems. This paper discusses the application and relevance of resilience to understanding and managing ecosystem change, and enhancing the capacity of land users to adapt to droughts. Drought can trigger vegetation change and factors such as grazing management can influence the likelihood of such transitions. Drought can cause differential mortality of perennial plants and this could provide an opportunity for rangeland restoration by opening up establishment sites for desirable species. The capacity of land users to cope with drought is influenced by the resilience of their agro-ecosystems, the diversity of livelihood options, access to resources and institutional support. By these criteria, current agricultural development approaches in South Africa, particularly in communal rangelands and areas of land reform, are unlikely to enhance land users' resilience to drought and other perturbations.
Full Text:

Quick View

Dynamics of larval fish and zooplankton in selected south and west coast estuaries of South Africa

- Montoya-Maya, Phanor Hernando

Authors: Montoya-Maya, Phanor Hernando
Date: 2009
Subjects: Marine zooplankton -- South Africa , Zooplankton -- South Africa , Fishes -- Larvae -- South Africa , Estuarine ecology -- South Africa , Estuaries -- South Africa -- Management , Environmental monitoring -- South Africa , Coastal zone management -- South Africa , Estuarine area conservation -- South Africa
Language: English
Type: Thesis , Masters , MSc
Identifier: vital:5263 , http://hdl.handle.net/10962/d1005107 , Marine zooplankton -- South Africa , Zooplankton -- South Africa , Fishes -- Larvae -- South Africa , Estuarine ecology -- South Africa , Estuaries -- South Africa -- Management , Environmental monitoring -- South Africa , Coastal zone management -- South Africa , Estuarine area conservation -- South Africa
Description: Larval fish and zooplankton assemblages were studied in nine south and west coast estuaries in the cool-temperate and the cool/warm-temperate boundary region between June 2003 and March 2004. This study served to provide new information on previously unstudied estuaries and expand on existing knowledge of larval fish and zooplankton assemblages associated with various estuary types. The south and west coast estuaries sampled in this study showed lower salinities (12.2 - 13.7), lower water temperatures (14.5 - 16.9 °C) and higher turbidities (k = 0.02 - 0.04) in winter and spring while higher salinities (21.7 - 21.8), higher water temperatures (21.7 - 23.1°C) and lower turbidities (k <0.02) were observed in summer and autumn. Mean winter and summer water temperatures in estuaries were lower than those observed in warm-temperate and subtropical systems by other researchers. A total of 49274 larval fishes were caught, comprising 9 orders, 20 families, 29 genera and 47 taxa. The clupeid Gilchristella aestuaria (78.8 %) dominated the larval fish assemblages and occurred in all estuaries. The majority (70 %) of identified species are endemic to southern Africa and 96.4 % of larval fishes caught were estuary-resident species. The zooplankton study yielded a total of 44 taxa, comprising 7 phyla, >20 orders and >35 families. The copepod Pseudodiaptomus hessei dominated (59 %) the zooplankton and occurred in similar densities to those observed in other South African estuaries. Larval fish and zooplankton varied across seasons, peaking simultaneously in summer although zooplankton showed additional density peaks during the closed phase of some estuaries. Both plankton components were more abundant in the oligohaline and mesohaline zones within the estuaries. Freshwater input, estuary type and the biogeography of the area influenced the composition and structure of larval fish and zooplankton assemblages in these estuaries. The findings suggest that the estuaries are functioning as successful breeding areas for the larvae of endemic estuary-resident fish species and that these estuaries have to be managed to ensure an adequate freshwater supply to maintain the biological integrity of the ecosystem, specially the maintenance of the highly productive River-Estuary Interface (REI) regions.
Full Text:

Quick View

Economic diversification of a mining town: a case study of Oranjemund

- Helmuth, Angelo

Authors: Helmuth, Angelo
Date: 2009
Subjects: Economic development -- Namibia -- Oranjemund -- Case studies Mineral industries -- Namibia -- Oranjemund -- Case studies Sustainable development -- Namibia -- Oranjemund
Language: English
Type: Thesis , Masters , MBA
Identifier: vital:723 , http://hdl.handle.net/10962/d1003843
Description: Can mining industries and mining based localities promote Local Economic Development (LED)? This case study, on the mining town of Oranjemund, seeks to examine the economic diversification prospects of the town. Stakeholder views are considered and their aspirations determined, through an interview process. Relevant theories on economic development, growth and sustainability are outline. Lessons are drawn from local and international empirical studies on mining towns. The roles and contributions stakeholders and institutions could realize that could lead to local economic diversification and LED are defined. The opportunities and threats that could affect the town’s LED process are identified. This paper concludes that it is imperative that sound relationships be developed amongst key stakeholders. It further, recommends that a strategic LED plan be designed for Oranjemund and that national government, through the regional and local authority, lead the process.
Full Text:

Quick View

Economic responsiveness in organisational psychology curricula

- Van Niekerk, Roelf

Authors: Van Niekerk, Roelf
Date: 2009
Subjects: Psychology, Industrial -- Study and teaching (Higher) -- South Africa Universities and colleges -- Curricula -- South Africa College graduates -- Employment -- South Africa
Language: English
Type: Thesis , Masters , MEd
Identifier: vital:1319 , http://hdl.handle.net/10962/d1003952
Description: This study focused on a topic at the intersection of two contexts, namely curriculum responsiveness and industrial/organisational psychology (IOP). The rationale for this study is based on two considerations. Firstly, a review of the IOP curricula offered at ten prominent South African universities revealed little overlap. This suggests that academic departments are not guided by shared principles when they implement decisions about the content or sequencing of curriculum content. Secondly, the Department of Education urges academics to design curricula that are relevant and responsive to contemporary conditions. These two considerations motivated the investigation of the following research question: What key performance areas (KPAs) do employers specify when they advertise positions suitable for IOP graduates? The investigation had two aims, namely (a) to systematically analyse the KPAs specified in job advertisements and (b) to compile KPA templates that may be used by IOP departments who wish to revise or transform their curricula. The research design of this study has five characteristics, namely that it is: (a) qualitative, (b) naturalistic, (c), descriptive, (d) applied, and (e) strategic. The study employed a purposive sampling strategy that involved the collection of documentary data (job advertisements aimed at recruiting IOP graduates) over a 52-week period (N=1115). The data was content analysed by means of a six-step documentary analysis method. Specific strategies were employed to enhance the validity of the findings. These strategies focused on credibility, transferability, dependability, and confirmability. Similarly, the ethical standing of the investigation was promoted by addressing four considerations, namely autonomy and respect for dignity, non-maleficence, beneficence, and justice. The data analysis procedure produced comprehensive and detailed qualitative descriptions of (a) 21 occupational categories, (b) 4070 KPA themes and (c) 84 KPA clusters. In addition, the number of occupational categories, KPA themes and KPA clusters were recorded and interpreted. In addition, the data analysis procedure produced comprehensive KPA templates that IOP departments may find useful. The templates reflect the KPAs specified by advertisements aimed at recruiting IOP graduates for a range of occupational categories and were designed to be used as benchmarks against which the economic responsiveness of curricula can be compared.
Full Text:

Quick View

Editorial: environmental-education research in the year of COP 15

- Lotz-Sisitka, Heila, Kronlid, David O

Authors: Lotz-Sisitka, Heila , Kronlid, David O
Date: 2009
Language: English
Type: text , article
Identifier: http://hdl.handle.net/10962/67356 , vital:29080 , https://www.ajol.info/index.php/sajee/article/view/122784
Description: publisher version , Introduction: This year there has literally been a cacophony surrounding the implications of climate change, as the world geared up for the 15th Conference of the Parties (COP 15) in Copenhagen, where it was expected that the largest ever gathering of world leaders would sign binding agreements to reduce carbon emissions to keep global temperatures from rising by more than 2⁰C. As we make the final contributions to the refinement of this editorial, late in December 2009, it is concerning to note that this did not happen, that civil society voices were marginalised at the COP 15 and that there has been little progress on a socially just and ecologically sound global climate change deal. The stark reality remains that developing countries – southern African countries in particular – remain most vulnerable to the risks associated with global climate change. Havnevik (2007) stated a while ago that: The ways in which poverty, consumption and climate change are addressed, tend to blur historical, structural and power features underlying global inequalities. This makes possible the focus on market forces, such as carbon trading, to resolve the problems. However, these market solutions will not suffice, and may only delay a real solution, which will then have to be developed in a situation of more acute global social injustice and possibly deeper conflicts … Issues related to inequality, energy and climate are of a global character: there is no longer one solution for the South and one for the North. (18,19) So where does the current state of climate change and the political failures surrounding responses to climate change leave education research in developing and developed nations? What are the implications for environmental education researchers in southern Africa and elsewhere? These are some of the questions pondered in this edition of the Southern African Journal of Environmental Education (SAJEE). As one of us (Kronlid) reflects in a Think Piece in this journal: ‘the world is one and many and … the complexities associated with climate change means that we have a shared global systematic problem manifested in a myriad different concrete ways in people’s everyday life throughout the globe. We need many different kinds and modes of climate change education research’ (Kronlid, this edition).
Full Text:

Quick View

Effect of laundry activities on in-stream concentrations of linear alkylbenzene sulfonate in a small rural South African river

- Gordon, Andrew K, Muller, Wilhelmine J, Gysman, N, Marshall, S J, Sparham, C J, O'Connor, S M, Whelan, M J

Authors: Gordon, Andrew K , Muller, Wilhelmine J , Gysman, N , Marshall, S J , Sparham, C J , O'Connor, S M , Whelan, M J
Date: 2009
Language: English
Type: text , Article
Identifier: vital:7094 , http://hdl.handle.net/10962/d1012427
Description: In many parts of the world clothes are washed near to or in rivers and streams. Little information is available on resulting concentrations of detergent ingredients or on any potential effects caused. In this study, the fate of a commonly used anionic surfactant, linear alkylbenzene sulphonate (LAS) was investigated in a reach of the Balfour River (Eastern Cape Province, South Africa) which was regularly used as a site for laundry activity. Samples of river water were collected upstream of the main washing site and at a number of locations downstream on several occasions in winter and summer. Sediment samples were also collected and analysed. In addition, a household survey was conducted to ascertain the amount of detergent used and the distribution of washing practices. The results of the survey suggested that the use of riverside locations for laundry activities was seasonal. Most washing tended to be done at home during the winter with riverside sites used more frequently during the summer months. The monitoring data showed that LAS concentrations in water were very variable. They were occasionally high in the immediate vicinity of the laundry site (up to 342 µg L− 1) but were generally very low (< 11 µg L− 1) at downstream monitoring stations, suggesting that LAS was rapidly dissipated by a combination of degradation, hydrodynamic dispersion and dilution. Concentrations in the immediate vicinity of the washing site were lower than expected on the basis of the household survey because most waste water was disposed of on the river bank rather than directly in the river. No ecological effects are expected from LAS emissions at this site.
Full Text:

Quick View

Effect of peripheral fused ring substitution on the optical spectroscopy and electronic structure of metal phthalocyanine complexes

- Chidawanyika, Wadzanai J U, Mack, John, Shimizu, Soji, Kobayashi, Nagao, Nyokong, Tebello

Authors: Chidawanyika, Wadzanai J U , Mack, John , Shimizu, Soji , Kobayashi, Nagao , Nyokong, Tebello
Date: 2009
Subjects: To be catalogued
Language: English
Type: text , article
Identifier: http://hdl.handle.net/10962/263353 , vital:53620 , xlink:href="https://doi.org/10.1142/S1088424609001339"
Description: In this paper the impact of peripheral substitution with a strongly withdrawing fused ring group on the optical spectroscopy of a metal phthalocyanine complex is analyzed. We report the synthesis of [9 (or 10), 16 (or 17), 23 (or 24)-tri-tert-butylimidophthalocyaninato]zinc(II) (ZnttbIPc), which should eventually prove to be a useful precursor for forming dimeric compounds. The electronic structure is analyzed through a detailed analysis of the UV-visible absorption and magnetic circular dichroism spectra and time-dependent density functional theory calculations. Other than a marked splitting of the Q band, the spectrum is broadly similar to that of ZnPc in terms of the main π → π* electronic bands. The vibrational bands differ markedly in the Q band region when an imido group is added to ligand periphery, relative to what is observed in the case of zinc mononaphthotribenzotetraazaporphyrin (Zn3B1N) with an additional fused benzene ring. The absorption and emission spectra lack mirror symmetry as is the case with ZnPc and thus provide possible evidence for a second set of electronic origins in the Q band region arising from n → π* rather then π → π* transitions.
Full Text:

Showing items 161 - 180 of 505