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Comparison of Task Scheduling Algorithms for Traffic Surveillance Application Using Fog Computing

- Sinqadu, Mluleki, Shibeshi, Zelalem S, Khalid, Khuram

  • Authors: Sinqadu, Mluleki , Shibeshi, Zelalem S , Khalid, Khuram
  • Date: 2022
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/429150 , vital:72563 , https://doi.org/10.1007/978-3-030-89776-5_3
  • Description: One of the issues that service consumers face when using cloud-based solutions is the delay in processing large and real-time data. Fog computing has been introduced as a solution to this issue since it allows the data to be processed at the edge of a network while enabling different tasks to be scheduled for processing in fog devices at the edge network. These devices still require cloud resources to give them the capacity of processing real-time applications. However, scheduling these tasks must be made in such a way that they do not consume all the available resources on a fog device. When a task consumes all available resources, it can lead to network breakdown or high latency which is not acceptable for real-time applications. Therefore, to address this problem, this chapter proposes a task scheduling technique for traffic surveillance vehicular network application through smart cameras. We used the iFogSim simulator, where the scenario of vehicle tracking is considered. Simulations are conducted to find an efficient scheduling algorithm among a pool of available ones that can optimize the energy consumption and average delay of our proposed real-time application model. The results show that the First Come First Serve (FCFS) scheduling algorithm outperforms the Short Job First (SJF), Generalized Priority (GP) and Round Robin (RR) counterparts in terms of average latency, energy usage, execution time and network usage.
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  • Date Issued: 2022

Conceptualising public-private partnerships for social innovation through community engagement in higher education institutions

- Sibhensana, Bertha, Maistry, Savathrie M

  • Authors: Sibhensana, Bertha , Maistry, Savathrie M
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/426269 , vital:72337 , xlink:href="https://hdl.handle.net/10520/ejc-high_v37_n1_a11"
  • Description: The achievement of human social and economic development has been equated to social innovation. Innovation that focuses on the marginalised communities in South Africa becomes necessary to redress the inequalities created pre-democracy. As social institutions, higher education institutions are well positioned to deal with the challenges of the 21st century, which include poverty, unemployment and inequality, through promoting social innovation. In democratic South Africa the relationship between an institution of higher learning and the community can be viewed as a social innovation. This submission implies that one of the objectives of community engagement as a core function of universities, is to drive the social innovation agenda. The university’s contributions to community development can be viewed in terms of its ability to commit to social innovation. It is a better vehicle for understanding and creating social value in all its forms.
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  • Date Issued: 2022

Constellations, technicality, iconisation and Eskom: A case from South Africa’s Business Day

- Siebörger, Ian, Adendorff, Ralph D

  • Authors: Siebörger, Ian , Adendorff, Ralph D
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/385350 , vital:68010 , xlink:href="https://doi.org/10.2989/16073614.2022.2040369"
  • Description: This article uses Legitimation Code Theory (LCT) and systemic functional linguistics (SFL) to explore interactions between various resources for building economic and political knowledge in a 2015 article from Business Day, a South African newspaper, concerning the country’s energy crisis. We use LCT to observe how three constellations are built in the article: a ‘developmental state’ constellation; a ‘neo-liberal’ constellation; and another underarticulated constellation that selectively draws ideas from both the preceding constellations. These constellations are built through the unfolding of the text using various linguistic resources, which we describe using SFL, including technicality and iconisation. We identify instances where words are charged with both ideational and axiological meaning concurrently, challenging existing understandings of the process of iconisation.
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  • Date Issued: 2022

Cultural Seascapes in the ‘Sea of Calms’ and La Restinga Coast

- De la Cruz-Modino, Raquel, Piñeiro-Corbeira, Cristina, Aswani, Shankar, González-Cruz, Carla, Domínguez, David, Ordóñez García, Paula, Santana-Talavera, Agustín, Pascual-Fernández, José

  • Authors: De la Cruz-Modino, Raquel , Piñeiro-Corbeira, Cristina , Aswani, Shankar , González-Cruz, Carla , Domínguez, David , Ordóñez García, Paula , Santana-Talavera, Agustín , Pascual-Fernández, José
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , book
  • Identifier: http://hdl.handle.net/10962/391319 , vital:68641 , ISBN 978-3-031-07289-5 , https://doi.org/10.1007/978-3-031-07289-5
  • Description: El Hierro has been characterized by the balance between human development and environmental sustainability. The island was historically far from the mass tourism developments dominant on the other Canary Islands. Tourism accommodations in El Hierro are few compared to more developed coastal areas in the Archipelago, and recreational activities are mainly linked to cultural and natural sites and resources. This chapter focuses on La Restinga fishing village and its coasts, where the ‘Sea of Calms’ and one multiple-use Marine Reserve (MR) are located, both of which became popular over the last decade. The tourist development experience has promoted a new way of looking at the sea and conceptualizing its habitats and populations. In 2014, after the submarine volcano eruption occurred in 2011, we estimated that at least 25,391 dives had been carried out in the diving spots established by the MR and other diving sites close to La Restinga. Despite the difficulties experienced after the volcano eruption, a unique imaginaire has been consolidated, thanks to the image of the island's exclusive nature and iconic elements. In addition, the rapid recovery of the destination is an excellent example of how the tourism system can adapt and incorporate unexpected events such as volcanic eruptions.
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  • Date Issued: 2022

Dark brown three-legged round African clay pot

  • Date: 2022 , 2022-10-05
  • Subjects: Bam, Brigalia , Pottery, African
  • Language: English
  • Type: realia
  • Identifier: http://hdl.handle.net/10948/56874 , vital:57197
  • Description: Dark brown round African clay pot, with three legs and a shield pattern. Interior of pot is cream coloured. , Donated/gifted to Nelson Mandela University Archives , Forms part of: Brigalia Bam collection
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  • Date Issued: 2022

Decoration of glass wool with zinc (II) phthalocyanine for the photocatalytic transformation of methyl orange

- Sindelo, Azole, Britton, Jonathan, Lanterna, Anabel E, Scaiano, Juan C, Nyokong, Tebello

  • Authors: Sindelo, Azole , Britton, Jonathan , Lanterna, Anabel E , Scaiano, Juan C , Nyokong, Tebello
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/295742 , vital:57374 , xlink:href="https://doi.org/10.1016/j.jphotochem.2022.114127"
  • Description: Zinc phthalocyanines containing one (mono carboxy phenoxy, ZnMCPPc), four (tetra carboxy phenoxy, ZnTCPPc), and eight (tetra isophthalic acid, ZnTIPAPc) carboxyl groups were covalently conjugated to amine-functionalized glass wool (GW). The GW-Pcs were characterized and evaluated for singlet oxygen generation. The photocatalytic efficiencies of the GW-Pcs were assessed using methyl orange. Glass wool alone and the modified conjugates exhibited low to no degradation of methyl orange in the dark. The improved catalytic rate was observed for GW-ZnMCPPc and GW-ZnTCPPc compared to GW-ZnTIPAPc due to the latter's lower singlet oxygen quantum yield generation. In addition, the modified glass wool was recyclable, making it suitable candidates for future environmental applications.
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  • Date Issued: 2022

Deep Palmprint Recognition with Alignment and Augmentation of Limited Training Samples

- Brown, Dane, Bradshaw, Karen L

  • Authors: Brown, Dane , Bradshaw, Karen L
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/440249 , vital:73760 , xlink:href="https://doi.org/10.1007/s42979-021-00859-3"
  • Description: This paper builds upon a previously proposed automatic palmprint alignment and classification system. The proposed system was geared towards palmprints acquired from either contact or contactless sensors. It was robust to finger location and fist shape changes—accurately extracting the palmprints in images without fingers. An extension to this previous work includes comparisons of traditional and deep learning models, both with hyperparameter tuning. The proposed methods are compared with related verification systems and a detailed evaluation of open-set identification. The best results were yielded by a proposed Convolutional Neural Network, based on VGG-16, and outperforming tuned VGG-16 and Xception architectures. All deep learning algorithms are provided with augmented data, included in the tuning process, enabling significant accuracy gains. Highlights include near-zero and zero EER on IITD-Palmprint verification using one training sample and leave-one-out strategy, respectively. Therefore, the proposed palmprint system is practical as it is effective on data containing many and few training examples.
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  • Date Issued: 2022

Design and fabrication of electrochemical sensor based on molecularly imprinted polymer loaded onto silver nanoparticles for the detection of 17-β-Estradiol

- Regasa, Melkamu Biyana, Nyokong, Tebello

  • Authors: Regasa, Melkamu Biyana , Nyokong, Tebello
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/300287 , vital:57913 , xlink:href="https://doi.org/10.1002/jmr.2978"
  • Description: In this research report, we prepared an electrochemical sensor based on the molecularly imprinted poly(p-aminophenol) supported by silver nanoparticles capped with 2-mercaptobenzoxazole for the selective and sensitive detection of endocrine disrupting 17-β-estradiol (E2). The electropolymerization of the functional monomer prepared the proposed molecularly imprinted polymer (MIP) composite-based sensor in the presence of E2 as a template. The recognition materials were characterized using Fourier transform infrared, cyclic voltammetry (CV), square wave voltammetry (SWV), scanning electron microscopy, energy-dispersive X-ray spectroscopy and X-ray powder diffraction techniques. The electrochemical measurements were performed by employing both CV and SWV methods. We did the optimization of critical parameters affecting the sensor performances through the experimental design and verification. The developed sensor showed a linear range from 10 pM to 100 nM with the calculated quantification and detection limits of 1.86 and 6.19 pM, respectively. The incorporation of AgNP with high electrical conductivity into the MIP matrix enhanced the sensor's performance. Furthermore, the sensor was applied to determine E2 in real water samples without any sample preconcentration steps to achieve the percent recovery of 91.87% to 98.36% and acceptable reusability and storage stability performances.
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  • Date Issued: 2022

Detecting and removing sample contamination in phylogenomic data: an example and its implications for Cicadidae phylogeny (Insecta Hemiptera).

- Owen, Christopher L, Marshall, David C, Wade, Elizabeth J, Meister, Russ, Goemans, Geert, Kunte, Krushnamegh, Moulds, Max, Hill, Kathy, Villet, Martin H, Pham, Thai-Hong, Kortyna, Michelle, Lemmon, Emily M, Lemmon, Alan R, Simon, Chris

  • Authors: Owen, Christopher L , Marshall, David C , Wade, Elizabeth J , Meister, Russ , Goemans, Geert , Kunte, Krushnamegh , Moulds, Max , Hill, Kathy , Villet, Martin H , Pham, Thai-Hong , Kortyna, Michelle , Lemmon, Emily M , Lemmon, Alan R , Simon, Chris
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/440749 , vital:73809 , https://doi.org/10.1093/sysbio/syac043
  • Description: Contamination of a genetic sample with DNA from one or more nontarget species is a continuing concern of molecular phylogenetic studies, both Sanger sequencing studies and next-generation sequencing studies. We developed an automated pipeline for identifying and excluding likely cross-contaminated loci based on the detection of bimodal distributions of patristic distances across gene trees. When contamination occurs between samples within a data set, a comparison between a contaminated sample and its contaminant taxon will yield bimodal distributions with one peak close to zero patristic distance. This new method does not rely on a priori knowledge of taxon relatedness nor does it determine the causes(s) of the contamination. Exclusion of putatively contaminated loci from a data set generated for the insect family Cicadidae showed that these sequences were affecting some topological patterns and branch supports, although the effects were sometimes subtle, with some contamination-influenced relationships exhibiting strong bootstrap support. Long tip branches and outlier values for one anchored phylogenomic pipeline statistic (AvgNHomologs) were correlated with the presence of contamination.
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  • Date Issued: 2022

Developing Relationships for Community-Based Research at Rhodes University: Values, Principles and Challenges

- Rouillard, Tessa, Deponselle, Keagan, Bezerra, Joana C

  • Authors: Rouillard, Tessa , Deponselle, Keagan , Bezerra, Joana C
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/426430 , vital:72352 , xlink:href="https://doi.org/10.3390/su142315525"
  • Description: In addition to providing benefits to people, protected areas are valued in ways that go beyond the tangible. A sense of place, and the collection of values, feelings, and meanings associated with a place, can illuminate people-place relationships. Understanding how people relate to a place is essential in acquiring support for protected areas. This research investigates tourists’ and residents’ sense of place in Knysna, an open-access section of the Garden Route National Park, South Africa. Data was collected through questionnaires and semi-structured interviews. The sense of place was characterised using five variables: physical, cultural, social, dependent, and ideological. Although ‘physical’ was the dominant variable for both tourists and residents, the ‘ideological’ for residents and the ‘cultural’ for tourists came second, highlighting the importance of safe places and recreational activities, respectively. The physical environment influences sense of place, and the importance of protected areas to stakeholders offers an opportunity for management to engage with the public.
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  • Date Issued: 2022

Developing Relationships for Community-Based Research at Rhodes University: Values, Principles and Challenges

- Hornby, Diana, Maistry, Savathrie M

  • Authors: Hornby, Diana , Maistry, Savathrie M
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , book chapter
  • Identifier: http://hdl.handle.net/10962/433524 , vital:72981 , ISBN 978-3-030-86401-9 , https://doi.org/10.1007/978-3-030-86402-6_6
  • Description: Post-apartheid education policy in South Africa mandates that universities should become more responsive to the socio-economic development of the country, positioning community engagement as a core function of higher education. Community engagement in all its forms, and particularly in the form of community-based research, should develop the social responsibility of both students and the institution by providing opportunities for partnering in community-based projects to promote the social good, thus narrowing the gap between universities and communities. The Community Engagement Division at Rhodes University in the Eastern Cape province of South Africa, supported by the highest level of management of the institution, was fully aware that removal of the ‘ivory tower’ image was a herculean task. Thus, they developed a set of values and principles to guide the establishment of community partnerships with the community the university serves. This chapter explains these values and principles, using the Reviving Schools community engagement initiative as an example. It discusses some of the challenges experienced and how they were overcome to build research relationships and a sense of ‘community’ between Rhodes University and its external partners in Makhanda.
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  • Date Issued: 2022

Development and in vitro biological studies of polymer-based wound dressings with a high haemostatic ability for the management of wounds

- Nqoro, Xhamla https://orcid.org/0000-0002-2065-3629

  • Authors: Nqoro, Xhamla https://orcid.org/0000-0002-2065-3629
  • Date: 2022
  • Subjects: Wound healing , Surgical wound infections , Wound treatment equipment industry
  • Language: English
  • Type: Doctoral theses , text
  • Identifier: http://hdl.handle.net/10353/27970 , vital:71404
  • Description: Wounds are usually accompanied by complications such as excessive bleeding and bacteria invasion. The design of wound dressings that rapidly stop excessive bleeding and inhibit bacterial invasion is crucial to promoting accelerated wound healing. To meet the abovementioned requirements in wound dressings, topical gels were prepared from sodium alginate SA and carboxymethylcellulose CMC. The wound dressings were loaded with an antifibrinolytic agent, tranexamic acid TA, essential oils, and a variety of metal-based nanoparticles, and carbon-based biomaterials. The scanning electron microscopy SEM and X-ray diffraction XRD confirmed the successful formation of the nanoparticles. The prepared formulations exhibited in vitro drug release kinetics that best fitted with the Korsmeyer-Peppas model. These gels exhibited good spreadability and viscosity, showing a shear-thinning behaviour with pH between 6.7 and 7.3, signifying suitability for skin application and ease of application. The prepared topical gels exhibited significant antibacterial effects against gram-negative and gram-positive strains of bacteria. SA EO-based formulations showed high antibacterial activity across all bacterial strains, followed by SA-based formulations compared to CMC-based formulations, which exhibited moderate antibacterial activity. Moreover, the prepared gels showed good cytocompatibility, promoted cell proliferation, and exhibited 80 percent wound closure on day 3 compared to the untreated group, which showed a 38 percent wound reduction in vitro. Excellent blood clotting properties were observed with CMC-based gels compared to other formulations. However, all the prepared formulations exhibited outstanding blood clotting ability compared to the control, showing that they can promote rapid blood coagulation. The features presented by the prepared gels reveal that they are suitable for rapid wound healing , Thesis (PhD) -- Faculty of Science and Agriculture, 2022
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  • Date Issued: 2022

Digitalisation and Transformative Learning for Sustainable Futures in Rural Africa Leaving No One Behind

- Shetye, Nyanta, Lotz-Sisitka, Heila, Albrecht, Eike, Durr, Sarah, Marx, Dirk, Chirambo, Dumisani, Metelerkamp, Luke, van Zyl-Bulitta, Verena

  • Authors: Shetye, Nyanta , Lotz-Sisitka, Heila , Albrecht, Eike , Durr, Sarah , Marx, Dirk , Chirambo, Dumisani , Metelerkamp, Luke , van Zyl-Bulitta, Verena
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , book chapter
  • Identifier: http://hdl.handle.net/10962/435263 , vital:73143 , ISBN 9781928502241 , https://www.taylorfrancis.com/chapters/oa-edit/10.4324/9781003274322-14/digitalisation-transformative-learning-sustainable-futures-rural-africa-niyanta-shetye-heila-lotz-sisitka-eike-albrecht-sarah-durr-dirk-marx-dumisani-chirambo-luke-metelerkamp-verena-van-zyl-bulitta
  • Description: This chapter assesses the use of Information and Telecommunication Technologies (ICTs) for social and community learning to achieve sustainable development in rural communities in Africa. It focuses on new and emerging trends in the cooperation between the African Union and European Union (AU–EU) and links two thematic areas; namely green transitions and digital transformations. The chapter highlights low-cost and effective digital learning solutions. It is based on a literature review and cases that provide insight into potential AU–EU cooperation and the “leave no one behind” agenda. The chapter argues that in addition to digital technology transfer, innovation and investments are needed in building a learning-centred support for green transitioning and digital cooperation. Hence, we focus on transformative learning opportunities and informal Education for Sustainable Development (ESD). In response to ICTs becoming a catalyst for such a transformation, we seek insights into how constructive AU–EU cooperation and co-learning can pave ways for societal transformations, particularly in rural communities.
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  • Date Issued: 2022

Double stimulation and transformative agency for leadership development of school learners in Southern Africa

- Grant, Carolyn

  • Authors: Grant, Carolyn
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/281035 , vital:55685 , xlink:href="https://doi.org/10.1080/14681366.2020.1805495"
  • Description: Learners, because of their minor status, are a virtual absence in everyday school leadership work, particularly on the African continent. School leadership, therefore, continues to be misconceived as an adult phenomenon. Framed by Cultural Historical Activity Theory, this paper reports on a Southern African Higher Education studythat engages with the Vygotskian principle of ‘double stimulation’ and its relationship to transformative agency in the context of a school-based learner leadership development initiative. One school change project was purposively selected as the case, and data were drawn from a postgraduate student research report and self-reflective journal. Drawing on the Sannino model of double stimulation, the paper explores the phases of double stimulation as well as instances of transformative agency evident in the data, and speculates about the relationship between double stimulation and transformative agency in the leadership development of learners.
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  • Date Issued: 2022

Drowning in data, thirsty for information and starved for understanding: A biodiversity information hub for cooperative environmental monitoring in South Africa

- MacFadyen, Sandra, Allsopp, Nicky, Altwegg, Res, Archibald, Sally, Botha, Judith, Bradshaw, Karen L, Carruthers, Jane, De Klerk, Helen, de Vos, Alta, Distiller, Greg, Foord, Stefan, Freitag-Ronaldson, Stefanie, Gibbs, Richard, Hamer, Michelle, Landi, Pietro, MacFayden, Duncan, Manuel, Jeffrey, Midgley, Guy, Moncrieff, Glenn, Munch, Zahn, Mutanga, Onisimo, Sershen, Nenguda, Rendani, Ngwenya, Mzabalazo, Parker, Daniel M, Peel, Mike, Power, John, Pretorius, Joachim, Ramdhani, Syd, Robertson, Mark P, Rushworth, Ian, Skowno, Andrew, Slingsby, Jasper, Turner, Andrew, Visser, Vernon, van Wageningen, Gerhard, Hui, Cang

Electrocatalytic activity of benzothiazole substituted cobalt phthalocyanine in the presence of detonation nanodiamonds

- Ncwane, Lunathi, Mpeta, Lekhetho S, Nyokong, Tebello

  • Authors: Ncwane, Lunathi , Mpeta, Lekhetho S , Nyokong, Tebello
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/295753 , vital:57375 , xlink:href="https://doi.org/10.1016/j.diamond.2022.109319"
  • Description: This work reports on the synthesis and electrochemical sensing properties of benzothiazole substituted cobalt phthalocyanine (CoPc) when π-π stacked on detonation nanodiamonds (to form CoPc-DNDs(ππ). The synthesized materials were characterized using UV–visible, mass, Fourier transform infrared, and Raman spectroscopies as well as transmission electron microscopy and dynamic light scattering. The electrochemical studies were conducted using cyclic voltammetry, electrochemical impedance spectroscopy and chronoamperometry. Hydrazine was utilized as an analyte of interest, due to its mutagenic and carcinogenic effects. Glassy carbon electrodes (GCE) were modified with DNDs, CoPc, and CoPc-DNDs(ππ) represented as GCE/DNDs, GCE/CoPc and GCE/ CoPc-DNDs(ππ). GCE was also modified sequential addition of the CoPc and DNDs onto the GCE, represented as GCE/CoPc-DNDs(seq) when CoPc is placed before DNDs on the electrode and GCE/DNDs-CoPc(seq) when DNDs are placed before CoPc, where seq represents sequential. GCE/CoPc-DNDs(ππ) electrode gave better results in terms of limit of detection (1.68 μM), sensitivity (9.59 μA.mM−1) and catalytic rate constant (1.25 × 106 M−1 s−1).
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  • Date Issued: 2022

Electrochemical detection of human epidermal growth factor receptor 2 using an aptamer on cobalt phthalocyanines–Cerium oxide nanoparticle conjugate

- Centane, Sixolile, Mgidlana, Sithi, Openda, Yolanda, Nyokong, Tebello

  • Authors: Centane, Sixolile , Mgidlana, Sithi , Openda, Yolanda , Nyokong, Tebello
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/299835 , vital:57859 , xlink:href="https://doi.org/10.1016/j.bioelechem.2022.108146"
  • Description: The role of the biointerface design towards the development of an impedimetric biosensor for the electrochemical detection of human epidermal growth factor receptor 2 (HER2) is investigated. Two novel cobalt phthalocyanines: cobalt tetraphenyl acetic acid phthalocyanine and cobalt tetraphenyl propionic acid phthalocyanine are compared as signal amplifiers and immobilization platforms of the HB5 aptamer towards the electrochemical detection of HER2. In addition, the phthalocyanines are coupled with the metal based cerium oxide nanoparticles. The efficiency of each electrode modification step and the performance of the constructed aptasensors were assessed by impedance spectroscopy. The aptasensors showed very low limit of detection values (all less than 0.2 ng/mL) with high sensitivity and stability. Furthermore, the aptasensors showed very good performance even in human serum samples. Considering these results, the aptasensors demonstrate great potential for improved monitoring of human epidermal growth factor receptor 2 levels for the management of breast cancers.
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  • Date Issued: 2022

Enacting Environmental Ethics Education for Wildlife Conservation using an Afrophilic ‘Philosophy for Children’approach

- Bhurekeni, John

  • Authors: Bhurekeni, John
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/389821 , vital:68487 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/224689"
  • Description: Environmental Ethics Education has in recent years emerged as a critical tool for wildlife conservation research. Despite this, Environmental Ethics Education is paradoxically predominated by traditional forms of western science such as the concept of the Anthropocene which appears to exclude aspects of African life-worlds where the natural environment is considered a heritage component and is linked to onto-ethical understandings of human existence. The purpose of this study is to explore how African heritage-based knowledges and practices are understood by children who identify and understand the relevance of their totems and taboos associated with them, in relation to wildlife conservation. The study from which this paper is derived utilised formative interventionist methodology complemented by a multi-voiced decolonial approach to explore whether children-participants aged 8 to 11 years understand the purposes of their totems and associated taboos. To achieve this I used an Afrophilic Philosophy for Children pedagogical approach, which foregrounds dialogical learning and development of critical reflexive thinking skills. Emerging findings indicated that children associated their totems and connected taboos as tools for protection against environmental pollution and for minimising resource over-extraction. Findings further demonstrated improved learner agency and development of ethical reasoning among children. As participants’ respect for environmental conservation and sustainability was informed by the significance placed on their totems, I recommend the need for schools to develop generative curricula that take seriously context-based solutions to environmental problems. Future research should also consider understanding environmental conservation issues from a context-based perspective, which can inform existing heritage practices and pedagogies.
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  • Date Issued: 2022

Enhanced mitochondria destruction on MCF-7 and HeLa cell lines in vitro using triphenyl-phosphonium-labelled phthalocyanines in ultrasound-assisted photodynamic therapy activity

- Nene, Lindokuhle Cindy, Magadla, Aviwe, Nyokong, Tebello

  • Authors: Nene, Lindokuhle Cindy , Magadla, Aviwe , Nyokong, Tebello
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/295766 , vital:57376 , xlink:href="https://doi.org/10.1016/j.jphotobiol.2022.112553"
  • Description: This work reports on the reactive oxygen species (ROS) generation and the therapeutic activities of new triphenyl-phosphonium-labelled phthalocyanines (Pcs), the 2,9,16,23-tetrakis(N-(N-butyl-4-triphenyl-phosphonium)- pyridine-4-yloxy) Zn(II) Pc (3) and 2,9,16,23-tetrakis-(N-(N-butyl-4-triphenyl-phosphonium)-morpholino) Zn(II) Pc (4) upon exposure to light, ultrasound and the combination of light and ultrasound. Two types of ROS were detected: the singlet oxygen (1O2) and hydroxyl radicals. For light irradiations, only the 1O2 was detected. An increase in the ROS generation was observed for samples treated with the combination of light and ultrasound compared to the light and ultrasound mono-treatments. The in vitro anticancer activity through photodynamic (PDT) and sonodynamic (SDT) therapy for the Pcs were also determined and compared to the photo-sonodynamic combination therapy (PSDT). The two cancer cell lines used for the in vitro studies included the Michigan Cancer Foundation-7 (MCF-7) breast cancer and Henrietta Lacks (HeLa) cervical cancer cell lines. The SDT treatments showed improved therapeutic efficacy on the cancer cells for both the Pcs compared to PDT. PSDT showed better therapeutic efficacy compared to both the PDT and SDT mono-treatments.
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  • Date Issued: 2022

Enhanced Solar Efficiency via Incorporation of Plasmonic Gold Nanostructures in a Titanium Oxide/Eosin Y Dye-Sensitized Solar Cell

- Nyembe, Sanele, Chindeka, Francis, Ndlovu, Gebhu, Mkhohlakali, Andile, Nyokong, Tebello, Sikhwiyhilu, Lucy

  • Authors: Nyembe, Sanele , Chindeka, Francis , Ndlovu, Gebhu , Mkhohlakali, Andile , Nyokong, Tebello , Sikhwiyhilu, Lucy
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/295783 , vital:57377 , xlink:href="https://doi.org/10.3390/nano12101715"
  • Description: Plasmonic gold nanoparticles significantly improved the efficiency of a TiO2 and Eosin Y based dye-sensitized solar cell from 2.4 to 6.43%. The gold nanoparticles’ sizes that were tested were 14 nm, 30 nm and 40 nm synthesized via the systematic reduction of citrate concentration using the Turkevich method. Prestine TiO2 without plasmonic gold nanoparticles yielded an efficiency of 2.4%. However, the loading of 40 nm gold nanoparticles into the TiO2 matrix yielded the highest DSSC efficiency of 6.43% compared to 30 nm (5.91%) and 14 nm (2.6%). The relatively high efficiency demonstrated by plasmonic gold nanoparticles is ascribed to light absorption/scattering, hot electron injection and plasmon-induced resonance energy transfer (PIRET), influenced by the size of the gold nanoparticles.
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  • Date Issued: 2022
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