Management, Processing and Analysis of Cryptographic Network Protocols
- Cowie, Bradley, Irwin, Barry V W, Barnett, Richard J
- Authors: Cowie, Bradley , Irwin, Barry V W , Barnett, Richard J
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428687 , vital:72529 , https://d1wqtxts1xzle7.cloudfront.net/30968790/ISSA2009Proceedings-libre.pdf?1393060231=andresponse-content-disposi-tion=inline%3B+filename%3DAN_ANALYSIS_OF_AUTHENTICATION_FOR_PASSIV.pdfandExpires=1714732172andSignature=Ei8RhR2pCSUNGCNE40DugEyFamcyTxPuuRq9gslD~WGlNqPEgG3FL7VFRQCKXhZBWyAfGRjMtBmNDJ7Sjsgex12WxW9Fj8XdpB7Bfz23FuLc-t2YRM-2joKOHJQLxWJlfZiOzxDvVGZeM3zCHj~f3NUeY1~n6PtVtLzNdL8glIg5dzDTTIE6ms2YlxmnO6JvlzQwOWdHaUbHsZzMGOV19UPtBk-UJzHSq3NRyPe4-XNZQLNK-mEEcMGsLk6nkyXIsW2QJ7gtKW1nNkr6EMkAGSOnDai~pSqzb2imspMnlPRigAPPISrNHO79rP51H9bu1WvbRZv1KVkGvM~sRmfl28A__andKey-Pair-Id=APKAJLOHF5GGSLRBV4ZA#page=499
- Description: The use of cryptographic protocols as a means to provide security to web servers and services at the transport layer, by providing both en-cryption and authentication to data transfer, has become increasingly popular. However, we note that it is rather difficult to perform legitimate analysis, intrusion detection and debugging on cryptographic protocols, as the data that passes through is encrypted. In this paper we assume that we have legitimate access to the data and that we have the private key used in transactions and thus we will be able decrypt the data. The objective is to produce a suitable application framework that allows for easy recovery and secure storage of cryptographic keys; including ap-propriate tools to decapsulate traffic and to decrypt live packet streams or precaptured traffic contained in PCAP files. The resultant processing will then be able to provide a clear-text stream which can be used for further analysis.
- Full Text:
- Authors: Cowie, Bradley , Irwin, Barry V W , Barnett, Richard J
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428687 , vital:72529 , https://d1wqtxts1xzle7.cloudfront.net/30968790/ISSA2009Proceedings-libre.pdf?1393060231=andresponse-content-disposi-tion=inline%3B+filename%3DAN_ANALYSIS_OF_AUTHENTICATION_FOR_PASSIV.pdfandExpires=1714732172andSignature=Ei8RhR2pCSUNGCNE40DugEyFamcyTxPuuRq9gslD~WGlNqPEgG3FL7VFRQCKXhZBWyAfGRjMtBmNDJ7Sjsgex12WxW9Fj8XdpB7Bfz23FuLc-t2YRM-2joKOHJQLxWJlfZiOzxDvVGZeM3zCHj~f3NUeY1~n6PtVtLzNdL8glIg5dzDTTIE6ms2YlxmnO6JvlzQwOWdHaUbHsZzMGOV19UPtBk-UJzHSq3NRyPe4-XNZQLNK-mEEcMGsLk6nkyXIsW2QJ7gtKW1nNkr6EMkAGSOnDai~pSqzb2imspMnlPRigAPPISrNHO79rP51H9bu1WvbRZv1KVkGvM~sRmfl28A__andKey-Pair-Id=APKAJLOHF5GGSLRBV4ZA#page=499
- Description: The use of cryptographic protocols as a means to provide security to web servers and services at the transport layer, by providing both en-cryption and authentication to data transfer, has become increasingly popular. However, we note that it is rather difficult to perform legitimate analysis, intrusion detection and debugging on cryptographic protocols, as the data that passes through is encrypted. In this paper we assume that we have legitimate access to the data and that we have the private key used in transactions and thus we will be able decrypt the data. The objective is to produce a suitable application framework that allows for easy recovery and secure storage of cryptographic keys; including ap-propriate tools to decapsulate traffic and to decrypt live packet streams or precaptured traffic contained in PCAP files. The resultant processing will then be able to provide a clear-text stream which can be used for further analysis.
- Full Text:
Managerial perceptions of corporate social responsibility and social practices present at McDonalds South Africa
- Authors: Böckle, Ingrid
- Date: 2009
- Subjects: Social responsibility of business -- South Africa -- Case studies , Business ethics -- South Africa -- Case studies , Management -- Moral and ethical aspects -- South Africa -- Case studies , Executives -- Professional ethics -- South Africa -- Case studies , Corporate governance -- Moral and ethical aspects -- South Africa -- Case studies , Business logistics -- Moral and ethical aspects -- South Africa -- Case studies , McDonald's Corporation
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3300 , http://hdl.handle.net/10962/d1003088
- Description: This study deals with corporate social responsibility (CSR) and focuses on managerial perceptions of CSR at McDonald’s South Africa (SA) and how social responsibility is translated into social practices. The key objectives of the research are: to analyse McDonald’s both internationally and locally in South Africa to establish whether CSR policies exist, then to investigate how these policies are perceived and integrated by outlet managers. Lastly to investigate what kind of social responsibility (SR) involvement, if at all, occurs at outlet level. The research site covers three regions in South Africa, which are the Eastern Cape, Western Cape and Gauteng. The total research sample is 38. 33 interviewees were outlet managers, who were purposively selected, and 5 additional interviews took place with: 2 McDonald’s SA Head Office representatives, 2 interviews with beneficiaries of McDonald’s SR involvement and 1 with the trade union SACCAWU. The research was carried out through questionnaires and semi-structured interviews. The design of this research is based on an interpretive social science approach. The aim of the research was to investigate outlet managers’ perceptions of CSR and social practices present at McDonald’s SA outlets. The key findings of the research indicate that: CSR policies at McDonald’s SA head office are not communicated sufficiently to outlet managers, SR involvement is evident, especially for initiatives focusing on children’s welfare, but far too little occurs at the outlet level. There are also too few checks on social involvement by head office and no formal reporting system is available to the outlets except through an internal magazine, called the Big Mag. There is no official CSR report at McDonald’s SA. The fact that no report exists makes this study more relevant since this research investigates matters pertaining to CSR and social practices. The overall significance of the study is that it brings to the forefront the importance of internal company and external broader regulation which is part of the greater debate of CSR. This is because the analysis of managerial perceptions and implementation of CSR shows some unwarranted discrepancies between policies and practices, locally, nationally and internationally even within the same organisation.
- Full Text:
- Authors: Böckle, Ingrid
- Date: 2009
- Subjects: Social responsibility of business -- South Africa -- Case studies , Business ethics -- South Africa -- Case studies , Management -- Moral and ethical aspects -- South Africa -- Case studies , Executives -- Professional ethics -- South Africa -- Case studies , Corporate governance -- Moral and ethical aspects -- South Africa -- Case studies , Business logistics -- Moral and ethical aspects -- South Africa -- Case studies , McDonald's Corporation
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3300 , http://hdl.handle.net/10962/d1003088
- Description: This study deals with corporate social responsibility (CSR) and focuses on managerial perceptions of CSR at McDonald’s South Africa (SA) and how social responsibility is translated into social practices. The key objectives of the research are: to analyse McDonald’s both internationally and locally in South Africa to establish whether CSR policies exist, then to investigate how these policies are perceived and integrated by outlet managers. Lastly to investigate what kind of social responsibility (SR) involvement, if at all, occurs at outlet level. The research site covers three regions in South Africa, which are the Eastern Cape, Western Cape and Gauteng. The total research sample is 38. 33 interviewees were outlet managers, who were purposively selected, and 5 additional interviews took place with: 2 McDonald’s SA Head Office representatives, 2 interviews with beneficiaries of McDonald’s SR involvement and 1 with the trade union SACCAWU. The research was carried out through questionnaires and semi-structured interviews. The design of this research is based on an interpretive social science approach. The aim of the research was to investigate outlet managers’ perceptions of CSR and social practices present at McDonald’s SA outlets. The key findings of the research indicate that: CSR policies at McDonald’s SA head office are not communicated sufficiently to outlet managers, SR involvement is evident, especially for initiatives focusing on children’s welfare, but far too little occurs at the outlet level. There are also too few checks on social involvement by head office and no formal reporting system is available to the outlets except through an internal magazine, called the Big Mag. There is no official CSR report at McDonald’s SA. The fact that no report exists makes this study more relevant since this research investigates matters pertaining to CSR and social practices. The overall significance of the study is that it brings to the forefront the importance of internal company and external broader regulation which is part of the greater debate of CSR. This is because the analysis of managerial perceptions and implementation of CSR shows some unwarranted discrepancies between policies and practices, locally, nationally and internationally even within the same organisation.
- Full Text:
Manicured
- Authors: Knowles, Corinne R
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , poem
- Identifier: http://hdl.handle.net/10962/468895 , vital:77139 , ISBN 0028-4459 , https://journals.co.za/doi/epdf/10.10520/EJC47808
- Description: New Coin is one of South Africa's most established and influential poetry journals. It publishes poetry, and poetry-related reviews, commentary and interviews. New Coin places a particular emphasis on evolving forms and experimental use of the English language in poetry in the South African context. In this sense it has traced the most exciting trends and currents in contemporary poetry in South Africa for a decade of more. The journal is published twice a year in June and December by the Institute for the Study of English in Africa (ISEA), Rhodes University.
- Full Text:
- Authors: Knowles, Corinne R
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , poem
- Identifier: http://hdl.handle.net/10962/468895 , vital:77139 , ISBN 0028-4459 , https://journals.co.za/doi/epdf/10.10520/EJC47808
- Description: New Coin is one of South Africa's most established and influential poetry journals. It publishes poetry, and poetry-related reviews, commentary and interviews. New Coin places a particular emphasis on evolving forms and experimental use of the English language in poetry in the South African context. In this sense it has traced the most exciting trends and currents in contemporary poetry in South Africa for a decade of more. The journal is published twice a year in June and December by the Institute for the Study of English in Africa (ISEA), Rhodes University.
- Full Text:
Mariculture as a means to add value to the east coast rock lobster Panulirus homarus rubellus subsistence fishery : a physiological approach to define transport and growout protocols for wild caught juveniles
- Authors: Kemp, Justin Oliver Gordon
- Date: 2009
- Subjects: Lobster fisheries -- South Africa , Lobster culture -- South Africa , Lobsters -- Growth -- South Africa , Mariculture -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5299 , http://hdl.handle.net/10962/d1005144
- Description: In a context of declining capture fisheries and public pressure for greater access to marine resources, marine aquaculture is receiving increasing interest from the South African government as a means to increase the diversity of economic activities in coastal regions, thereby providing employment and reducing poverty. The east coast rock lobster Panulirus homarus rubellus is currently harvested by subsistence fisherman along the former Transkei coastline of south-east South Africa and presents a possible opportunity for ongrowing wild juvenile lobsters in culture facilities. Lack of compliance coupled with poor enforcement of the minimum size limit (65 mm carapace length) has resulted in the ongoing harvest of undersize size lobsters by subsistence fishers. Generally, fishers either consume these undersize lobsters or sell them to tourists for low prices. In line with international trends in rock lobster aquaculture, interest has subsequently arisen in the possibilities of ongrowing these undersize lobsters as a means of adding value to the P. h rubellus resource for subsistence fishers. The aim of this physiological study was to assess the biological feasibility of harvesting, transporting and culturing wild caught juvenile lobsters, thereby provide empirical data to inform the development of suitable transport and culture protocols. The experimental objectives were to asses the effect of temperature on growth and survival of P. h. rubellus, as well as the effects of a suite of extrinsic and intrinsic factors on ammonia excretion and oxygen consumption. Juvenile lobsters were collected by hand from near-shore reefs (2-15 m depth) off Mdumbi in the former Transkei, Eastern Cape Province and transported by road (7 hours) to the Port Alfred Marine Research Laboratory where they were held in a recirculating culture system. The effect of temperature over a range of 9.7 °C (18.9±0.7 to 28.6±1.5 °C) on the growth and survival of juvenile P. h. rubellus fed a diet of fresh mussel flesh was investigated. Specific growth rate (SGR) was significantly different between temperatures (p = 0.01), with the highest values recorded for the 24 °C and 28 °C treatments. There was no significant difference in moult increment (MI) between temperatures, however, intermoult period (IMP) differed significantly between temperatures (p = 0.0015) with mean IMP lowest at 24 °C, although not significantly different from the means of the 26 °C and 28 °C treatments. IMP was highest at 19 °C and 21 °C. Apparent feed intake was significantly different between treatments (p < 0.0001) and exhibited a strong positive correlation with increasing temperature. Food conversion ratio (FCR) differed significantly between temperatures (p = 0.02) with 24 °C exhibiting the most efficient FCR. The results for growth rate and food conversion efficiency suggested that 24 °C is optimal for the growout of juvenile P. h. rubellus. In the second study, the effect of body weight, emersion, daily rhythm, feeding and ambient ammonia on the total ammonia nitrogen (TAN) excretion rate was investigated. Body weight (n = 16, range of 16.8 – 322 g) was positively correlated to daytime TAN excretion rate (mg h⁻¹). Re-immersion after one hour emersion in a moist environment was characterized by a significant increase in TAN excretion rate for the first hour compared to pre-immersion levels. The amount of TAN excreted during this period was as expected if basal TAN excretion rates were maintained during emersion. TAN excretion rates returned to pre-emersion levels by the end of the second hour. There was no evidence of a daily rhythm in TAN excretion rate for P. h. rubellus. TAN excretion rates were elevated following feeding. An initial peak in TAN excretion rate after seven hours (7.58 times pre-feeding rate) was followed by a smaller peak after 13 hours (6.69 times pre-feeding rate). TAN excretion rate dropped to levels not significantly different from pre-feeding levels after 23 hours and consistently returned to pre-feeding levels after 42 hours. The TAN excretion rates of lobster exposed for two hours to an ambient TAN concentration of 1.02±0.10 mg l⁻¹ and 2.3± 0.2 mg l⁻¹ were not significantly different from TAN excretion rates recorded at low ambient water TAN prior to exposure. Exposure to an ambient TAN concentration of 4.45±0.78 mg l⁻¹ had a significant effect on the TAN excretion rate, with pronounced ammonia uptake occurring for all animals at this concentration. The third study investigated the effects of body weight, diurnal rhythm, feeding and emersion on lobster oxygen consumption. Body weight was positively correlated to both standard and active oxygen consumption (mg O2 h⁻¹) while body weight was negatively correlated to mass-specific standard oxygen uptake (mg O2 g⁻¹ h⁻¹). Diurnal rhythm exhibited a strong effect on the lobsters oxygen consumption, with average night time values 67% greater than those recorded during the day. This was related to activity driven by intrinsic nocturnal foraging behaviour. Feeding resulted in a classic specific dynamic action (SDA) response, with postprandial oxygen consumption increasing to a peak before decreasing gradually to preprandial levels. Emersion resulted in a significant increase in oxygen consumption, with lobsters rapidly recovering to pre-emersion levels after four hours. Results from these studies suggest that the capture, transport and culture of juvenile P. h. rubellus is biologically feasible. Empirical data generated were used to provide recommendations regarding species optimised transport and culture protocols. A purge time of 48 hours before transport is suggested to ensure that ammonia excretion and oxygen consumption are at basal levels. Furthermore, emersed transport for a period of one hour is characterised by rapid recovery upon re-immersion. In order to prevent the accumulation of stressors, it is suggested that consecutive periods of emersion are interjected with recovery periods (five hours) in water to allow the removal of accumulated ammonia and repayment of the oxygen debt incurred. The recorded ammonia rates indicate that a biological filter size of 4.8 m³ is recommended for 1000 kg of fed lobsters in a culture situation, although this can be reduced considerably if lobsters are being held without feeding (0.72 m³). A flow rate of 112 l kg⁻¹ h⁻¹ is required to meet the metabolic requirements of lobsters. Bottlenecks to the viable commercial culture of P. h. rubellus, and the ability of this practice to provide the socio-economic benefits that were envisioned, are discussed.
- Full Text:
- Authors: Kemp, Justin Oliver Gordon
- Date: 2009
- Subjects: Lobster fisheries -- South Africa , Lobster culture -- South Africa , Lobsters -- Growth -- South Africa , Mariculture -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5299 , http://hdl.handle.net/10962/d1005144
- Description: In a context of declining capture fisheries and public pressure for greater access to marine resources, marine aquaculture is receiving increasing interest from the South African government as a means to increase the diversity of economic activities in coastal regions, thereby providing employment and reducing poverty. The east coast rock lobster Panulirus homarus rubellus is currently harvested by subsistence fisherman along the former Transkei coastline of south-east South Africa and presents a possible opportunity for ongrowing wild juvenile lobsters in culture facilities. Lack of compliance coupled with poor enforcement of the minimum size limit (65 mm carapace length) has resulted in the ongoing harvest of undersize size lobsters by subsistence fishers. Generally, fishers either consume these undersize lobsters or sell them to tourists for low prices. In line with international trends in rock lobster aquaculture, interest has subsequently arisen in the possibilities of ongrowing these undersize lobsters as a means of adding value to the P. h rubellus resource for subsistence fishers. The aim of this physiological study was to assess the biological feasibility of harvesting, transporting and culturing wild caught juvenile lobsters, thereby provide empirical data to inform the development of suitable transport and culture protocols. The experimental objectives were to asses the effect of temperature on growth and survival of P. h. rubellus, as well as the effects of a suite of extrinsic and intrinsic factors on ammonia excretion and oxygen consumption. Juvenile lobsters were collected by hand from near-shore reefs (2-15 m depth) off Mdumbi in the former Transkei, Eastern Cape Province and transported by road (7 hours) to the Port Alfred Marine Research Laboratory where they were held in a recirculating culture system. The effect of temperature over a range of 9.7 °C (18.9±0.7 to 28.6±1.5 °C) on the growth and survival of juvenile P. h. rubellus fed a diet of fresh mussel flesh was investigated. Specific growth rate (SGR) was significantly different between temperatures (p = 0.01), with the highest values recorded for the 24 °C and 28 °C treatments. There was no significant difference in moult increment (MI) between temperatures, however, intermoult period (IMP) differed significantly between temperatures (p = 0.0015) with mean IMP lowest at 24 °C, although not significantly different from the means of the 26 °C and 28 °C treatments. IMP was highest at 19 °C and 21 °C. Apparent feed intake was significantly different between treatments (p < 0.0001) and exhibited a strong positive correlation with increasing temperature. Food conversion ratio (FCR) differed significantly between temperatures (p = 0.02) with 24 °C exhibiting the most efficient FCR. The results for growth rate and food conversion efficiency suggested that 24 °C is optimal for the growout of juvenile P. h. rubellus. In the second study, the effect of body weight, emersion, daily rhythm, feeding and ambient ammonia on the total ammonia nitrogen (TAN) excretion rate was investigated. Body weight (n = 16, range of 16.8 – 322 g) was positively correlated to daytime TAN excretion rate (mg h⁻¹). Re-immersion after one hour emersion in a moist environment was characterized by a significant increase in TAN excretion rate for the first hour compared to pre-immersion levels. The amount of TAN excreted during this period was as expected if basal TAN excretion rates were maintained during emersion. TAN excretion rates returned to pre-emersion levels by the end of the second hour. There was no evidence of a daily rhythm in TAN excretion rate for P. h. rubellus. TAN excretion rates were elevated following feeding. An initial peak in TAN excretion rate after seven hours (7.58 times pre-feeding rate) was followed by a smaller peak after 13 hours (6.69 times pre-feeding rate). TAN excretion rate dropped to levels not significantly different from pre-feeding levels after 23 hours and consistently returned to pre-feeding levels after 42 hours. The TAN excretion rates of lobster exposed for two hours to an ambient TAN concentration of 1.02±0.10 mg l⁻¹ and 2.3± 0.2 mg l⁻¹ were not significantly different from TAN excretion rates recorded at low ambient water TAN prior to exposure. Exposure to an ambient TAN concentration of 4.45±0.78 mg l⁻¹ had a significant effect on the TAN excretion rate, with pronounced ammonia uptake occurring for all animals at this concentration. The third study investigated the effects of body weight, diurnal rhythm, feeding and emersion on lobster oxygen consumption. Body weight was positively correlated to both standard and active oxygen consumption (mg O2 h⁻¹) while body weight was negatively correlated to mass-specific standard oxygen uptake (mg O2 g⁻¹ h⁻¹). Diurnal rhythm exhibited a strong effect on the lobsters oxygen consumption, with average night time values 67% greater than those recorded during the day. This was related to activity driven by intrinsic nocturnal foraging behaviour. Feeding resulted in a classic specific dynamic action (SDA) response, with postprandial oxygen consumption increasing to a peak before decreasing gradually to preprandial levels. Emersion resulted in a significant increase in oxygen consumption, with lobsters rapidly recovering to pre-emersion levels after four hours. Results from these studies suggest that the capture, transport and culture of juvenile P. h. rubellus is biologically feasible. Empirical data generated were used to provide recommendations regarding species optimised transport and culture protocols. A purge time of 48 hours before transport is suggested to ensure that ammonia excretion and oxygen consumption are at basal levels. Furthermore, emersed transport for a period of one hour is characterised by rapid recovery upon re-immersion. In order to prevent the accumulation of stressors, it is suggested that consecutive periods of emersion are interjected with recovery periods (five hours) in water to allow the removal of accumulated ammonia and repayment of the oxygen debt incurred. The recorded ammonia rates indicate that a biological filter size of 4.8 m³ is recommended for 1000 kg of fed lobsters in a culture situation, although this can be reduced considerably if lobsters are being held without feeding (0.72 m³). A flow rate of 112 l kg⁻¹ h⁻¹ is required to meet the metabolic requirements of lobsters. Bottlenecks to the viable commercial culture of P. h. rubellus, and the ability of this practice to provide the socio-economic benefits that were envisioned, are discussed.
- Full Text:
Meeting democracy’s challenge developments:
- Authors: Dugmore, Harry
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159389 , vital:40293 , https://hdl.handle.net/10520/EJC139935
- Description: In a context of declining public participation, can mobile phone technology and 'new media' be used to involve more people in local decision-making, asks Harry Dug more in this exploration of the implications of mobile communication on journalism in the developing world.
- Full Text:
- Authors: Dugmore, Harry
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159389 , vital:40293 , https://hdl.handle.net/10520/EJC139935
- Description: In a context of declining public participation, can mobile phone technology and 'new media' be used to involve more people in local decision-making, asks Harry Dug more in this exploration of the implications of mobile communication on journalism in the developing world.
- Full Text:
Metal (Co, Fe) tribenzotetraazachlorin–fullerene conjugates
- Ozoemena, Kenneth I, Mamuru, Solomon A, Fukuda, Takamitsu, Kobayashi, Nagao, Nyokong, Tebello
- Authors: Ozoemena, Kenneth I , Mamuru, Solomon A , Fukuda, Takamitsu , Kobayashi, Nagao , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263464 , vital:53630 , xlink:href="https://doi.org/10.1016/j.elecom.2009.04.011"
- Description: Novel hexabutylsulphonyltribenzotetraazachlorin–fullerene (C60) complexes of iron (FeHBSTBTAC–C60) and cobalt (CoHBSTBTAC–C60) have been synthesized and their electrochemistry and oxygen reduction reaction (ORR) compared with their octabutylsulphonylphthalocyanine analogues (FeOBSPc and CoOBSPc). It is proved that electron-withdrawing substituents (–SO2Bu and C60) on phthalocyanine macrocycle exhibit distinct impact on the solution electrochemistry of these metallophthalocyanine (MPc) complexes. The more electron-withdrawing C60 substituent suppressed ORR compared to the –SO2Bu in alkaline medium. FeOBSPc showed the best ORR activity involving a direct 4-electron mechanism, a rate constant of ∼1 × 108 cm3 mol−1 s−1 and a Tafel slope of −171 mV dec−1.
- Full Text:
- Authors: Ozoemena, Kenneth I , Mamuru, Solomon A , Fukuda, Takamitsu , Kobayashi, Nagao , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263464 , vital:53630 , xlink:href="https://doi.org/10.1016/j.elecom.2009.04.011"
- Description: Novel hexabutylsulphonyltribenzotetraazachlorin–fullerene (C60) complexes of iron (FeHBSTBTAC–C60) and cobalt (CoHBSTBTAC–C60) have been synthesized and their electrochemistry and oxygen reduction reaction (ORR) compared with their octabutylsulphonylphthalocyanine analogues (FeOBSPc and CoOBSPc). It is proved that electron-withdrawing substituents (–SO2Bu and C60) on phthalocyanine macrocycle exhibit distinct impact on the solution electrochemistry of these metallophthalocyanine (MPc) complexes. The more electron-withdrawing C60 substituent suppressed ORR compared to the –SO2Bu in alkaline medium. FeOBSPc showed the best ORR activity involving a direct 4-electron mechanism, a rate constant of ∼1 × 108 cm3 mol−1 s−1 and a Tafel slope of −171 mV dec−1.
- Full Text:
Metallophthalocyanine Based Carbon Paste Electrodes for the Determination of 2′, 3′‐Dideoxyinosine
- Ozoemena, Kenneth I, Stefan-van Staden, Raluca-Ioana, Nyokong, Tebello
- Authors: Ozoemena, Kenneth I , Stefan-van Staden, Raluca-Ioana , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263430 , vital:53627 , xlink:href="https://doi.org/10.1002/elan.200904581"
- Description: Novel electrochemical sensors based on carbon paste impregnated with metallopthalocyanine (MPc, M=Co, Fe) complexes, have been constructed for the assay of anti-HIV drug 2′,3′-dideoxyinosine (didanosine, DDI). Both modified electrodes showed electrocatalytic activity towards the oxidation of dideoxyinosine in phosphate buffer pH 7.4 with a working concentration range of 10−6–10−4 mol/L and a detection limit of 10−7 mol/L magnitude order. The sensor proved to be highly reliable for the assay of the purity of DDI - raw material as well as for the uniformity content test of Videx tablets.
- Full Text:
- Authors: Ozoemena, Kenneth I , Stefan-van Staden, Raluca-Ioana , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263430 , vital:53627 , xlink:href="https://doi.org/10.1002/elan.200904581"
- Description: Novel electrochemical sensors based on carbon paste impregnated with metallopthalocyanine (MPc, M=Co, Fe) complexes, have been constructed for the assay of anti-HIV drug 2′,3′-dideoxyinosine (didanosine, DDI). Both modified electrodes showed electrocatalytic activity towards the oxidation of dideoxyinosine in phosphate buffer pH 7.4 with a working concentration range of 10−6–10−4 mol/L and a detection limit of 10−7 mol/L magnitude order. The sensor proved to be highly reliable for the assay of the purity of DDI - raw material as well as for the uniformity content test of Videx tablets.
- Full Text:
Microsatellite markers for the roman, Chrysoblephus laticeps (Teleostei: Sparidae), an overexploited seabream from South Africa
- Teske, Peter R, Cowley, Paul D, Forget, Fabian R, Beheregaray, Luciano B
- Authors: Teske, Peter R , Cowley, Paul D , Forget, Fabian R , Beheregaray, Luciano B
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/445690 , vital:74414 , https://doi.org/10.1111/j.1755-0998.2009.02595.x
- Description: Eleven polymorphic microsatellite loci were developed from an enrichment library of the roman, Chrysoblephus laticeps, and characterized for 40 individuals collected in Africa's largest and oldest Marine Protected Area (MPA), the Tsitsikamma National Park. The number of alleles per locus ranged from three to 19, and heterozygosities ranged from 0.20 to 0.85. A significant departure from Hardy–Weinberg equilibrium was detected for one locus, and linkage disequilibrium was identified among three pairs of loci. The markers will be useful to detect whether populations resident in MPAs along the South African coast are genetically connected, and whether there is spillover of recruits into adjacent exploited areas.
- Full Text:
- Authors: Teske, Peter R , Cowley, Paul D , Forget, Fabian R , Beheregaray, Luciano B
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/445690 , vital:74414 , https://doi.org/10.1111/j.1755-0998.2009.02595.x
- Description: Eleven polymorphic microsatellite loci were developed from an enrichment library of the roman, Chrysoblephus laticeps, and characterized for 40 individuals collected in Africa's largest and oldest Marine Protected Area (MPA), the Tsitsikamma National Park. The number of alleles per locus ranged from three to 19, and heterozygosities ranged from 0.20 to 0.85. A significant departure from Hardy–Weinberg equilibrium was detected for one locus, and linkage disequilibrium was identified among three pairs of loci. The markers will be useful to detect whether populations resident in MPAs along the South African coast are genetically connected, and whether there is spillover of recruits into adjacent exploited areas.
- Full Text:
Mobile monitors: protecting the will of the people
- Authors: Dugmore, Harry
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159377 , vital:40292 , https://hdl.handle.net/10520/EJC139912
- Description: The use of mobile phone technology in recent African elections has empowered citizens, allowing them to put in place the checks and balances needed to make elections freer and fairer in Africa - and elsewhere in the world, writes Harry Dugmore.
- Full Text:
- Authors: Dugmore, Harry
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159377 , vital:40292 , https://hdl.handle.net/10520/EJC139912
- Description: The use of mobile phone technology in recent African elections has empowered citizens, allowing them to put in place the checks and balances needed to make elections freer and fairer in Africa - and elsewhere in the world, writes Harry Dugmore.
- Full Text:
Models of development for blowfly sister species Chrysomya chloropyga and Chrysomya putoria
- Richards, Cameron S, Crous, Kendall L, Villet, Martin H
- Authors: Richards, Cameron S , Crous, Kendall L , Villet, Martin H
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/${Handle} , vital:73967 , https://doi.org/10.1111/j.1365-2915.2008.00767.x
- Description: Developmental curves for the sister species Chrysomya chloropyga (Wiedemann, 1818) and Chrysomya putoria (Wiedemann, 1830) (Diptera: Calliphoridae) were established at eight and 10 different constant temperatures, respectively, using developmental landmarks and body length as measures of age. The thermal summation constants (K) and developmental threshold (D0) were calculated for five developmental landmarks using a previously described method. Isomorphen and isomegalen diagrams were also constructed for the purpose of estimating postmortem intervals (PMIs). Chrysomya chloropyga had an average developmental threshold value (D0) of 10.91 °C (standard error [SE] = 0.94 °C, n = 5), significantly lower than that of C. putoria (13.42 °C, SE = 0.45 °C, n = 5) (paired t‐test: t = − 4.63, d.f. = 8, P 0.00). Similarly, K values for C. chloropyga were larger than those for C. putoria for all developmental events except onset of the wandering phase. These are the first data that can be used to calculate minimum PMIs and predict population growth of C. chloropyga and C. putoria in Africa; the data indicate that developmental data for one of these species cannot be used as surrogate data for the sister species.
- Full Text:
- Authors: Richards, Cameron S , Crous, Kendall L , Villet, Martin H
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/${Handle} , vital:73967 , https://doi.org/10.1111/j.1365-2915.2008.00767.x
- Description: Developmental curves for the sister species Chrysomya chloropyga (Wiedemann, 1818) and Chrysomya putoria (Wiedemann, 1830) (Diptera: Calliphoridae) were established at eight and 10 different constant temperatures, respectively, using developmental landmarks and body length as measures of age. The thermal summation constants (K) and developmental threshold (D0) were calculated for five developmental landmarks using a previously described method. Isomorphen and isomegalen diagrams were also constructed for the purpose of estimating postmortem intervals (PMIs). Chrysomya chloropyga had an average developmental threshold value (D0) of 10.91 °C (standard error [SE] = 0.94 °C, n = 5), significantly lower than that of C. putoria (13.42 °C, SE = 0.45 °C, n = 5) (paired t‐test: t = − 4.63, d.f. = 8, P 0.00). Similarly, K values for C. chloropyga were larger than those for C. putoria for all developmental events except onset of the wandering phase. These are the first data that can be used to calculate minimum PMIs and predict population growth of C. chloropyga and C. putoria in Africa; the data indicate that developmental data for one of these species cannot be used as surrogate data for the sister species.
- Full Text:
Molecular and biochemical analysis of the diet of the black rhinoceros
- Authors: Kgopa, Ananias Hodi
- Date: 2009 , 2013-07-15
- Subjects: Black rhinoceros -- South Africa -- Eastern Cape , Browse (Animal food) -- South Africa -- Eastern Cape -- Analysis , Black rhinoceros -- Manure -- Analysis , Phenols , Antioxidants , Plant ecology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4064 , http://hdl.handle.net/10962/d1004721 , Black rhinoceros -- South Africa -- Eastern Cape , Browse (Animal food) -- South Africa -- Eastern Cape -- Analysis , Black rhinoceros -- Manure -- Analysis , Phenols , Antioxidants , Plant ecology -- South Africa -- Eastern Cape
- Description: The black rhinoceros, Diceros bicornis, is listed as critically endangered. The black rhinoceros population in the Great Fish River Reserve (GFRR) has increased steadily to a current estimate of one hundred animals since the re-introduction of four animals in 1986. In an effort to contribute to the effective conservation and management of this species, dietary composition was studied in the medium Portulcaria thicket vegetation of the GFRR. This study used a molecular approach to determine the diet of the black rhinoceros of the GFRR by sequencing the ribulose bisphosphate carboxylase large subunit (rbcL) gene in plants and dung. Twenty-three plant species were collected from the reserve, and 802 bp of the rbcL gene were sequenced. These plant sequences were used as a reference database for the identification of plant sequences generated from black rhinoceros dung. Initial studies investigated the amplification, cloning and sequencing of DNA extracted from the dung samples which indicated the viability of the molecular approach. Thereafter, dung generated rbcL DNA was analyzed by GS FLX sequencing. Of the plant sequences identified by comparison to the GenBank database, Carissa bispinosa was the most prevalent. The study further characterized the antioxidant activities and phenolic content of plants eaten by the black rhinoceros using four different assays. Phyllanthus verrucosus, Putterlickia pyracantha, Maytenus capitata, Euclea undulata and Ozoroa mucrunata consistently had high antioxidant activities when assayed against 2,2-azinobis (3-ethyl benzothiazolium-6-sulfonic acid) (ABTSʹ⁺), 2,2-diphenyl-1-picrylhydrazyl (DPPHʹ), and ferric reducing antioxidant potentials (FRAP) and phenolic content when evaluated using the Folin-Ciocalteu assay. The majority of plants investigated showed low antioxidant potentials and low phenolic content. The extent to which antioxidants influenced the browse selection by the black rhinoceros remains inconclusive.
- Full Text:
- Authors: Kgopa, Ananias Hodi
- Date: 2009 , 2013-07-15
- Subjects: Black rhinoceros -- South Africa -- Eastern Cape , Browse (Animal food) -- South Africa -- Eastern Cape -- Analysis , Black rhinoceros -- Manure -- Analysis , Phenols , Antioxidants , Plant ecology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4064 , http://hdl.handle.net/10962/d1004721 , Black rhinoceros -- South Africa -- Eastern Cape , Browse (Animal food) -- South Africa -- Eastern Cape -- Analysis , Black rhinoceros -- Manure -- Analysis , Phenols , Antioxidants , Plant ecology -- South Africa -- Eastern Cape
- Description: The black rhinoceros, Diceros bicornis, is listed as critically endangered. The black rhinoceros population in the Great Fish River Reserve (GFRR) has increased steadily to a current estimate of one hundred animals since the re-introduction of four animals in 1986. In an effort to contribute to the effective conservation and management of this species, dietary composition was studied in the medium Portulcaria thicket vegetation of the GFRR. This study used a molecular approach to determine the diet of the black rhinoceros of the GFRR by sequencing the ribulose bisphosphate carboxylase large subunit (rbcL) gene in plants and dung. Twenty-three plant species were collected from the reserve, and 802 bp of the rbcL gene were sequenced. These plant sequences were used as a reference database for the identification of plant sequences generated from black rhinoceros dung. Initial studies investigated the amplification, cloning and sequencing of DNA extracted from the dung samples which indicated the viability of the molecular approach. Thereafter, dung generated rbcL DNA was analyzed by GS FLX sequencing. Of the plant sequences identified by comparison to the GenBank database, Carissa bispinosa was the most prevalent. The study further characterized the antioxidant activities and phenolic content of plants eaten by the black rhinoceros using four different assays. Phyllanthus verrucosus, Putterlickia pyracantha, Maytenus capitata, Euclea undulata and Ozoroa mucrunata consistently had high antioxidant activities when assayed against 2,2-azinobis (3-ethyl benzothiazolium-6-sulfonic acid) (ABTSʹ⁺), 2,2-diphenyl-1-picrylhydrazyl (DPPHʹ), and ferric reducing antioxidant potentials (FRAP) and phenolic content when evaluated using the Folin-Ciocalteu assay. The majority of plants investigated showed low antioxidant potentials and low phenolic content. The extent to which antioxidants influenced the browse selection by the black rhinoceros remains inconclusive.
- Full Text:
Movement bahaviour of three South African inshore sparid species in rocky intertidal and shallow subtidal habitats
- Authors: Watt-Pringle, Peter Andrew
- Date: 2009
- Subjects: Sparidae -- South Africa , Diplodus , Sparodon Durbanensis , Fisheries -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5302 , http://hdl.handle.net/10962/d1005147 , Sparidae -- South Africa , Diplodus , Sparodon Durbanensis , Fisheries -- South Africa
- Description: This study investigated the movement behaviour of three inshore South African sparids – blacktail (Diplodus sargus capensis), zebra (Diplodus cervinus hottentotus) and white musselcracker (Sparodon durbanensis), popular inshore fishery species caught in appreciable numbers along much of the South African coast. The first study component examined movements of juveniles in a rocky intertidal nursery area at Schoenmakerskop near Port Elizabeth. Juveniles in a single gully were tagged with Visible Implant Elastomer (VIE) and resighted at the study site on snorkelling gear over a seven-month period. Tagged zebra and musselcracker displayed limited movement between potential low tide refuges, being observed repeatedly in the same gully over the full duration of the study. However, blacktail displayed greater movements and were seen infrequently in the later period of the study, probably having undergone an ontogenetic habitat shift to subtidal areas. There was evidence that blacktail maintain use of their intertidal nursery over high tide, during which the other two species moved into shallower areas adjacent to their low tide refuge. The results of three national tagging programs were analysed to determine the movement patterns of adolescent and adult fishes. The coast-wide ORI-WWF National Voluntary Tagging Program and two dedicated research programs in marine protected areas (MPAs) at De Hoop MPA and Tsitsikamma National Park (TNP) recorded few large-scale movements of tagged adult blacktail, zebra and juvenile musselcracker. High spatial-resolution data from the TNP suggested movements were usually on scales far smaller than one km. Together with long periods at liberty for many recaptured individuals, this suggests these fishes are longterm residents of small home range areas. However, tagged musselcracker over 600 mm forklength (adults) were observed to make large-scale movements, including some in excess of 800 km from Eastern Cape to KwaZulu-Natal waters. Predominantly eastward movements of adults recaptured during the spawning season indicate seasonal spawning migrations that occur in different regions of the coast. These enable the use of prevailing oceanographic currents to disperse eggs and larvae to suitable rocky nursery habitat. The third component of this study made use of high-resolution data on the temporal and spatial distribution of catches by scientific angling in the TNP to examine the daily activity patterns of the study species in relation to diel and tidal cycles, and habitat use. Blacktail capture probability was correlated with the diurnal light cycle, with peaks close to twilight suggesting elevated crepuscular foraging activity. Catches of blacktail, zebra and small musselcracker were correlated with the tidal cycle, foraging peaking over high tide periods. All three species used shallow inshore habitats extensively for foraging, blacktail showing a preference for sandy areas, while zebra and small musselcracker preferred shallow reef. Capture probability of larger musselcracker, however, was unrelated to habitat, possibly evidence of increasing area and habitat use with an ontogenetic change in diet. The lifetime movement patterns of these three species are discussed in relation to conservation measures and their management in South African fisheries. Restricted movement throughout post-settlement life for blacktail and zebra, and during the juvenile phase for musselcracker, makes local populations vulnerable to overexploitation. At present, MPAs probably play an important role in protecting local blacktail and zebra populations from overexploitation, and limited post-settlement movements mean the degree of larval dispersal between protected and adjacent areas will likely determine the effectiveness of MPAs in enhancing fisheries for these species. By contrast, MPAs likely provide recruits to fisheries for musselcracker during ontogenetic movements and dispersal from MPAs during spawning migrations. MPAs only offer partial protection to adult musselcracker populations in the spawning season, but this could nevertheless be significant under high levels of exploitation.
- Full Text:
- Authors: Watt-Pringle, Peter Andrew
- Date: 2009
- Subjects: Sparidae -- South Africa , Diplodus , Sparodon Durbanensis , Fisheries -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5302 , http://hdl.handle.net/10962/d1005147 , Sparidae -- South Africa , Diplodus , Sparodon Durbanensis , Fisheries -- South Africa
- Description: This study investigated the movement behaviour of three inshore South African sparids – blacktail (Diplodus sargus capensis), zebra (Diplodus cervinus hottentotus) and white musselcracker (Sparodon durbanensis), popular inshore fishery species caught in appreciable numbers along much of the South African coast. The first study component examined movements of juveniles in a rocky intertidal nursery area at Schoenmakerskop near Port Elizabeth. Juveniles in a single gully were tagged with Visible Implant Elastomer (VIE) and resighted at the study site on snorkelling gear over a seven-month period. Tagged zebra and musselcracker displayed limited movement between potential low tide refuges, being observed repeatedly in the same gully over the full duration of the study. However, blacktail displayed greater movements and were seen infrequently in the later period of the study, probably having undergone an ontogenetic habitat shift to subtidal areas. There was evidence that blacktail maintain use of their intertidal nursery over high tide, during which the other two species moved into shallower areas adjacent to their low tide refuge. The results of three national tagging programs were analysed to determine the movement patterns of adolescent and adult fishes. The coast-wide ORI-WWF National Voluntary Tagging Program and two dedicated research programs in marine protected areas (MPAs) at De Hoop MPA and Tsitsikamma National Park (TNP) recorded few large-scale movements of tagged adult blacktail, zebra and juvenile musselcracker. High spatial-resolution data from the TNP suggested movements were usually on scales far smaller than one km. Together with long periods at liberty for many recaptured individuals, this suggests these fishes are longterm residents of small home range areas. However, tagged musselcracker over 600 mm forklength (adults) were observed to make large-scale movements, including some in excess of 800 km from Eastern Cape to KwaZulu-Natal waters. Predominantly eastward movements of adults recaptured during the spawning season indicate seasonal spawning migrations that occur in different regions of the coast. These enable the use of prevailing oceanographic currents to disperse eggs and larvae to suitable rocky nursery habitat. The third component of this study made use of high-resolution data on the temporal and spatial distribution of catches by scientific angling in the TNP to examine the daily activity patterns of the study species in relation to diel and tidal cycles, and habitat use. Blacktail capture probability was correlated with the diurnal light cycle, with peaks close to twilight suggesting elevated crepuscular foraging activity. Catches of blacktail, zebra and small musselcracker were correlated with the tidal cycle, foraging peaking over high tide periods. All three species used shallow inshore habitats extensively for foraging, blacktail showing a preference for sandy areas, while zebra and small musselcracker preferred shallow reef. Capture probability of larger musselcracker, however, was unrelated to habitat, possibly evidence of increasing area and habitat use with an ontogenetic change in diet. The lifetime movement patterns of these three species are discussed in relation to conservation measures and their management in South African fisheries. Restricted movement throughout post-settlement life for blacktail and zebra, and during the juvenile phase for musselcracker, makes local populations vulnerable to overexploitation. At present, MPAs probably play an important role in protecting local blacktail and zebra populations from overexploitation, and limited post-settlement movements mean the degree of larval dispersal between protected and adjacent areas will likely determine the effectiveness of MPAs in enhancing fisheries for these species. By contrast, MPAs likely provide recruits to fisheries for musselcracker during ontogenetic movements and dispersal from MPAs during spawning migrations. MPAs only offer partial protection to adult musselcracker populations in the spawning season, but this could nevertheless be significant under high levels of exploitation.
- Full Text:
Mulch tower treatment system for greywater reuse Part II: destructive testing and effluent treatment
- Tandlich, Roman, Zuma, Bongumusa M, Whittington-Jones, Kevin J, Burgess, Jo E
- Authors: Tandlich, Roman , Zuma, Bongumusa M , Whittington-Jones, Kevin J , Burgess, Jo E
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71547 , vital:29863 , https://doi.org/10.1016/j.desal.2008.03.031
- Description: The mulch tower (MT) system described in Part I was tested to failure to determine its range of operating conditions. An increase in the influent temperature led to a statistically significant release of components of the chemical oxygen demand (COD) and the five day biochemical oxygen demand (BOD5), as well as phosphates from the MT system. Heterotrophic plate count (HPC) of the mulch layer dropped from 1.2 (± 0.6) × 106/g dry weight to 1.5 (± 0.3) × 105/g dry weight of the mulch layer with increases of the influent temperature. This indicates that the increase in influent temperature killed off some of the active biomass in the MT biofilm. After a five day drying period under active aeration, the MT system retained the ability to remove COD, total suspended solids (TSS), and nitrates. Greywater treatment by the MT system became impossible after a 48 day drying period under active aeration. Chlorination of the simulated MT effluent with a mixture of sodium dichloroisocyanurate and trichloroisocyanuric acid decreased the faecal coliform concentrations (FC) and the total coliform concentrations (TC) below 800 CFUs/100 ml within 65 h. Beyond 65 h, the pH of the effluent became highly acidic. To maintain optimum performance influent should be fed into the MT system at least once every 5 days, sufficient aeration should be guaranteed, and the MT effluent should be chlorinated for 65 h to eliminate all pathogens before any reuse.
- Full Text: false
Mulch tower treatment system for greywater reuse Part II: destructive testing and effluent treatment
- Authors: Tandlich, Roman , Zuma, Bongumusa M , Whittington-Jones, Kevin J , Burgess, Jo E
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71547 , vital:29863 , https://doi.org/10.1016/j.desal.2008.03.031
- Description: The mulch tower (MT) system described in Part I was tested to failure to determine its range of operating conditions. An increase in the influent temperature led to a statistically significant release of components of the chemical oxygen demand (COD) and the five day biochemical oxygen demand (BOD5), as well as phosphates from the MT system. Heterotrophic plate count (HPC) of the mulch layer dropped from 1.2 (± 0.6) × 106/g dry weight to 1.5 (± 0.3) × 105/g dry weight of the mulch layer with increases of the influent temperature. This indicates that the increase in influent temperature killed off some of the active biomass in the MT biofilm. After a five day drying period under active aeration, the MT system retained the ability to remove COD, total suspended solids (TSS), and nitrates. Greywater treatment by the MT system became impossible after a 48 day drying period under active aeration. Chlorination of the simulated MT effluent with a mixture of sodium dichloroisocyanurate and trichloroisocyanuric acid decreased the faecal coliform concentrations (FC) and the total coliform concentrations (TC) below 800 CFUs/100 ml within 65 h. Beyond 65 h, the pH of the effluent became highly acidic. To maintain optimum performance influent should be fed into the MT system at least once every 5 days, sufficient aeration should be guaranteed, and the MT effluent should be chlorinated for 65 h to eliminate all pathogens before any reuse.
- Full Text: false
Mulch tower treatment system Part I: Overall performance in greywater treatment
- Zuma, Bongumusa M, Tandlich, Roman, Whittington-Jones, Kevin J, Burgess, Jo E
- Authors: Zuma, Bongumusa M , Tandlich, Roman , Whittington-Jones, Kevin J , Burgess, Jo E
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71537 , vital:29862 , https://doi.org/10.1016/j.desal.2008.03.030
- Description: A mulch tower (MT) system for greywater treatment is introduced in this paper. Materials used to assemble the MT system included mulch, coarse sand, fine and coarse gravel. Limited removal efficiency of the MT system was demonstrated for alkalinity, total hardness, pH, Cl–, PO43–, NH4+, and SO42–, with the estimated cumulative removals ranging from 7 to 12%. Intermediate removal efficiency was observed for chemical oxygen demand (COD), NO3–, and S2– with the estimated cumulative removals ranging from 24 to 28%. The highest removal efficiency was observed for the total suspended solids (TSS) with the estimated cumulative removal equal to 52%. Given the minute residence time in the MT system, the results obtained were promising and justify scale-up studies for potential on-site applications. The MT effluent did not meet hygienic norms with respect to the faecal coliform concentration (FC) and the total coliform concentration (TC), and further effluent treatment is required before any discharge or reuse of the treated greywater. Further research should focus on characterisation of the microbial community of the MT, and the fate of Cl–, PO43–, NH4+, and SO42–.
- Full Text: false
- Authors: Zuma, Bongumusa M , Tandlich, Roman , Whittington-Jones, Kevin J , Burgess, Jo E
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71537 , vital:29862 , https://doi.org/10.1016/j.desal.2008.03.030
- Description: A mulch tower (MT) system for greywater treatment is introduced in this paper. Materials used to assemble the MT system included mulch, coarse sand, fine and coarse gravel. Limited removal efficiency of the MT system was demonstrated for alkalinity, total hardness, pH, Cl–, PO43–, NH4+, and SO42–, with the estimated cumulative removals ranging from 7 to 12%. Intermediate removal efficiency was observed for chemical oxygen demand (COD), NO3–, and S2– with the estimated cumulative removals ranging from 24 to 28%. The highest removal efficiency was observed for the total suspended solids (TSS) with the estimated cumulative removal equal to 52%. Given the minute residence time in the MT system, the results obtained were promising and justify scale-up studies for potential on-site applications. The MT effluent did not meet hygienic norms with respect to the faecal coliform concentration (FC) and the total coliform concentration (TC), and further effluent treatment is required before any discharge or reuse of the treated greywater. Further research should focus on characterisation of the microbial community of the MT, and the fate of Cl–, PO43–, NH4+, and SO42–.
- Full Text: false
Municipal commonage policy and livestock owners : findings from the Eastern Cape, South Africa
- Davenport, Nicholas A, Gambiza, James
- Authors: Davenport, Nicholas A , Gambiza, James
- Date: 2009
- Language: English
- Type: Article
- Identifier: vital:6628 , http://hdl.handle.net/10962/d1006820
- Description: The new African National Congress government announced after 1994 that municipal commonage would be a pillar of their land reform programme. The Department of Land Affairs spearheaded this by acquiring new land to complement the existing ‘old’ commonages. The aim of old commonage was to supplement the income of poor urban residents through the subsistence user system whereas new commonage was intended as a ‘stepping stone’ for emergent farmers. We investigated the differences between old and new commonage farmers as well as how they perceived the Makana local municipality's capacity to manage the commonage. The results showed that local institutions were weak. Only 46% of the old commonage farmers were members of a local livestock association whereas 74% of the new commonage farmers were members. Most old commonage farmers (59%) were dissatisfied with local government's management of the commonage. In contrast, only 37% of the new commonage farmers were dissatisfied with the management of the commonage. There were no differences between old and new commonage farmers in terms of livestock owners’ characteristics and mean annual net direct-use value of livestock. There were also no differences in the age of the two types of commonage farmers. Furthermore, there was no association between the type of commonage and level of education. The mean annual net direct-use value of livestock on old commonage was R6308 compared with R9707 on new commonage. Although the income from livestock for new commonage farmers varied slightly from that of old commonage farmers, the annual productive output per farmer on old commonage was R473 ha−1, three times higher than that of new commonage farmers which was R134 ha−1. We suggest that new land policy legislation is needed in which poverty as well as the legal arrangements between all stakeholders is clearly defined. Furthermore, national departments need to be more involved with local municipalities to increase local management capacity.
- Full Text:
- Authors: Davenport, Nicholas A , Gambiza, James
- Date: 2009
- Language: English
- Type: Article
- Identifier: vital:6628 , http://hdl.handle.net/10962/d1006820
- Description: The new African National Congress government announced after 1994 that municipal commonage would be a pillar of their land reform programme. The Department of Land Affairs spearheaded this by acquiring new land to complement the existing ‘old’ commonages. The aim of old commonage was to supplement the income of poor urban residents through the subsistence user system whereas new commonage was intended as a ‘stepping stone’ for emergent farmers. We investigated the differences between old and new commonage farmers as well as how they perceived the Makana local municipality's capacity to manage the commonage. The results showed that local institutions were weak. Only 46% of the old commonage farmers were members of a local livestock association whereas 74% of the new commonage farmers were members. Most old commonage farmers (59%) were dissatisfied with local government's management of the commonage. In contrast, only 37% of the new commonage farmers were dissatisfied with the management of the commonage. There were no differences between old and new commonage farmers in terms of livestock owners’ characteristics and mean annual net direct-use value of livestock. There were also no differences in the age of the two types of commonage farmers. Furthermore, there was no association between the type of commonage and level of education. The mean annual net direct-use value of livestock on old commonage was R6308 compared with R9707 on new commonage. Although the income from livestock for new commonage farmers varied slightly from that of old commonage farmers, the annual productive output per farmer on old commonage was R473 ha−1, three times higher than that of new commonage farmers which was R134 ha−1. We suggest that new land policy legislation is needed in which poverty as well as the legal arrangements between all stakeholders is clearly defined. Furthermore, national departments need to be more involved with local municipalities to increase local management capacity.
- Full Text:
Myth, Music & Modernism: the Wagnerian dimension in Virginia Woolf's Mrs Dalloway and the waves and James Joyce’s Finnegans Wake
- Authors: McGregor, Jamie Alexander
- Date: 2009
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/77069 , vital:30662
- Description: The study of Wagner's influence on the modernist novel is an established field with clear room for further contributions. Very little of the criticism undertaken to date takes full cognizance of the philosophical content of Wagner's dramas: a revolutionary form of romanticism that calls into question the very nature of the world, its most radical component being Schopenhauer's version of transcendental idealism. The compatibility of this doctrine with Wagner's earlier work, with its already marked privileging of myth over history, enabled his later dramas, consciously influenced by Schopenhauer, to crown a body of work greater than the sum of its parts. In works by Virginia Woolf and James Joyce, the "translation" of Wagnerian ideas into novelistic form demonstrates how they might be applied in "real life". In Mrs Dalloway, the figure of Septimus can be read as partly modelled on Wagner's heroes Siegfried and Tristan, two outstanding examples of the opposing heroic types found throughout his oeuvre, whose contrasting attributes are fused in Septimus's bipolar personality. The Wagnerian pattern also throws light on Septimus's transcendental "relationship" with a woman he does not even know, and on the implied noumenal identity of seemingly isolated individuals. In The Waves, the allusions to both Parsifal and the Ring need to be reconsidered in light of the fact that these works' heroes are all but identical (a fact overlooked in previous criticism); as Wagner's solar hero par excellence, Siegfried is central to the novel's cyclical symbolism. The Waves also revisits the question of identity but in a more cosmic context – the metaphysical unity of everything. In Finnegans Wake, the symbolism of the cosmic cycle is again related to the Ring, as are Wagner's two heroic types to the Shem / Shaun opposition (the Joyce / Woolf parallels here have also been overlooked in criticism to date). All three texts reveal a fascination with the two contrasting faces of a Wagnerian hero who embodies the dual nature of reality, mirroring in himself the eternal rise and fall of world history and, beyond them, the timeless stasis of myth.
- Full Text:
- Authors: McGregor, Jamie Alexander
- Date: 2009
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/77069 , vital:30662
- Description: The study of Wagner's influence on the modernist novel is an established field with clear room for further contributions. Very little of the criticism undertaken to date takes full cognizance of the philosophical content of Wagner's dramas: a revolutionary form of romanticism that calls into question the very nature of the world, its most radical component being Schopenhauer's version of transcendental idealism. The compatibility of this doctrine with Wagner's earlier work, with its already marked privileging of myth over history, enabled his later dramas, consciously influenced by Schopenhauer, to crown a body of work greater than the sum of its parts. In works by Virginia Woolf and James Joyce, the "translation" of Wagnerian ideas into novelistic form demonstrates how they might be applied in "real life". In Mrs Dalloway, the figure of Septimus can be read as partly modelled on Wagner's heroes Siegfried and Tristan, two outstanding examples of the opposing heroic types found throughout his oeuvre, whose contrasting attributes are fused in Septimus's bipolar personality. The Wagnerian pattern also throws light on Septimus's transcendental "relationship" with a woman he does not even know, and on the implied noumenal identity of seemingly isolated individuals. In The Waves, the allusions to both Parsifal and the Ring need to be reconsidered in light of the fact that these works' heroes are all but identical (a fact overlooked in previous criticism); as Wagner's solar hero par excellence, Siegfried is central to the novel's cyclical symbolism. The Waves also revisits the question of identity but in a more cosmic context – the metaphysical unity of everything. In Finnegans Wake, the symbolism of the cosmic cycle is again related to the Ring, as are Wagner's two heroic types to the Shem / Shaun opposition (the Joyce / Woolf parallels here have also been overlooked in criticism to date). All three texts reveal a fascination with the two contrasting faces of a Wagnerian hero who embodies the dual nature of reality, mirroring in himself the eternal rise and fall of world history and, beyond them, the timeless stasis of myth.
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Nathaniel Merriman’s lecture: “Shakspeare, as Bearing on English History”
- Authors: Wright, Laurence
- Date: 2009
- Language: English
- Type: text , article
- Identifier: vital:7060 , http://hdl.handle.net/10962/d1007424 , http://hdl.handle.net/10520/EJC48132
- Description: preprint , “Shakspeare, as Bearing on English History” is the second of two lectures on Shakespeare given by Archdeacon Nathaniel Merriman in Grahamstown in 1857. The first was delivered in the Court House on the 2nd September 1857, and the second two months later, on Friday 6th November that same year, again in the Court House. The lecture was published in 1858. An article placing the lectures in their local context appeared in Shakespeare in Southern Africa 20 (2008): 25-37, accompanying an annotated edition of the first lecture, “On the Study of Shakspeare”. Readers desiring details of the editorial principles adopted in producing annotated editions of the two lectures are referred to the introductory material prefacing the first lecture.
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- Authors: Wright, Laurence
- Date: 2009
- Language: English
- Type: text , article
- Identifier: vital:7060 , http://hdl.handle.net/10962/d1007424 , http://hdl.handle.net/10520/EJC48132
- Description: preprint , “Shakspeare, as Bearing on English History” is the second of two lectures on Shakespeare given by Archdeacon Nathaniel Merriman in Grahamstown in 1857. The first was delivered in the Court House on the 2nd September 1857, and the second two months later, on Friday 6th November that same year, again in the Court House. The lecture was published in 1858. An article placing the lectures in their local context appeared in Shakespeare in Southern Africa 20 (2008): 25-37, accompanying an annotated edition of the first lecture, “On the Study of Shakspeare”. Readers desiring details of the editorial principles adopted in producing annotated editions of the two lectures are referred to the introductory material prefacing the first lecture.
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National identity and nation-building in post-apartheid South Africa
- Authors: Stinson, Andrew Todd
- Date: 2009
- Subjects: Post-apartheid era -- South Africa , South Africa -- Politics and government -- 1994- , Nationalism -- South Africa , Civil society -- South Africa , Democracy -- South Africa , South Africa -- Social policy , Ethnicity -- South Africa , South Africa -- Economic conditions -- 1991- , South Africa -- Social conditions -- 1994-
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2832 , http://hdl.handle.net/10962/d1003042
- Description: Throughout South Africa’s post-Apartheid history, the ANC-led government has undertaken a distinct nation-building program in pursuit of “a truly united, democratic and prosperous South Africa” (ANC, 2007). This is reflected in a two-pronged approach, coupling political and socioeconomic transformation with the social-psychological aspect of forging a broad and inclusive national consciousness. The ANC’s “rainbow nation” approach embraces cultural diversity through what I shall call the practice of “interculturalism”. Interculturalism is a way of recognizing commonalities, reducing tensions and promoting the formation of social partnerships among different cultural groups. The ANC has also promoted a civic culture based on the principles of liberal democracy, non-racism, equality and the protection of individual rights. Interculturalism and civic nationalism are critically important factors to South African nation-building since together they foster a shared public culture and support meaningful participation in the creation of a truly just and democratic South Africa. Unfortunately, in many ways South African society remains deeply divided by race, ethnicity and economic inequality. This thesis analyses various theoretical approaches to national identity and nationbuilding with the aim of identifying several concepts which arguably throw light on the problems of South African nation-building and national identity formation. It is argued that interculturalism and civic nationalism are context appropriate approaches which have been adopted by the ANC to further an inclusive sense of shared public culture and promote participation in the creation of a shared public future. These approaches have led to the limited emergence of a broad South African national identity. However, South Africa’s commitment to socio-economic transformation has been less successful in generating widespread support for a broad national identity. While some of those previously disadvantaged under Apartheid have benefited from poverty alleviation schemes, service delivery initiatives and black economic empowerment programs, many continue to suffer from homelessness, unemployment and worsening economic conditions. Increasing economic marginalization has caused growing discontent among South Africa’s poor and constitutes the biggest threat to the formation of a cohesive national identity in South African society. Ultimately, it is argued that while interculturalism and civic nationalism have played an important role in fostering the growth of a broad national identity, true South African social cohesion will fail to emerge without a massive and sustained commitment to wide-ranging socio-economic transformation.
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- Authors: Stinson, Andrew Todd
- Date: 2009
- Subjects: Post-apartheid era -- South Africa , South Africa -- Politics and government -- 1994- , Nationalism -- South Africa , Civil society -- South Africa , Democracy -- South Africa , South Africa -- Social policy , Ethnicity -- South Africa , South Africa -- Economic conditions -- 1991- , South Africa -- Social conditions -- 1994-
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2832 , http://hdl.handle.net/10962/d1003042
- Description: Throughout South Africa’s post-Apartheid history, the ANC-led government has undertaken a distinct nation-building program in pursuit of “a truly united, democratic and prosperous South Africa” (ANC, 2007). This is reflected in a two-pronged approach, coupling political and socioeconomic transformation with the social-psychological aspect of forging a broad and inclusive national consciousness. The ANC’s “rainbow nation” approach embraces cultural diversity through what I shall call the practice of “interculturalism”. Interculturalism is a way of recognizing commonalities, reducing tensions and promoting the formation of social partnerships among different cultural groups. The ANC has also promoted a civic culture based on the principles of liberal democracy, non-racism, equality and the protection of individual rights. Interculturalism and civic nationalism are critically important factors to South African nation-building since together they foster a shared public culture and support meaningful participation in the creation of a truly just and democratic South Africa. Unfortunately, in many ways South African society remains deeply divided by race, ethnicity and economic inequality. This thesis analyses various theoretical approaches to national identity and nationbuilding with the aim of identifying several concepts which arguably throw light on the problems of South African nation-building and national identity formation. It is argued that interculturalism and civic nationalism are context appropriate approaches which have been adopted by the ANC to further an inclusive sense of shared public culture and promote participation in the creation of a shared public future. These approaches have led to the limited emergence of a broad South African national identity. However, South Africa’s commitment to socio-economic transformation has been less successful in generating widespread support for a broad national identity. While some of those previously disadvantaged under Apartheid have benefited from poverty alleviation schemes, service delivery initiatives and black economic empowerment programs, many continue to suffer from homelessness, unemployment and worsening economic conditions. Increasing economic marginalization has caused growing discontent among South Africa’s poor and constitutes the biggest threat to the formation of a cohesive national identity in South African society. Ultimately, it is argued that while interculturalism and civic nationalism have played an important role in fostering the growth of a broad national identity, true South African social cohesion will fail to emerge without a massive and sustained commitment to wide-ranging socio-economic transformation.
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New soluble methylendioxy-phenoxy-substituted zinc phthalocyanine derivatives : synthesis, photophysical and photochemical studies
- Erdoğmuş, Ali, Nyokong, Tebello
- Authors: Erdoğmuş, Ali , Nyokong, Tebello
- Date: 2009
- Language: English
- Type: Article
- Identifier: vital:6572 , http://hdl.handle.net/10962/d1004135
- Description: The syntheses of new three phthalonitriles (1, 2 and 3), together with photophysical and photochemical properties of the resulting peripherally and non-peripherally tetrakis- and octakis 3,4-(methylendioxy)-phenoxy-substituted zinc phthalocyanines (4, 5 and 6) are described for the first time. Complexes 4, 5 and 6 have been synthesized and characterized by elemental analysis, IR, 1H NMR spectroscopy, electronic spectroscopy and mass spectra. Complexes 4, 5 and 6 have good solubility in organic solvents such as CHCl3, DCM, DMSO, DMF, THF and toluene and are mainly not aggregated (except for complex 6 in DMSO) within a wide concentration range. General trends are described for singlet oxygen, photodegradation, fluorescence quantum yields, triplet quantum yields and triplet life times of these complexes in DMSO and toluene. Complex 4 has higher singlet oxygen quantum yields, fluorescence quantum yields, triplet quantum yields and triplet life times than complexes 5 and 6. The effect of the solvents on the photophysical and photochemical parameters of the zinc(II) phthalocyanines (4, 5 and 6) are also reported.
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- Authors: Erdoğmuş, Ali , Nyokong, Tebello
- Date: 2009
- Language: English
- Type: Article
- Identifier: vital:6572 , http://hdl.handle.net/10962/d1004135
- Description: The syntheses of new three phthalonitriles (1, 2 and 3), together with photophysical and photochemical properties of the resulting peripherally and non-peripherally tetrakis- and octakis 3,4-(methylendioxy)-phenoxy-substituted zinc phthalocyanines (4, 5 and 6) are described for the first time. Complexes 4, 5 and 6 have been synthesized and characterized by elemental analysis, IR, 1H NMR spectroscopy, electronic spectroscopy and mass spectra. Complexes 4, 5 and 6 have good solubility in organic solvents such as CHCl3, DCM, DMSO, DMF, THF and toluene and are mainly not aggregated (except for complex 6 in DMSO) within a wide concentration range. General trends are described for singlet oxygen, photodegradation, fluorescence quantum yields, triplet quantum yields and triplet life times of these complexes in DMSO and toluene. Complex 4 has higher singlet oxygen quantum yields, fluorescence quantum yields, triplet quantum yields and triplet life times than complexes 5 and 6. The effect of the solvents on the photophysical and photochemical parameters of the zinc(II) phthalocyanines (4, 5 and 6) are also reported.
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NGOs and rural movements in contemporary South Africa
- Authors: Helliker, Kirk D
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71252 , vital:29823 , https://doi.org/10.1080/02533952.2013.806415
- Description: This article provides a critical examination of relationships between non-governmental organisations (NGOs) and rural movements in post-apartheid South Africa, particularly with regard to the possible subordination of movements to NGOs. In discussing NGOs as a particular organisational form, and in reviewing some arguments pertaining to NGOs and rural movements globally, I explore whether NGOs in South Africa have a progressive role to play in agrarian transformation.
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- Authors: Helliker, Kirk D
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71252 , vital:29823 , https://doi.org/10.1080/02533952.2013.806415
- Description: This article provides a critical examination of relationships between non-governmental organisations (NGOs) and rural movements in post-apartheid South Africa, particularly with regard to the possible subordination of movements to NGOs. In discussing NGOs as a particular organisational form, and in reviewing some arguments pertaining to NGOs and rural movements globally, I explore whether NGOs in South Africa have a progressive role to play in agrarian transformation.
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