'We must start with our own children’: reflectively researching intergenerational leadership for social justice, education, and sustainability
- Authors: Lotz-Sisitka, Heila
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/437207 , vital:73353 , ISBN 978-9086862528 , https://doi.org/10.3920/978-90-8686-802-5_1
- Description: This paper was prepared today, 13 December 2013, for this book on ‘Intergenerational learning and transformative leader-ship for sustainable futures’, to be released in November 2014 at a World Conference to mark the end of the UN Decade of Education for Sustainable Development (UN-DESD) in Nago-ya, Japan. The UNDESD was born in Johannesburg in 2002; it was an outcome of the Johannesburg Implementation Plan formulated by world leaders at the World Summit on Sustaina-ble Development, hosted by the South African government, building on the earlier Rio Earth Summit. Nelson Rolihlahla Mandela attended the opening of the World Summit on Sus-tainable Development soon after he left office as the first dem-ocratically elected President of the Republic of South Africa. He passed away a week ago today, on 5 December 2013, at the age of 95. His life story is well known. I write here about his words ‘We must start with our own children’.
- Full Text:
- Authors: Lotz-Sisitka, Heila
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/437207 , vital:73353 , ISBN 978-9086862528 , https://doi.org/10.3920/978-90-8686-802-5_1
- Description: This paper was prepared today, 13 December 2013, for this book on ‘Intergenerational learning and transformative leader-ship for sustainable futures’, to be released in November 2014 at a World Conference to mark the end of the UN Decade of Education for Sustainable Development (UN-DESD) in Nago-ya, Japan. The UNDESD was born in Johannesburg in 2002; it was an outcome of the Johannesburg Implementation Plan formulated by world leaders at the World Summit on Sustaina-ble Development, hosted by the South African government, building on the earlier Rio Earth Summit. Nelson Rolihlahla Mandela attended the opening of the World Summit on Sus-tainable Development soon after he left office as the first dem-ocratically elected President of the Republic of South Africa. He passed away a week ago today, on 5 December 2013, at the age of 95. His life story is well known. I write here about his words ‘We must start with our own children’.
- Full Text:
A comparative photophysicochemical study of mono substituted phthalocyanines grafted onto silica nanoparticles
- Fashina, Adebayo, Antunes, Edith M, Nyokong, Tebello
- Authors: Fashina, Adebayo , Antunes, Edith M , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193844 , vital:45399 , xlink:href="https://doi.org/10.1142/S1088424614500138"
- Description: In this study, we report on the covalent linking of carboxylic acid functionalized silica nanoparticles with zinc phthalocyanine mono-substituted non-peripherally and peripherally with either a 4-amino phenoxy (1, peripheral and 2, non-peripheral) or an amino group (3 peripheral). The grafting is achieved via the formation of an amide bond between the carboxylic acid of the silica nanoparticles and the amino group of the phthalocyanine complexes. The hybrid nanoparticles retained the amorphous nature of silica nanoparticles after conjugation. A slight decrease in fluorescence and a general improvement in triplet quantum yields compared to free Pcs were observed. Triplet lifetimes for 2-SiNPs and 3-SiNPs also improved when compared to the free phthalocyanine. The changes in singlet oxygen quantum yields upon conjugation were minimal.
- Full Text:
- Authors: Fashina, Adebayo , Antunes, Edith M , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193844 , vital:45399 , xlink:href="https://doi.org/10.1142/S1088424614500138"
- Description: In this study, we report on the covalent linking of carboxylic acid functionalized silica nanoparticles with zinc phthalocyanine mono-substituted non-peripherally and peripherally with either a 4-amino phenoxy (1, peripheral and 2, non-peripheral) or an amino group (3 peripheral). The grafting is achieved via the formation of an amide bond between the carboxylic acid of the silica nanoparticles and the amino group of the phthalocyanine complexes. The hybrid nanoparticles retained the amorphous nature of silica nanoparticles after conjugation. A slight decrease in fluorescence and a general improvement in triplet quantum yields compared to free Pcs were observed. Triplet lifetimes for 2-SiNPs and 3-SiNPs also improved when compared to the free phthalocyanine. The changes in singlet oxygen quantum yields upon conjugation were minimal.
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A Note on the (Continued) Ability of the Yield Curve to Forecast Economic Downturns in South Africa
- Authors: Botha, Ferdi , Keeton, Gavin
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/395994 , vital:69142 , xlink:href="https://doi.org/10.1111/saje.12053"
- Description: In 2002-2003, the South African yield spread falsely signalled a downswing that never materialised. This paper provides two reasons for this false signal. First, while the Reserve Bank never actually officially declared the start of a downswing, by alternative measures a downswing did actually occur. It is this severe weakness in economic activity at that time that the yield curve pointed to. Second, short-term interest rates in 2003 were higher than they should have been because of a mistake made in measuring consumer price inflation. Because South Africa had recently introduced an inflation-targeting regime, policy interest rates were, as a result of this error, kept too high for too long. This policy mistake was rectified as soon as the error in the Consumer Price Index was discovered. Thus, the yield curve in 2003 pointed to the reality that short-term interest rates were too high and risked pushing the economy into full blown recession. This is demonstrated by the fact that it was a fall in long bond interest rates that caused the yield spread to turn negative, indicating expectations that short-term interest rates would need to be cut – as indeed they were.
- Full Text:
- Authors: Botha, Ferdi , Keeton, Gavin
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/395994 , vital:69142 , xlink:href="https://doi.org/10.1111/saje.12053"
- Description: In 2002-2003, the South African yield spread falsely signalled a downswing that never materialised. This paper provides two reasons for this false signal. First, while the Reserve Bank never actually officially declared the start of a downswing, by alternative measures a downswing did actually occur. It is this severe weakness in economic activity at that time that the yield curve pointed to. Second, short-term interest rates in 2003 were higher than they should have been because of a mistake made in measuring consumer price inflation. Because South Africa had recently introduced an inflation-targeting regime, policy interest rates were, as a result of this error, kept too high for too long. This policy mistake was rectified as soon as the error in the Consumer Price Index was discovered. Thus, the yield curve in 2003 pointed to the reality that short-term interest rates were too high and risked pushing the economy into full blown recession. This is demonstrated by the fact that it was a fall in long bond interest rates that caused the yield spread to turn negative, indicating expectations that short-term interest rates would need to be cut – as indeed they were.
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A promising biological control agent for the invasive alien plant, Pereskia aculeata Miller (Cactaceae), in South Africa
- Paterson, Iain D, Mdodana, Lumka A, Mpekula, Ongezwa, Mabunda, Bheki D, Hill, Martin P
- Authors: Paterson, Iain D , Mdodana, Lumka A , Mpekula, Ongezwa , Mabunda, Bheki D , Hill, Martin P
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/416806 , vital:71387 , xlink:href="https://doi.org/10.1080/09583157.2014.919439"
- Description: Pereskia aculeata Miller (Cactaceae) is an invasive alien plant from Central and South America that has become a problematic environmental weed in South Africa. A potential biological control agent, the stem-wilter, Catorhintha schaffneri Brailovsky and Garcia (Coreidae), was collected in southern Brazil and imported into quarantine in South Africa. Field host range data suggested that C. schaffneri has a host range restricted to P. aculeata. No-choice nymph survival tests were then conducted on 27 test plant species in 9 families. Survival to the adult stage was only recorded on P. aculeata and the closely related Pereskia grandifolia Haw. (Cactaceae). Mortality was significantly higher on P. grandifolia with only 3% of the nymphs reaching the adult stage compared with 74% on P. aculeata indicating that P. aculeata is the primary host plant. P. grandifolia is native in South America and is of no agricultural importance in South Africa so any feeding on P. grandifolia in South Africa would have no negative environmental or economic consequences. In other tests, adult survival on P. aculeata [25.8 days (SE ± 3.74)] was significantly longer than on other test plant species [4.3 days (SE ± 0.36)] further confirming the host specificity of the species. Impact studies conducted in quarantine indicated that C. schaffneri is damaging to P. aculeata, significantly reducing the number of leaves and the shoot lengths of plants, even at relatively low insect densities. C. schaffneri is safe for release in South Africa and is likely to be a damaging and effective agent.
- Full Text:
- Authors: Paterson, Iain D , Mdodana, Lumka A , Mpekula, Ongezwa , Mabunda, Bheki D , Hill, Martin P
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/416806 , vital:71387 , xlink:href="https://doi.org/10.1080/09583157.2014.919439"
- Description: Pereskia aculeata Miller (Cactaceae) is an invasive alien plant from Central and South America that has become a problematic environmental weed in South Africa. A potential biological control agent, the stem-wilter, Catorhintha schaffneri Brailovsky and Garcia (Coreidae), was collected in southern Brazil and imported into quarantine in South Africa. Field host range data suggested that C. schaffneri has a host range restricted to P. aculeata. No-choice nymph survival tests were then conducted on 27 test plant species in 9 families. Survival to the adult stage was only recorded on P. aculeata and the closely related Pereskia grandifolia Haw. (Cactaceae). Mortality was significantly higher on P. grandifolia with only 3% of the nymphs reaching the adult stage compared with 74% on P. aculeata indicating that P. aculeata is the primary host plant. P. grandifolia is native in South America and is of no agricultural importance in South Africa so any feeding on P. grandifolia in South Africa would have no negative environmental or economic consequences. In other tests, adult survival on P. aculeata [25.8 days (SE ± 3.74)] was significantly longer than on other test plant species [4.3 days (SE ± 0.36)] further confirming the host specificity of the species. Impact studies conducted in quarantine indicated that C. schaffneri is damaging to P. aculeata, significantly reducing the number of leaves and the shoot lengths of plants, even at relatively low insect densities. C. schaffneri is safe for release in South Africa and is likely to be a damaging and effective agent.
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A reflection on the use of case studies as a methodology for social learning research in sub Saharan Africa
- Cundill, Georgina, Lotz-Sisitka, Heila, Mukute, Mutizwa, Belay, Million, Shackleton, Sheona E, Kulundu, Iinjairu
- Authors: Cundill, Georgina , Lotz-Sisitka, Heila , Mukute, Mutizwa , Belay, Million , Shackleton, Sheona E , Kulundu, Iinjairu
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/436636 , vital:73288 , ISBN 1573-5214 , https://doi.org/10.1016/j.njas.2013.04.001
- Description: A recent review has highlighted that the methodology most commonly employed to research social learning has been the individual case study. We draw on four examples of social learning research in the environmental and sustainability sci-ences from sub-Saharan Africa to reflect on possible reasons behind the preponderance of case study research in this field, and to identify common elements that may be significant for social learning research more generally. We find that a com-mon interest in change oriented social learning, and therefore processes of change, makes case studies a necessary ap-proach because long term process analyses are required that are sensitive to social-ecological contexts. Common elements of the examples reflected upon included: a focus on initiating, tracking and/or understanding a process of change toward sustainability; long term research; an action research agenda that involves reflecting on data with research participants; and temporal, process based analysis of data coupled with in-depth theoretical analysis. This paper highlights that there is significant scope for exploratory research that compares case studies of social learning research to generate a deeper un-derstanding of social learning processes, and their relationship to human agency and societal change.
- Full Text:
- Authors: Cundill, Georgina , Lotz-Sisitka, Heila , Mukute, Mutizwa , Belay, Million , Shackleton, Sheona E , Kulundu, Iinjairu
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/436636 , vital:73288 , ISBN 1573-5214 , https://doi.org/10.1016/j.njas.2013.04.001
- Description: A recent review has highlighted that the methodology most commonly employed to research social learning has been the individual case study. We draw on four examples of social learning research in the environmental and sustainability sci-ences from sub-Saharan Africa to reflect on possible reasons behind the preponderance of case study research in this field, and to identify common elements that may be significant for social learning research more generally. We find that a com-mon interest in change oriented social learning, and therefore processes of change, makes case studies a necessary ap-proach because long term process analyses are required that are sensitive to social-ecological contexts. Common elements of the examples reflected upon included: a focus on initiating, tracking and/or understanding a process of change toward sustainability; long term research; an action research agenda that involves reflecting on data with research participants; and temporal, process based analysis of data coupled with in-depth theoretical analysis. This paper highlights that there is significant scope for exploratory research that compares case studies of social learning research to generate a deeper un-derstanding of social learning processes, and their relationship to human agency and societal change.
- Full Text:
A reflection on the use of case studies as a methodology for social learning research in sub Saharan Africa
- Cundill, Georgina, Lotz-Sisitka, Heila, 1965-, Mukute, Mutizwa, Ali, Million Belay, Shackleton, Sheona E, Kulundu-Bolus, Injairu M
- Authors: Cundill, Georgina , Lotz-Sisitka, Heila, 1965- , Mukute, Mutizwa , Ali, Million Belay , Shackleton, Sheona E , Kulundu-Bolus, Injairu M
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182832 , vital:43884 , xlink:href="https://doi.org/10.1016/j.njas.2013.04.001"
- Description: A recent review has highlighted that the methodology most commonly employed to research social learning has been the individual case study. We draw on four examples of social learning research in the environmental and sustainability sciences from sub-Saharan Africa to reflect on possible reasons behind the preponderance of case study research in this field, and to identify common elements that may be significant for social learning research more generally. We find that a common interest in change oriented social learning, and therefore processes of change, makes case studies a necessary approach because long term process analyses are required that are sensitive to social-ecological contexts. Common elements of the examples reflected upon included: a focus on initiating, tracking and/or understanding a process of change toward sustainability; long term research; an action research agenda that involves reflecting on data with research participants; and temporal, process based analysis of data coupled with in-depth theoretical analysis. This paper highlights that there is significant scope for exploratory research that compares case studies of social learning research to generate a deeper understanding of social learning processes, and their relationship to human agency and societal change.
- Full Text:
- Authors: Cundill, Georgina , Lotz-Sisitka, Heila, 1965- , Mukute, Mutizwa , Ali, Million Belay , Shackleton, Sheona E , Kulundu-Bolus, Injairu M
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182832 , vital:43884 , xlink:href="https://doi.org/10.1016/j.njas.2013.04.001"
- Description: A recent review has highlighted that the methodology most commonly employed to research social learning has been the individual case study. We draw on four examples of social learning research in the environmental and sustainability sciences from sub-Saharan Africa to reflect on possible reasons behind the preponderance of case study research in this field, and to identify common elements that may be significant for social learning research more generally. We find that a common interest in change oriented social learning, and therefore processes of change, makes case studies a necessary approach because long term process analyses are required that are sensitive to social-ecological contexts. Common elements of the examples reflected upon included: a focus on initiating, tracking and/or understanding a process of change toward sustainability; long term research; an action research agenda that involves reflecting on data with research participants; and temporal, process based analysis of data coupled with in-depth theoretical analysis. This paper highlights that there is significant scope for exploratory research that compares case studies of social learning research to generate a deeper understanding of social learning processes, and their relationship to human agency and societal change.
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Accounting student's success factors: an exploratory investigation
- Authors: Stack, Elizabeth M
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/2134 , vital:20258
- Description: This presentation is aimed at identifying possible success factors leading to the success of students studying accounting, as well as to hightlight some of the problems they may face.
- Full Text:
- Authors: Stack, Elizabeth M
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/2134 , vital:20258
- Description: This presentation is aimed at identifying possible success factors leading to the success of students studying accounting, as well as to hightlight some of the problems they may face.
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Adolescent pregnancy: A feminist issue
- Authors: Macleod, Catriona I
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/434360 , vital:73051 , ISBN 978-1-4899-8025-0 , https://link.springer.com/chapter/10.1007/978-1-4899-8026-7_6
- Description: Pregnancy and mothering are enduring and central concerns of feminism. DiQuinzo (1999) sums this up in stating that “mothering is both an important site at which the central concepts of feminist theory are elaborated and a site at which these concepts are challenged and reworked.” Stephens (2004) argues, ‘…reproduction and mothering are central to theories of patriarchy and women’s unequal position in Western society…Childbirth can paradoxically be seen as both a cause of women’s subordinate position in society and a means of empowerment.’ Yet, despite the pivotal nature of pregnancy and mothering in feminist literature, there has been surprisingly little direct engagement by feminists in the area of ‘adolescent pregnancy.’ The engagement that there has been is a whisper in relation to the plethora of public health, medical, and psychological writings on ‘adolescent pregnancy.’ The feminists who have engaged with ‘adolescent pregnancy’ have, from their initial engagement and to varying degrees, tried to undermine simple interpretations of ‘adolescent pregnancy’ as a social problem and to link micro- and macro-level gender relations to occurrence of, and responses to, ‘adolescent pregnancy.’ Thus, for example, in the 1980s, Chilman (1985) asserted, ‘Sexism particularly afflicts programs and policies for these young people [unmarried teenage parents] as well as the behaviors that lead up to their becoming unmarried parents.’ In the 1990s, Pillow (1997), using a combination of feminist and postmodern theory, argued that ‘teen research and policy interventions can be understood as entrenched in the dilemmas of modernism, resulting often in normative assumptions that reflect our paradoxical attitudes and practices concerning female sexuality.’ More recently, Wilson and Huntington (2005) observed ‘adolescent pregnancy’ at a time when rates of fertility among young women are decreasing in ‘Western’ societies is ‘underpinned by changing social and political imperatives regarding the role of women in these countries.’
- Full Text:
- Authors: Macleod, Catriona I
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/434360 , vital:73051 , ISBN 978-1-4899-8025-0 , https://link.springer.com/chapter/10.1007/978-1-4899-8026-7_6
- Description: Pregnancy and mothering are enduring and central concerns of feminism. DiQuinzo (1999) sums this up in stating that “mothering is both an important site at which the central concepts of feminist theory are elaborated and a site at which these concepts are challenged and reworked.” Stephens (2004) argues, ‘…reproduction and mothering are central to theories of patriarchy and women’s unequal position in Western society…Childbirth can paradoxically be seen as both a cause of women’s subordinate position in society and a means of empowerment.’ Yet, despite the pivotal nature of pregnancy and mothering in feminist literature, there has been surprisingly little direct engagement by feminists in the area of ‘adolescent pregnancy.’ The engagement that there has been is a whisper in relation to the plethora of public health, medical, and psychological writings on ‘adolescent pregnancy.’ The feminists who have engaged with ‘adolescent pregnancy’ have, from their initial engagement and to varying degrees, tried to undermine simple interpretations of ‘adolescent pregnancy’ as a social problem and to link micro- and macro-level gender relations to occurrence of, and responses to, ‘adolescent pregnancy.’ Thus, for example, in the 1980s, Chilman (1985) asserted, ‘Sexism particularly afflicts programs and policies for these young people [unmarried teenage parents] as well as the behaviors that lead up to their becoming unmarried parents.’ In the 1990s, Pillow (1997), using a combination of feminist and postmodern theory, argued that ‘teen research and policy interventions can be understood as entrenched in the dilemmas of modernism, resulting often in normative assumptions that reflect our paradoxical attitudes and practices concerning female sexuality.’ More recently, Wilson and Huntington (2005) observed ‘adolescent pregnancy’ at a time when rates of fertility among young women are decreasing in ‘Western’ societies is ‘underpinned by changing social and political imperatives regarding the role of women in these countries.’
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Advantages of using development models of the carrion beetles Thanatophilus micans (Fabricius) and T. mutilatus (Castelneau)(Coleoptera Silphidae) for estimating minimum post mortem intervals, verified with case data
- Ridgeway, Jaryd A, Midgley, John M, Collett, Isabel J, Villet, Martin H
- Authors: Ridgeway, Jaryd A , Midgley, John M , Collett, Isabel J , Villet, Martin H
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/441737 , vital:73911 , https://doi.org/10.1007/s00414-013-0865-0
- Description: Some beetles are as useful as blow flies for estimating the minimum post mortem interval (PMImin) or time since death. Examples include Thanatophilus micans (Fabricius) and Thanatophilus mutilatus (Castelneau), two geographically and ecologically overlapping African beetles. Molecular means of identifying these species, descriptions of their natural history, thermal summation models for the development of each species, and a case in which T. micans was recovered are presented. These beetles colonise bodies soon after death, their development spans more time than that of flies, and they may be little affected by maggot-generated heat. From an experimental perspective, they can be reared individually, which allows the identification of sick individuals and has analytical advantages relative to fly larvae that must be reared in groups. Estimating minimum post mortem intervals for both species using the case data strongly suggests that developmental models parameterised for one species should not be used to make forensic estimates for closely related species for which no specific model is available and emphasises the need for correct identifications.
- Full Text:
- Authors: Ridgeway, Jaryd A , Midgley, John M , Collett, Isabel J , Villet, Martin H
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/441737 , vital:73911 , https://doi.org/10.1007/s00414-013-0865-0
- Description: Some beetles are as useful as blow flies for estimating the minimum post mortem interval (PMImin) or time since death. Examples include Thanatophilus micans (Fabricius) and Thanatophilus mutilatus (Castelneau), two geographically and ecologically overlapping African beetles. Molecular means of identifying these species, descriptions of their natural history, thermal summation models for the development of each species, and a case in which T. micans was recovered are presented. These beetles colonise bodies soon after death, their development spans more time than that of flies, and they may be little affected by maggot-generated heat. From an experimental perspective, they can be reared individually, which allows the identification of sick individuals and has analytical advantages relative to fly larvae that must be reared in groups. Estimating minimum post mortem intervals for both species using the case data strongly suggests that developmental models parameterised for one species should not be used to make forensic estimates for closely related species for which no specific model is available and emphasises the need for correct identifications.
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An exploration of geolocation and traffic visualisation using network flows
- Pennefather, Sean, Irwin, Barry V W
- Authors: Pennefather, Sean , Irwin, Barry V W
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/429597 , vital:72625 , 10.1109/ISSA.2014.6950
- Description: A network flow is a data record that represents characteristics associated with a unidirectional stream of packets transmitted between two hosts using an IP layer protocol. As a network flow only represents statistics relating to the data transferred in the stream, the effectiveness of utilizing network flows for traffic visualization to aid in cyber defense is not immediately apparent and needs further exploration. The goal of this research is to explore the use of network flows for data visualization and geolocation.
- Full Text:
- Authors: Pennefather, Sean , Irwin, Barry V W
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/429597 , vital:72625 , 10.1109/ISSA.2014.6950
- Description: A network flow is a data record that represents characteristics associated with a unidirectional stream of packets transmitted between two hosts using an IP layer protocol. As a network flow only represents statistics relating to the data transferred in the stream, the effectiveness of utilizing network flows for traffic visualization to aid in cyber defense is not immediately apparent and needs further exploration. The goal of this research is to explore the use of network flows for data visualization and geolocation.
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An improved larval diet for commercial mass rearing of the false codling moth, Thaumatotibia leucotreta (Meyrick)(Lepidoptera: Tortricidae)
- Moore, Sean D, Richards, G I, Chambers, Craig B, Hendry, Donald A
- Authors: Moore, Sean D , Richards, G I , Chambers, Craig B , Hendry, Donald A
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/452206 , vital:75111 , https://hdl.handle.net/10520/EJC150955
- Description: False codling moth, Thaumatotibia leucotreta (Meyrick) (Lepidoptera:Tortricidae), is endemic to sub-Saharan Africa (Newton 1998). It is a pest of citrus (Newton 1998), stone fruit (Daiber 1978), macadamias (La Croix and Thindwa 1986), avocados (Erichsen and Schoeman 1992) and various other agricultural crops. All available control methods were recently reviewed by Moore and Hattingh (2012). Included amongst these is the use of granulovirus (Cryptophlebia leucotreta granulovirus (CrleGV)) sprays, inundative releases of egg parasitoids and the sterile insect technique (SIT). All of these require production of large numbers of T. leucotreta. CrleGV and the egg parasitoid, Trichogrammatoidea cryptophlebiae (Nagaraja) (Hymenoptera: Trichogrammatidae), are produced in vivo (Moore et al. 2011) and for SIT, the sterilized adult male moth is the product (Hofmeyr et al. 2005).
- Full Text:
- Authors: Moore, Sean D , Richards, G I , Chambers, Craig B , Hendry, Donald A
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/452206 , vital:75111 , https://hdl.handle.net/10520/EJC150955
- Description: False codling moth, Thaumatotibia leucotreta (Meyrick) (Lepidoptera:Tortricidae), is endemic to sub-Saharan Africa (Newton 1998). It is a pest of citrus (Newton 1998), stone fruit (Daiber 1978), macadamias (La Croix and Thindwa 1986), avocados (Erichsen and Schoeman 1992) and various other agricultural crops. All available control methods were recently reviewed by Moore and Hattingh (2012). Included amongst these is the use of granulovirus (Cryptophlebia leucotreta granulovirus (CrleGV)) sprays, inundative releases of egg parasitoids and the sterile insect technique (SIT). All of these require production of large numbers of T. leucotreta. CrleGV and the egg parasitoid, Trichogrammatoidea cryptophlebiae (Nagaraja) (Hymenoptera: Trichogrammatidae), are produced in vivo (Moore et al. 2011) and for SIT, the sterilized adult male moth is the product (Hofmeyr et al. 2005).
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Antimicrobial properties and isotope investigations of South African honey
- Khan, F, Hill, Jaclyn M, Kaehler, Sven, Allsopp, M, van Vuuren, S
- Authors: Khan, F , Hill, Jaclyn M , Kaehler, Sven , Allsopp, M , van Vuuren, S
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/444539 , vital:74249 , https://doi.org/10.1111/jam.12533
- Description: The therapeutic potential of honey for the treatment of wound infections is well documented. However, South African (SA) honey has been poorly explored as an antimicrobial agent and given the well‐established antimicrobial properties of the indigenous plant species from SA, there is the potential that honey from this geographical region may exhibit noteworthy anti‐infective properties. In this study, the antimicrobial properties of 42 SA honey samples were determined.
- Full Text:
- Authors: Khan, F , Hill, Jaclyn M , Kaehler, Sven , Allsopp, M , van Vuuren, S
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/444539 , vital:74249 , https://doi.org/10.1111/jam.12533
- Description: The therapeutic potential of honey for the treatment of wound infections is well documented. However, South African (SA) honey has been poorly explored as an antimicrobial agent and given the well‐established antimicrobial properties of the indigenous plant species from SA, there is the potential that honey from this geographical region may exhibit noteworthy anti‐infective properties. In this study, the antimicrobial properties of 42 SA honey samples were determined.
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Application of carbon black and iron phthalocyanine composites in bioelectricity production at a brewery wastewater fed microbial fuel cell
- Mshoperi, Edith, Fogel, Ronen, Limson, Janice
- Authors: Mshoperi, Edith , Fogel, Ronen , Limson, Janice
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431050 , vital:72740 , xlink:href="https://doi.org/10.1016/j.electacta.2013.11.01"
- Description: Aerobic cathode microbial fuel cells (MFCs) have been widely researched to provide bioremediation of wastewaters, coupled to sustainable energy production. In order to effectively accomplish this aim, suitable catalysts and catalyst supports for oxygen reduction reaction (ORR) are required. While iron phthaloycanine (FePc), supported on multi-walled carbon nanotubes has previously been studied for this function, cost of industrial production may hinder this. Importantly, this study examines the use of several available grades of carbon black for their relative suitability to perform as supports for FePc in MFC formats. Voltammetric studies showed that the different grades of carbon black provided varying lowering of the ORR overpotential, between ∼160 and ∼270 mV relative to unmodified GCEs, and an optimum grade (N326) was selected for further study. Carbon black/FePC composite electrodes exhibited comparable lowering of the ORR overpotential (606 mV) to potentials previously reported to nanotube/FePc composites (620 mV), as well as lowered charge-transfer resistance compared to electrodes solely modified with FePc. When applied as cathode modifiers in dual chambered MFCs utilising Enterobacter cloacae, the combined use of carbon black and FePc provided greater power densities than either alone; composite electrodes obtaining ∼400% power density, compared to unmodified electrodes. Modification of the anode with carbon black further increased power density, generating power densities an order of magnitude larger than those obtained at unmodified electrodes. The ability of beer brewery waste water (BBWW) to generate power at these modified surfaces yielded permissible power densities (∼40% that of reinforced clostridial media). Differences observed, in particular under agitation, are attributed to variations in nutrient content and nutrient complexity, between the two fuel substrates.
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- Authors: Mshoperi, Edith , Fogel, Ronen , Limson, Janice
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431050 , vital:72740 , xlink:href="https://doi.org/10.1016/j.electacta.2013.11.01"
- Description: Aerobic cathode microbial fuel cells (MFCs) have been widely researched to provide bioremediation of wastewaters, coupled to sustainable energy production. In order to effectively accomplish this aim, suitable catalysts and catalyst supports for oxygen reduction reaction (ORR) are required. While iron phthaloycanine (FePc), supported on multi-walled carbon nanotubes has previously been studied for this function, cost of industrial production may hinder this. Importantly, this study examines the use of several available grades of carbon black for their relative suitability to perform as supports for FePc in MFC formats. Voltammetric studies showed that the different grades of carbon black provided varying lowering of the ORR overpotential, between ∼160 and ∼270 mV relative to unmodified GCEs, and an optimum grade (N326) was selected for further study. Carbon black/FePC composite electrodes exhibited comparable lowering of the ORR overpotential (606 mV) to potentials previously reported to nanotube/FePc composites (620 mV), as well as lowered charge-transfer resistance compared to electrodes solely modified with FePc. When applied as cathode modifiers in dual chambered MFCs utilising Enterobacter cloacae, the combined use of carbon black and FePc provided greater power densities than either alone; composite electrodes obtaining ∼400% power density, compared to unmodified electrodes. Modification of the anode with carbon black further increased power density, generating power densities an order of magnitude larger than those obtained at unmodified electrodes. The ability of beer brewery waste water (BBWW) to generate power at these modified surfaces yielded permissible power densities (∼40% that of reinforced clostridial media). Differences observed, in particular under agitation, are attributed to variations in nutrient content and nutrient complexity, between the two fuel substrates.
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Applications of lead phthalocyanines embedded in electrospun fibers for the photoinactivation of Escherichia coli in water
- Osifeko, Olawale L, Nyokong, Tebello
- Authors: Osifeko, Olawale L , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189898 , vital:44945 , xlink:href="https://doi.org/10.1016/j.dyepig.2014.05.010"
- Description: Lead (II) pyridyloxyphthalocyanine (PbTpyPc) and its quaternized form (PbTepyPc) were synthesized and the photophysical behavior examined. Low fluorescence quantum yields (ΦF) of 0.01 and 0.02 were observed for PbTepyPc and PbTpyPc, respectively. The singlet oxygen quantum yields (ΦΔ) were 0.60 and 0.68, for PbTepyPc and PbTpyPc, respectively using DPBF as a quencher in DMF. Singlet oxygen production of the embedded sensitizers in electrospun fiber were quantified using ADMA and were found to be ΦΔ = 0.41 and ΦΔ = 0.21 for PbTepyPc and PbTpyPc, respectively. Photodynamic inactivation of Escherichia coli (E. coli) with the quaternized photosensitizer at 5 μM, totally inactivated the E. coli (with log CFU = 10 decrease). Only 0.4 log CFU decrease was obtained with PbTpyPc. The embedded non-quaternized photosensitizer (PbTpyPc) was less active on the gram negative bacteria but the quaternized photosensitizer (PbTepyPc) was effective towards inactivation of E. coli.
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- Authors: Osifeko, Olawale L , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189898 , vital:44945 , xlink:href="https://doi.org/10.1016/j.dyepig.2014.05.010"
- Description: Lead (II) pyridyloxyphthalocyanine (PbTpyPc) and its quaternized form (PbTepyPc) were synthesized and the photophysical behavior examined. Low fluorescence quantum yields (ΦF) of 0.01 and 0.02 were observed for PbTepyPc and PbTpyPc, respectively. The singlet oxygen quantum yields (ΦΔ) were 0.60 and 0.68, for PbTepyPc and PbTpyPc, respectively using DPBF as a quencher in DMF. Singlet oxygen production of the embedded sensitizers in electrospun fiber were quantified using ADMA and were found to be ΦΔ = 0.41 and ΦΔ = 0.21 for PbTepyPc and PbTpyPc, respectively. Photodynamic inactivation of Escherichia coli (E. coli) with the quaternized photosensitizer at 5 μM, totally inactivated the E. coli (with log CFU = 10 decrease). Only 0.4 log CFU decrease was obtained with PbTpyPc. The embedded non-quaternized photosensitizer (PbTpyPc) was less active on the gram negative bacteria but the quaternized photosensitizer (PbTepyPc) was effective towards inactivation of E. coli.
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Argumentative and trustworthy scholars
- McKenna, Sioux, Boughey, Chrissie
- Authors: McKenna, Sioux , Boughey, Chrissie
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187216 , vital:44580 , xlink:href="https://doi.org/10.1080/13562517.2014.934351"
- Description: Research-intensive universities, such as the Russell Group in the UK, the Ivy League Colleges in the USA and the Sandstone Universities in Australia, enjoy particular status in the higher education landscape. They are, however, also often associated with social elitism and selectivity, and this has led to critique as higher education systems seek to widen access. This article looks at how academic staff are discursively constructed in five such institutions in South Africa through an analysis of documentation submitted as part of a national review. Three interrelated discourses are identified: a discourse of ‘staff as scholars’ whereby research is privileged over teaching, a discourse of ‘academic argumentation’ whereby a critical disposition is valued and is called upon by academics to resist development initiatives and a discourse of ‘trust’ whereby it is assumed that academics share a value system and should thus be trusted to undertake quality teaching without interference.
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- Authors: McKenna, Sioux , Boughey, Chrissie
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187216 , vital:44580 , xlink:href="https://doi.org/10.1080/13562517.2014.934351"
- Description: Research-intensive universities, such as the Russell Group in the UK, the Ivy League Colleges in the USA and the Sandstone Universities in Australia, enjoy particular status in the higher education landscape. They are, however, also often associated with social elitism and selectivity, and this has led to critique as higher education systems seek to widen access. This article looks at how academic staff are discursively constructed in five such institutions in South Africa through an analysis of documentation submitted as part of a national review. Three interrelated discourses are identified: a discourse of ‘staff as scholars’ whereby research is privileged over teaching, a discourse of ‘academic argumentation’ whereby a critical disposition is valued and is called upon by academics to resist development initiatives and a discourse of ‘trust’ whereby it is assumed that academics share a value system and should thus be trusted to undertake quality teaching without interference.
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Behavior of palladium nanoparticles in the absence or presence of cobalt tetraaminophthalocyanine for the electrooxidation of hydrazine
- Maringa, Audacity, Nyokong, Tebello
- Authors: Maringa, Audacity , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189796 , vital:44932 , xlink:href="https://doi.org/10.1002/elan.201400028"
- Description: We report on the electrodeposition of palladium nanoparticles (PdNPs) on a glassy carbon electrode (GCE) and onto a poly-CoTAPc-GCE (CoTAPc=cobalt tetraamino phthalocyanine) surface. The electrodes are denoted as PdNPs-GCE and PdNPs/poly-CoTAPc-GCE, respectively. PdNPs/poly-CoTAPc-GCE showed the best activity for the oxidation of hydrazine at the lowest potential of −0.28 V and with the highest currents. The results were further supported by electrochemical impedance spectroscopy (EIS) which showed that there was less resistance to charge transfer for PdNPs/poly-CoTAPc-GCE compared to PdNPs-GCE. The catalytic rate constant for hydrazine oxidation was 6.12×108 cm3 mol−1 s−1 using PdNPs/poly-CoTAPc-GCE.
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- Authors: Maringa, Audacity , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189796 , vital:44932 , xlink:href="https://doi.org/10.1002/elan.201400028"
- Description: We report on the electrodeposition of palladium nanoparticles (PdNPs) on a glassy carbon electrode (GCE) and onto a poly-CoTAPc-GCE (CoTAPc=cobalt tetraamino phthalocyanine) surface. The electrodes are denoted as PdNPs-GCE and PdNPs/poly-CoTAPc-GCE, respectively. PdNPs/poly-CoTAPc-GCE showed the best activity for the oxidation of hydrazine at the lowest potential of −0.28 V and with the highest currents. The results were further supported by electrochemical impedance spectroscopy (EIS) which showed that there was less resistance to charge transfer for PdNPs/poly-CoTAPc-GCE compared to PdNPs-GCE. The catalytic rate constant for hydrazine oxidation was 6.12×108 cm3 mol−1 s−1 using PdNPs/poly-CoTAPc-GCE.
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Book Review: Community of insecurity
- Authors: Magadla, Siphokazi
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/298606 , vital:57720 , xlink:href="https://doi.org/10.1080/02589001.2014.936174"
- Description: Laurie Nathan's Community of Insecurity is a thoughtful engagement with the ‘establishment, evolution and effectiveness of the regional security arrangements of the Southern African Development Community (SADC)’ (1). He argues that it is of ‘great significance and irony that many of the major disputes among member states have been around the orientation and strategies of peacemaking and regional security’. Nathan's empirical claims about the SADC security architecture are drawn from his ‘insider perspective’ due to his involvement in official efforts to design a common security regime in Southern Africa, which include his service as regional security advisor to the SADC Secretariat from 1992 to 1996, to the Foreign Minister of Mozambique Pascoal Mocumbi from 1994 to 1995, to the South African Minister of Defence Joe Modise and the Deputy Minister of Defence Ronnie Kasrils between 1994 and 1999 and to the Foreign Minister of Swaziland Albert Shabangu when he oversaw the SADC Organ on Politics, Defence and Security Cooperation in 1999–2000 (12–13). This ‘insider’ view has allowed him to make a compelling challenge to current theoretical debates about SADC's status as a security community, that is, a community with an affinity amongst member states that is ‘so strong that they enjoy dependable expectations of peaceful change and thus regard the prospect of war among them as inconceivable’(129). While other commentators see SADC as either a ‘nascent’, ‘embryonic’ or ‘emerging’ security community, Nathan argues forcefully that ‘this perspective is mistaken’ as SADC continues to be demonstrative of a what he describes as a ‘community of insecurity’.
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- Authors: Magadla, Siphokazi
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/298606 , vital:57720 , xlink:href="https://doi.org/10.1080/02589001.2014.936174"
- Description: Laurie Nathan's Community of Insecurity is a thoughtful engagement with the ‘establishment, evolution and effectiveness of the regional security arrangements of the Southern African Development Community (SADC)’ (1). He argues that it is of ‘great significance and irony that many of the major disputes among member states have been around the orientation and strategies of peacemaking and regional security’. Nathan's empirical claims about the SADC security architecture are drawn from his ‘insider perspective’ due to his involvement in official efforts to design a common security regime in Southern Africa, which include his service as regional security advisor to the SADC Secretariat from 1992 to 1996, to the Foreign Minister of Mozambique Pascoal Mocumbi from 1994 to 1995, to the South African Minister of Defence Joe Modise and the Deputy Minister of Defence Ronnie Kasrils between 1994 and 1999 and to the Foreign Minister of Swaziland Albert Shabangu when he oversaw the SADC Organ on Politics, Defence and Security Cooperation in 1999–2000 (12–13). This ‘insider’ view has allowed him to make a compelling challenge to current theoretical debates about SADC's status as a security community, that is, a community with an affinity amongst member states that is ‘so strong that they enjoy dependable expectations of peaceful change and thus regard the prospect of war among them as inconceivable’(129). While other commentators see SADC as either a ‘nascent’, ‘embryonic’ or ‘emerging’ security community, Nathan argues forcefully that ‘this perspective is mistaken’ as SADC continues to be demonstrative of a what he describes as a ‘community of insecurity’.
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Carbon nanotube-enhanced photoelectrochemical properties of metallo-octacarboxyphthalocyanines
- Mphahlele, Nonhlanhla E, Le Roux, Lukas, Jafta, Charl J, Cele, Leskev, Mathe, Mkhulu K, Nyokong, Tebello, Kobayashi, Nagao, Ozoemena, Kenneth I
- Authors: Mphahlele, Nonhlanhla E , Le Roux, Lukas , Jafta, Charl J , Cele, Leskev , Mathe, Mkhulu K , Nyokong, Tebello , Kobayashi, Nagao , Ozoemena, Kenneth I
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241595 , vital:50953 , xlink:href="https://doi.org/10.1007/s10853-013-7710-1"
- Description: The photoelectrochemistry of metallo-octacarboxyphthalocyanines (MOCPc, where M = Zn or Si(OH)2) integrated with MWCNTs for the development of dye-sensitized solar cells (DSSCs) is reported. The DSSC performance (obtained from the photo-chronoamperometric and photo-impedimetric data) decreased as ZnOCPc > (OH)2SiOCPc. The incorporation of the MWCNTs on the surface of the TiO2 film (MOCPc–MWCNT systems) gave higher photocurrent density than the bare MOCPc complexes. Also, from the EIS results, the MOCPc–MWCNT hybrids gave faster charge transport kinetics (approximately three times faster) compared to the bare MOCPc complexes. The electron lifetime was slightly longer (ca. 6 ms) at the ZnOCPc systems than at the (OH)2SiOCPc system (ca. 4 ms) meaning that the presence of the MWCNTs on the surface of the TiO2 film did not show any significant improvement on preventing charge recombination process.
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- Authors: Mphahlele, Nonhlanhla E , Le Roux, Lukas , Jafta, Charl J , Cele, Leskev , Mathe, Mkhulu K , Nyokong, Tebello , Kobayashi, Nagao , Ozoemena, Kenneth I
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241595 , vital:50953 , xlink:href="https://doi.org/10.1007/s10853-013-7710-1"
- Description: The photoelectrochemistry of metallo-octacarboxyphthalocyanines (MOCPc, where M = Zn or Si(OH)2) integrated with MWCNTs for the development of dye-sensitized solar cells (DSSCs) is reported. The DSSC performance (obtained from the photo-chronoamperometric and photo-impedimetric data) decreased as ZnOCPc > (OH)2SiOCPc. The incorporation of the MWCNTs on the surface of the TiO2 film (MOCPc–MWCNT systems) gave higher photocurrent density than the bare MOCPc complexes. Also, from the EIS results, the MOCPc–MWCNT hybrids gave faster charge transport kinetics (approximately three times faster) compared to the bare MOCPc complexes. The electron lifetime was slightly longer (ca. 6 ms) at the ZnOCPc systems than at the (OH)2SiOCPc system (ca. 4 ms) meaning that the presence of the MWCNTs on the surface of the TiO2 film did not show any significant improvement on preventing charge recombination process.
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Celebrating 30 years of Feminism and Psychology
- Macleod, Catriona I, Capdevila, Rose, Marecek, Jeanne, Braun, Virginia, Gavey, Nicola, Wilkinson, Sue
- Authors: Macleod, Catriona I , Capdevila, Rose , Marecek, Jeanne , Braun, Virginia , Gavey, Nicola , Wilkinson, Sue
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/444262 , vital:74211 , xlink:href="https://doi.org/10.1007/s11205-013-0452-2"
- Description: Feminism and Psychology (FandP) was launched in 1991 with a sense of possibility, enthusiasm and excitement as well as a sense of urgent need – to critique and reconstruct mainstream psychology (theory, research methods, and clinical practice). Thirty years have now passed since the first issue was produced. Thirty volumes with three or four issues have been published each year, thanks to the efforts of many. On the occasion of FandP’s 30th anniversary, we, the present and past editors, reflect on successes, changes and challenges in relation to the journal. We celebrate the prestigious awards accruing to the journal, its editors, and authors, and the significant contributions the journal has made to critical feminist scholarship at the interface of feminisms and psychologies. We note some of the theoretical and methodological developments and social changes witnessed over the last three decades. We highlight challenges facing feminist researchers in academia as well as international feminist publishing. We conclude that the initial enthusiasm and excitement expressed by the then editorial collective was justified. But, there is still much work to be done.
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- Authors: Macleod, Catriona I , Capdevila, Rose , Marecek, Jeanne , Braun, Virginia , Gavey, Nicola , Wilkinson, Sue
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/444262 , vital:74211 , xlink:href="https://doi.org/10.1007/s11205-013-0452-2"
- Description: Feminism and Psychology (FandP) was launched in 1991 with a sense of possibility, enthusiasm and excitement as well as a sense of urgent need – to critique and reconstruct mainstream psychology (theory, research methods, and clinical practice). Thirty years have now passed since the first issue was produced. Thirty volumes with three or four issues have been published each year, thanks to the efforts of many. On the occasion of FandP’s 30th anniversary, we, the present and past editors, reflect on successes, changes and challenges in relation to the journal. We celebrate the prestigious awards accruing to the journal, its editors, and authors, and the significant contributions the journal has made to critical feminist scholarship at the interface of feminisms and psychologies. We note some of the theoretical and methodological developments and social changes witnessed over the last three decades. We highlight challenges facing feminist researchers in academia as well as international feminist publishing. We conclude that the initial enthusiasm and excitement expressed by the then editorial collective was justified. But, there is still much work to be done.
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Characterization of electrodes modified by one pot or step by step electro-click reaction and axial ligation of iron tetracarboxyphthalocyanine
- Maringa, Audacity, Mashazi, Philani N, Nyokong, Tebello
- Authors: Maringa, Audacity , Mashazi, Philani N , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193892 , vital:45403 , xlink:href="https://doi.org/10.1016/j.electacta.2014.09.011"
- Description: The modification of the glassy carbon electrode (GCE) was carried out using two methods. The first method is simultaneous electropolymerization and electro-click followed by immersion into a solution of dimethyl formamide (DMF) containing FeTCPc. The second method is step by step whereby electropolymerization is carried out first followed by electro-click and then immersion into a DMF solution containing FeTCPc. From the electrochemical characterization, it was observed that the second route (step by step method) was the best as indicated by the ferricyanide studies (cyclic voltammetry and scanning electrochemical microscopy). In the electrooxidation of hydrazine, we obtained a potential of 0.26 V. Of interest were the detection limit of 6.4 μM and the catalytic rate constant of 2.1 × 109 cm3 mol−1 s−1. This shows that the sensor can be used for the electrooxidation of hydrazine.
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- Authors: Maringa, Audacity , Mashazi, Philani N , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193892 , vital:45403 , xlink:href="https://doi.org/10.1016/j.electacta.2014.09.011"
- Description: The modification of the glassy carbon electrode (GCE) was carried out using two methods. The first method is simultaneous electropolymerization and electro-click followed by immersion into a solution of dimethyl formamide (DMF) containing FeTCPc. The second method is step by step whereby electropolymerization is carried out first followed by electro-click and then immersion into a DMF solution containing FeTCPc. From the electrochemical characterization, it was observed that the second route (step by step method) was the best as indicated by the ferricyanide studies (cyclic voltammetry and scanning electrochemical microscopy). In the electrooxidation of hydrazine, we obtained a potential of 0.26 V. Of interest were the detection limit of 6.4 μM and the catalytic rate constant of 2.1 × 109 cm3 mol−1 s−1. This shows that the sensor can be used for the electrooxidation of hydrazine.
- Full Text: