Entrepreneurial mindset and entrepreneurial education as tools for sustainable SMES
- Authors: Mbanga, Nelisa
- Date: 2016
- Subjects: Entrepreneurship -- South Africa Small business -- South Africa New business enterprises -- Management
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/11277 , vital:26905
- Description: Small and Medium Enterprises are the engines of economic development. In developing countries, they play an irreplaceable role in poverty alleviation through creation of jobs and contribution towards the countries’ gross domestic products. South Africa is faced with a challenge of high failure rate of SMEs despite the efforts by government to support and grow this sector. For a country to have a strong sustainable economy, sustainable and successful SME sector is necessary. Literature reviews have demonstrated that incorporating sustainability aspect into entrepreneurship improves the performance of businesses. Research on implementation of sustainability principles by SMEs is limited and SMEs have been left out in sustainability teachings and monitoring. The purpose of the study was to analyse the role played by entrepreneurial mind-set and entrepreneurial education on sustainability of SMEs. The research was conducted amongst 10 SME owners/managers with businesses located in the Buffalo City Metropolitan Municipality. Case study method using a semi-structured interview guide was conducted. Results were transcribed, analysed and interpreted. Results of the research demonstrated that SME owners/managers possess entrepreneurial mind-set, which is a necessity to run a successful business. There was also evidence that entrepreneurial education enhances entrepreneurial mind-set of SME owners/managers. SMEs owners/managers also demonstrated that they implement sustainability principles informally with no guiding documents. With regards to implementation of sustainability principles, there was no noticeable difference between SME owners/managers who had undergone entrepreneurship education and the ones who had not gone through entrepreneurship education. This highlighted the need to incorporate sustainability issues in entrepreneurship education courses. The study brings contribution towards building sustainable SMEs.
- Full Text:
- Date Issued: 2016
- Authors: Mbanga, Nelisa
- Date: 2016
- Subjects: Entrepreneurship -- South Africa Small business -- South Africa New business enterprises -- Management
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/11277 , vital:26905
- Description: Small and Medium Enterprises are the engines of economic development. In developing countries, they play an irreplaceable role in poverty alleviation through creation of jobs and contribution towards the countries’ gross domestic products. South Africa is faced with a challenge of high failure rate of SMEs despite the efforts by government to support and grow this sector. For a country to have a strong sustainable economy, sustainable and successful SME sector is necessary. Literature reviews have demonstrated that incorporating sustainability aspect into entrepreneurship improves the performance of businesses. Research on implementation of sustainability principles by SMEs is limited and SMEs have been left out in sustainability teachings and monitoring. The purpose of the study was to analyse the role played by entrepreneurial mind-set and entrepreneurial education on sustainability of SMEs. The research was conducted amongst 10 SME owners/managers with businesses located in the Buffalo City Metropolitan Municipality. Case study method using a semi-structured interview guide was conducted. Results were transcribed, analysed and interpreted. Results of the research demonstrated that SME owners/managers possess entrepreneurial mind-set, which is a necessity to run a successful business. There was also evidence that entrepreneurial education enhances entrepreneurial mind-set of SME owners/managers. SMEs owners/managers also demonstrated that they implement sustainability principles informally with no guiding documents. With regards to implementation of sustainability principles, there was no noticeable difference between SME owners/managers who had undergone entrepreneurship education and the ones who had not gone through entrepreneurship education. This highlighted the need to incorporate sustainability issues in entrepreneurship education courses. The study brings contribution towards building sustainable SMEs.
- Full Text:
- Date Issued: 2016
Environmental factors influencing ecotonal changes in an indigenous forest in the Keiskammahoek Forest Estate, Eastern Cape, South Africa
- Authors: Kiva, Luthando
- Date: 2016
- Subjects: Forest ecology -- South Africa -- Eastern Cape Forests and forestry -- South Africa -- Eastern Cape Forest conservation -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/2743 , vital:28071
- Description: This study investigates environmental factors influencing ecotonal changes in the Dontsa Forest Management Unit (FMU) of the Keiskammahoek Estate Forest which is located in the Amatole Mountains of the Eastern Cape in the Republic of South Africa. The patterns of forest edge movement were analysed to show trends of forest edge movement from 1975 to 1985, 1975 to 1992, 1975 to 2002, 1975 to 2014, 1985 to 1992, 1985 to 2002, 1985 to 2014, 1992 to 2002, 1992 to 2014 and 2002 to 2014 by digitizing and assessing the scale of forest edge movement using georeferenced aerial photographs. Belt transects were established in six sites that were selected on the basis of physiographic elements for determination of the driving forces of forest ecotonal changes. The results of the study show that the forest edge moved positive towards the grassland biome while in other sites there was contraction of the forest edge from 1975 to 2014. The findings of the study show that some forest patches moved with few individual pioneer species towards the grassland while indigenous species dominated in the ecotone area of the forest in other research sites. D whyteana, A latifolius, R melanophloes, A facultus, R prenoides, C aurea, C bispinosa, C inerme, and S martina are the plant species with high density in the forest ecotone while A latifolius, R prenoides, R melanophloes were highly distributed along the grassland area. The results also show that harvesting of Pinus patula and illegal harvesting of understory species are major factors that result in ecotonal changes of Dontsa FMU. The research sites adjacent to residential areas have experienced reduction of ecotone area as compared to the research sites in high altitude areas of the Amathole Mountains where there is less disturbance. The eastern facing aspect of the forest exhibited a high density of plants in the forest ecotone as compared to the west facing slope.
- Full Text:
- Date Issued: 2016
- Authors: Kiva, Luthando
- Date: 2016
- Subjects: Forest ecology -- South Africa -- Eastern Cape Forests and forestry -- South Africa -- Eastern Cape Forest conservation -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/2743 , vital:28071
- Description: This study investigates environmental factors influencing ecotonal changes in the Dontsa Forest Management Unit (FMU) of the Keiskammahoek Estate Forest which is located in the Amatole Mountains of the Eastern Cape in the Republic of South Africa. The patterns of forest edge movement were analysed to show trends of forest edge movement from 1975 to 1985, 1975 to 1992, 1975 to 2002, 1975 to 2014, 1985 to 1992, 1985 to 2002, 1985 to 2014, 1992 to 2002, 1992 to 2014 and 2002 to 2014 by digitizing and assessing the scale of forest edge movement using georeferenced aerial photographs. Belt transects were established in six sites that were selected on the basis of physiographic elements for determination of the driving forces of forest ecotonal changes. The results of the study show that the forest edge moved positive towards the grassland biome while in other sites there was contraction of the forest edge from 1975 to 2014. The findings of the study show that some forest patches moved with few individual pioneer species towards the grassland while indigenous species dominated in the ecotone area of the forest in other research sites. D whyteana, A latifolius, R melanophloes, A facultus, R prenoides, C aurea, C bispinosa, C inerme, and S martina are the plant species with high density in the forest ecotone while A latifolius, R prenoides, R melanophloes were highly distributed along the grassland area. The results also show that harvesting of Pinus patula and illegal harvesting of understory species are major factors that result in ecotonal changes of Dontsa FMU. The research sites adjacent to residential areas have experienced reduction of ecotone area as compared to the research sites in high altitude areas of the Amathole Mountains where there is less disturbance. The eastern facing aspect of the forest exhibited a high density of plants in the forest ecotone as compared to the west facing slope.
- Full Text:
- Date Issued: 2016
Environmental management in military activities of the South African National Defence Force
- Authors: Magagula, Hezekiel Bheki
- Date: 2016
- Subjects: South Africa -- South African Defence Force Military bases -- Environmental aspects Hazardous waste site remediation
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/5927 , vital:29430
- Description: This thesis presents research findings on current environmental management practices used by the South African National Defence Force (SANDF). Two case studies are presented; the first is the Grahamstown Military Installation (6 South African Infantry Battalion) and the second the South African Army Combat Training Centre (42 Brigade). A combination of three sampling techniques, namely, the stratified, purposive and link-tracing (snowball) samplings were employed and structured questionnaires and semi-structured interviews with key SANDF officials were used as primary data. In addition, secondary data sources in the form of inter alia the first and second editions of the Environmental Management Plan for Defence (2001 & 2008 respectively); the development and implementation of environmental education and training in the military: a joint United States-Republic of South Africa Environmental Working Group Project (2003); Overarching Strategic Statement for 2011; Integrated Environmental Management Information Series: Linking Environmental Impact Assessment and Environmental Management Systems (2004); The Department of Defence Strategic Plan (2010): Republic of South Africa and the South African Defence Review (2012) were studied. In addition, field observations were also carried out within the two military installations training areas between July, 2011 and November, 2013. Primary data on the conditions of training areas, waste removal after training exercises, pollution prevention measures, and rehabilitation efforts to restore degraded training ranges were collected. Furthermore, composite surface sediment samples and water samples were collected for analysis. A total of fifty-six surface sediments and thirty water samples were analysed for the concentrations of heavy metals using the ICP-MS. These attitudes and perceptions are predominantly positive. Statistical analysis (ANOVA) did not reveal any significant differences in responses, especially, between military ranks. However, sporadic significant differences were found in five of the statements in the questionnaire from respondents with different service periods. Furthermore, the emphasis placed on environmental protection within defence force activities worldwide has compelled the South African Department of Defence and Military Veterans (DoDMV) to regulate the management of the environment within its properties. Yet, these efforts have faced numerous challenges ranging from financial to human resource deficiencies. It was found that environmental management practices and programmes at different military installations vary significantly. Consequently, six environmental management programmes were identified at South African Army Combat Training Centre, while only one environmental management programme was identified at Grahamstown Military Installation. This programme is a collaborative effort between the SANDF/DoDMV and the Department of Water Affairs and Sanitation to eradicate invasive alien plant species. In the light of the analysis of official documents and interviews with respondents, it was established that the DoDMV does not have a budget for environmental management services and environmental management is yet to be incorporated into formal military training programmes. There is a severe shortage of environmentally qualified and knowledgeable personnel within the SANDF. Subsequently, all these drawbacks lead to the failure of the implementation of the Defence Force’s Environmental Management System (EMS) and inadequate management of the environment at military installations of the SANDF. Consequently, these challenges have severely compromised the commitment of the SANDF to honour its environmental management obligations. Such deficiencies tend to undermine the sustainable utilisation of the national assets entrusted to the Defence Force. Therefore, this thesis argues that environmental management programmes for the SANDF are based on a very weak foundation. This thesis proposes an ideal model for the successful implementation of the EMS and management of the environment at SANDF military installations. The analysis of water and soil samples led to the identification and quantification of heavy mental pollutants. The concentrations of heavy metals in water samples were varying between <0.01 to <0.05mg/l, but generally constant. Thus, no significant or meaningful statistical results were obtained. Pearson’s correlation coefficient was used to analyse the concentrations of heavy metals obtained in the sediment samples.
- Full Text:
- Date Issued: 2016
- Authors: Magagula, Hezekiel Bheki
- Date: 2016
- Subjects: South Africa -- South African Defence Force Military bases -- Environmental aspects Hazardous waste site remediation
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/5927 , vital:29430
- Description: This thesis presents research findings on current environmental management practices used by the South African National Defence Force (SANDF). Two case studies are presented; the first is the Grahamstown Military Installation (6 South African Infantry Battalion) and the second the South African Army Combat Training Centre (42 Brigade). A combination of three sampling techniques, namely, the stratified, purposive and link-tracing (snowball) samplings were employed and structured questionnaires and semi-structured interviews with key SANDF officials were used as primary data. In addition, secondary data sources in the form of inter alia the first and second editions of the Environmental Management Plan for Defence (2001 & 2008 respectively); the development and implementation of environmental education and training in the military: a joint United States-Republic of South Africa Environmental Working Group Project (2003); Overarching Strategic Statement for 2011; Integrated Environmental Management Information Series: Linking Environmental Impact Assessment and Environmental Management Systems (2004); The Department of Defence Strategic Plan (2010): Republic of South Africa and the South African Defence Review (2012) were studied. In addition, field observations were also carried out within the two military installations training areas between July, 2011 and November, 2013. Primary data on the conditions of training areas, waste removal after training exercises, pollution prevention measures, and rehabilitation efforts to restore degraded training ranges were collected. Furthermore, composite surface sediment samples and water samples were collected for analysis. A total of fifty-six surface sediments and thirty water samples were analysed for the concentrations of heavy metals using the ICP-MS. These attitudes and perceptions are predominantly positive. Statistical analysis (ANOVA) did not reveal any significant differences in responses, especially, between military ranks. However, sporadic significant differences were found in five of the statements in the questionnaire from respondents with different service periods. Furthermore, the emphasis placed on environmental protection within defence force activities worldwide has compelled the South African Department of Defence and Military Veterans (DoDMV) to regulate the management of the environment within its properties. Yet, these efforts have faced numerous challenges ranging from financial to human resource deficiencies. It was found that environmental management practices and programmes at different military installations vary significantly. Consequently, six environmental management programmes were identified at South African Army Combat Training Centre, while only one environmental management programme was identified at Grahamstown Military Installation. This programme is a collaborative effort between the SANDF/DoDMV and the Department of Water Affairs and Sanitation to eradicate invasive alien plant species. In the light of the analysis of official documents and interviews with respondents, it was established that the DoDMV does not have a budget for environmental management services and environmental management is yet to be incorporated into formal military training programmes. There is a severe shortage of environmentally qualified and knowledgeable personnel within the SANDF. Subsequently, all these drawbacks lead to the failure of the implementation of the Defence Force’s Environmental Management System (EMS) and inadequate management of the environment at military installations of the SANDF. Consequently, these challenges have severely compromised the commitment of the SANDF to honour its environmental management obligations. Such deficiencies tend to undermine the sustainable utilisation of the national assets entrusted to the Defence Force. Therefore, this thesis argues that environmental management programmes for the SANDF are based on a very weak foundation. This thesis proposes an ideal model for the successful implementation of the EMS and management of the environment at SANDF military installations. The analysis of water and soil samples led to the identification and quantification of heavy mental pollutants. The concentrations of heavy metals in water samples were varying between <0.01 to <0.05mg/l, but generally constant. Thus, no significant or meaningful statistical results were obtained. Pearson’s correlation coefficient was used to analyse the concentrations of heavy metals obtained in the sediment samples.
- Full Text:
- Date Issued: 2016
Epistemological access in a science foundation course: a social realist perspective
- Authors: Ellery, Karen
- Date: 2016
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1335 , http://hdl.handle.net/10962/d1021309
- Description: This dissertation examines how educational practices of a multidisciplinary, integrated science foundation course, Introduction to Science Concepts and Methods (ISCM), at Rhodes University in South Africa, enable and/or constrain epistemological access to a range of mainstream science disciplines. Students in the ISCM course are mainly African, working-class, first-generation higher education learners whose home language is seldom English. This study is motivated firstly by poor success of working-class African students in higher education in South Africa in general and in the sciences in particular, and secondly by the need for closely theorised, empirical work to guide necessary transformational change that will contribute to equity and, thus, to greater social justice. Since I teach in ISCM and coordinate the programme in which it is located, I also have a personal and professional interest in improving my own practice. Conceptually the study draws on Morrow’s (2007, 2009) and various literacy theorists interpretations of the concept of epistemological access, which in this study is about becoming and being a participant in an academic practice by virtue of learning both the knowledge as well as the norms, values and beliefs that constitute the practice. Theoretically and analytically the study draws on Maton’s (2014a) Legitimation Code Theory (LCT) and on various aspects of Bernstein’s (2000) code theory work. Codes are the organising principles or ‘rules of the game’ of practices and code theory is premised on the idea that power and control in education systems manifest themselves through the structural and interactional aspects of educational practices, and therefore have the capacity to include or exclude. Analysing educational practices using code theory enables characterisation of the practices, highlights their underpinning principles, and allows for their effects to be considered. This layered approach to analysis indicates that a critical realist depth ontology serves as an underlabourer to code theory. The desired ‘effect’ of educational practices in this study, is students gaining epistemological access to science, or science disciplines, in higher education. The overall approach is a single, in-depth, qualitative case study with a primary focus on what is legitimated in ISCM educational practices (curriculum, pedagogy, assessment) and how students respond to these practices. A lesser focus is how ex-ISCM students are responding to educational practices in the first-year, first-semester Cell Biology, Chemistry, Earth Sciences and Physics mainstream courses, and whether they are attaining epistemological access. To examine educational practices in ISCM and mainstream courses data from document analysis, interviews, observations and critical reflections are analysed through developing external languages of description. The two LCT code dimensions of Specialisation (what or who specialises a practice) and Semantics (how meaning relates to context and empirical referents) are used to examine curriculum, Bernstein’s (2000) framing of the regulative and instructional discourses are drawn on in considering pedagogy, and an adapted cognitive process level model assists in analysing assessment practices. To examine student responses to educational practices Bernstein’s (ibid.) concept of acquisition of recognition and realisation rules is used. Since ISCM serves the dual purpose of developing scientific conceptual knowledge, as well as supporting student learning in an academic context, a complex picture of practices and underpinning codes emerges. Based on epistemological concerns of developing students as scientists, ISCM legitimates an epistemic-context knowledge code and a rhizomatic/worldly curriculum code. If students produce the legitimated epistemic-context scientific ‘text’, they have attained epistemic access. Based on axiological concerns of the learning context, ISCM also legitimates a learning-context knower code. By producing the legitimate learning-context ‘text’ of an autonomous, self-regulated science learner, students demonstrate they have attained learning-context access. Both forms of access are key for student success, and combined they constitute epistemological access. The findings of the study indicate that framing and legitimation of educational practices in ISCM, by most accounts, should be promoting epistemological access. When epistemological access is not attained in ISCM it is suggested this is likely due to both a code clash at the learning-context level and competing code demands between epistemic-context and learning-context concerns. Poor access in mainstream courses appears to be exacerbated by both a narrow-based knowledge code and little or no support for a learning-context knower code. The study concludes by outlining a two-tiered conceptual model of epistemological access in the sciences based on the mutually integrative components of epistemic- and learning-context access. Because of inequitable outcomes in science mainstream courses at Rhodes University based on race and/or class I argue for far-reaching transformative pedagogies throughout the faculty, and in the broader South African science higher education sector, that address and accommodate issues of diversity and difference. This should include, amongst other things, a weakening of epistemic relations to create space for a strengthening of learning-context social relations. This is not a suggestion to move away from a science knowledge code, which I argue is based on powerful knowledge to which all students must gain access, but instead a shift in emphasis to better support previously educationally disenfranchised students and to understand in a more rigorous manner what epistemological access means to them as individuals. In light of the recent disruptive and angry student calls for decolonisation of the curriculum, this is an urgent imperative.
- Full Text:
- Date Issued: 2016
- Authors: Ellery, Karen
- Date: 2016
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1335 , http://hdl.handle.net/10962/d1021309
- Description: This dissertation examines how educational practices of a multidisciplinary, integrated science foundation course, Introduction to Science Concepts and Methods (ISCM), at Rhodes University in South Africa, enable and/or constrain epistemological access to a range of mainstream science disciplines. Students in the ISCM course are mainly African, working-class, first-generation higher education learners whose home language is seldom English. This study is motivated firstly by poor success of working-class African students in higher education in South Africa in general and in the sciences in particular, and secondly by the need for closely theorised, empirical work to guide necessary transformational change that will contribute to equity and, thus, to greater social justice. Since I teach in ISCM and coordinate the programme in which it is located, I also have a personal and professional interest in improving my own practice. Conceptually the study draws on Morrow’s (2007, 2009) and various literacy theorists interpretations of the concept of epistemological access, which in this study is about becoming and being a participant in an academic practice by virtue of learning both the knowledge as well as the norms, values and beliefs that constitute the practice. Theoretically and analytically the study draws on Maton’s (2014a) Legitimation Code Theory (LCT) and on various aspects of Bernstein’s (2000) code theory work. Codes are the organising principles or ‘rules of the game’ of practices and code theory is premised on the idea that power and control in education systems manifest themselves through the structural and interactional aspects of educational practices, and therefore have the capacity to include or exclude. Analysing educational practices using code theory enables characterisation of the practices, highlights their underpinning principles, and allows for their effects to be considered. This layered approach to analysis indicates that a critical realist depth ontology serves as an underlabourer to code theory. The desired ‘effect’ of educational practices in this study, is students gaining epistemological access to science, or science disciplines, in higher education. The overall approach is a single, in-depth, qualitative case study with a primary focus on what is legitimated in ISCM educational practices (curriculum, pedagogy, assessment) and how students respond to these practices. A lesser focus is how ex-ISCM students are responding to educational practices in the first-year, first-semester Cell Biology, Chemistry, Earth Sciences and Physics mainstream courses, and whether they are attaining epistemological access. To examine educational practices in ISCM and mainstream courses data from document analysis, interviews, observations and critical reflections are analysed through developing external languages of description. The two LCT code dimensions of Specialisation (what or who specialises a practice) and Semantics (how meaning relates to context and empirical referents) are used to examine curriculum, Bernstein’s (2000) framing of the regulative and instructional discourses are drawn on in considering pedagogy, and an adapted cognitive process level model assists in analysing assessment practices. To examine student responses to educational practices Bernstein’s (ibid.) concept of acquisition of recognition and realisation rules is used. Since ISCM serves the dual purpose of developing scientific conceptual knowledge, as well as supporting student learning in an academic context, a complex picture of practices and underpinning codes emerges. Based on epistemological concerns of developing students as scientists, ISCM legitimates an epistemic-context knowledge code and a rhizomatic/worldly curriculum code. If students produce the legitimated epistemic-context scientific ‘text’, they have attained epistemic access. Based on axiological concerns of the learning context, ISCM also legitimates a learning-context knower code. By producing the legitimate learning-context ‘text’ of an autonomous, self-regulated science learner, students demonstrate they have attained learning-context access. Both forms of access are key for student success, and combined they constitute epistemological access. The findings of the study indicate that framing and legitimation of educational practices in ISCM, by most accounts, should be promoting epistemological access. When epistemological access is not attained in ISCM it is suggested this is likely due to both a code clash at the learning-context level and competing code demands between epistemic-context and learning-context concerns. Poor access in mainstream courses appears to be exacerbated by both a narrow-based knowledge code and little or no support for a learning-context knower code. The study concludes by outlining a two-tiered conceptual model of epistemological access in the sciences based on the mutually integrative components of epistemic- and learning-context access. Because of inequitable outcomes in science mainstream courses at Rhodes University based on race and/or class I argue for far-reaching transformative pedagogies throughout the faculty, and in the broader South African science higher education sector, that address and accommodate issues of diversity and difference. This should include, amongst other things, a weakening of epistemic relations to create space for a strengthening of learning-context social relations. This is not a suggestion to move away from a science knowledge code, which I argue is based on powerful knowledge to which all students must gain access, but instead a shift in emphasis to better support previously educationally disenfranchised students and to understand in a more rigorous manner what epistemological access means to them as individuals. In light of the recent disruptive and angry student calls for decolonisation of the curriculum, this is an urgent imperative.
- Full Text:
- Date Issued: 2016
Equal pay for equal work
- Authors: Paul, Gary William
- Date: 2016
- Subjects: Equal pay for equal work -- South Africa , Labor laws and legislation -- South Africa , Pay equity -- South Africa
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: http://hdl.handle.net/10948/5343 , vital:20830
- Description: The notion of Decent Work has been broadly advocated since 1999 by means of various International Labour Organisation (ILO) Conventions. Through these Conventions and as part of its Decent Work Agenda, the ILO strives to foster the creation of social and economic systems, capable of ensuring basic security and employment and adaptable to rapidly changing local and global economic circumstances. The Decent Work Agenda has been widely accepted as an important strategy to eradicate poverty and enable socio-economic development. It is submitted that the concept of Decent Work as contemplated by the ILO, firstly focuses on the payment of an income, which allows the working individual a good life. It secondly strives to ensure that everybody has an equal chance to develop themselves; that working conditions are safe; that there is no instance of child and forced labour; and that discrimination does not occur. The elimination of discrimination in the workplace is not only an ever-evolving pursuit, given that it continues to manifest in innumerable forms, but it has also proven to be an extremely pervasive pursuit as evidenced by the jurisdiction-specific literature review in this study. The jurisdictions focused on in this study are the United States of America, the United Kingdom and Australia. This study concerns itself with pay-related discrimination which strains ILO Conventions No 100 and 111. Convention 100 focuses on equal pay for equal work and Convention No 111 focuses on the elimination of all forms of discrimination in the workplace. In spite of extensive legislative developments in the various jurisdictions which form part of this study, enhanced by the creation of various practical mechanisms to enable the elimination of pay-related discrimination, the stubborn problem of discriminatory pay practices has survived structured and deliberate attempts to get rid of it. In South Africa, the amendment to section 6(4) of the Employment Equity Act, assented on 1 August 2014, specifically describes a difference in conditions of employment between employees of the same employer performing the same or substantially the same work or work of equal value based on any one or more of the grounds listed in section 6(1), as unfair discrimination. This amendment therefore seeks to prohibit such unfair discriminatory practices. Based on the newness of this amendment and the fact that courts have not yet delivered judgments arising from litigation related to this particular amendment, a sense of uncertainty exists with respect to the adequacy of the amended section 6 in the Employment Equity Amendment Act. If progress in the other jurisdictions in this regard is anything to go by, there is no reason to believe that the amendment to section 6 will be a panacea capable of addressing all alleged discriminatory pay practices.
- Full Text:
- Date Issued: 2016
- Authors: Paul, Gary William
- Date: 2016
- Subjects: Equal pay for equal work -- South Africa , Labor laws and legislation -- South Africa , Pay equity -- South Africa
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: http://hdl.handle.net/10948/5343 , vital:20830
- Description: The notion of Decent Work has been broadly advocated since 1999 by means of various International Labour Organisation (ILO) Conventions. Through these Conventions and as part of its Decent Work Agenda, the ILO strives to foster the creation of social and economic systems, capable of ensuring basic security and employment and adaptable to rapidly changing local and global economic circumstances. The Decent Work Agenda has been widely accepted as an important strategy to eradicate poverty and enable socio-economic development. It is submitted that the concept of Decent Work as contemplated by the ILO, firstly focuses on the payment of an income, which allows the working individual a good life. It secondly strives to ensure that everybody has an equal chance to develop themselves; that working conditions are safe; that there is no instance of child and forced labour; and that discrimination does not occur. The elimination of discrimination in the workplace is not only an ever-evolving pursuit, given that it continues to manifest in innumerable forms, but it has also proven to be an extremely pervasive pursuit as evidenced by the jurisdiction-specific literature review in this study. The jurisdictions focused on in this study are the United States of America, the United Kingdom and Australia. This study concerns itself with pay-related discrimination which strains ILO Conventions No 100 and 111. Convention 100 focuses on equal pay for equal work and Convention No 111 focuses on the elimination of all forms of discrimination in the workplace. In spite of extensive legislative developments in the various jurisdictions which form part of this study, enhanced by the creation of various practical mechanisms to enable the elimination of pay-related discrimination, the stubborn problem of discriminatory pay practices has survived structured and deliberate attempts to get rid of it. In South Africa, the amendment to section 6(4) of the Employment Equity Act, assented on 1 August 2014, specifically describes a difference in conditions of employment between employees of the same employer performing the same or substantially the same work or work of equal value based on any one or more of the grounds listed in section 6(1), as unfair discrimination. This amendment therefore seeks to prohibit such unfair discriminatory practices. Based on the newness of this amendment and the fact that courts have not yet delivered judgments arising from litigation related to this particular amendment, a sense of uncertainty exists with respect to the adequacy of the amended section 6 in the Employment Equity Amendment Act. If progress in the other jurisdictions in this regard is anything to go by, there is no reason to believe that the amendment to section 6 will be a panacea capable of addressing all alleged discriminatory pay practices.
- Full Text:
- Date Issued: 2016
Ericoid fungal inoculation of blueberry under commercial production in South Africa
- Bizabani, Christine, Fontenla, Sonia, Dames, Joanna F
- Authors: Bizabani, Christine , Fontenla, Sonia , Dames, Joanna F
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/448610 , vital:74746 , https://doi.org/10.1016/j.scienta.2016.06.029
- Description: Ericoid mycorrhizal (ERM) fungi are known to enhance growth of plants belonging to the Ericaceae family. However, the outcomes of root-fungal associations in this family are influenced by several factors such as soil nutrient status, climatic conditions, host variety and fungal partner. The aim of this study was (i) to determine whether symbiotic fungal structures form in roots of Misty (Vaccinium corymbosum) and Brightwell (V. ashei) blueberry varieties, following inoculation with Leohumicola, Oidiodendron maius and Meliniomyces fungal species, and (ii) evaluate inoculation effects on the growth of blueberry varieties. The study was conducted for 60 weeks under commercial production conditions at Amathole Berries, Sutterheim, South Africa. All three fungi were isolated from Erica plants growing naturally in Albany Centre of Endemism of South Africa. All ERM formed mycorrhizal structures characteristic of typical ericoid colonisation in the roots of both Misty and Brightwell. However, percentage colonisation was low. The highest colonisation percentage, 20.4%, was observed in Misty inoculated with Oidiodendron maius. Colonisation was significantly different compared to un-inoculated controls in the Misty variety. In both varieties inoculated with either Leohumicola or Meliniomyces did not improve (p > 0.05) shoot growth and biomass. All fungal species improved root biomass in Misty but not in Brightwell. This indicates that ERM inoculation may potentially benefit plant of Misty and that responses to ERM inoculation vary between blueberry varieties.
- Full Text:
- Date Issued: 2016
- Authors: Bizabani, Christine , Fontenla, Sonia , Dames, Joanna F
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/448610 , vital:74746 , https://doi.org/10.1016/j.scienta.2016.06.029
- Description: Ericoid mycorrhizal (ERM) fungi are known to enhance growth of plants belonging to the Ericaceae family. However, the outcomes of root-fungal associations in this family are influenced by several factors such as soil nutrient status, climatic conditions, host variety and fungal partner. The aim of this study was (i) to determine whether symbiotic fungal structures form in roots of Misty (Vaccinium corymbosum) and Brightwell (V. ashei) blueberry varieties, following inoculation with Leohumicola, Oidiodendron maius and Meliniomyces fungal species, and (ii) evaluate inoculation effects on the growth of blueberry varieties. The study was conducted for 60 weeks under commercial production conditions at Amathole Berries, Sutterheim, South Africa. All three fungi were isolated from Erica plants growing naturally in Albany Centre of Endemism of South Africa. All ERM formed mycorrhizal structures characteristic of typical ericoid colonisation in the roots of both Misty and Brightwell. However, percentage colonisation was low. The highest colonisation percentage, 20.4%, was observed in Misty inoculated with Oidiodendron maius. Colonisation was significantly different compared to un-inoculated controls in the Misty variety. In both varieties inoculated with either Leohumicola or Meliniomyces did not improve (p > 0.05) shoot growth and biomass. All fungal species improved root biomass in Misty but not in Brightwell. This indicates that ERM inoculation may potentially benefit plant of Misty and that responses to ERM inoculation vary between blueberry varieties.
- Full Text:
- Date Issued: 2016
Establishing a waste management system for Cape Peninsula University of Technology
- Authors: Myamya, Luyolo Ebenezer
- Date: 2016
- Subjects: Waste minimization -- South Africa Sanitary engineering -- South Africa Environmental management -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/11670 , vital:26949
- Description: Communities around the globe are confronted by environmental challenges such as waste management. These challenges are further aggravated by factors such the increasing volumes of waste, landfills that are running out of capacity and scarcity of suitable land to construct new landfill sites. The National Waste Management Strategy requires participation from all members of society including households, businesses, community organisations, nongovernmental organisations, parastatals and the three spheres of government, to promote practices that minimise the volumes of waste generated. The purpose of the research was to assess and investigate the current waste management practices at the Cape Peninsula University of Technology (CPUT), and recommend a waste management system. The research employed a quantitative approach, where participants were asked to complete a survey questionnaire. A literature review was conducted on waste management at higher learning institutions, with particular focus on the contribution that a university can make in alleviating some of the adverse effects of waste management. The outcome of the review highlighted some of the opportunities and barriers that can either disrupt or augment the process of implementing a waste management system. The results from the research revealed that CPUT does not conform to the hierarchy of waste management, and there is no waste management policy in place. The effect of this is that the stakeholders were not satisfied with the lack of leadership on waste related challenges. By developing a policy, providing leadership, conducting awareness campaigns and prioritising environmental challenges such responsible management waste, could improve the image of the institution in the eyes if its stakeholders.
- Full Text:
- Date Issued: 2016
- Authors: Myamya, Luyolo Ebenezer
- Date: 2016
- Subjects: Waste minimization -- South Africa Sanitary engineering -- South Africa Environmental management -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/11670 , vital:26949
- Description: Communities around the globe are confronted by environmental challenges such as waste management. These challenges are further aggravated by factors such the increasing volumes of waste, landfills that are running out of capacity and scarcity of suitable land to construct new landfill sites. The National Waste Management Strategy requires participation from all members of society including households, businesses, community organisations, nongovernmental organisations, parastatals and the three spheres of government, to promote practices that minimise the volumes of waste generated. The purpose of the research was to assess and investigate the current waste management practices at the Cape Peninsula University of Technology (CPUT), and recommend a waste management system. The research employed a quantitative approach, where participants were asked to complete a survey questionnaire. A literature review was conducted on waste management at higher learning institutions, with particular focus on the contribution that a university can make in alleviating some of the adverse effects of waste management. The outcome of the review highlighted some of the opportunities and barriers that can either disrupt or augment the process of implementing a waste management system. The results from the research revealed that CPUT does not conform to the hierarchy of waste management, and there is no waste management policy in place. The effect of this is that the stakeholders were not satisfied with the lack of leadership on waste related challenges. By developing a policy, providing leadership, conducting awareness campaigns and prioritising environmental challenges such responsible management waste, could improve the image of the institution in the eyes if its stakeholders.
- Full Text:
- Date Issued: 2016
Establishing the links between performance improvement programmes, maturity and performance to facilitate improvement strategy formulation
- Authors: Ebrahim, Zahier
- Date: 2016
- Subjects: Automobile industry and trade , Lean manufacturing , Organizational effectiveness
- Language: English
- Type: Thesis , Doctoral , DBA
- Identifier: http://hdl.handle.net/10948/6865 , vital:21155
- Description: The automotive components manufacturing sector is facing tremendous pressure to remain competitive in a global economy. The application of performance improvement techniques to optimise factor production inputs remains a key strategic mechanism to effect the necessary change towards competitiveness. The high failure rate of these programmes, however, is a risk factor that should be considered by manufacturing firms. The investment into the implementation of these programmes will yield no return if the organisational maturity profile is not considered. The expected gains may not materialise and the execution of critical projects may take much longer than required. It is for this reason that an approach towards selecting the correct Performance Improvement Programme to optimise the performance of companies is a business imperative. Through a better understanding of the relationships between Performance Improvement Programmes and Organisational Maturity Variables, implementation success rates can increase, leading to improved results and sustainability. The approach taken to this research was quantitative in nature. Various descriptive and inferential statistics were applied to the selected respondents from the Eastern Cape automotive sector. The respondents had a working knowledge of Lean Manufacturing, Total Productive Maintenance (TPM) and Six Sigma. The research instrument was administered through an online survey. The research sought to identify whether there was a relationship amongst the variables under the three identified constructs. The research also sought to establish whether there was a difference between the specific Performance Improvement Programmes’ and Organisational Maturity Variables’ relationships. This affirmed the use of a new framework that integrates the programmes on the basis of their relationship to Organisational Maturity Variables. The research also provided insight into the challenges of the industry from a performance perspective and linked these with the relationship between Organisational Maturity Variables and Organisational Performance Variables. This allowed the researcher to include this additional insight as a consideration in the integrated implementation framework developed as part of the research. The results show that good consideration should be given to the Organisational Maturity Variables as these variables are related to the successful adoption of Performance Improvement Programmes. The research also shows that Lean Manufacturing, Total Productive Maintenance and Six Sigma are related to an organisations’ maturity profile in different ways. These results support the integrated Performance Improvement Programme approach, using a common set of tools and selecting the necessary programme specific tools based on a firm’s maturity profile. The research affords industry a framework to aid in decision making considering the relationships tested as part of this research. The linkages between Performance Programmes, Organisational Maturity Variables and Organisational Performance Variables are now more specific in nature.
- Full Text:
- Date Issued: 2016
- Authors: Ebrahim, Zahier
- Date: 2016
- Subjects: Automobile industry and trade , Lean manufacturing , Organizational effectiveness
- Language: English
- Type: Thesis , Doctoral , DBA
- Identifier: http://hdl.handle.net/10948/6865 , vital:21155
- Description: The automotive components manufacturing sector is facing tremendous pressure to remain competitive in a global economy. The application of performance improvement techniques to optimise factor production inputs remains a key strategic mechanism to effect the necessary change towards competitiveness. The high failure rate of these programmes, however, is a risk factor that should be considered by manufacturing firms. The investment into the implementation of these programmes will yield no return if the organisational maturity profile is not considered. The expected gains may not materialise and the execution of critical projects may take much longer than required. It is for this reason that an approach towards selecting the correct Performance Improvement Programme to optimise the performance of companies is a business imperative. Through a better understanding of the relationships between Performance Improvement Programmes and Organisational Maturity Variables, implementation success rates can increase, leading to improved results and sustainability. The approach taken to this research was quantitative in nature. Various descriptive and inferential statistics were applied to the selected respondents from the Eastern Cape automotive sector. The respondents had a working knowledge of Lean Manufacturing, Total Productive Maintenance (TPM) and Six Sigma. The research instrument was administered through an online survey. The research sought to identify whether there was a relationship amongst the variables under the three identified constructs. The research also sought to establish whether there was a difference between the specific Performance Improvement Programmes’ and Organisational Maturity Variables’ relationships. This affirmed the use of a new framework that integrates the programmes on the basis of their relationship to Organisational Maturity Variables. The research also provided insight into the challenges of the industry from a performance perspective and linked these with the relationship between Organisational Maturity Variables and Organisational Performance Variables. This allowed the researcher to include this additional insight as a consideration in the integrated implementation framework developed as part of the research. The results show that good consideration should be given to the Organisational Maturity Variables as these variables are related to the successful adoption of Performance Improvement Programmes. The research also shows that Lean Manufacturing, Total Productive Maintenance and Six Sigma are related to an organisations’ maturity profile in different ways. These results support the integrated Performance Improvement Programme approach, using a common set of tools and selecting the necessary programme specific tools based on a firm’s maturity profile. The research affords industry a framework to aid in decision making considering the relationships tested as part of this research. The linkages between Performance Programmes, Organisational Maturity Variables and Organisational Performance Variables are now more specific in nature.
- Full Text:
- Date Issued: 2016
Estuarine species and habitat :distribution and connectivity
- Veldkornet, Dimitri Allastair
- Authors: Veldkornet, Dimitri Allastair
- Date: 2016
- Subjects: Estuarine ecology -- Research -- South Africa Estuarine fishes -- Speciation -- South Africa , Aquatic plants -- South Africa
- Language: English
- Type: Thesis , Doctoral , PHD
- Identifier: http://hdl.handle.net/10948/45388 , vital:38604
- Description: This study explored the distribution of estuarine macrophyte genetic lineages, species and habitats in relation to environmental gradients at various spatial scales. A database was assembled to determine the area and species composition of different estuarine habitats. This can now be used to retrieve information as a baseline for further monitoring and conservation planning. Research has shown that macrophytes occur over a wide range of physiochemical conditions, suggesting that these species have great genetic and phenotypic variation to occupy broad niche ranges. In eight estuaries along the South African coast, sediment and groundwater characteristics were measured in quadrants spanning the salt marsh, ecotone and terrestrial habitats. The results suggested that, in the absence of competition and disturbance at the salt marsh-terrestrial boundary, salt marshes would be unaffected by sea-level rise; and they would migrate landward. However, disturbance at the landward margin of salt marshes has already resulted in changes in species composition and altered environmental conditions. This promotes the encroachment of terrestrial alien invasive plants, leading to a loss of connectivity. A holistic assessment of land-cover changes showed that only 28% of South African estuaries still remain in a natural state. The delineation of all estuaries needs to be consistent and inclusive of all estuarine physical and biological processes, to curb future changes. The research results have been used in national assessments of estuarine health; and they have made a significant contribution to estuary-management plans. In addition, three scientific articles have been published from the thesis; and two more are currently under review.
- Full Text:
- Date Issued: 2016
- Authors: Veldkornet, Dimitri Allastair
- Date: 2016
- Subjects: Estuarine ecology -- Research -- South Africa Estuarine fishes -- Speciation -- South Africa , Aquatic plants -- South Africa
- Language: English
- Type: Thesis , Doctoral , PHD
- Identifier: http://hdl.handle.net/10948/45388 , vital:38604
- Description: This study explored the distribution of estuarine macrophyte genetic lineages, species and habitats in relation to environmental gradients at various spatial scales. A database was assembled to determine the area and species composition of different estuarine habitats. This can now be used to retrieve information as a baseline for further monitoring and conservation planning. Research has shown that macrophytes occur over a wide range of physiochemical conditions, suggesting that these species have great genetic and phenotypic variation to occupy broad niche ranges. In eight estuaries along the South African coast, sediment and groundwater characteristics were measured in quadrants spanning the salt marsh, ecotone and terrestrial habitats. The results suggested that, in the absence of competition and disturbance at the salt marsh-terrestrial boundary, salt marshes would be unaffected by sea-level rise; and they would migrate landward. However, disturbance at the landward margin of salt marshes has already resulted in changes in species composition and altered environmental conditions. This promotes the encroachment of terrestrial alien invasive plants, leading to a loss of connectivity. A holistic assessment of land-cover changes showed that only 28% of South African estuaries still remain in a natural state. The delineation of all estuaries needs to be consistent and inclusive of all estuarine physical and biological processes, to curb future changes. The research results have been used in national assessments of estuarine health; and they have made a significant contribution to estuary-management plans. In addition, three scientific articles have been published from the thesis; and two more are currently under review.
- Full Text:
- Date Issued: 2016
Evaluating farmers' perceptions and the impact of bush encroachment on herbaceous vegetation and soil nutrients in Sheshegu communal rangelands of the Eastern Cape, South Africa
- Authors: Tokozwayo, Sive
- Date: 2016
- Subjects: Range management -- South Africa -- Eastern Cape Brush -- Control -- South Africa -- Eastern Cape Communal rangelands -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/2733 , vital:28066
- Description: Communal rangelands occupy 13 percent of the agricultural land in South Africa, and these rangelands serve as a source of feed to livestock. These areas are threatened by bush encroachment due to poor rangeland management. This study was conducted in Alice (Sheshegu communal area) and the objective was to assess farmers' perceptions and the impact of bush encroachment on herbaceous vegetation and soil nutrients. Structured questionnaires were used to assess indigenous knowledge of communal farmers on the impact of bush encroachment on rangelands. Fourty (40) respondents from households who owned livestock were randomly selected and interviewed at Sheshegu village. About 89 percent of communal farmers perceived that change of their grasslands to encroached savannas was caused by unreliable rainfall, prolonged drought, and poor rangeland management. Rangeland assessment was performed at four sites (Scattered, Moderate, Mixed and Dense bushland. 100mx50m were demarcated per site, and four 100m transects were laid parallel to each other, 30m apart. The step point method was used to determine both species composition and basal cover. Biomass production was determined by harvesting forage within randomly-paced a 0.25m2 quadrats. Aristada congesta and Eragrostis obtuse were the most dominating grass species in dense, mixed and moderate bushland. Scattered bushland was dominated by Themeda triandra. Biomass production increases with increase in bush density and basal cover improved from winter to summer season. Increaser grass species increase with the increase in bush density, this indicated that the rangeland was poorly managed and palatable species were being replaced by less palatable ones. Species composition of woody plants was determined within a 200m2 belt transect in all sites. Maytenus polycantha, Aloe ferox, Erehia rigida and lucas capensis were the most dominant woody species in Mixed bushland while Acacia karroo was most dominated in Scattered, Moderate and Dense bushland. Woody density showed no significant differences (P> 0.05) between Dense, Mixed and Moderate bushland. Woody plant density in all these sites exceed 2500 plants/ha, which showed that the rangeland was encroached with woody plants. Soil nutrient content was determined for each site. Five samples of soil were collected per site to test the effect of bush encroachment on soil nutrient composition. The concentration of nitrogen and soil pH increased with increase in bush density, while that of potassium, phosphorous, magnesium, sodium and sulphur showed no significant differences (P>0.05) across all homogenous vegetation units. The study revealed that Sheshegu communal farmers are aware of both negative and positive effects of encroachment on their community, and also argue that the government is not willing to support communal farmers in the process of reducing the spread of bush encroachment. It was concluded that the concentration of nitrogen and soil pH increased with increasing bush density and that bush encroachment had negative effects on herbaceous species. It was recommended that communal farmers should be formulating rangeland rules and regulations to manage rangeland resources. Rangeland rules and regulations should be based on the management of livestock management during grazing and harvesting of rangeland resources. The harvesting of woody and good timing of application of fire can also reduce the spread of bush encroachment. Veld resting and rotational grazing can also improve fuel load which is required for burning of woody plants. Furthermore, Department of agriculture should also provide workshops or training to communal farmers use different approaches or cheap ways of reducing bush encroachment and conserving rangeland resources.
- Full Text:
- Date Issued: 2016
- Authors: Tokozwayo, Sive
- Date: 2016
- Subjects: Range management -- South Africa -- Eastern Cape Brush -- Control -- South Africa -- Eastern Cape Communal rangelands -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/2733 , vital:28066
- Description: Communal rangelands occupy 13 percent of the agricultural land in South Africa, and these rangelands serve as a source of feed to livestock. These areas are threatened by bush encroachment due to poor rangeland management. This study was conducted in Alice (Sheshegu communal area) and the objective was to assess farmers' perceptions and the impact of bush encroachment on herbaceous vegetation and soil nutrients. Structured questionnaires were used to assess indigenous knowledge of communal farmers on the impact of bush encroachment on rangelands. Fourty (40) respondents from households who owned livestock were randomly selected and interviewed at Sheshegu village. About 89 percent of communal farmers perceived that change of their grasslands to encroached savannas was caused by unreliable rainfall, prolonged drought, and poor rangeland management. Rangeland assessment was performed at four sites (Scattered, Moderate, Mixed and Dense bushland. 100mx50m were demarcated per site, and four 100m transects were laid parallel to each other, 30m apart. The step point method was used to determine both species composition and basal cover. Biomass production was determined by harvesting forage within randomly-paced a 0.25m2 quadrats. Aristada congesta and Eragrostis obtuse were the most dominating grass species in dense, mixed and moderate bushland. Scattered bushland was dominated by Themeda triandra. Biomass production increases with increase in bush density and basal cover improved from winter to summer season. Increaser grass species increase with the increase in bush density, this indicated that the rangeland was poorly managed and palatable species were being replaced by less palatable ones. Species composition of woody plants was determined within a 200m2 belt transect in all sites. Maytenus polycantha, Aloe ferox, Erehia rigida and lucas capensis were the most dominant woody species in Mixed bushland while Acacia karroo was most dominated in Scattered, Moderate and Dense bushland. Woody density showed no significant differences (P> 0.05) between Dense, Mixed and Moderate bushland. Woody plant density in all these sites exceed 2500 plants/ha, which showed that the rangeland was encroached with woody plants. Soil nutrient content was determined for each site. Five samples of soil were collected per site to test the effect of bush encroachment on soil nutrient composition. The concentration of nitrogen and soil pH increased with increase in bush density, while that of potassium, phosphorous, magnesium, sodium and sulphur showed no significant differences (P>0.05) across all homogenous vegetation units. The study revealed that Sheshegu communal farmers are aware of both negative and positive effects of encroachment on their community, and also argue that the government is not willing to support communal farmers in the process of reducing the spread of bush encroachment. It was concluded that the concentration of nitrogen and soil pH increased with increasing bush density and that bush encroachment had negative effects on herbaceous species. It was recommended that communal farmers should be formulating rangeland rules and regulations to manage rangeland resources. Rangeland rules and regulations should be based on the management of livestock management during grazing and harvesting of rangeland resources. The harvesting of woody and good timing of application of fire can also reduce the spread of bush encroachment. Veld resting and rotational grazing can also improve fuel load which is required for burning of woody plants. Furthermore, Department of agriculture should also provide workshops or training to communal farmers use different approaches or cheap ways of reducing bush encroachment and conserving rangeland resources.
- Full Text:
- Date Issued: 2016
Evaluating late payment-induced waste in South Africa through lean construction principles
- Authors: Akuffo-Ntow, Eric Ayesu
- Date: 2016
- Subjects: Construction industry -- South Africa -- Finance , Lean manufacturing -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/8867 , vital:26437
- Description: Central to the sustainable and competitive growth of the South African construction industry is a predictable cash flow through on time payment by clients to contractors. However, chronic late payments, a recurring problem in the industry, especially in the public sector, is bringing untold hardship to contractors by derailing their competitiveness and also eroding the trust among the supply chain partners to the extent that some firms end up closing business in the industry. The situation is viewed from the lean construction perspective as an obstacle that is preventing the accrual of the required value to project parties in the construction industry. This research addresses the causes of late payments to contractors and the role of the quantity surveyor (QS) in terms of influencing early payment from a lean construction perspective. A mixed method approach was used for compiling the primary data for the study. Sequentially, one hundred and two (102) quantitative and twelve (12) interview questionnaires were administered to selected contractors and construction professionals working predominantly on public sector projects. The findings revealed that the approval process for evaluation and certification by the client- appointed agent and intermediary institutions is taking longer than contractually allowed, with parties independently undertaking their evaluation prior to the certification date. This is found to be adverse to achieving consensus on the values of the works for authorisation. Other significant barriers are the lack of funds to authorise payment, random auditor general’s documentation changes, lack of administrators’ system integration and capacity to handle cyclical payment processing. Also, contractors have been found to be in default of timeously submitting complete claim documents. It is therefore recommended that the client agents should partner with the contractor in regular design and documentation reviews, arranging the payment process and should also meet jointly to prepare monthly evaluations. In addition, contractors should be mentored from the onset of the project regarding all the necessary documentation and supporting documents that will be required by the client to ensure that payment approvals are not delayed. The payment authori-sation agent’s capacity should be enhanced through training and improved powers as a singular point of control to perform efficiently and their systems and processes should be integrated to ensure that all parties are implementing the same protocols.
- Full Text:
- Date Issued: 2016
- Authors: Akuffo-Ntow, Eric Ayesu
- Date: 2016
- Subjects: Construction industry -- South Africa -- Finance , Lean manufacturing -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/8867 , vital:26437
- Description: Central to the sustainable and competitive growth of the South African construction industry is a predictable cash flow through on time payment by clients to contractors. However, chronic late payments, a recurring problem in the industry, especially in the public sector, is bringing untold hardship to contractors by derailing their competitiveness and also eroding the trust among the supply chain partners to the extent that some firms end up closing business in the industry. The situation is viewed from the lean construction perspective as an obstacle that is preventing the accrual of the required value to project parties in the construction industry. This research addresses the causes of late payments to contractors and the role of the quantity surveyor (QS) in terms of influencing early payment from a lean construction perspective. A mixed method approach was used for compiling the primary data for the study. Sequentially, one hundred and two (102) quantitative and twelve (12) interview questionnaires were administered to selected contractors and construction professionals working predominantly on public sector projects. The findings revealed that the approval process for evaluation and certification by the client- appointed agent and intermediary institutions is taking longer than contractually allowed, with parties independently undertaking their evaluation prior to the certification date. This is found to be adverse to achieving consensus on the values of the works for authorisation. Other significant barriers are the lack of funds to authorise payment, random auditor general’s documentation changes, lack of administrators’ system integration and capacity to handle cyclical payment processing. Also, contractors have been found to be in default of timeously submitting complete claim documents. It is therefore recommended that the client agents should partner with the contractor in regular design and documentation reviews, arranging the payment process and should also meet jointly to prepare monthly evaluations. In addition, contractors should be mentored from the onset of the project regarding all the necessary documentation and supporting documents that will be required by the client to ensure that payment approvals are not delayed. The payment authori-sation agent’s capacity should be enhanced through training and improved powers as a singular point of control to perform efficiently and their systems and processes should be integrated to ensure that all parties are implementing the same protocols.
- Full Text:
- Date Issued: 2016
Evaluating revenue collection and allocation challenges faced by Ndlambe Local Municipality (Eastern Cape Province)
- Pieters, Nonkqubela Ntomboxolo
- Authors: Pieters, Nonkqubela Ntomboxolo
- Date: 2016
- Subjects: Municipal corporations -- Taxation -- South Africa -- Eastern Cape Municipal finance -- South Africa -- Eastern Cape Local government -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: http://hdl.handle.net/10353/4442 , vital:28333
- Description: In this project, the researcher evaluates revenue collection and allocation challenges faced by South African Municipalities in the case of NDLAMBE Local Municipality and this research project consist of five Chapters. Chapter one introduces and outlines the setting of the study and also provides the problem statement, research questions, research objectives and significance of the study. The chapter further clarifies the key concepts and terms that were used in the study, delimitation and limitations of the study. Chapter two provides a critical discussion of the concept of revenue collection and allocation, focusing on the various perspective of revenue. A source of municipal revenue and revenue collection and allocation model is explained as well as theoretical framework that guides it. Chapter three gives an account of the research design and methodology used in the study and in this study the researcher used the qualitative research approach as a data collection technique and document surveys were used because it is cheap and it saves time. The chapter also highlights the revenue collection and allocation applicable to the study and conclude by discussing the data analysis techniques that were used in the empirical study. Chapter four dealt with the data analysis of data collected presentation and discussion of the results and the researcher analyzed data using the filtering technique and content analysis. Chapter five drew conclusions and made scientific recommendations based on the research findings.The municipality is largely dependent on grants from upper spheres of government and generate less than 20 percent of current expenditures from own resources. As a whole, the revenue collection and allocation challenge of the NDLAMBE Local Municipality, given the current scenario of flows, is a reason for concern. Due to historical and political factors, local governments in South Africa differ substantially in terms of potential revenue base, but it may be that in many cases potential revenue is not exploited and that the high level of dependency on grants, high level of bad debts and lack of political will to be more self-reliant is the result of poor revenue in NDLAMBE Local Municipality.
- Full Text:
- Date Issued: 2016
- Authors: Pieters, Nonkqubela Ntomboxolo
- Date: 2016
- Subjects: Municipal corporations -- Taxation -- South Africa -- Eastern Cape Municipal finance -- South Africa -- Eastern Cape Local government -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: http://hdl.handle.net/10353/4442 , vital:28333
- Description: In this project, the researcher evaluates revenue collection and allocation challenges faced by South African Municipalities in the case of NDLAMBE Local Municipality and this research project consist of five Chapters. Chapter one introduces and outlines the setting of the study and also provides the problem statement, research questions, research objectives and significance of the study. The chapter further clarifies the key concepts and terms that were used in the study, delimitation and limitations of the study. Chapter two provides a critical discussion of the concept of revenue collection and allocation, focusing on the various perspective of revenue. A source of municipal revenue and revenue collection and allocation model is explained as well as theoretical framework that guides it. Chapter three gives an account of the research design and methodology used in the study and in this study the researcher used the qualitative research approach as a data collection technique and document surveys were used because it is cheap and it saves time. The chapter also highlights the revenue collection and allocation applicable to the study and conclude by discussing the data analysis techniques that were used in the empirical study. Chapter four dealt with the data analysis of data collected presentation and discussion of the results and the researcher analyzed data using the filtering technique and content analysis. Chapter five drew conclusions and made scientific recommendations based on the research findings.The municipality is largely dependent on grants from upper spheres of government and generate less than 20 percent of current expenditures from own resources. As a whole, the revenue collection and allocation challenge of the NDLAMBE Local Municipality, given the current scenario of flows, is a reason for concern. Due to historical and political factors, local governments in South Africa differ substantially in terms of potential revenue base, but it may be that in many cases potential revenue is not exploited and that the high level of dependency on grants, high level of bad debts and lack of political will to be more self-reliant is the result of poor revenue in NDLAMBE Local Municipality.
- Full Text:
- Date Issued: 2016
Evaluating the multi-threading countermeasure
- Frieslaar, Ibrahim, Irwin, Barry V W
- Authors: Frieslaar, Ibrahim , Irwin, Barry V W
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428352 , vital:72505 , https://researchspace.csir.co.za/dspace/bitstream/handle/10204/9041/Frieslaar_2016.pdf?sequence=1andisAllowed=y
- Description: This research investigates the resistance of the multi-threaded coun-termeasure to side channel analysis (SCA) attacks. The multi-threaded countermeasure is attacked using the Correlation Power Analysis (CPA) and template attacks. Additionally, it is compared to the existing hiding countermeasure. Furthermore, additional signal processing techniques are used to increase the attack success ratio. It is demon-strated that the multi-threaded countermeasure is able to outperform the existing countermeasures by withstanding the CPA and template at-tacks. Furthermore, the multi-threaded countermeasure is unaffected by the elastic alignment and filtering techniques as opposed to the existing countermeasures. The research concludes that the multithreaded coun-termeasure is indeed a secure implementation to mitigate SCA attacks.
- Full Text:
- Date Issued: 2016
- Authors: Frieslaar, Ibrahim , Irwin, Barry V W
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428352 , vital:72505 , https://researchspace.csir.co.za/dspace/bitstream/handle/10204/9041/Frieslaar_2016.pdf?sequence=1andisAllowed=y
- Description: This research investigates the resistance of the multi-threaded coun-termeasure to side channel analysis (SCA) attacks. The multi-threaded countermeasure is attacked using the Correlation Power Analysis (CPA) and template attacks. Additionally, it is compared to the existing hiding countermeasure. Furthermore, additional signal processing techniques are used to increase the attack success ratio. It is demon-strated that the multi-threaded countermeasure is able to outperform the existing countermeasures by withstanding the CPA and template at-tacks. Furthermore, the multi-threaded countermeasure is unaffected by the elastic alignment and filtering techniques as opposed to the existing countermeasures. The research concludes that the multithreaded coun-termeasure is indeed a secure implementation to mitigate SCA attacks.
- Full Text:
- Date Issued: 2016
Evaluation of flocculating potentials and charecterization of bioflocculants produced by three bacterial isolates from Algoa Bay, South Africa
- Authors: Okaiyeto, Kunle
- Date: 2016
- Subjects: Flocculation Water -- Purification -- Flocculation Water quality management
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/2633 , vital:27947
- Description: Flocculation has been widely adopted as one of the most effective methods to remove colloidal particles in water or wastewater treatment. Synthetic flocculants are conventionally used because of their high flocculating efficiency and cost-effectiveness. However, they have been reported to have hazardous properties and implicated in some serious health problems including senile dementia and neuro-toxicity, as well as being recalcitrant in the environment. Consequently, efforts are being geared away from the use of synthetic flocculants in water and wastewater treatment. Hence, the need for safe and eco-friendly flocculants has become imperative. Compared with synthetic flocculants, bioflocculants have special advantages such as safety, biodegradability and harmlessness to the environment and humans; attributes which make them potential alternatives in water treatment, downstream as well as fermentation processes. In the current study, the potentials of bacterial isolates recovered from Algoa Bay in the Eastern Cape Province of South Africa for bioflocculant production were investigated. The bacterial isolates were identified by polymerase chain reaction (PCR) as belonging to the Bacillus genus. The analysis of 16S ribosomal deoxyribonucleic acid (rDNA) nucleotide sequence of isolate M72 showed 99 percent similarity to Bacillus toyonensis strain BCT-7112 and was deposited in the GenBank as Bacillus toyonensis strain AEMREG6 with accession number KP406731. Likewise, the 16S rDNA nucleotide sequences of isolates M69 and M67 showed 98 percent sequence similarity to Bacillus licheniformis strain W7 and Bacillus algicola strain QD43 respectively; and M67 isolate was subsequently deposited in the GenBank as Bacillus sp. AEMREG7 with accession number KF933697.1. The results of the nutritional requirements and fermentation conditions revealed that optimum inoculum size for REG-6 production was 4 percent (v/v), while 5 percent (v/v) and 3 percent (v/v) were most favourable for MBF-W7 and MBF-UFH production respectively. Glucose was the best carbon source for the production of bioflocculants (REG-6 and MBF-UFH) by Bacillus toyonensis AEMREG6 and Bacillus sp. AEMREG7 respectively, while maltose supported optimum bioflocculant (MBF-W7) production by Bacillus specie. Inorganic nitrogen (NH4NO3) was the favoured nitrogen source for both REG-6 and MBF-W7 production, while mixed nitrogen sources [yeast extract + urea + (NH4)2SO4] supported the maximum production of MBF-UFH. The initial medium pH for REG-6 was 5, while MBF-W7 and MBF-UFH were both maximally produced at the initial pH of 6. After a 96 h cultivation period under optimal culture conditions, 3.2 g of purified REG-6 with a maximum flocculating activity of 77 percent was recovered from 1 L fermented broth of Bacillus toyonensis AEMREG6. Yields of 3.8 g and 1.6 g pure bioflocculants with the respective highest flocculating activities of 94.9 percent and 83.2 percent were also obtained from 1 L, 72 h-fermented broths of Bacillus licheniformis and Bacillus sp. AEMREG7 respectively. Furthermore, all the three bioflocculants (REG-6, MBF-W7 and MBF-UFH), displayed thermal stability within the temperature range of 50 to 100 oC, with strong flocculating activities of over 80 percent against kaolin suspension over a wide range of pH range (3–11) and relatively low dosage requirements of 0.1-03 mg/ml in the presence of divalent cations in the treatment of kaolin clay suspension and Thyme River waters. Chemical composition analyses of the bioflocculants showed them to be glycoproteins with a predominantly polysaccharide backbones as shown by the following carbohydrate/protein (w/w) ratios: 77.8 percent:11.5 percent (REG-6); 73.7 percent:6.2 percent (MBF-W7) and 76 percent:14 percent (MBF-UFH).
- Full Text:
- Date Issued: 2016
- Authors: Okaiyeto, Kunle
- Date: 2016
- Subjects: Flocculation Water -- Purification -- Flocculation Water quality management
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/2633 , vital:27947
- Description: Flocculation has been widely adopted as one of the most effective methods to remove colloidal particles in water or wastewater treatment. Synthetic flocculants are conventionally used because of their high flocculating efficiency and cost-effectiveness. However, they have been reported to have hazardous properties and implicated in some serious health problems including senile dementia and neuro-toxicity, as well as being recalcitrant in the environment. Consequently, efforts are being geared away from the use of synthetic flocculants in water and wastewater treatment. Hence, the need for safe and eco-friendly flocculants has become imperative. Compared with synthetic flocculants, bioflocculants have special advantages such as safety, biodegradability and harmlessness to the environment and humans; attributes which make them potential alternatives in water treatment, downstream as well as fermentation processes. In the current study, the potentials of bacterial isolates recovered from Algoa Bay in the Eastern Cape Province of South Africa for bioflocculant production were investigated. The bacterial isolates were identified by polymerase chain reaction (PCR) as belonging to the Bacillus genus. The analysis of 16S ribosomal deoxyribonucleic acid (rDNA) nucleotide sequence of isolate M72 showed 99 percent similarity to Bacillus toyonensis strain BCT-7112 and was deposited in the GenBank as Bacillus toyonensis strain AEMREG6 with accession number KP406731. Likewise, the 16S rDNA nucleotide sequences of isolates M69 and M67 showed 98 percent sequence similarity to Bacillus licheniformis strain W7 and Bacillus algicola strain QD43 respectively; and M67 isolate was subsequently deposited in the GenBank as Bacillus sp. AEMREG7 with accession number KF933697.1. The results of the nutritional requirements and fermentation conditions revealed that optimum inoculum size for REG-6 production was 4 percent (v/v), while 5 percent (v/v) and 3 percent (v/v) were most favourable for MBF-W7 and MBF-UFH production respectively. Glucose was the best carbon source for the production of bioflocculants (REG-6 and MBF-UFH) by Bacillus toyonensis AEMREG6 and Bacillus sp. AEMREG7 respectively, while maltose supported optimum bioflocculant (MBF-W7) production by Bacillus specie. Inorganic nitrogen (NH4NO3) was the favoured nitrogen source for both REG-6 and MBF-W7 production, while mixed nitrogen sources [yeast extract + urea + (NH4)2SO4] supported the maximum production of MBF-UFH. The initial medium pH for REG-6 was 5, while MBF-W7 and MBF-UFH were both maximally produced at the initial pH of 6. After a 96 h cultivation period under optimal culture conditions, 3.2 g of purified REG-6 with a maximum flocculating activity of 77 percent was recovered from 1 L fermented broth of Bacillus toyonensis AEMREG6. Yields of 3.8 g and 1.6 g pure bioflocculants with the respective highest flocculating activities of 94.9 percent and 83.2 percent were also obtained from 1 L, 72 h-fermented broths of Bacillus licheniformis and Bacillus sp. AEMREG7 respectively. Furthermore, all the three bioflocculants (REG-6, MBF-W7 and MBF-UFH), displayed thermal stability within the temperature range of 50 to 100 oC, with strong flocculating activities of over 80 percent against kaolin suspension over a wide range of pH range (3–11) and relatively low dosage requirements of 0.1-03 mg/ml in the presence of divalent cations in the treatment of kaolin clay suspension and Thyme River waters. Chemical composition analyses of the bioflocculants showed them to be glycoproteins with a predominantly polysaccharide backbones as shown by the following carbohydrate/protein (w/w) ratios: 77.8 percent:11.5 percent (REG-6); 73.7 percent:6.2 percent (MBF-W7) and 76 percent:14 percent (MBF-UFH).
- Full Text:
- Date Issued: 2016
Evaluation of Fungcoal as a bioprocess technology for self-cladding of waste coal dumps
- Authors: Sekhohola, Lerato M
- Date: 2016
- Subjects: Coal mine waste , Fungi -- Biotechnology , Coal -- Biodegradation , Bermuda grass -- Biotechnology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5959 , http://hdl.handle.net/10962/d1019992
- Description: Low-grade coal, a poor source of energy, has long been regarded as waste material by the coal mining industry. Biological degradation of this coal material by ligninolytic fungal strains presents a viable strategy towards eliminating this unusable fossil fuel. To this end, a novel and patented bioprocess termed Fungcoal was developed. Fungcoal is a biological process utilised in the in situ treatment of waste coal and is based on the mutualistic relationship between the fungus Neosartorya fischeri and the graminaceous species Cynodon dactylon. The process facilitates the rapid conversion of waste coal into soil-like material that stimulates establishment of vegetation for eventual coal dump rehabilitation. While a number of in vitro studies have identified various fungal strains as efficient coal degraders, the mechanisms involved in the Fungcoal-stimulated degradation process have not been fully elucidated. Furthermore, implementation of Fungcoal at both pilot and commercial scale has not been achieved. Thus the objective of this work was to investigate Fungcoal as a bioprocess via examining the role of coal degrading fungi (CDF) and grasses as biocatalysts in coal biodegradation and for the self-cladding of waste coal dumps. Initially, waste coal degradation by N. fischeri, strain ECCN 84, was investigated, specifically focusing on the mechanisms underpinning the process. In vitro studies showed the addition of waste coal induced active fungal colonisation resulting in increased fungal biomass. Increased extracellular laccase (LAC) activity, occuring concomitantly with an increase in hyphal peroxisome proliferation, was also observed in the coal supplied fungal cultures. Analysis of the colonised waste coal revealed a time dependent reduction in the percentage weight of elemental carbon coupled with an increase in elemental oxygen. The results supported metabolism and degradation of waste coal by N. fischeri strain ECCN 84 and involvement of fungal extracellular laccase. The contribution of C. dactylon, a C4 grass species to in situ biodegradation of waste coal in the presence of coal degrading and mycorrhizal fungi (MF) was also investigated. Enhanced degradation of the waste coal into a humic soil-like material was observed within the rhizosphere. Analysis of the resultant substrate revealed an increased concentration of highly oxidised humic-like substances (HS). Fungi remained viable in the rhizosphere up to 47 weeks post-inoculation and cultivation of C. dactylon, indicating the resultant humic substance-rich rhizosphere provided an environment conducive for microbial proliferation and activity. Furthermore, humic substance enrichment of waste coal substrates supported germination and seedling emergence of several agronomic species including Zea mays (corn), Phaseolus vulgaris (bean), Pisum sativum (pea), and Spinacia oleracea (spinach). Use of various cladding materials to support coal biodegradation, by fungus-grass mutualism and rehabilitation of waste dumps was evaluated at commercial scale. While substantial physico-chemical changes were not evident in the absence of cladding or where waste coal was used as cladding material, successful establishment of grass cover and diversity was achieved within three hydrological cycles on dumps cladded with weathered coal. Work presented in this thesis successfully demonstrates the degradation of waste coal by N. fischeri. The biodegradation process included enhanced extracellular LAC activity coupled with increased 3 waste coal oxidation. Increased HS concentration of waste coal substrate supported germination and early seedling establishment of several agronomic species. At commercial scale a co-substrate in the form of carbon-rich weathered coal was essential to support fungus-grass mutualism and Fungcoal-induced rehabilitation. These findings support the developed Fungcoal concept and the underpinning rationale that the phyto-biodegradation of waste coal indeed depends on the mutualistic interactions between grass root exudates and the ligninolytic and mycorrhizal fungi. Taken together, these findings provide practical evidence of the contribution of fungi and grasses as mutualists in the biodegradation of waste coal and sustainable rehabilitation of waste coal dumps
- Full Text:
- Date Issued: 2016
- Authors: Sekhohola, Lerato M
- Date: 2016
- Subjects: Coal mine waste , Fungi -- Biotechnology , Coal -- Biodegradation , Bermuda grass -- Biotechnology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5959 , http://hdl.handle.net/10962/d1019992
- Description: Low-grade coal, a poor source of energy, has long been regarded as waste material by the coal mining industry. Biological degradation of this coal material by ligninolytic fungal strains presents a viable strategy towards eliminating this unusable fossil fuel. To this end, a novel and patented bioprocess termed Fungcoal was developed. Fungcoal is a biological process utilised in the in situ treatment of waste coal and is based on the mutualistic relationship between the fungus Neosartorya fischeri and the graminaceous species Cynodon dactylon. The process facilitates the rapid conversion of waste coal into soil-like material that stimulates establishment of vegetation for eventual coal dump rehabilitation. While a number of in vitro studies have identified various fungal strains as efficient coal degraders, the mechanisms involved in the Fungcoal-stimulated degradation process have not been fully elucidated. Furthermore, implementation of Fungcoal at both pilot and commercial scale has not been achieved. Thus the objective of this work was to investigate Fungcoal as a bioprocess via examining the role of coal degrading fungi (CDF) and grasses as biocatalysts in coal biodegradation and for the self-cladding of waste coal dumps. Initially, waste coal degradation by N. fischeri, strain ECCN 84, was investigated, specifically focusing on the mechanisms underpinning the process. In vitro studies showed the addition of waste coal induced active fungal colonisation resulting in increased fungal biomass. Increased extracellular laccase (LAC) activity, occuring concomitantly with an increase in hyphal peroxisome proliferation, was also observed in the coal supplied fungal cultures. Analysis of the colonised waste coal revealed a time dependent reduction in the percentage weight of elemental carbon coupled with an increase in elemental oxygen. The results supported metabolism and degradation of waste coal by N. fischeri strain ECCN 84 and involvement of fungal extracellular laccase. The contribution of C. dactylon, a C4 grass species to in situ biodegradation of waste coal in the presence of coal degrading and mycorrhizal fungi (MF) was also investigated. Enhanced degradation of the waste coal into a humic soil-like material was observed within the rhizosphere. Analysis of the resultant substrate revealed an increased concentration of highly oxidised humic-like substances (HS). Fungi remained viable in the rhizosphere up to 47 weeks post-inoculation and cultivation of C. dactylon, indicating the resultant humic substance-rich rhizosphere provided an environment conducive for microbial proliferation and activity. Furthermore, humic substance enrichment of waste coal substrates supported germination and seedling emergence of several agronomic species including Zea mays (corn), Phaseolus vulgaris (bean), Pisum sativum (pea), and Spinacia oleracea (spinach). Use of various cladding materials to support coal biodegradation, by fungus-grass mutualism and rehabilitation of waste dumps was evaluated at commercial scale. While substantial physico-chemical changes were not evident in the absence of cladding or where waste coal was used as cladding material, successful establishment of grass cover and diversity was achieved within three hydrological cycles on dumps cladded with weathered coal. Work presented in this thesis successfully demonstrates the degradation of waste coal by N. fischeri. The biodegradation process included enhanced extracellular LAC activity coupled with increased 3 waste coal oxidation. Increased HS concentration of waste coal substrate supported germination and early seedling establishment of several agronomic species. At commercial scale a co-substrate in the form of carbon-rich weathered coal was essential to support fungus-grass mutualism and Fungcoal-induced rehabilitation. These findings support the developed Fungcoal concept and the underpinning rationale that the phyto-biodegradation of waste coal indeed depends on the mutualistic interactions between grass root exudates and the ligninolytic and mycorrhizal fungi. Taken together, these findings provide practical evidence of the contribution of fungi and grasses as mutualists in the biodegradation of waste coal and sustainable rehabilitation of waste coal dumps
- Full Text:
- Date Issued: 2016
Evaluation of p-menthane-3, 8-diol citronellal acetal as a suitable bio-plasticizer for polyvinyl chloride
- Authors: Ncanywa, Luphumlo
- Date: 2016
- Subjects: Polyvinyl chloride Chlorine compounds
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/45898 , vital:39317
- Description: The main aim of this project is to test novel naturally-derived plasticizers (bio-plasticizers) synthesized at Innoventon and to determine if they are a suitable replacement for conventional plasticizers used to plasticize polyvinyl chloride. Polyvinyl chloride (PVC) is one of the most common plastics used in the world because of its durability and low cost. PVC when blended with plasticizers is a versatile thermoplastic and is used in many applications. A plasticizer is a substance that is added to a material, usually a polymer, to increase flexibility, softness and workability. Many elastomers and polymers are tough and dry; therefore they need plasticizers to make them useful. A plasticizer must be thoroughly incorporated in the elastomer or polymer in order for it to be effective. There are many types of plasticizers used in the world. Phthalate plasticizers are the most commonly used plasticizers of the past century. They comprise 92% of the global production of plasticizers. DEHP (di-ethyl hexyl phthalate) is the most widely used phthalate plasticizer. Phthalate plasticizers have been proved to be harmful to the environment and human beings. They can cause many harmful diseases to humans e.g. kidney failure, heart disease, liver failure, fertility and growth disorders. They lower testosterone in baby boys that are exposed through breast milk. In light of the above, the use of certain phthalates has been banned in cosmetics and consumer products. Since there is sufficient evidence to raise fears over the use of phthalate plasticizers, there is a great opportunity to find a way to replace phthalate plasticizers in PVC with bio-plasticizers. The current study represents the first step in developing alternative plasticizers for PVC and other polymers. These alternative plasticizers are characterized by low toxicity, low migration and are less harmful to the environment and human beings. p-menthane-3, 8-diol citronellal acetal is one such proposed bio-plasticizer which has a similar structure to the phthalates and has been previously reported by Innoventon to have potential plasticizing characteristics. During this study PVC was plasticized with PMD-citronellal acetal and tested for plasticizing properties. The plasticizing effect of PMD-citronellal acetal in PVC films was compared to that of conventional plasticizer dibutyl phthalate (DBP). The two plasticizers‟ performance was evaluated by preparing PVC films with varying amounts of each plasticizer and PMD-citronellal acetal subjecting the films to a series of tests. Tensile strength and elongation tests were performed on the plasticized and unplasticized films but these tests did not produce consistent results due to premature failures on the films. However, tensile strength was reduced in some films for both plasticizers compared to unplasticized film. Elongation and flexibility were increased in some samples as the percentage of plasticizer in each film was increased. Glass transition temperatures were determined for the plasticized and unplasticized PVC films. Glass transition temperature of both plasticizers was reduced as the percentage of plasticizer in each film was increased. Multiple regression analysis was done on the data to compare the similarity of the two plasticizers. The statistical tests showed that DBP and PMD-citronellal acetal have the same plasticization property with regard to glass transition temperature of PVC. The thermal stability of the PVC films with the two plasticizers was evaluated. Similar thermal stability was observed on the PVC, PVC with DBP and PVC with PMD-citronellal acetal. The leaching of the PMD-citronellal acetal and DBP were compared. The plasticizer loss increased as the percentage of each plasticizer in the PVC increased. The relationship between the percentage of the plasticizers and leaching rate was further analysed using multiple linear regressions. The two plasticizers were found to have the same leaching rate. FTIR analysis was performed on the plasticized and unplasticized PVC films to identify functional groups present and to determine whether the plasticizers formed any bonds with PVC functional groups. The characteristics bands of PVC were observed in FTIR. The FTIR spectra indicated that the plasticizers were incorporated into the PVC matrix without bonding. The results of the tests showed that PMD-citronellal acetal can be a suitable bio-plasticizer for PVC since it exhibited similar plasticization properties to DBP with regard to glass transition temperatures, leaching rates and thermal stability. Regarding tensile strength and elongation, further testing has to be done as the preliminary results were inconclusive. PMDcitronellal acetal was shown to be a possible alternative for DBP.
- Full Text:
- Date Issued: 2016
- Authors: Ncanywa, Luphumlo
- Date: 2016
- Subjects: Polyvinyl chloride Chlorine compounds
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/45898 , vital:39317
- Description: The main aim of this project is to test novel naturally-derived plasticizers (bio-plasticizers) synthesized at Innoventon and to determine if they are a suitable replacement for conventional plasticizers used to plasticize polyvinyl chloride. Polyvinyl chloride (PVC) is one of the most common plastics used in the world because of its durability and low cost. PVC when blended with plasticizers is a versatile thermoplastic and is used in many applications. A plasticizer is a substance that is added to a material, usually a polymer, to increase flexibility, softness and workability. Many elastomers and polymers are tough and dry; therefore they need plasticizers to make them useful. A plasticizer must be thoroughly incorporated in the elastomer or polymer in order for it to be effective. There are many types of plasticizers used in the world. Phthalate plasticizers are the most commonly used plasticizers of the past century. They comprise 92% of the global production of plasticizers. DEHP (di-ethyl hexyl phthalate) is the most widely used phthalate plasticizer. Phthalate plasticizers have been proved to be harmful to the environment and human beings. They can cause many harmful diseases to humans e.g. kidney failure, heart disease, liver failure, fertility and growth disorders. They lower testosterone in baby boys that are exposed through breast milk. In light of the above, the use of certain phthalates has been banned in cosmetics and consumer products. Since there is sufficient evidence to raise fears over the use of phthalate plasticizers, there is a great opportunity to find a way to replace phthalate plasticizers in PVC with bio-plasticizers. The current study represents the first step in developing alternative plasticizers for PVC and other polymers. These alternative plasticizers are characterized by low toxicity, low migration and are less harmful to the environment and human beings. p-menthane-3, 8-diol citronellal acetal is one such proposed bio-plasticizer which has a similar structure to the phthalates and has been previously reported by Innoventon to have potential plasticizing characteristics. During this study PVC was plasticized with PMD-citronellal acetal and tested for plasticizing properties. The plasticizing effect of PMD-citronellal acetal in PVC films was compared to that of conventional plasticizer dibutyl phthalate (DBP). The two plasticizers‟ performance was evaluated by preparing PVC films with varying amounts of each plasticizer and PMD-citronellal acetal subjecting the films to a series of tests. Tensile strength and elongation tests were performed on the plasticized and unplasticized films but these tests did not produce consistent results due to premature failures on the films. However, tensile strength was reduced in some films for both plasticizers compared to unplasticized film. Elongation and flexibility were increased in some samples as the percentage of plasticizer in each film was increased. Glass transition temperatures were determined for the plasticized and unplasticized PVC films. Glass transition temperature of both plasticizers was reduced as the percentage of plasticizer in each film was increased. Multiple regression analysis was done on the data to compare the similarity of the two plasticizers. The statistical tests showed that DBP and PMD-citronellal acetal have the same plasticization property with regard to glass transition temperature of PVC. The thermal stability of the PVC films with the two plasticizers was evaluated. Similar thermal stability was observed on the PVC, PVC with DBP and PVC with PMD-citronellal acetal. The leaching of the PMD-citronellal acetal and DBP were compared. The plasticizer loss increased as the percentage of each plasticizer in the PVC increased. The relationship between the percentage of the plasticizers and leaching rate was further analysed using multiple linear regressions. The two plasticizers were found to have the same leaching rate. FTIR analysis was performed on the plasticized and unplasticized PVC films to identify functional groups present and to determine whether the plasticizers formed any bonds with PVC functional groups. The characteristics bands of PVC were observed in FTIR. The FTIR spectra indicated that the plasticizers were incorporated into the PVC matrix without bonding. The results of the tests showed that PMD-citronellal acetal can be a suitable bio-plasticizer for PVC since it exhibited similar plasticization properties to DBP with regard to glass transition temperatures, leaching rates and thermal stability. Regarding tensile strength and elongation, further testing has to be done as the preliminary results were inconclusive. PMDcitronellal acetal was shown to be a possible alternative for DBP.
- Full Text:
- Date Issued: 2016
Evaluation of physiochemical qualities and heavy metal levels of the final effluents of some wastewater treatment facilities in the Eastern Cape Province of South Africa
- Authors: Kulati, Thanduxolo Cullinan
- Date: 2016
- Subjects: Water -- Purification Sewage -- Purification
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/1547 , vital:27417
- Description: Water is the most abundant substance in nature and vital for life activities. The major water sources for use are surface water bodies such as rivers and lakes, and underground aquifers and pore spaces down the water table (Ring, 2003). Water derived from these sources is not necessarily pure since it contains dissolved inorganic and organic substances, living organisms (viruses, bacteria, etc). For these reasons, water intended for domestic uses should be free from toxic substances and microorganisms that are of health significance (WHO, 2005). The availability and quality of water always have played an important role in determining the quality of life. Water quality is closely linked to water use and to the state of economic development (Chennakrishnan et al., 2008). Ground and surface waters can be contaminated by several sources. In urban areas, the careless disposal of industrial effluents and other wastes may contribute greatly to the poor quality of water (Mathuthu et al., 1997). In most developing countries, most areas are located on the watersheds which are the end points of effluents discharged from various industries (Oberholster and Ashton, 2008). South Africa, as a developing country, is experiencing rapid demographic changes due to urbanization, industrialization and population growth. The country has also been identified as being water-scarce, which can lead to a challenge of meeting the increasing water demand due to industrialization and urbanization. Such population growth increase may result in an increase in wastewater output, especially around urban areas.
- Full Text:
- Date Issued: 2016
- Authors: Kulati, Thanduxolo Cullinan
- Date: 2016
- Subjects: Water -- Purification Sewage -- Purification
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/1547 , vital:27417
- Description: Water is the most abundant substance in nature and vital for life activities. The major water sources for use are surface water bodies such as rivers and lakes, and underground aquifers and pore spaces down the water table (Ring, 2003). Water derived from these sources is not necessarily pure since it contains dissolved inorganic and organic substances, living organisms (viruses, bacteria, etc). For these reasons, water intended for domestic uses should be free from toxic substances and microorganisms that are of health significance (WHO, 2005). The availability and quality of water always have played an important role in determining the quality of life. Water quality is closely linked to water use and to the state of economic development (Chennakrishnan et al., 2008). Ground and surface waters can be contaminated by several sources. In urban areas, the careless disposal of industrial effluents and other wastes may contribute greatly to the poor quality of water (Mathuthu et al., 1997). In most developing countries, most areas are located on the watersheds which are the end points of effluents discharged from various industries (Oberholster and Ashton, 2008). South Africa, as a developing country, is experiencing rapid demographic changes due to urbanization, industrialization and population growth. The country has also been identified as being water-scarce, which can lead to a challenge of meeting the increasing water demand due to industrialization and urbanization. Such population growth increase may result in an increase in wastewater output, especially around urban areas.
- Full Text:
- Date Issued: 2016
Evaluation of the implementation of local economic development policy for poverty alleviation at selected municipalities in the province of eastern cape (2012-2014)
- Authors: Sidumo, Andile Morrison
- Date: 2016
- Subjects: Economic development -- South Africa -- Eastern Cape Sustainable development -- South Africa -- Eastern Cape Poverty -- Government policy -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/7708 , vital:30708
- Description: This thesis evaluated the implementation of local economic development policy for poverty alleviation at selected municipalities in the Province of the Eastern Cape. Poverty is a global challenge of sustainable development that faces communities at international, national, provincial and local sphere of government however, the focus was at selected municipalities in the Province of Eastern Cape. It is the responsibility of municipal authorities to satisfy the basic needs and promote the general welfare of communities at specific geographic areas in the Province which is vastly rural depending on agriculture and partly on the industrial development. Local economic development is a tool or method to alleviate poverty.
- Full Text:
- Date Issued: 2016
- Authors: Sidumo, Andile Morrison
- Date: 2016
- Subjects: Economic development -- South Africa -- Eastern Cape Sustainable development -- South Africa -- Eastern Cape Poverty -- Government policy -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/7708 , vital:30708
- Description: This thesis evaluated the implementation of local economic development policy for poverty alleviation at selected municipalities in the Province of the Eastern Cape. Poverty is a global challenge of sustainable development that faces communities at international, national, provincial and local sphere of government however, the focus was at selected municipalities in the Province of Eastern Cape. It is the responsibility of municipal authorities to satisfy the basic needs and promote the general welfare of communities at specific geographic areas in the Province which is vastly rural depending on agriculture and partly on the industrial development. Local economic development is a tool or method to alleviate poverty.
- Full Text:
- Date Issued: 2016
Evaluation of the incidence of enteric viruses, Vibrio species and Escherichia coli pathotypes in effluents of two wastewater treatment plants located in Keiskammahoek and Stutterheim in the Eastern Cape Province of South Africa
- Authors: Adefisoye, Martins Ajibade
- Date: 2016
- Subjects: Escherichia coli -- South Africa -- Eastern Cape Water -- Purification -- South Africa -- Eastern Cape Effluent quality -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/3165 , vital:28328
- Description: South Africa is currently experiencing water shortage crisis, a challenge that has been attributed not only to the scarcity of freshwater, but also to fast degrading water quality. Factors such as rapid urbanisation, population and economic growth, climate change as well as poor operational and maintenance of many of the exisiting water/wastewater treatment facilities have been acknowledged as important contributors to degrading water quality in the country. Untreated or inadequately treated discharged wastewater effluents constitute point source pollution to many freshwater environments in South Africa. Hence, it becomes imperative to evaluate wastewater discharges in other to protect the scarce freshwater resource, the environment and public health. Over a twelve-month sampling period (September 2012 to August 2013), we assessed the bacteriological, virological and physicochemical qualities of the discharged final effluents of two wastewater treatment facilities in the Eastern Cape Province of South Africa. For the physicochemical assessment, a total of 144 final effluent samples were collected from both the final effluent tanks (FE) and the discharge points (DP) of the treatment facilities. Physicochemical parameters including pH, temperature, turbidity, total dissolved solids (TDS), dissolved oxygen (DO), electrical conductivity (EC) and free chlorine concentration were determined on site while biological oxygen demand (BOD), nitrate (NO3-), nitrite (NO2-), phosphate (PO4-) and chemical oxygen demand (COD) were determined in the laboratory. The bacteriological analysis of the samples was done using standard membrane filtration (MF) technique. Bacterial group assessed included: faecal indicator bacteria (faecal coliforms and E. coli) and Vibrio species, while the antibiotic susceptibility profiles of selected E. coli and Vibrio species isolates against some selected antibiotics commonly used in human therapy and veterinary medicine were determind using the standard agar-disc diffusion method. The occurrence and concentrations of human enteric viruses including: human adenovirus (HAdV), hepatitis A virus (HAV) and rotavirus (RoV) in the samples were determined by TaqMan-based real-time polymerase chain reaction (qPCR) following concentration by adsorption-elution method. The physicochemical characteristics of the samples ranged as follows: pH (6.5 – 7.6), TDS (95 – 171 mg/L), EC (134 – 267 μS/cm), temperature (12 – 27 °C), turbidity (1.5 – 65.7 mg/L), free chlorine (0.08 – 0.72 mg/L), DO (2.06 – 9.81 mg/L), BOD (0.13 – 9.81 mg/L), NO3- (0 – 21.5 mg/L), NO2- (0 – 0.72 mg/L), PO4- (0 – 18.3 mg/L) and COD (27 – 680 mg/L). Some of the characteristic such as pH, TDS, EC, temperature, nitrite and DO (on most instances) complied with recommended guidelines. Other characteristics, however, including turbidity, BOD, nitrate, phosphate and COD fell short of the recommended guidelines. All the 48 samples analysed for bacteriological qualities tested positive for the presence of the bacterial groups with significant (P≤0.05) seasonal variation in their densities. Faecal coliforms were detected in counts ranging from 1 CFU/100ml to 2.7 × 104 CFU/100ml. Presumptive E. coli counts ranged generally between 1 CFU/100ml – 1.4 × 105 CFU/100ml while counts of presumptive Vibrio species ranged between 4 CFU/100ml – 1.4 × 104 CFU/100ml. Molecular identification of the presumptive isolates by polymerase chain reactions PCR gave positive reaction rates of 76.2 percent (381/500) and 69.8 percent (279/400) for E.coli and Vibrio species respectively. The antibiotic susceptibility profiling of 205 PCR-confirmed Vibiro isolates against 18 commomly used antibiotics showed resistance frequencies ranging from 0.5 percent (imipenem) to 96.1 percent (penicillin G) at recommended breakpoint concentrations. Eighty-one percent (166/205) of the Vibrio isolates showed multidrug resistance (resistance to 3 or more antibiotics) with the most common multiple antibiotic resistance phenotype (MARP) being AP-T-TM-SMX-PG-NI-PB, occurring in 8 isolates.
- Full Text:
- Date Issued: 2016
- Authors: Adefisoye, Martins Ajibade
- Date: 2016
- Subjects: Escherichia coli -- South Africa -- Eastern Cape Water -- Purification -- South Africa -- Eastern Cape Effluent quality -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/3165 , vital:28328
- Description: South Africa is currently experiencing water shortage crisis, a challenge that has been attributed not only to the scarcity of freshwater, but also to fast degrading water quality. Factors such as rapid urbanisation, population and economic growth, climate change as well as poor operational and maintenance of many of the exisiting water/wastewater treatment facilities have been acknowledged as important contributors to degrading water quality in the country. Untreated or inadequately treated discharged wastewater effluents constitute point source pollution to many freshwater environments in South Africa. Hence, it becomes imperative to evaluate wastewater discharges in other to protect the scarce freshwater resource, the environment and public health. Over a twelve-month sampling period (September 2012 to August 2013), we assessed the bacteriological, virological and physicochemical qualities of the discharged final effluents of two wastewater treatment facilities in the Eastern Cape Province of South Africa. For the physicochemical assessment, a total of 144 final effluent samples were collected from both the final effluent tanks (FE) and the discharge points (DP) of the treatment facilities. Physicochemical parameters including pH, temperature, turbidity, total dissolved solids (TDS), dissolved oxygen (DO), electrical conductivity (EC) and free chlorine concentration were determined on site while biological oxygen demand (BOD), nitrate (NO3-), nitrite (NO2-), phosphate (PO4-) and chemical oxygen demand (COD) were determined in the laboratory. The bacteriological analysis of the samples was done using standard membrane filtration (MF) technique. Bacterial group assessed included: faecal indicator bacteria (faecal coliforms and E. coli) and Vibrio species, while the antibiotic susceptibility profiles of selected E. coli and Vibrio species isolates against some selected antibiotics commonly used in human therapy and veterinary medicine were determind using the standard agar-disc diffusion method. The occurrence and concentrations of human enteric viruses including: human adenovirus (HAdV), hepatitis A virus (HAV) and rotavirus (RoV) in the samples were determined by TaqMan-based real-time polymerase chain reaction (qPCR) following concentration by adsorption-elution method. The physicochemical characteristics of the samples ranged as follows: pH (6.5 – 7.6), TDS (95 – 171 mg/L), EC (134 – 267 μS/cm), temperature (12 – 27 °C), turbidity (1.5 – 65.7 mg/L), free chlorine (0.08 – 0.72 mg/L), DO (2.06 – 9.81 mg/L), BOD (0.13 – 9.81 mg/L), NO3- (0 – 21.5 mg/L), NO2- (0 – 0.72 mg/L), PO4- (0 – 18.3 mg/L) and COD (27 – 680 mg/L). Some of the characteristic such as pH, TDS, EC, temperature, nitrite and DO (on most instances) complied with recommended guidelines. Other characteristics, however, including turbidity, BOD, nitrate, phosphate and COD fell short of the recommended guidelines. All the 48 samples analysed for bacteriological qualities tested positive for the presence of the bacterial groups with significant (P≤0.05) seasonal variation in their densities. Faecal coliforms were detected in counts ranging from 1 CFU/100ml to 2.7 × 104 CFU/100ml. Presumptive E. coli counts ranged generally between 1 CFU/100ml – 1.4 × 105 CFU/100ml while counts of presumptive Vibrio species ranged between 4 CFU/100ml – 1.4 × 104 CFU/100ml. Molecular identification of the presumptive isolates by polymerase chain reactions PCR gave positive reaction rates of 76.2 percent (381/500) and 69.8 percent (279/400) for E.coli and Vibrio species respectively. The antibiotic susceptibility profiling of 205 PCR-confirmed Vibiro isolates against 18 commomly used antibiotics showed resistance frequencies ranging from 0.5 percent (imipenem) to 96.1 percent (penicillin G) at recommended breakpoint concentrations. Eighty-one percent (166/205) of the Vibrio isolates showed multidrug resistance (resistance to 3 or more antibiotics) with the most common multiple antibiotic resistance phenotype (MARP) being AP-T-TM-SMX-PG-NI-PB, occurring in 8 isolates.
- Full Text:
- Date Issued: 2016
Evaluation of the medicinal potentials of Bulbine Abyssinica A. rich in the management of diabetes mellitus in the Eastern Cape, South Africa
- Authors: Kibiti, Cromwell Mwiti
- Date: 2016
- Subjects: Medicinal plants -- South Africa -- Eastern Cape Diabetes -- Alternative treatment -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/3077 , vital:28252
- Description: Diabetes mellitus is a chronic physiological carbohydrate metabolic disorder with significant impact on the economy, quality of life and life expectancy in South Africa. Herbal medicine has become the alternative therapy in the management of this disease. However, their safety and effectiveness have not been investigated. To address this, one of the plants used in Eastern Cape Province, South Africa, Bulbine abyssinica A. Rich (Asphodelaceae), was evaluated. Bulbine abyssinica is one of the species used in the management of diabetes mellitus. This plant was mentioned during an ethnobotanical survey conducted in Nkonkobe municipality of the Eastern Cape Province. Though a decoction prepared from the whole plant is used in the treatment of diabetes mellitus, the mechanism of action and its safety has not been elucidated. Thus, this research work was designed to contribute to the understanding of the possible mechanism of action of B. abyssinica as an antidiabetic medicinal plant and its toxic potentials to the users. The aqueous extract exhibited remarkable inhibitory activity onα-amylase (estimated inhibitory concentration (IC)50 value of 3.28 μg/ml), while the acetone extract exhibited weak inhibitory activity. The acetone extract exhibited notable α-glucosidase inhibitory activity (IC50 value of 4.27 μg/ml) while aqueous extract had significantly weak activity. The Lineweaver-Burk double reciprocal plots revealed that the aqueous extract exerts noncompetitive inhibition on the α-amylase activity while the acetone extract exerts a near competitive inhibitory pattern on the α-glucosidase activity. The extracts from the plant possessed high free radical scavenging activities, with acetone extract exhibiting the highest activities in all assay models used except with ferric reducing power and nitric oxide (NO) scavenging ability. The aqueous extract exhibited the highest ferric reducing power and nitric oxide radical mopping strength while the essential oil exhibited the highest scavenging activities with 1,1-diphenyl-2-picrylhydrazyl (DPPH) and relatively high ferric reducing power and nitric oxide scavenging ability. The acetone extract and the essential oil of this species exhibited higher albumin denaturation inhibition than the aqueous extract while the latter showed the greatest membrane lysis protection. The essential oil, acetone and aqueous extracts from this plant significantly inhibited the growth of Shigelle flexneri, Pseudomonas aeruginosa, Staphylococcus aureus and Enterococcus faecalis. Klebsiella pneumonia, Proteus vulgaris and Streptococcus pyogens growth were inhibited by acetone and aqueous extracts. The essential oil also showed inhibitory activity against Proteus vulgaris. However, the extracts were active against the growth of only three fungi species. The essential oil showed significant inhibitory activity against Trichophyton rubrum. The aqueous extract inhibited the growth of Microsporum gypseum while the acetone extract was active against Microsporum canis, and Microsporum gypseum. The carbohydrate, crude fibre, moisture, ash, crude protein and crude fat of approximately 74.8 percent, 8.9 percent, 8.8 percent, 8 percent, 7.7 percent and 0.6 percent, respectively, were detected in this plant. The species is characterized by moderate levels of oxalates, phytic acids, Vitamin A, Vitamin C and Vitamin E. Potassium and calcium were present in highest levels, while magnesium, iron, sodium, aluminium and phosphorus were moderately present. Manganese, zinc and copper where in low amounts. These vitamins and mineral elements were within their recommended daily allowance (RDA) in humans. The investigation also revealed appreciable amounts of total phenols, flavonoids, flavanols, proanthocyanidins and alkaloids in both acetone and aqueous extracts while saponins and tannins were in trace amounts. The essential oil was characterized by large quantities of terpenes (91.9 percent) and small fraction of esters (8.01 percent).
- Full Text:
- Date Issued: 2016
- Authors: Kibiti, Cromwell Mwiti
- Date: 2016
- Subjects: Medicinal plants -- South Africa -- Eastern Cape Diabetes -- Alternative treatment -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/3077 , vital:28252
- Description: Diabetes mellitus is a chronic physiological carbohydrate metabolic disorder with significant impact on the economy, quality of life and life expectancy in South Africa. Herbal medicine has become the alternative therapy in the management of this disease. However, their safety and effectiveness have not been investigated. To address this, one of the plants used in Eastern Cape Province, South Africa, Bulbine abyssinica A. Rich (Asphodelaceae), was evaluated. Bulbine abyssinica is one of the species used in the management of diabetes mellitus. This plant was mentioned during an ethnobotanical survey conducted in Nkonkobe municipality of the Eastern Cape Province. Though a decoction prepared from the whole plant is used in the treatment of diabetes mellitus, the mechanism of action and its safety has not been elucidated. Thus, this research work was designed to contribute to the understanding of the possible mechanism of action of B. abyssinica as an antidiabetic medicinal plant and its toxic potentials to the users. The aqueous extract exhibited remarkable inhibitory activity onα-amylase (estimated inhibitory concentration (IC)50 value of 3.28 μg/ml), while the acetone extract exhibited weak inhibitory activity. The acetone extract exhibited notable α-glucosidase inhibitory activity (IC50 value of 4.27 μg/ml) while aqueous extract had significantly weak activity. The Lineweaver-Burk double reciprocal plots revealed that the aqueous extract exerts noncompetitive inhibition on the α-amylase activity while the acetone extract exerts a near competitive inhibitory pattern on the α-glucosidase activity. The extracts from the plant possessed high free radical scavenging activities, with acetone extract exhibiting the highest activities in all assay models used except with ferric reducing power and nitric oxide (NO) scavenging ability. The aqueous extract exhibited the highest ferric reducing power and nitric oxide radical mopping strength while the essential oil exhibited the highest scavenging activities with 1,1-diphenyl-2-picrylhydrazyl (DPPH) and relatively high ferric reducing power and nitric oxide scavenging ability. The acetone extract and the essential oil of this species exhibited higher albumin denaturation inhibition than the aqueous extract while the latter showed the greatest membrane lysis protection. The essential oil, acetone and aqueous extracts from this plant significantly inhibited the growth of Shigelle flexneri, Pseudomonas aeruginosa, Staphylococcus aureus and Enterococcus faecalis. Klebsiella pneumonia, Proteus vulgaris and Streptococcus pyogens growth were inhibited by acetone and aqueous extracts. The essential oil also showed inhibitory activity against Proteus vulgaris. However, the extracts were active against the growth of only three fungi species. The essential oil showed significant inhibitory activity against Trichophyton rubrum. The aqueous extract inhibited the growth of Microsporum gypseum while the acetone extract was active against Microsporum canis, and Microsporum gypseum. The carbohydrate, crude fibre, moisture, ash, crude protein and crude fat of approximately 74.8 percent, 8.9 percent, 8.8 percent, 8 percent, 7.7 percent and 0.6 percent, respectively, were detected in this plant. The species is characterized by moderate levels of oxalates, phytic acids, Vitamin A, Vitamin C and Vitamin E. Potassium and calcium were present in highest levels, while magnesium, iron, sodium, aluminium and phosphorus were moderately present. Manganese, zinc and copper where in low amounts. These vitamins and mineral elements were within their recommended daily allowance (RDA) in humans. The investigation also revealed appreciable amounts of total phenols, flavonoids, flavanols, proanthocyanidins and alkaloids in both acetone and aqueous extracts while saponins and tannins were in trace amounts. The essential oil was characterized by large quantities of terpenes (91.9 percent) and small fraction of esters (8.01 percent).
- Full Text:
- Date Issued: 2016