- Title
- Electrochemical behavior of phthalocyanines containing high oxidation state central metals
- Creator
- Chauke, Vongani, Arslanoglu, Yasin, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2011
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/247111
- Identifier
- vital:51547
- Identifier
- xlink:href="https://doi.org/10.1016/j.poly.2011.05.028"
- Description
- The syntheses of 2,(3)-(peripheral) and 1,(4)-(non-peripheral) (2-mercaptopyridine)phthalocyanine complexes of titanium(IV) oxide (5a and 6a, respectively), vanadium(IV) oxide (7a and 8a, respectively) and tantalum(V) hydroxide (9a, peripheral only) and their electrochemical characterization are presented in this report. Their electrochemistry is compared to that of thiophenyl and thiobenzyl substituted derivatives. The non-peripherally substituted complexes are more difficult to reduce than peripherally substituted derivatives. In addition, the mercaptopyridine substituted derivatives are more difficult to reduce compared to benzylmercapto and phenylmercapto derivatives, and aryl easier reduce than alkyl substitution. Spectroelectrochemistry of the complexes confirmed metal and ring redox processes for TaPc and TiPc derivatives and ring based processes only for VPc complexes.
- Format
- computer, online resource, application/pdf, 1 online resource (8 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Polyhedron, Chauke, V.P., Arslanoglu, Y. and Nyokong, T., 2011. Electrochemical behavior of phthalocyanines containing high oxidation state central metals: Titanium (IV), vanadium (IV), and tantalum (V). Polyhedron, 30(12), pp.2132-2139, Polyhedron volume 30 number 12 p. 2132 2011 0277-5387
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
- Hits: 547
- Visitors: 611
- Downloads: 71
Collections
RU Department of Chemistry
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details | SOURCE1 | Electrochemical behavior of phthalocyanines containing high oxidation state central metals.pdf | 662 KB | Adobe Acrobat PDF | View Details |