- Title
- Push–pull type manganese (III) corroles
- Creator
- Liang, Xu, Fang, Junjia, Li, Minzhi, Chen, Qiuyun, Mack, John, Molupe, Nthabeleng, Nyokong, Tebello, Zhu, Weihua
- Subject
- To be catalogued
- Date
- 2017
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/189201
- Identifier
- vital:44826
- Identifier
- xlink:href="https://doi.org/10.1142/S1088424617500778"
- Description
- The synthesis of three low symmetry A2B type Mn(III)triarylcorroles with meso-aryl substituents that provide push–pull electron-donating and -withdrawing properties is reported. An analysis of the structure-property relationships for the optical and redox properties has been carried out through a comparison with the results of theoretical calculations. The results demonstrate that A2B type Mn(III)triarylcorroles interact strongly with cell-free circulating tumor deoxyribonucleic acid (ctDNA) in solution, and that the interaction constants are enhanced when a stronger electron-donating substituent is introduced at the 10-position of the meso-triarylcorrole ligand.
- Format
- computer, online resource, application/pdf, 1 online resource (8 pages), pdf
- Publisher
- World Scientific Publishers
- Language
- English
- Relation
- Journal of Porphyrins and Phthalocyanines, Liang, X., Fang, J., Li, M., Chen, Q., Mack, J., Molupe, N., Nyokong, T. and Zhu, W., 2017. Push–pull type manganese (III) corroles: Synthesis, electronic structures and tunable interactions with ctDNA. Journal of Porphyrins and Phthalocyanines, 21(11), pp.751-758, Journal of Porphyrins and Phthalocyanines volume 21 number 11 p. 751 2017 1099-1409
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the World Scientific Copyright and Permissions Statement (https://0-www.worldscientific.com.wam.seals.ac.za/page/permissions)
- Rights
- Closed Access
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Collections
Mack, John (Associate Prof)
Nyokong, Tebello (Distinguished Professor)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Push–pull type manganese (III) corroles.pdf | 549 KB | Adobe Acrobat PDF | View Details Download |