- Title
- Photophysics and NLO properties of Ga (III) and In (III) phthalocyaninates bearing diethyleneglycol chains
- Creator
- Managa, Muthumuni, Khene, Samson M, Britton, Jonathan, Martynov, Alexander G, Gorbunova, Yulia G, Tsivadze, Aslan Y, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2018
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/237822
- Identifier
- vital:50556
- Identifier
- xlink:href="https://doi.org/10.1142/S1088424618500128"
- Description
- This work reports on synthesis and characterizations of Ga(III) and In(III) complexes, formed by 2,3-bis[2′′-(2′′′′-hydroxyethoxy)ethoxy]-9,10,16,17,23,24-hexa-nn-butoxy phthalocyanine (1H2) coordinating acetatoindium(III) (1InOAc) and hydroxogallium(III) (1GaOH) Photophysical properties of hydroxogallium(III) phthalocyaninate 1GaOH and acetatoindium(III) phthalocyaninate 1InOAc were studied by UV-vis, fluorescence spectroscopy and time-resolved methods. The nonlinear absorption of the complexes was studied using the Z-scan technique at 532 nm and 10 ns pulse in DMSO and in thin films formed by composite with poly(bisphenol A carbonate) — PBC. The magnitude of absorption coefficients and other nonlinear optical parameters estimated in this work showed that complex 1InOAc exhibited the strongest nonlinear optical behavior in comparison with 1GaOH in solution and a reverse tendency when embedded in PBC thin films. DFT calculations were used to rationalize these results.
- Format
- computer, online resource, application/pdf, 1 online resource (12 pages), pdf
- Publisher
- World Scientific Publishing
- Language
- English
- Relation
- Journal of Porphyrins and Phthalocyanines, Managa, M., Khene, S., Britton, J., Martynov, A.G., Gorbunova, Y.G., Tsivadze, A.Y. and Nyokong, T., 2018. Photophysics and NLO properties of Ga (III) and In (III) phthalocyaninates bearing diethyleneglycol chains. Journal of Porphyrins and Phthalocyanines, 22(01n03), pp.137-148, Journal of Porphyrins and Phthalocyanines volume 22 number 01n03 p. 137 2018 1099-1409
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the World Scientific Copyright and Permissions Statement (https://0-www.worldscientific.com.wam.seals.ac.za/page/permissions)
- Rights
- Closed Access
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Khene, Samson Mielie (Assoc Prof)
Britton, Jonathan (Dr)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
SDG 03. Good Health and Well-Being
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details | SOURCE1 | Photophysics and NLO properties of Ga.pdf | 644 KB | Adobe Acrobat PDF | View Details |