An exploration into how Grade 3 Foundation Phase teachers implement differentiated instructional practices in their mathematics classrooms
- Authors: Jack, Nomzamo Bridget
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424057 , vital:72120
- Description: Today’s teaching space is more diverse than before. As a result, differentiated instruction is considered helpful in supporting learner diversity. This teaching approach considers socio-cultural, multiple intelligences, and learning styles also termed learning preferences of learners. It is against this view that I wanted to investigate the implementation of differentiated instruction teaching practices in the Foundation Phase. This study explored differentiated teaching strategies and procedures in mathematics teaching, and I observed four Grade 3 teachers. The theoretical framework underlying this study was the theory of practice architectures. This study is located within an interpretivist paradigm within which I employed a case study research design. The collection of the data sets was through observations and semi-structured interviews. For an analysis of observations, I used a deductive approach. On the other hand, for the semi-structured interviews, I use an inductive approach to discover patterns and themes that I applied during the data analysis process. The validation process was done by giving interview transcripts and a summary of discussions to respondents to verify their responses and check for any misinterpretations. Rich data sets were analysed concerning the research questions, which were as follows: What are the current differentiated instruction teaching practices used by Grade 3 Mathematics teachers? How can the teachers’ differentiated instruction teaching practices be understood in terms of doings, sayings and relatings? How are differentiated instruction teaching practices made visible through the lens of the Theory of Practice Architecture? The findings from the study revealed that the use of learners’ everyday language influences their understanding of mathematics terminology. The study discovered that learners were more comfortable using English to make sense of mathematics terms instead of using isiXhosa, the Language of Learning and Teaching in the Foundation Phase. Additionally, linking learning to learners’ everyday English language enabled them to learn mathematics terms in a relaxed and non-threatening situation, while isiXhosa seemed to constrain learning. Further, the findings revealed that teachers were unclear about differentiated instruction. That was evident when they did not know the elements of differentiated instruction. Thus, the study recommends that teachers need to be supported through workshops to enable them to enact differentiated instruction in their teaching. , Thesis (MEd) -- Faculty of Education, Secondary and Post-School Education, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Jack, Nomzamo Bridget
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424057 , vital:72120
- Description: Today’s teaching space is more diverse than before. As a result, differentiated instruction is considered helpful in supporting learner diversity. This teaching approach considers socio-cultural, multiple intelligences, and learning styles also termed learning preferences of learners. It is against this view that I wanted to investigate the implementation of differentiated instruction teaching practices in the Foundation Phase. This study explored differentiated teaching strategies and procedures in mathematics teaching, and I observed four Grade 3 teachers. The theoretical framework underlying this study was the theory of practice architectures. This study is located within an interpretivist paradigm within which I employed a case study research design. The collection of the data sets was through observations and semi-structured interviews. For an analysis of observations, I used a deductive approach. On the other hand, for the semi-structured interviews, I use an inductive approach to discover patterns and themes that I applied during the data analysis process. The validation process was done by giving interview transcripts and a summary of discussions to respondents to verify their responses and check for any misinterpretations. Rich data sets were analysed concerning the research questions, which were as follows: What are the current differentiated instruction teaching practices used by Grade 3 Mathematics teachers? How can the teachers’ differentiated instruction teaching practices be understood in terms of doings, sayings and relatings? How are differentiated instruction teaching practices made visible through the lens of the Theory of Practice Architecture? The findings from the study revealed that the use of learners’ everyday language influences their understanding of mathematics terminology. The study discovered that learners were more comfortable using English to make sense of mathematics terms instead of using isiXhosa, the Language of Learning and Teaching in the Foundation Phase. Additionally, linking learning to learners’ everyday English language enabled them to learn mathematics terms in a relaxed and non-threatening situation, while isiXhosa seemed to constrain learning. Further, the findings revealed that teachers were unclear about differentiated instruction. That was evident when they did not know the elements of differentiated instruction. Thus, the study recommends that teachers need to be supported through workshops to enable them to enact differentiated instruction in their teaching. , Thesis (MEd) -- Faculty of Education, Secondary and Post-School Education, 2023
- Full Text:
- Date Issued: 2023-10-13
An analysis of the interpretation and application of anti-tax avoidance legislation in the Income Tax Act, 58 of 1962 (as amended)
- Denhere, Munyaradzi Blessing
- Authors: Denhere, Munyaradzi Blessing
- Date: 2023-03-31
- Subjects: South Africa. Income Tax Act, 1962 , Income tax Law and legislation South Africa , Tax evasion South Africa , Tax assessment South Africa , Statutes South Africa Interpretation and construction
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/419436 , vital:71644
- Description: Assessed losses provide opportunities to avoid taxation by using various arrangements or transactions. Legislation has been introduced to combat these forms of tax avoidance, in the form of sections 20, 20A, 103(2) and 103(4), and sections 80A to 80L. These sections have also frequently been considered by the courts. The research problem was therefore the analysis of the interaction and effect of the provisions in the Income Tax Act dealing with the use of assessed losses for the purpose of tax avoidance, and the case law interpretation of these provisions. The main goal of the research was to critically analyse the scope and effect of sections 20, 20A, and 103(2) and 102(4), and sections 80A to 80L of the Income Tax Act, dealing with assessed losses, together with the interpretation by the courts. The research was situated within the interpretative paradigm, adopted a qualitative approach, with a doctrinal methodology. As the research was carried out using only publicly available documents, no ethical considerations applied. In addressing the goal of the research, the thesis first discussed the concept of tax avoidance and its consequences. The two main interpretative approaches adopted by the courts, including with regard to tax provisions – the strict literal and the purposive approaches – were described. The thesis then proceeded to analyse sections 20, 20A, 103(2) and 103(4), and sections 80A to 80L, together with the relevant case law, and in the case of sections 80A to 80L, with the use of a hypothetical example, to illustrate the application of the sections. The conclusion arrived at was that the sections discussed in the thesis are adequate to address the problem of the misuse of assessed losses to avoid tax. , Thesis (MCom) -- Faculty of Commerce, Accounting, 2023
- Full Text:
- Date Issued: 2023-03-31
- Authors: Denhere, Munyaradzi Blessing
- Date: 2023-03-31
- Subjects: South Africa. Income Tax Act, 1962 , Income tax Law and legislation South Africa , Tax evasion South Africa , Tax assessment South Africa , Statutes South Africa Interpretation and construction
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/419436 , vital:71644
- Description: Assessed losses provide opportunities to avoid taxation by using various arrangements or transactions. Legislation has been introduced to combat these forms of tax avoidance, in the form of sections 20, 20A, 103(2) and 103(4), and sections 80A to 80L. These sections have also frequently been considered by the courts. The research problem was therefore the analysis of the interaction and effect of the provisions in the Income Tax Act dealing with the use of assessed losses for the purpose of tax avoidance, and the case law interpretation of these provisions. The main goal of the research was to critically analyse the scope and effect of sections 20, 20A, and 103(2) and 102(4), and sections 80A to 80L of the Income Tax Act, dealing with assessed losses, together with the interpretation by the courts. The research was situated within the interpretative paradigm, adopted a qualitative approach, with a doctrinal methodology. As the research was carried out using only publicly available documents, no ethical considerations applied. In addressing the goal of the research, the thesis first discussed the concept of tax avoidance and its consequences. The two main interpretative approaches adopted by the courts, including with regard to tax provisions – the strict literal and the purposive approaches – were described. The thesis then proceeded to analyse sections 20, 20A, 103(2) and 103(4), and sections 80A to 80L, together with the relevant case law, and in the case of sections 80A to 80L, with the use of a hypothetical example, to illustrate the application of the sections. The conclusion arrived at was that the sections discussed in the thesis are adequate to address the problem of the misuse of assessed losses to avoid tax. , Thesis (MCom) -- Faculty of Commerce, Accounting, 2023
- Full Text:
- Date Issued: 2023-03-31
An analysis of womxn’s understanding of South African public health awareness campaigns’ messages on HIV/AIDS using cognitive interviewing
- Authors: Simpo, Hazel
- Date: 2023-03-30
- Subjects: HIV infections Risk factors , AIDS (Disease) Risk factors , Womxn , Cognitive interview , Awareness campaign , HIV infections South Africa , AIDS (Disease) South Africa
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/408738 , vital:70521
- Description: Besides having the most extensive antiretroviral therapy (ART) treatment programme, South Africa faces the highest epidemic rate, with womxn and children most affected. Several prevention strategies have been implemented to curb the spread of HIV/AIDS in South Africa, including free access to print form awareness campaigns that come through pamphlets, posters and billboards. However, most public health sector awareness and educational programmes carry uniform messages that are then carried out in heterogeneous contexts leading to the miscomprehension of the intended messages. This study aimed to explore womxn’s understanding of public health awareness content on the prevention of HIV/AIDS. The focus was on examining their interpretation of universal HIV/AIDS awareness messages in their heterogeneous contexts, which might provide obstacles to womxn’s reproductive health and well-being using a reproductive justice framework. This study employed a cognitive interviewing methodology to collect data from the participants to obtain information about how participants understand and perceive knowledge and how they arrive at specific answers or judgements. Twenty-eight (28) womxn aged between 18 and 30 years were purposively sampled for this study from four (4) local healthcare facilities in Makhanda: the Grahamstown Municipality (Anglo-African) Clinic, the Joza Clinic, the Settlers Day Hospital and the Raglan Road Clinic. Thematic network analysis (Attride-Stirling, 2001) was used to analyse the data collected from the study. One global theme emerged from the dataset: Barriers to HIV prevention, care and treatment. The barriers were identified mainly due to social constructions of hegemonic masculinity, individual versus cultural expectations, and outdated awareness content. The findings from the study suggest that almost all the challenges that womxn faced in terms of understanding and interpreting the awareness materials stemmed from structural factors in the South African context. The findings also suggest that cognitive interviewing methodology can be reconceptualised as an endeavour that cuts across a wide range of fields. , Thesis (MSocSci) -- Faculty of Humanities, Psychology, 2023
- Full Text:
- Date Issued: 2023-03-30
- Authors: Simpo, Hazel
- Date: 2023-03-30
- Subjects: HIV infections Risk factors , AIDS (Disease) Risk factors , Womxn , Cognitive interview , Awareness campaign , HIV infections South Africa , AIDS (Disease) South Africa
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/408738 , vital:70521
- Description: Besides having the most extensive antiretroviral therapy (ART) treatment programme, South Africa faces the highest epidemic rate, with womxn and children most affected. Several prevention strategies have been implemented to curb the spread of HIV/AIDS in South Africa, including free access to print form awareness campaigns that come through pamphlets, posters and billboards. However, most public health sector awareness and educational programmes carry uniform messages that are then carried out in heterogeneous contexts leading to the miscomprehension of the intended messages. This study aimed to explore womxn’s understanding of public health awareness content on the prevention of HIV/AIDS. The focus was on examining their interpretation of universal HIV/AIDS awareness messages in their heterogeneous contexts, which might provide obstacles to womxn’s reproductive health and well-being using a reproductive justice framework. This study employed a cognitive interviewing methodology to collect data from the participants to obtain information about how participants understand and perceive knowledge and how they arrive at specific answers or judgements. Twenty-eight (28) womxn aged between 18 and 30 years were purposively sampled for this study from four (4) local healthcare facilities in Makhanda: the Grahamstown Municipality (Anglo-African) Clinic, the Joza Clinic, the Settlers Day Hospital and the Raglan Road Clinic. Thematic network analysis (Attride-Stirling, 2001) was used to analyse the data collected from the study. One global theme emerged from the dataset: Barriers to HIV prevention, care and treatment. The barriers were identified mainly due to social constructions of hegemonic masculinity, individual versus cultural expectations, and outdated awareness content. The findings from the study suggest that almost all the challenges that womxn faced in terms of understanding and interpreting the awareness materials stemmed from structural factors in the South African context. The findings also suggest that cognitive interviewing methodology can be reconceptualised as an endeavour that cuts across a wide range of fields. , Thesis (MSocSci) -- Faculty of Humanities, Psychology, 2023
- Full Text:
- Date Issued: 2023-03-30
Experiences of men vlogging about substance use disorder recovery on YouTube
- Authors: Chele, Palesa Shené
- Date: 2023-03-30
- Subjects: Substance abuse Treatment , Sobriety , Alcoholics Anonymous , Narcotics Anonymous , Recovery , Remission , Video blogs
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/408829 , vital:70529
- Description: The journey of substance use recovery is an inherently dynamic and on-going process. It is advanced through secure social support systems. Furthermore, requiring the explicit practice of self-advancement and self-efficacy. However, in South Africa, despite the continued upsurge of substance abuse, there remains a substantial gap between the high demand for treatment and the limited capacity to provide state-funded treatment. In addition, various psychosocial and socio-economic factors further impede access to treatment or recovery support. Thus, within communities facing SUD treatment barriers the exploration of individual lived experiences may deepen understandings of how men experience the journey of substance use recovery. , Thesis (MA) -- Faculty of Humanities, Psychology, 2023
- Full Text:
- Date Issued: 2023-03-30
- Authors: Chele, Palesa Shené
- Date: 2023-03-30
- Subjects: Substance abuse Treatment , Sobriety , Alcoholics Anonymous , Narcotics Anonymous , Recovery , Remission , Video blogs
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/408829 , vital:70529
- Description: The journey of substance use recovery is an inherently dynamic and on-going process. It is advanced through secure social support systems. Furthermore, requiring the explicit practice of self-advancement and self-efficacy. However, in South Africa, despite the continued upsurge of substance abuse, there remains a substantial gap between the high demand for treatment and the limited capacity to provide state-funded treatment. In addition, various psychosocial and socio-economic factors further impede access to treatment or recovery support. Thus, within communities facing SUD treatment barriers the exploration of individual lived experiences may deepen understandings of how men experience the journey of substance use recovery. , Thesis (MA) -- Faculty of Humanities, Psychology, 2023
- Full Text:
- Date Issued: 2023-03-30
Patterns of inclusion and exclusion among trans women in South Africa: a critical narrative inquiry
- Authors: Shabalala, Siyanda Buyile
- Date: 2023-03-30
- Subjects: Transgender women South Africa , Genderism , Social inclusion , Social integration , Social exclusion , Social isolation , Narrative
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/408874 , vital:70533
- Description: Trans women have for the most part remained grossly marginalised in gender development frameworks that have concerned themselves with resolving the historical disenfranchisement of women in patriarchal societies. Considering this continuing systemic erasure of trans subjectivity, this study has aimed to foreground transness, engaging trans women’s experiences of inclusion and exclusion to better understand the traditionally oppressive institutionality of gender in South Africa from a historically silenced trans standpoint. Semi-structured individual interviews were conducted with five trans women living in South Africa. Data was transcribed and analysed using narrative analysis. Mapping the structures, practices and norms that contribute to the marginalisation of trans women in South Africa, the study found that trans women face economic vulnerability driven by familial rejection along with structural discrimination in a gender-biased labour system. Furthermore, trans women were revealed to contend with institutional erasure and stigmatisation in sex-segregated healthcare structures as well as invisibilisation in cisnormative South African knowledge systems that underrepresent trans identities and their viewpoints of the world. Underlyingly, the societal exclusion of trans women emerged as centrally organised by a structure of genderism that rigidly assumes the binariness and fixedness of gender, principally in ways that restrict trans women's right to self-determine as women. Genderism was observed to collude with factors of race and class in a largely capitalist post-apartheid South African society, working concurrently and jointly to reinforce the social exclusion of trans women. However, often subtle narratives of trans social inclusion located marginalising cisgender power in South African democracy as contested terrain. , Thesis (MA) -- Faculty of Humanities, Psychology, 2023
- Full Text:
- Date Issued: 2023-03-30
- Authors: Shabalala, Siyanda Buyile
- Date: 2023-03-30
- Subjects: Transgender women South Africa , Genderism , Social inclusion , Social integration , Social exclusion , Social isolation , Narrative
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/408874 , vital:70533
- Description: Trans women have for the most part remained grossly marginalised in gender development frameworks that have concerned themselves with resolving the historical disenfranchisement of women in patriarchal societies. Considering this continuing systemic erasure of trans subjectivity, this study has aimed to foreground transness, engaging trans women’s experiences of inclusion and exclusion to better understand the traditionally oppressive institutionality of gender in South Africa from a historically silenced trans standpoint. Semi-structured individual interviews were conducted with five trans women living in South Africa. Data was transcribed and analysed using narrative analysis. Mapping the structures, practices and norms that contribute to the marginalisation of trans women in South Africa, the study found that trans women face economic vulnerability driven by familial rejection along with structural discrimination in a gender-biased labour system. Furthermore, trans women were revealed to contend with institutional erasure and stigmatisation in sex-segregated healthcare structures as well as invisibilisation in cisnormative South African knowledge systems that underrepresent trans identities and their viewpoints of the world. Underlyingly, the societal exclusion of trans women emerged as centrally organised by a structure of genderism that rigidly assumes the binariness and fixedness of gender, principally in ways that restrict trans women's right to self-determine as women. Genderism was observed to collude with factors of race and class in a largely capitalist post-apartheid South African society, working concurrently and jointly to reinforce the social exclusion of trans women. However, often subtle narratives of trans social inclusion located marginalising cisgender power in South African democracy as contested terrain. , Thesis (MA) -- Faculty of Humanities, Psychology, 2023
- Full Text:
- Date Issued: 2023-03-30
Philosophical inquiry into the value of liberal education
- Authors: Wotshela, Siphosihle
- Date: 2023-03-30
- Subjects: Liberal education , Education, Humanistic Philosophy , Education, Humanistic South Africa , Education, Humanistic Social aspects South Africa , Jacob Klein
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/408954 , vital:70540
- Description: Throughout history, scholars have offered numerous conceptions of liberal education, with each scholar providing a slightly and sometimes extremely different idea of what liberal education actually is, what it entails, and what value one stands to gain by partaking in this particular type of education. In this thesis, I inquire into the topic of liberal education in an attempt to clearly understand what value partaking in this type of education offers the contemporary South African. In the process, I offer a defence against what I refer to as the societal context problem—a problem that questions the possibility of a universal benefit that can be obtained by partaking in liberal education. I also offer a comprehensive argument for the preference of Jacob Klein’s conception of liberal education, making the claim that Klein’s conception and the value he identifies with his conception is more convincing than that offered by other scholars because Klein’s conception and the value associated with the conception is universal in a way that allows it to remain relevant even when confronted with the problem of societal context. , Thesis (MA) -- Faculty of Humanities, Philosophy, 2023
- Full Text:
- Date Issued: 2023-03-30
- Authors: Wotshela, Siphosihle
- Date: 2023-03-30
- Subjects: Liberal education , Education, Humanistic Philosophy , Education, Humanistic South Africa , Education, Humanistic Social aspects South Africa , Jacob Klein
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/408954 , vital:70540
- Description: Throughout history, scholars have offered numerous conceptions of liberal education, with each scholar providing a slightly and sometimes extremely different idea of what liberal education actually is, what it entails, and what value one stands to gain by partaking in this particular type of education. In this thesis, I inquire into the topic of liberal education in an attempt to clearly understand what value partaking in this type of education offers the contemporary South African. In the process, I offer a defence against what I refer to as the societal context problem—a problem that questions the possibility of a universal benefit that can be obtained by partaking in liberal education. I also offer a comprehensive argument for the preference of Jacob Klein’s conception of liberal education, making the claim that Klein’s conception and the value he identifies with his conception is more convincing than that offered by other scholars because Klein’s conception and the value associated with the conception is universal in a way that allows it to remain relevant even when confronted with the problem of societal context. , Thesis (MA) -- Faculty of Humanities, Philosophy, 2023
- Full Text:
- Date Issued: 2023-03-30
Biochemical and genetic analysis of the Mycobacterium smegmatis CnoX Chaperedoxin
- Authors: Watkins, Ariana Heloise Jo
- Date: 2023-03-29
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/422403 , vital:71939
- Description: Mycobacterium (M.) tuberculosis (Mtb) encounters numerous physical and chemical stresses associated with host immunity during infection. These include exposure to reactive oxygen, chlorine and nitrogen species, low pH, hypoxia, nutrient starvation, and metal toxicity. Cellular proteins are particularly susceptible to damage by these stresses, and the ability to prevent their irreversible damage is consequently crucial for bacterial growth and survival. Mtb employs a network of proteins that includes chaperones, disaggregases, and proteases to maintain the integrity of its proteome. The chaperedoxin, CnoX, is a recently identified stress-inducible chaperone that combines redox and holdase activities to prevent the over-oxidation and aggregation of proteins in E. coli and other proteobacterial species. In this study, we identified orthologs of the E. coli CnoX (EcCnoX) in Mtb and M. smegmatis (Msm). Bioinformatics analysis of the Mtb and Msm CnoX orthologs (MtCnoX and MsCnoX, respectively) revealed that they possess similar domains, domain architectures and predicted tertiary structures as previously characterised CnoX enzymes, i.e. an N-terminal thioredoxin (Trx) domain fused to a C-terminal TPR-motif containing domain. The EcCnoX, MsCnoX, and MtCnoX enzymes were expressed as recombinant, His-tagged proteins in E. coli and purified to near homogeneity. Biochemical analysis of the recombinant CnoX enzymes revealed that the MsCnoX and MtCnoX both lack thiol-disulphide oxidoreductase (thioredoxin) activity, as evidenced by their inability to catalyse the reduction of the disulphide bonds of insulin in vitro. Both mycobacterial CnoX enzymes displayed activity as chaperones (holdases) during thermal aggregation assays of the model substrate, malate dehydrogenase (MDH). In contrast to previously reported findings for EcCnoX, the holdase activity of the mycobacterial CnoX enzymes was constitutive and did not require exposure to hypochlorous acid (HOCl) for activation. To establish the physiological role of CnoX in Msm, cnoX knockdown (KD) and knockout (KO) mutants were generated using CRISPRi-mediated gene silencing or homologous recombination, respectively. Consistent with previous findings, CnoX activity was not essential for the growth of Msm under conventional growth conditions. Reducing or eliminating CnoX activity in the Msm KD or KO mutants, respectively, did not confer increased sensitivity to HOCl as has been observed for an E. coli cnoX mutant. Reduced CnoX activity in Msm did, however, confer sensitivity to the superoxide generator, plumbagin, and front-line antitubercular drugs rifampicin and isoniazid. The combination of biochemical and physiological data presented suggests that MsCnoX may function as a holdase for substrates following proteotoxic damage induced by certain types of oxidants, a line of investigation that will be pursued in future studies. , Thesis (MSc) -- Faculty of Science, Biochemistry and Microbiology, 2023
- Full Text:
- Date Issued: 2023-03-29
- Authors: Watkins, Ariana Heloise Jo
- Date: 2023-03-29
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/422403 , vital:71939
- Description: Mycobacterium (M.) tuberculosis (Mtb) encounters numerous physical and chemical stresses associated with host immunity during infection. These include exposure to reactive oxygen, chlorine and nitrogen species, low pH, hypoxia, nutrient starvation, and metal toxicity. Cellular proteins are particularly susceptible to damage by these stresses, and the ability to prevent their irreversible damage is consequently crucial for bacterial growth and survival. Mtb employs a network of proteins that includes chaperones, disaggregases, and proteases to maintain the integrity of its proteome. The chaperedoxin, CnoX, is a recently identified stress-inducible chaperone that combines redox and holdase activities to prevent the over-oxidation and aggregation of proteins in E. coli and other proteobacterial species. In this study, we identified orthologs of the E. coli CnoX (EcCnoX) in Mtb and M. smegmatis (Msm). Bioinformatics analysis of the Mtb and Msm CnoX orthologs (MtCnoX and MsCnoX, respectively) revealed that they possess similar domains, domain architectures and predicted tertiary structures as previously characterised CnoX enzymes, i.e. an N-terminal thioredoxin (Trx) domain fused to a C-terminal TPR-motif containing domain. The EcCnoX, MsCnoX, and MtCnoX enzymes were expressed as recombinant, His-tagged proteins in E. coli and purified to near homogeneity. Biochemical analysis of the recombinant CnoX enzymes revealed that the MsCnoX and MtCnoX both lack thiol-disulphide oxidoreductase (thioredoxin) activity, as evidenced by their inability to catalyse the reduction of the disulphide bonds of insulin in vitro. Both mycobacterial CnoX enzymes displayed activity as chaperones (holdases) during thermal aggregation assays of the model substrate, malate dehydrogenase (MDH). In contrast to previously reported findings for EcCnoX, the holdase activity of the mycobacterial CnoX enzymes was constitutive and did not require exposure to hypochlorous acid (HOCl) for activation. To establish the physiological role of CnoX in Msm, cnoX knockdown (KD) and knockout (KO) mutants were generated using CRISPRi-mediated gene silencing or homologous recombination, respectively. Consistent with previous findings, CnoX activity was not essential for the growth of Msm under conventional growth conditions. Reducing or eliminating CnoX activity in the Msm KD or KO mutants, respectively, did not confer increased sensitivity to HOCl as has been observed for an E. coli cnoX mutant. Reduced CnoX activity in Msm did, however, confer sensitivity to the superoxide generator, plumbagin, and front-line antitubercular drugs rifampicin and isoniazid. The combination of biochemical and physiological data presented suggests that MsCnoX may function as a holdase for substrates following proteotoxic damage induced by certain types of oxidants, a line of investigation that will be pursued in future studies. , Thesis (MSc) -- Faculty of Science, Biochemistry and Microbiology, 2023
- Full Text:
- Date Issued: 2023-03-29
An investigation into water and sanitation in the Eastern Cape Province and potential for implementation of biotechnology platforms
- Authors: Gumunyu, Wilbert
- Date: 2022-10-14
- Subjects: Sewage South Africa Eastern Cape , Sanitation South Africa Eastern Cape , Algae Biotechnology , Biotechnology , Sewage Purification Biological treatment , Algal biofuels
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362830 , vital:65366
- Description: In contemporary South Africa, a country in transition, destruction rather than reconstruction seems commonplace. Electricity supply is at an all-time low and ‘load shedding’ is an almost daily occurrence. Similarly, more fragility of water delivery and sanitation service is being reported with the likelihood of ‘water shedding’ a soon-to-be reality. In view of the ever-increasing reported mismanagement of South Africa’s water and sanitation infrastructure, which is likely nearing the point of collapse if not already collapsed, this thesis set out to interrogate at a provincial and municipal level the status of water and sanitation in Chris Hani District Municipality (CHDM), Eastern Cape Province. One major driver behind this study was to evaluate provincial and municipal water/wastewater infrastructure as a platform to support implementation of locally developed bioprocess technologies. First, publicly available historical data was used to derive a baseline or benchmark from which to determine gains/losses in compliance, water quality and efficiency. The period 2009-2013/4 during which Blue and Green Drop reporting was routine, was used as an appropriate start point. Data thus derived indicated that, at provincial and district municipality (DM) level, potable water supply was by bulk water schemes and, sanitation was typically by waste stabilization pond (WSP) treatment of municipal sewage. The derived benchmark for the period 2009-2013/14 indicated that most plants were not compliant (~75% of the Eastern Cape Province water treatment plants (WTP) operating between average performance to critical state), operated either at- or above design capacity (Eastern Cape Province, 16%; CHDM, 19%). A large number of plants for the province (62.4%) and district (81.25%) had hydraulic design capacity or average daily flows that were unknown (information not provided in available literature or plant reports) and final effluent did not always meet the general standard (70.3% of the CHDM wastewater treatment works (WWTW)). To determine the contemporary state (2020 - 2022) of water and sanitation within CHDM, a scoping exercise of WTP and WWTW in selected local municipalities was carried out. This was done along a west-east transect by appraising WTP and WWTW in the towns of Cradock, Tarkastad, Komani, Tsomo, Cacadu, and Ngcobo. Furthermore, targeted assessment of the Queenstown WTP and the Cradock WWTW was used to derive real-time data on the status of water and sanitation infrastructure. Results showed that water and sanitation services within CHDM had, in the years between 2009-2013/14 to date, deteriorated. Freshwater demand significantly exceeded capability of water supply schemes, where demand was as much as three times greater than reported available supply. For most WWTW, operation was in excess of capacity and between 1.52 and 12 times installed hydraulic loading. The targeted scoping exercise revealed that Queenstown WTP is a moderate risk plant (Cumulative risk rating, CRR = 11 and maximum risk rating, MRR = 47.8%), whereas Cradock WWTW was in working condition but with challenges and some infrastructural dysfunction. Assessment of water/effluent quality revealed that turbidity and TOC were above SANS 241 general limit. Non-compliance in terms of nitrate/nitrite-N, ammonium-N, phosphate-P, TSS, total coliforms, E. Coli, and free chlorine was evident at Cradock WWTW. Unstructured interviews with plant operators corroborated these findings. The overwhelming support for bulk schemes for potable water provision and WSP for sanitation indicated a partially water secure municipal district but derelict in terms of its sanitation services. The later, it was concluded, in particular provides an ideal opportunity for implementation of platform technologies to support bioprocesses for entrepreneurship, employment, economic benefit and to secure a closed circular economy for regional water and sanitation through valorisation of co-product streams. Among the co-product streams considered in this thesis are biomass, biogas, biofertilizers, biofuels and several high value chemical products. , Thesis (MSc) -- Faculty of Science, Institute for Environmental Biotechnology, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Gumunyu, Wilbert
- Date: 2022-10-14
- Subjects: Sewage South Africa Eastern Cape , Sanitation South Africa Eastern Cape , Algae Biotechnology , Biotechnology , Sewage Purification Biological treatment , Algal biofuels
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362830 , vital:65366
- Description: In contemporary South Africa, a country in transition, destruction rather than reconstruction seems commonplace. Electricity supply is at an all-time low and ‘load shedding’ is an almost daily occurrence. Similarly, more fragility of water delivery and sanitation service is being reported with the likelihood of ‘water shedding’ a soon-to-be reality. In view of the ever-increasing reported mismanagement of South Africa’s water and sanitation infrastructure, which is likely nearing the point of collapse if not already collapsed, this thesis set out to interrogate at a provincial and municipal level the status of water and sanitation in Chris Hani District Municipality (CHDM), Eastern Cape Province. One major driver behind this study was to evaluate provincial and municipal water/wastewater infrastructure as a platform to support implementation of locally developed bioprocess technologies. First, publicly available historical data was used to derive a baseline or benchmark from which to determine gains/losses in compliance, water quality and efficiency. The period 2009-2013/4 during which Blue and Green Drop reporting was routine, was used as an appropriate start point. Data thus derived indicated that, at provincial and district municipality (DM) level, potable water supply was by bulk water schemes and, sanitation was typically by waste stabilization pond (WSP) treatment of municipal sewage. The derived benchmark for the period 2009-2013/14 indicated that most plants were not compliant (~75% of the Eastern Cape Province water treatment plants (WTP) operating between average performance to critical state), operated either at- or above design capacity (Eastern Cape Province, 16%; CHDM, 19%). A large number of plants for the province (62.4%) and district (81.25%) had hydraulic design capacity or average daily flows that were unknown (information not provided in available literature or plant reports) and final effluent did not always meet the general standard (70.3% of the CHDM wastewater treatment works (WWTW)). To determine the contemporary state (2020 - 2022) of water and sanitation within CHDM, a scoping exercise of WTP and WWTW in selected local municipalities was carried out. This was done along a west-east transect by appraising WTP and WWTW in the towns of Cradock, Tarkastad, Komani, Tsomo, Cacadu, and Ngcobo. Furthermore, targeted assessment of the Queenstown WTP and the Cradock WWTW was used to derive real-time data on the status of water and sanitation infrastructure. Results showed that water and sanitation services within CHDM had, in the years between 2009-2013/14 to date, deteriorated. Freshwater demand significantly exceeded capability of water supply schemes, where demand was as much as three times greater than reported available supply. For most WWTW, operation was in excess of capacity and between 1.52 and 12 times installed hydraulic loading. The targeted scoping exercise revealed that Queenstown WTP is a moderate risk plant (Cumulative risk rating, CRR = 11 and maximum risk rating, MRR = 47.8%), whereas Cradock WWTW was in working condition but with challenges and some infrastructural dysfunction. Assessment of water/effluent quality revealed that turbidity and TOC were above SANS 241 general limit. Non-compliance in terms of nitrate/nitrite-N, ammonium-N, phosphate-P, TSS, total coliforms, E. Coli, and free chlorine was evident at Cradock WWTW. Unstructured interviews with plant operators corroborated these findings. The overwhelming support for bulk schemes for potable water provision and WSP for sanitation indicated a partially water secure municipal district but derelict in terms of its sanitation services. The later, it was concluded, in particular provides an ideal opportunity for implementation of platform technologies to support bioprocesses for entrepreneurship, employment, economic benefit and to secure a closed circular economy for regional water and sanitation through valorisation of co-product streams. Among the co-product streams considered in this thesis are biomass, biogas, biofertilizers, biofuels and several high value chemical products. , Thesis (MSc) -- Faculty of Science, Institute for Environmental Biotechnology, 2022
- Full Text:
- Date Issued: 2022-10-14
An investigation of the English language demands of mathematical texts on data handling used in intermediate phase mathematics
- Authors: Jones, Angela Peta
- Date: 2022-10-14
- Subjects: Mathematics Study and teaching (Elementary) South Africa , Middle school education South Africa , Information storage and retrieval systems Mathematics , Language complexity , Textbooks Readability , Language arts Correlation with content subjects South Africa , Content area reading South Africa
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/405259 , vital:70155
- Description: In the Intermediate Phase the majority of South African learners are transitioning from learning in their mother tongue to learning in English as well as from learning to read to reading to learn, and this is a major challenge. Textbooks are a key mediating artefact in the learning of mathematics and they present a challenge to the learner in terms of the language comprehension demands The data handling sections of mathematics textbooks are particularly dense in text. This is an important part of the mathematics curriculum as it is the beginning of statistical literacy learning. We need to be able to question, evaluate claims based on data, create arguments we can defend and use data meaningfully, it is thus crucial that learners acquire statistical literacy. This research sets out to examine the text in the data handling sections of four Intermediate Phase Mathematics book series in order to answer the following research question: What are the language comprehension demands of English mathematical texts on data handling that are used in South African Intermediate Phase Mathematics? The theories framing the study are Vygotsky’s sociocultural theory and Cummins’ second language acquisition theory. It is an interpretivist mixed method case study that takes the form of a document analysis.. The findings indicate that many units in the books analysed have a higher readability level than the grade level and will thus present a challenge to learners in terms of their ability to access the mathematical content. An analysis of the linguistic complexity revealed that the features contributing most to the complexity of the texts included words with seven or more letters, prepositional phrases, infinitives, complex verbs and complex/compound sentences. An examination of the non-textual elements revealed that most of them are accurate, connected, concise, contextual and these add to the comprehensibility although there were a few which could be possibly be distractors. It is hoped that the empirical findings of this study, will sensitise educators and publishers involved with the design of textbooks and workbooks to the type of language currently found and that they might give attention to the needs of English language learners when developing these texts. , Thesis (MEd) -- Faculty of Education, Education, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Jones, Angela Peta
- Date: 2022-10-14
- Subjects: Mathematics Study and teaching (Elementary) South Africa , Middle school education South Africa , Information storage and retrieval systems Mathematics , Language complexity , Textbooks Readability , Language arts Correlation with content subjects South Africa , Content area reading South Africa
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/405259 , vital:70155
- Description: In the Intermediate Phase the majority of South African learners are transitioning from learning in their mother tongue to learning in English as well as from learning to read to reading to learn, and this is a major challenge. Textbooks are a key mediating artefact in the learning of mathematics and they present a challenge to the learner in terms of the language comprehension demands The data handling sections of mathematics textbooks are particularly dense in text. This is an important part of the mathematics curriculum as it is the beginning of statistical literacy learning. We need to be able to question, evaluate claims based on data, create arguments we can defend and use data meaningfully, it is thus crucial that learners acquire statistical literacy. This research sets out to examine the text in the data handling sections of four Intermediate Phase Mathematics book series in order to answer the following research question: What are the language comprehension demands of English mathematical texts on data handling that are used in South African Intermediate Phase Mathematics? The theories framing the study are Vygotsky’s sociocultural theory and Cummins’ second language acquisition theory. It is an interpretivist mixed method case study that takes the form of a document analysis.. The findings indicate that many units in the books analysed have a higher readability level than the grade level and will thus present a challenge to learners in terms of their ability to access the mathematical content. An analysis of the linguistic complexity revealed that the features contributing most to the complexity of the texts included words with seven or more letters, prepositional phrases, infinitives, complex verbs and complex/compound sentences. An examination of the non-textual elements revealed that most of them are accurate, connected, concise, contextual and these add to the comprehensibility although there were a few which could be possibly be distractors. It is hoped that the empirical findings of this study, will sensitise educators and publishers involved with the design of textbooks and workbooks to the type of language currently found and that they might give attention to the needs of English language learners when developing these texts. , Thesis (MEd) -- Faculty of Education, Education, 2022
- Full Text:
- Date Issued: 2022-10-14
Country risk and stock market volatility in Africa: Measuring the contribution of political and economic risk factors
- Authors: Hoveni, Jamela Basani
- Date: 2022-10-14
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/405445 , vital:70172
- Description: Thesis embargoed. To be released in 2025. , Thesis (PhD) -- Faculty of Commerce, Economics and economic History, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Hoveni, Jamela Basani
- Date: 2022-10-14
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/405445 , vital:70172
- Description: Thesis embargoed. To be released in 2025. , Thesis (PhD) -- Faculty of Commerce, Economics and economic History, 2022
- Full Text:
- Date Issued: 2022-10-14
Design, synthesis, manufacture, characterization and evaluation of lipid nanocapsules in chitosan-iota-carrageenan based hydrogel scaffold as a potential anti-Covid-19 drug delivery system
- Authors: Mukubwa, Grady Kathondo
- Date: 2022-10-14
- Subjects: Nanocapsules Design , Hydrogel , COVID-19 (Disease) , Characterization , Drug delivery systems
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/364955 , vital:65665
- Description: Covid-19 is a deadly viral disease that has been rampant around the world since 2019. Although the successful introduction of the vaccine has reduced the spread of covid-19, new cases and deaths are still being recorded. To date, no specific curative antiviral treatment has been approved for covid-19. However, many existing antiviral drugs have been and are still being studied against covid-19 and some of them, such as Remdesivir, have shown promise and could be repurposed to treat this infection. Unfortunately, antiviral drugs are prone to resistance as most of them have poor biopharmaceutical properties, including low solubility, permeability and bioavailability, which could hinder any clinical success. Recent advances in nanotechnology-based delivery systems have made it possible to improve the biopharmaceutical properties of many drugs, especially those of poorly water-soluble drugs, by formulating them as lipid nanoparticles (LNP). Thus, in order to contribute to the fight against covid-19, this work aimed to develop Lipid Nanocapsules (LNC), based on some natural raw materials, which could improve the biopharmaceutical properties of antiviral drugs. In addition, since covid-19 infection is mainly respiratory, this work also aimed to fabricate a targeted delivery system based on a hydrogel capable of entrapping LNC and ensuring their efficient deposition and release in the lungs. The LNC consisted of a mixture of medium-chain triglycerides oil (MCT oil), crude soy lecithin, tween 80, NaCl and water, while the hydrogel consisted of a chitosan-grafted-iota carrageenan-grafted-poly (acrylamide-co-acrylic acid) system (CS-iCar-p (AAm-Co-AA)). Efavirenz (EFV), a drug with very low water solubility that has recently been demonstrated to have the potential to influence sars-cov-2 life cycle through different targets (3CLP, RdRp, Hellicase, 3’to5’exonuclease, 2’-O-ribose methyltransferase and EndoRNAse), was chosen as the model drug to evaluate the developed delivery system. The combination of LNP and hydrogel results in a delivery system known as the LNP-hydrogel composite, an emerging area of research in the field of drug delivery. To date, no research has reported the design and fabrication of an LNC-CS-iCar-p (AAm-Co-AA) hydrogel composite that could effectively deliver an antiviral drug to the lungs in addition to its advantages in terms of biological activities. Prior to the design of experiment, EFV solubility was assessed in water, labrafac lipophile 1349 and MCT oil. After that, the Design Expert Software version 13 was used to design the different experiments performed in this work. The I-optimal mixture design of experiments was performed for both LNC preparation and CS-iCar-p (AAm-Co-AA) hydrogel synthesis to study the impact of raw materials on the characteristics of these delivery systems. LNC were prepared using the phase inversion method while the free radical precipitation graft copolymerization method was used to synthesize hydrogel. In order to build polynomial models that could predict the amount of drug both LNC and CS-iCar-p (AAm-Co-AA) hydrogel can entrap, a D-optimal (custom) randomized design was performed. Moreover, various characterization techniques were used to investigate the physicochemical properties of the developed delivery systems. Thereafter, drug release studies were performed using a 1% sodium lauryl sulfate solution adjusted to either pH 4 or 7. Solubility studies revealed that EFV was more soluble in labrafac lipophile 1349 and in MCT oil than in water; therefore, given its affordability, MCT oil was used for the LNC formulation. The design of experiment carried out allowed the construction of polynomial models that could predict, on the one hand, the droplet size, the polydispersity index and the Zeta potential of LNC, which were respectively around 50nm, below 0.2 and below -33. On the other hand, the model could predict the swelling capacity of the synthesized hydrogel, which was optimised to about 30,000% (300 g of water to 1 g of hydrogel). This turned out to be influenced by the proportion of polymers, the ratio of monomers as well as the concentration of the cross-linking agent. In addition, the characterization techniques further supported the improvement of EFV solubility by highlighting its conversion into its amorphous state after encapsulation in LNC. They also confirmed successful synthesis of CS-iCar-p (AAm-co-AA) hydrogel. LNC were able to encapsulate about 87% of EFV while the synthesized CS-iCar-p (AAm-co-AA) hydrogel entrapped around 53% of EFV encapsulated in LNC. While LNC were able to release 42% and 27% of EFV after 74 hours in a 1% sodium lauryl sulfate solution (SLS) at pH 7 and pH 4 respectively, the LNC-CS-iCar-p (AAm-co-AA) hydrogel composite released about 50% and 40% of the drug after 9 days in the same release medium. Interestingly, the chemical integrity of the drug was preserved throughout the manufacturing process up to after its release, suggesting that the developed LNC-CS-iCar-p (AAm-co-AA) hydrogel composite could be used as a novel potential anticovid-19 drugs delivery system. , Thesis (MSc) -- Faculty of Science, Chemistry, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Mukubwa, Grady Kathondo
- Date: 2022-10-14
- Subjects: Nanocapsules Design , Hydrogel , COVID-19 (Disease) , Characterization , Drug delivery systems
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/364955 , vital:65665
- Description: Covid-19 is a deadly viral disease that has been rampant around the world since 2019. Although the successful introduction of the vaccine has reduced the spread of covid-19, new cases and deaths are still being recorded. To date, no specific curative antiviral treatment has been approved for covid-19. However, many existing antiviral drugs have been and are still being studied against covid-19 and some of them, such as Remdesivir, have shown promise and could be repurposed to treat this infection. Unfortunately, antiviral drugs are prone to resistance as most of them have poor biopharmaceutical properties, including low solubility, permeability and bioavailability, which could hinder any clinical success. Recent advances in nanotechnology-based delivery systems have made it possible to improve the biopharmaceutical properties of many drugs, especially those of poorly water-soluble drugs, by formulating them as lipid nanoparticles (LNP). Thus, in order to contribute to the fight against covid-19, this work aimed to develop Lipid Nanocapsules (LNC), based on some natural raw materials, which could improve the biopharmaceutical properties of antiviral drugs. In addition, since covid-19 infection is mainly respiratory, this work also aimed to fabricate a targeted delivery system based on a hydrogel capable of entrapping LNC and ensuring their efficient deposition and release in the lungs. The LNC consisted of a mixture of medium-chain triglycerides oil (MCT oil), crude soy lecithin, tween 80, NaCl and water, while the hydrogel consisted of a chitosan-grafted-iota carrageenan-grafted-poly (acrylamide-co-acrylic acid) system (CS-iCar-p (AAm-Co-AA)). Efavirenz (EFV), a drug with very low water solubility that has recently been demonstrated to have the potential to influence sars-cov-2 life cycle through different targets (3CLP, RdRp, Hellicase, 3’to5’exonuclease, 2’-O-ribose methyltransferase and EndoRNAse), was chosen as the model drug to evaluate the developed delivery system. The combination of LNP and hydrogel results in a delivery system known as the LNP-hydrogel composite, an emerging area of research in the field of drug delivery. To date, no research has reported the design and fabrication of an LNC-CS-iCar-p (AAm-Co-AA) hydrogel composite that could effectively deliver an antiviral drug to the lungs in addition to its advantages in terms of biological activities. Prior to the design of experiment, EFV solubility was assessed in water, labrafac lipophile 1349 and MCT oil. After that, the Design Expert Software version 13 was used to design the different experiments performed in this work. The I-optimal mixture design of experiments was performed for both LNC preparation and CS-iCar-p (AAm-Co-AA) hydrogel synthesis to study the impact of raw materials on the characteristics of these delivery systems. LNC were prepared using the phase inversion method while the free radical precipitation graft copolymerization method was used to synthesize hydrogel. In order to build polynomial models that could predict the amount of drug both LNC and CS-iCar-p (AAm-Co-AA) hydrogel can entrap, a D-optimal (custom) randomized design was performed. Moreover, various characterization techniques were used to investigate the physicochemical properties of the developed delivery systems. Thereafter, drug release studies were performed using a 1% sodium lauryl sulfate solution adjusted to either pH 4 or 7. Solubility studies revealed that EFV was more soluble in labrafac lipophile 1349 and in MCT oil than in water; therefore, given its affordability, MCT oil was used for the LNC formulation. The design of experiment carried out allowed the construction of polynomial models that could predict, on the one hand, the droplet size, the polydispersity index and the Zeta potential of LNC, which were respectively around 50nm, below 0.2 and below -33. On the other hand, the model could predict the swelling capacity of the synthesized hydrogel, which was optimised to about 30,000% (300 g of water to 1 g of hydrogel). This turned out to be influenced by the proportion of polymers, the ratio of monomers as well as the concentration of the cross-linking agent. In addition, the characterization techniques further supported the improvement of EFV solubility by highlighting its conversion into its amorphous state after encapsulation in LNC. They also confirmed successful synthesis of CS-iCar-p (AAm-co-AA) hydrogel. LNC were able to encapsulate about 87% of EFV while the synthesized CS-iCar-p (AAm-co-AA) hydrogel entrapped around 53% of EFV encapsulated in LNC. While LNC were able to release 42% and 27% of EFV after 74 hours in a 1% sodium lauryl sulfate solution (SLS) at pH 7 and pH 4 respectively, the LNC-CS-iCar-p (AAm-co-AA) hydrogel composite released about 50% and 40% of the drug after 9 days in the same release medium. Interestingly, the chemical integrity of the drug was preserved throughout the manufacturing process up to after its release, suggesting that the developed LNC-CS-iCar-p (AAm-co-AA) hydrogel composite could be used as a novel potential anticovid-19 drugs delivery system. , Thesis (MSc) -- Faculty of Science, Chemistry, 2022
- Full Text:
- Date Issued: 2022-10-14
Electrocatalytic activity of symmetric and asymmetric Co(II) and Mn(III) porphyrins in the presence of graphene quantum dots towards the oxidation of hydrazine
- Authors: Jokazi, Mbulelo
- Date: 2022-10-14
- Subjects: Electrocatalysis , Hydrazine , Quantum dots , Graphene , Porphyrins
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362894 , vital:65372
- Description: The influence of metal porphyrins in electro-oxidation of hydrazine is explored. A series of symmetric and asymmetric porphyrins alone and in the presence of graphene quantum dots (GQDs) are employed in this work. Tetra 4-aminophenyl porphyrin, manganese tetra 4-aminophenyl porphyrin, manganese tetra 4-aminophenyl porphyrin--GQDs, and manganese tetra 4-aminophenyl porphyrin@GQDs are the symmetric porphyrins. The asymmetric porphyrin and composites are 5, 10, 15-tris(aminophenyl)-20-(4-carboxyphenyl) porphyrins, manganese 5, 10, 15-tris(aminophenyl)-20-(4-carboxyphenyl) porphyrins, cobalt 5, 10, 15-tris(aminophenyl)-20-(4-carboxyphenyl) porphyrins, manganese 5, 10, 15-tris(aminophenyl)-20-(4-carboxyphenyl) porphyrins--GQDs, and cobalt 5, 10, 15-tris(aminophenyl)-20-(4-carboxyphenyl) porphyrins--GQDs. These complexes were synthesized and characterized accordingly and applied for electrocatalysis. The electrocatalytic experiments were carried out using glassy carbon electrode and the modification was through drop-dry method. The porphyrin and GQDs synthesized were characterized using UV-Vis spectroscopy, Mass spectrometry, X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy and energy dispersive x-ray spectroscopy. The modified electrodes were characterized using cyclic voltammetry and electrochemical Impedance spectroscopy. The introduction of metal ion in the center of the porphyrin improved electrocatalysis. The presence of push-pull substituents in the porphyrin lowered the oxidation potential and improved the catalysis. The presence of GQDs improved catalysis in both symmetric and asymmetric porphyrin compared to individual components. Cobalt porphyrins showed better activity than manganese porphyrin. , Thesis (MSc) -- Faculty of Science, Chemistry, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Jokazi, Mbulelo
- Date: 2022-10-14
- Subjects: Electrocatalysis , Hydrazine , Quantum dots , Graphene , Porphyrins
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362894 , vital:65372
- Description: The influence of metal porphyrins in electro-oxidation of hydrazine is explored. A series of symmetric and asymmetric porphyrins alone and in the presence of graphene quantum dots (GQDs) are employed in this work. Tetra 4-aminophenyl porphyrin, manganese tetra 4-aminophenyl porphyrin, manganese tetra 4-aminophenyl porphyrin--GQDs, and manganese tetra 4-aminophenyl porphyrin@GQDs are the symmetric porphyrins. The asymmetric porphyrin and composites are 5, 10, 15-tris(aminophenyl)-20-(4-carboxyphenyl) porphyrins, manganese 5, 10, 15-tris(aminophenyl)-20-(4-carboxyphenyl) porphyrins, cobalt 5, 10, 15-tris(aminophenyl)-20-(4-carboxyphenyl) porphyrins, manganese 5, 10, 15-tris(aminophenyl)-20-(4-carboxyphenyl) porphyrins--GQDs, and cobalt 5, 10, 15-tris(aminophenyl)-20-(4-carboxyphenyl) porphyrins--GQDs. These complexes were synthesized and characterized accordingly and applied for electrocatalysis. The electrocatalytic experiments were carried out using glassy carbon electrode and the modification was through drop-dry method. The porphyrin and GQDs synthesized were characterized using UV-Vis spectroscopy, Mass spectrometry, X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy and energy dispersive x-ray spectroscopy. The modified electrodes were characterized using cyclic voltammetry and electrochemical Impedance spectroscopy. The introduction of metal ion in the center of the porphyrin improved electrocatalysis. The presence of push-pull substituents in the porphyrin lowered the oxidation potential and improved the catalysis. The presence of GQDs improved catalysis in both symmetric and asymmetric porphyrin compared to individual components. Cobalt porphyrins showed better activity than manganese porphyrin. , Thesis (MSc) -- Faculty of Science, Chemistry, 2022
- Full Text:
- Date Issued: 2022-10-14
Exploring primary school mathematics teachers use of gamification in formative assessment: a case study
- Authors: Simelane, Thando
- Date: 2022-10-14
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/405412 , vital:70169
- Description: Technology integration has gained much influence with the emergence of technological tools in educational areas. The vast resources and opportunities that technologies and the Internet have brought new approaches, strategies, and tools to assess learners' performance in many subject areas. Teachers have many computer/mobile device applications and learning management systems. Most teachers are trying new ways of integrating technology into the mathematics classroom to increase the quality of teaching and learning. Thus, this study explored how primary school mathematics teachers use Kahoot as a formative assessment tool. The study adopted an exploratory case study underpinned by the interpretive paradigm. It was conducted in a primary school in the Shiselweni Region in Swaziland. The participants were ten mathematics teachers teaching different grades at the school. Data was generated using observations, workshops, structured questionnaires, journal reflections and focus group interviews. The theoretical and analytical framework that underpinned this study was a combination of Davis' (1989) Technology Acceptance Model (TAM) and Mishra & Koehler's (2006) Technological Pedagogical Content Knowledge (TPACK) framework. The study results showed that the perceptions and attitudes of primary school mathematics teachers towards using Kahoot generally appear to be positive. The study also revealed that all the participants found Kahoot helpful and perceived it as easy to use. The study found that the provision of technical support for teachers; and financial support for schools to implement technology use in the classroom were enabling factors for using Kahoot as a formative assessment technology. Constraining factors were lack of high-speed internet connectivity; and lack of basic technological knowledge for using Kahoot in formative assessment. The study concluded that Kahoot increases learner motivation, engagement, attention, enjoyment, and knowledge retention. This study recommended the integration of Kahoot gamification into the mathematics curriculum.The study recommends that there is a need for schools to initiate the presence of technologies in mathematics classrooms and encourage teachers to integrate technologies assessment and teaching. The study suggest future research to explore use of Kahoot as a formative assessment technology in resource-constrained schooling contexts using multiple cases. , Thesis (MEd) -- Faculty of Education, Education, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Simelane, Thando
- Date: 2022-10-14
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/405412 , vital:70169
- Description: Technology integration has gained much influence with the emergence of technological tools in educational areas. The vast resources and opportunities that technologies and the Internet have brought new approaches, strategies, and tools to assess learners' performance in many subject areas. Teachers have many computer/mobile device applications and learning management systems. Most teachers are trying new ways of integrating technology into the mathematics classroom to increase the quality of teaching and learning. Thus, this study explored how primary school mathematics teachers use Kahoot as a formative assessment tool. The study adopted an exploratory case study underpinned by the interpretive paradigm. It was conducted in a primary school in the Shiselweni Region in Swaziland. The participants were ten mathematics teachers teaching different grades at the school. Data was generated using observations, workshops, structured questionnaires, journal reflections and focus group interviews. The theoretical and analytical framework that underpinned this study was a combination of Davis' (1989) Technology Acceptance Model (TAM) and Mishra & Koehler's (2006) Technological Pedagogical Content Knowledge (TPACK) framework. The study results showed that the perceptions and attitudes of primary school mathematics teachers towards using Kahoot generally appear to be positive. The study also revealed that all the participants found Kahoot helpful and perceived it as easy to use. The study found that the provision of technical support for teachers; and financial support for schools to implement technology use in the classroom were enabling factors for using Kahoot as a formative assessment technology. Constraining factors were lack of high-speed internet connectivity; and lack of basic technological knowledge for using Kahoot in formative assessment. The study concluded that Kahoot increases learner motivation, engagement, attention, enjoyment, and knowledge retention. This study recommended the integration of Kahoot gamification into the mathematics curriculum.The study recommends that there is a need for schools to initiate the presence of technologies in mathematics classrooms and encourage teachers to integrate technologies assessment and teaching. The study suggest future research to explore use of Kahoot as a formative assessment technology in resource-constrained schooling contexts using multiple cases. , Thesis (MEd) -- Faculty of Education, Education, 2022
- Full Text:
- Date Issued: 2022-10-14
Revitalisation and indigenisation of the Science curriculum through drum making, drumming, music and dance
- Authors: Liveve, Angelius Kanyanga
- Date: 2022-10-14
- Subjects: Curriculum change Namibia , Science Study and teaching (Secondary) Namibia , Traditional ecological knowledge Namibia , Drum Performance , Drum making , Pedagogical content knowledge , Social learning
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/405482 , vital:70175 , DOI 10.21504/10962/405482
- Description: The integration of IK is a common phenomenon in many postcolonial states, where it is viewed as a means to redress the injustices of the colonial era. It is believed that the recognition of IK in education represents an acknowledgement of diversity and other ways of knowing. In Namibia, for instance, the National Curriculum for Basic Education encourages the integration of IK in Science teaching. However, this goal is still far from being achieved because the curriculum seems to be silent on how teachers should integrate IK into their teaching. As a result, research shows that many Science teachers in Namibia seem to find it difficult to integrate IK into their science teaching because they were not properly trained to do so during both their pre-service and in-service training. This suggests that there is a dire need to empower science teachers who are implementers of the curriculum on appropriate pedagogical content knowledge on how to integrate IK into their science teaching in particular. It is against this backdrop that this interventionist study sought to explore how to mobilise the indigenous technology of drum making, drumming, music and dance for cultural revitalisation and indigenisation of the science curriculum. The study is underpinned by an interpretivist paradigm and augmented with an indigenous research paradigm. The interpretivist paradigm enabled me to understand the teachers’ perspectives in their contexts. On the other hand, within the indigenous research paradigm, I used the Ubuntu perspective which afforded each of us an opportunity to understand each other’s ways of knowing, doing and being. Within these two complementary paradigms, a qualitative case study approach was employed. The case study was in the form of intervention with six Grade 10 Physics teachers from three senior secondary schools in the Kavango West Region in Namibia. Moreover, a critical friend who was a lecturer at the university and expert community members of the Unongo Cultural Youth Group who are the custodians of the cultural heritage. Data were generated using semi-structured interviews, workshop discussions (audio-recorded), observations (participatory and lesson observations), stimulated recall interviews as well as journal reflections. Vygotsky’s Socio-cultural Theory, Ogunniyi’s Contiguity Argumentation Theory and Mavhunga and Rollnick’s Topic-specific Pedagogical Content Knowledge were used as the theoretical lenses in this study. The data gathered were analysed thematically and then categorised into sub-themes and themes. The findings of the study revealed that tapping into the cultural heritage of community members through giving them a voice has great potential to revitalise and indigenise the science curriculum. It also emerged in this study that storytelling is a potential instructional strategy to make science accessible and relevant to learners. The use of the indigenous technology of drum making, drumming, music and dance contributed to the Physics teachers’ agency and empowered them to co-develop their learning and teaching support materials in the form of exemplar lesson plans that integrated IK. Moreover, their pedagogical content knowledge was enhanced through enacting such exemplar lessons and thereafter reflecting on them. The study thus recommends that those in academia should promote the use of indigenous technologies as hubs for mediating the learning of science concepts. It also recommends that learners should be taken out of their science classrooms into the community to learn IK and wisdom from expert community members, something which could assist them in understanding the science taught at school. This might also benefit teachers in effectively implementing the integration of IK in schools and thereby use learners’ cultural heritage as a starting point to enrich meaningful and authentic learning. , Thesis (PhD) -- Faculty of Education, Education, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Liveve, Angelius Kanyanga
- Date: 2022-10-14
- Subjects: Curriculum change Namibia , Science Study and teaching (Secondary) Namibia , Traditional ecological knowledge Namibia , Drum Performance , Drum making , Pedagogical content knowledge , Social learning
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/405482 , vital:70175 , DOI 10.21504/10962/405482
- Description: The integration of IK is a common phenomenon in many postcolonial states, where it is viewed as a means to redress the injustices of the colonial era. It is believed that the recognition of IK in education represents an acknowledgement of diversity and other ways of knowing. In Namibia, for instance, the National Curriculum for Basic Education encourages the integration of IK in Science teaching. However, this goal is still far from being achieved because the curriculum seems to be silent on how teachers should integrate IK into their teaching. As a result, research shows that many Science teachers in Namibia seem to find it difficult to integrate IK into their science teaching because they were not properly trained to do so during both their pre-service and in-service training. This suggests that there is a dire need to empower science teachers who are implementers of the curriculum on appropriate pedagogical content knowledge on how to integrate IK into their science teaching in particular. It is against this backdrop that this interventionist study sought to explore how to mobilise the indigenous technology of drum making, drumming, music and dance for cultural revitalisation and indigenisation of the science curriculum. The study is underpinned by an interpretivist paradigm and augmented with an indigenous research paradigm. The interpretivist paradigm enabled me to understand the teachers’ perspectives in their contexts. On the other hand, within the indigenous research paradigm, I used the Ubuntu perspective which afforded each of us an opportunity to understand each other’s ways of knowing, doing and being. Within these two complementary paradigms, a qualitative case study approach was employed. The case study was in the form of intervention with six Grade 10 Physics teachers from three senior secondary schools in the Kavango West Region in Namibia. Moreover, a critical friend who was a lecturer at the university and expert community members of the Unongo Cultural Youth Group who are the custodians of the cultural heritage. Data were generated using semi-structured interviews, workshop discussions (audio-recorded), observations (participatory and lesson observations), stimulated recall interviews as well as journal reflections. Vygotsky’s Socio-cultural Theory, Ogunniyi’s Contiguity Argumentation Theory and Mavhunga and Rollnick’s Topic-specific Pedagogical Content Knowledge were used as the theoretical lenses in this study. The data gathered were analysed thematically and then categorised into sub-themes and themes. The findings of the study revealed that tapping into the cultural heritage of community members through giving them a voice has great potential to revitalise and indigenise the science curriculum. It also emerged in this study that storytelling is a potential instructional strategy to make science accessible and relevant to learners. The use of the indigenous technology of drum making, drumming, music and dance contributed to the Physics teachers’ agency and empowered them to co-develop their learning and teaching support materials in the form of exemplar lesson plans that integrated IK. Moreover, their pedagogical content knowledge was enhanced through enacting such exemplar lessons and thereafter reflecting on them. The study thus recommends that those in academia should promote the use of indigenous technologies as hubs for mediating the learning of science concepts. It also recommends that learners should be taken out of their science classrooms into the community to learn IK and wisdom from expert community members, something which could assist them in understanding the science taught at school. This might also benefit teachers in effectively implementing the integration of IK in schools and thereby use learners’ cultural heritage as a starting point to enrich meaningful and authentic learning. , Thesis (PhD) -- Faculty of Education, Education, 2022
- Full Text:
- Date Issued: 2022-10-14
The regeneration of palmiet (prionium serratum) following hydrogeomorphic disturbance: a case study of the Kromme River wetland
- Authors: Van Eck, Caydon Daniël
- Date: 2022-10-14
- Subjects: Biogeomorphology South Africa Kromme Estuary (Eastern Cape) , Wetland ecology , Prionium serratum Regeneration , Fluvial geomorphology , River channels
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/365555 , vital:65759
- Description: The Kromme River wetland in the Eastern Cape of South Africa occupies a broad valley (up to 350 m wide) with a gentle longitudinal slope of less than 2 % that has been formed by cut-and-fill cycles that are initiated by trunk-tributary interactions. These hydrogeomorphic disturbance events trigger gully erosion and generate sediments, the coarse fraction of which is deposited less than 2 km downstream, leading to depositional floodout features that fill gullies headwards. This process has been occurring at intervals for at least 10 000 years, and as such pre-dates the introduction of European farming practices in the area. Plants that regenerate by colonising these features are thought to have evolved adaptions necessary to colonise intermittently produced bare sandy sediments. This study aimed to examine the regeneration ecology of palmiet (Prionium serratum), the dominant vegetation community within these cut-and-fill wetlands, by relating its regeneration characteristics to environmental factors in a reach of the Kromme River wetland that has experienced a recent hydrogeomorphic disturbance event (approximately 10 years before the commencement of this study). Palmiet was found to be regenerating on sedimentary deposits on beds of gullies and on depositional bars on the margins of gully beds. The large depositional floodout downstream of a large gully also favoured palmiet regeneration, where it was found to be regenerating along not only the active channel, but also along old abandoned flow paths and sometimes areas well elevated above the channel. The geomorphic features that favoured palmiet regeneration were characterised by coarse-grained sediments (mean particle size approximately 310 μm) with low organic matter content (0.61 %), a low depth to the water table and low elevation above the thalweg (mean depth to water table is approximately 0.6 m), and a relatively close distance to the thalweg (< 10 m). This understanding of palmiet’s regeneration characteristics was viewed in relation to existing literature on undisturbed palmiet wetland plant communities and its reported contribution to conditions that favour wetland formation through gully filling, which allowed for the creation of a conceptual model of palmiet regeneration, colonisation and long-term persistence. This model was based on the Fluvial Biogeomorphic Succession concept. It suggests that palmiet’s interaction with the hydrogeomorphic environment throughout the different stages of its life cycle results in self-organising biogeomorphic landforms. Over hundreds of years, the reciprocal interactions between palmiet, sediments and water, fills gullies and restores valley bottoms, ultimately leading to the formation of a wetland landform. It is further proposed that through continued accretion, the geomorphic wetland landscape becomes more and more disconnected from the hydrogeomorphic dynamics of the fluvial system, such that the prevailing conditions begin to favour fynbos establishment, which may outcompete palmiet. , Thesis (MSc) -- Faculty of Science, Geography, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Van Eck, Caydon Daniël
- Date: 2022-10-14
- Subjects: Biogeomorphology South Africa Kromme Estuary (Eastern Cape) , Wetland ecology , Prionium serratum Regeneration , Fluvial geomorphology , River channels
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/365555 , vital:65759
- Description: The Kromme River wetland in the Eastern Cape of South Africa occupies a broad valley (up to 350 m wide) with a gentle longitudinal slope of less than 2 % that has been formed by cut-and-fill cycles that are initiated by trunk-tributary interactions. These hydrogeomorphic disturbance events trigger gully erosion and generate sediments, the coarse fraction of which is deposited less than 2 km downstream, leading to depositional floodout features that fill gullies headwards. This process has been occurring at intervals for at least 10 000 years, and as such pre-dates the introduction of European farming practices in the area. Plants that regenerate by colonising these features are thought to have evolved adaptions necessary to colonise intermittently produced bare sandy sediments. This study aimed to examine the regeneration ecology of palmiet (Prionium serratum), the dominant vegetation community within these cut-and-fill wetlands, by relating its regeneration characteristics to environmental factors in a reach of the Kromme River wetland that has experienced a recent hydrogeomorphic disturbance event (approximately 10 years before the commencement of this study). Palmiet was found to be regenerating on sedimentary deposits on beds of gullies and on depositional bars on the margins of gully beds. The large depositional floodout downstream of a large gully also favoured palmiet regeneration, where it was found to be regenerating along not only the active channel, but also along old abandoned flow paths and sometimes areas well elevated above the channel. The geomorphic features that favoured palmiet regeneration were characterised by coarse-grained sediments (mean particle size approximately 310 μm) with low organic matter content (0.61 %), a low depth to the water table and low elevation above the thalweg (mean depth to water table is approximately 0.6 m), and a relatively close distance to the thalweg (< 10 m). This understanding of palmiet’s regeneration characteristics was viewed in relation to existing literature on undisturbed palmiet wetland plant communities and its reported contribution to conditions that favour wetland formation through gully filling, which allowed for the creation of a conceptual model of palmiet regeneration, colonisation and long-term persistence. This model was based on the Fluvial Biogeomorphic Succession concept. It suggests that palmiet’s interaction with the hydrogeomorphic environment throughout the different stages of its life cycle results in self-organising biogeomorphic landforms. Over hundreds of years, the reciprocal interactions between palmiet, sediments and water, fills gullies and restores valley bottoms, ultimately leading to the formation of a wetland landform. It is further proposed that through continued accretion, the geomorphic wetland landscape becomes more and more disconnected from the hydrogeomorphic dynamics of the fluvial system, such that the prevailing conditions begin to favour fynbos establishment, which may outcompete palmiet. , Thesis (MSc) -- Faculty of Science, Geography, 2022
- Full Text:
- Date Issued: 2022-10-14
Towards an improved understanding of episodic benthic turbidity events (Benthic Nepheloid Layer) on the Eastern Agulhas Bank, South Africa
- Authors: Johnstone, Brett Mordaunt
- Date: 2022-10-14
- Subjects: Nepheloid layer , Turbidity , Loligo reynaudii , Fisheries South Africa , Oceanography , Remote sensing , Altimetry , Climatic changes
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362883 , vital:65371
- Description: The harvest of Loligo reynaudii, or "chokka," represents a critical source of revenue and job creation in the historically impoverished Eastern Cape Province of South Africa. Due to the importance of visual stimuli in the reproductive processes, it has been hypothesized that a primary driver of successful reproduction is the clarity of the water column. The presence of increased particulate matter concentrations within the water column generates turbid conditions near the seafloor (visibility < 1m), that are proposed to restrict spawning activity. This benthic nepheloid layer (BNL) contains both organic and inorganic components, with the BNL intensity a function of bottom turbulence, substratum type, and detritus level. However, the spatial and temporal resolution of BNL intensity on the Eastern Agulhas Bank (EAB) and the environmental drivers thereof remain unknown. Here we show that benthic turbidity events are a common but highly variable occurrence on the EAB. Results from a 17-month time-series of in-situ and remote sensing data between 2002 – 2004 in Algoa Bay, supplemented by experiments in other bays important for spawning, show that turbid conditions existed for ∼ 30 % of the sample period. Exploration of environmental drivers, including the influence of wind, altimeter-derived significant wave height (Hs), sea surface temperature (SST), and chlorophyll-a (Chl-a) concentrations indicate that BNL intensity does not conform to a "one-size-fits-all" approach. Rather, complex local hydrological and physiochemical parameters control the BNL characteristics on the EAB. Global warming is likely to increase the frequency and intensity of extreme westerly-wind and storm events, promoting BNL events on the Eastern Agulhas Bank and possibly causing a shift in the reproductive strategy of chokka squid to the cooler mid shelf region. This is likely to have consequences for both the species in terms of reproductive success and the fishery, which is concentrated on inshore spawning aggregations. Future research needs to quantify and characterize the constituents, source particles and spatial-temporal variability of BNL events in order to build a predictive capacity. Through incorporating the qualitative analysis of the dynamics of nepheloid layers on the EAB into Regional Oceanographic Models (ROMS), General Linear Models (GLM) and particle distribution models such as DELFT-3D, it is possible to move toward predicting the timing and intensity of these events. , Thesis (MSc) -- Faculty of Science, Ichthyology and Fisheries Science, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Johnstone, Brett Mordaunt
- Date: 2022-10-14
- Subjects: Nepheloid layer , Turbidity , Loligo reynaudii , Fisheries South Africa , Oceanography , Remote sensing , Altimetry , Climatic changes
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362883 , vital:65371
- Description: The harvest of Loligo reynaudii, or "chokka," represents a critical source of revenue and job creation in the historically impoverished Eastern Cape Province of South Africa. Due to the importance of visual stimuli in the reproductive processes, it has been hypothesized that a primary driver of successful reproduction is the clarity of the water column. The presence of increased particulate matter concentrations within the water column generates turbid conditions near the seafloor (visibility < 1m), that are proposed to restrict spawning activity. This benthic nepheloid layer (BNL) contains both organic and inorganic components, with the BNL intensity a function of bottom turbulence, substratum type, and detritus level. However, the spatial and temporal resolution of BNL intensity on the Eastern Agulhas Bank (EAB) and the environmental drivers thereof remain unknown. Here we show that benthic turbidity events are a common but highly variable occurrence on the EAB. Results from a 17-month time-series of in-situ and remote sensing data between 2002 – 2004 in Algoa Bay, supplemented by experiments in other bays important for spawning, show that turbid conditions existed for ∼ 30 % of the sample period. Exploration of environmental drivers, including the influence of wind, altimeter-derived significant wave height (Hs), sea surface temperature (SST), and chlorophyll-a (Chl-a) concentrations indicate that BNL intensity does not conform to a "one-size-fits-all" approach. Rather, complex local hydrological and physiochemical parameters control the BNL characteristics on the EAB. Global warming is likely to increase the frequency and intensity of extreme westerly-wind and storm events, promoting BNL events on the Eastern Agulhas Bank and possibly causing a shift in the reproductive strategy of chokka squid to the cooler mid shelf region. This is likely to have consequences for both the species in terms of reproductive success and the fishery, which is concentrated on inshore spawning aggregations. Future research needs to quantify and characterize the constituents, source particles and spatial-temporal variability of BNL events in order to build a predictive capacity. Through incorporating the qualitative analysis of the dynamics of nepheloid layers on the EAB into Regional Oceanographic Models (ROMS), General Linear Models (GLM) and particle distribution models such as DELFT-3D, it is possible to move toward predicting the timing and intensity of these events. , Thesis (MSc) -- Faculty of Science, Ichthyology and Fisheries Science, 2022
- Full Text:
- Date Issued: 2022-10-14
Exploring the value of an educational partnership within a multilingual pre-school setting
- Authors: Maritz, Anneliese
- Date: 2022-10-04
- Subjects: Early childhood education Parent participation South Africa Eastern Cape , Early childhood teachers Training of , Home and school South Africa Eastern Cape , Parent-teacher relationships South Africa Eastern Cape , Communication and education South Africa Eastern Cape
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/327111 , vital:61082 , DOI 10.21504/10962/327111
- Description: This modest research project was situated in a multilingual Early Childhood Development (ECD) setting in the Eastern Cape (EC) province of South Africa. In the context of high levels of poverty and unemployment in the EC, issues such as under-funding, the nature of the training of practitioners, translating the importance of learning through play into practice, difficulties dealing with diverse cultural practices and the use of multiple languages, all impact ECD provision. Research has shown that parental involvement and creating parent-school partnerships can assist children to progress at school. The overall objectives of this project were to explore how a team in an ECD centre might communicate more effectively with parents and how early stimulation practices in home and school might benefit the child’s development. The theoretical framework draws upon Vygotsky’s (1978) socio-cultural historical theory, Bernstein’s (1971) elaborated and restricted language codes and Bourdieu’s (1977) concepts of social reproduction. A research project in the Netherlands Thuis in School, used an education partnership approach (Iliás et al., 2019). They developed a manual that was adapted for our local context by drawing from the theories mentioned, and to counter the dominant approaches where parenting programs have often been offered from a deficit, narrow perspective. Action Research guided the interventionist approach to workshop sessions, to enable mutual capacity-building of parents and practitioners. To ensure informed consent, participants’ first languages were used. High risk factors related to photographs and videos of participating parents and minor children were successfully addressed. Pre- and post-interviews and workshop data were analysed using template analysis, within a constructivist paradigm. Findings include vignettes to introduce the contexts and parents' ideas prior to the sessions. Then, sessions are summarised as action cycles, with key participants' responses. Finally, post-session evaluations highlight the topics the parents found most meaningful; and parents’ and practitioner accounts of changes in practices. This research illustrates ways that educational partnership elements can influence practice and policy, to improve home and school environments for the benefit of children. , Thesis (PhD) -- Faculty of Humanities, Psychology, 2022
- Full Text:
- Date Issued: 2022-10-04
- Authors: Maritz, Anneliese
- Date: 2022-10-04
- Subjects: Early childhood education Parent participation South Africa Eastern Cape , Early childhood teachers Training of , Home and school South Africa Eastern Cape , Parent-teacher relationships South Africa Eastern Cape , Communication and education South Africa Eastern Cape
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/327111 , vital:61082 , DOI 10.21504/10962/327111
- Description: This modest research project was situated in a multilingual Early Childhood Development (ECD) setting in the Eastern Cape (EC) province of South Africa. In the context of high levels of poverty and unemployment in the EC, issues such as under-funding, the nature of the training of practitioners, translating the importance of learning through play into practice, difficulties dealing with diverse cultural practices and the use of multiple languages, all impact ECD provision. Research has shown that parental involvement and creating parent-school partnerships can assist children to progress at school. The overall objectives of this project were to explore how a team in an ECD centre might communicate more effectively with parents and how early stimulation practices in home and school might benefit the child’s development. The theoretical framework draws upon Vygotsky’s (1978) socio-cultural historical theory, Bernstein’s (1971) elaborated and restricted language codes and Bourdieu’s (1977) concepts of social reproduction. A research project in the Netherlands Thuis in School, used an education partnership approach (Iliás et al., 2019). They developed a manual that was adapted for our local context by drawing from the theories mentioned, and to counter the dominant approaches where parenting programs have often been offered from a deficit, narrow perspective. Action Research guided the interventionist approach to workshop sessions, to enable mutual capacity-building of parents and practitioners. To ensure informed consent, participants’ first languages were used. High risk factors related to photographs and videos of participating parents and minor children were successfully addressed. Pre- and post-interviews and workshop data were analysed using template analysis, within a constructivist paradigm. Findings include vignettes to introduce the contexts and parents' ideas prior to the sessions. Then, sessions are summarised as action cycles, with key participants' responses. Finally, post-session evaluations highlight the topics the parents found most meaningful; and parents’ and practitioner accounts of changes in practices. This research illustrates ways that educational partnership elements can influence practice and policy, to improve home and school environments for the benefit of children. , Thesis (PhD) -- Faculty of Humanities, Psychology, 2022
- Full Text:
- Date Issued: 2022-10-04
Land expropriation without compensation: a study of constructions of the Parliamentary process in selected mainstream and “ground-up” media from 27 February – 12 August 2018
- Authors: Jacobs, Luzuko G
- Date: 2022-10
- Subjects: Discourse analysis , Communication Political aspects South Africa , Land reform Press coverage South Africa , Land reform Government policy South Africa , Communication in mass media , Frames (Sociology) South Africa , Journalism Political aspects South Africa , Moneyweb Holdings Ltd. , City Press (South Africa) , Afriforum (South Africa) , African Farmers’ Association of South Africa (AFASA)
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/297807 , vital:57630 , DOI 10.21504/10962/297807
- Description: This study investigates the constructions of land expropriation without compensation (LEwC) in the discourses of two mainstream media, Moneyweb and City Press, and two ground-up platforms, Afriforum and the African Farmers’ Association of South Africa (AFASA). It follows the February 2018 adoption by Parliament, of LEwC as a policy to reorder the country’s unequal and racially bifurcated economy. The motivations for, and opposition to the policy locate land as ‘the issue’ in conquest and capitalism. How land is signified therefore, is important to the understandings of ‘restitution’ and/or ‘resolution’. The news platforms selected here are diverse: Moneyweb focuses on investments. City Press concerns itself with politics. Afriforum and AFASA are alternative sphericules linked to ethnically- polarised quotidian concerns with land as a key focus. Discourses are central to how citizens see and construct themselves and one another as subjects. As such, media frames can be connected to justice and inter-‘race’ complexities. This is a study of media influences in cultivating certain meanings and understandings of tenuous and fractious political situations characterised by inequality and interracial enmity. The thesis draws from the Epistemologies of the South as well as Marxism to constitute the locus of its enunciation of colonisation, liberal capitalism, land question, justice, ideology, discourse, and framing. This framework is geared towards emic understanding of interrelated local and global contexts of the land question. Conceptual clarity is key to the development of an emancipatory imagination. Qualitative framing analysis and critical discourse analysis are used in this study to examine a diachronic corpus of 124 articles from the four platforms covering 167-days, from the adoption of the LEwC motion through the initial round of public hearings. The findings suggest a strong influence of the structures of coloniality in discourses across a wide political spectrum. The frames and counter-frames in the four platforms are simultaneously divergent and similar. Some are reactionary and conservative, others are liberal-transformational and even radical-prefigurative. All however, orbit around abyssal, North-centric, liberal capitalist normativity as the centripetal centre. The study proposes rethinking of the land question, a radical exorcism from land discourses, of structures of coloniality of power, knowledge, and being. Their mobilisation, predominance and naturalisation in political communication is anti-transformation and helps keep Black South Africans to this day, under the heavy yoke of an oppressive colonial and Apartheid reality as perpetual economic slaves. , Thesis (PhD) -- Faculty of Humanities, Journalism and Media Studies, 2022
- Full Text:
- Date Issued: 2022-10
- Authors: Jacobs, Luzuko G
- Date: 2022-10
- Subjects: Discourse analysis , Communication Political aspects South Africa , Land reform Press coverage South Africa , Land reform Government policy South Africa , Communication in mass media , Frames (Sociology) South Africa , Journalism Political aspects South Africa , Moneyweb Holdings Ltd. , City Press (South Africa) , Afriforum (South Africa) , African Farmers’ Association of South Africa (AFASA)
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/297807 , vital:57630 , DOI 10.21504/10962/297807
- Description: This study investigates the constructions of land expropriation without compensation (LEwC) in the discourses of two mainstream media, Moneyweb and City Press, and two ground-up platforms, Afriforum and the African Farmers’ Association of South Africa (AFASA). It follows the February 2018 adoption by Parliament, of LEwC as a policy to reorder the country’s unequal and racially bifurcated economy. The motivations for, and opposition to the policy locate land as ‘the issue’ in conquest and capitalism. How land is signified therefore, is important to the understandings of ‘restitution’ and/or ‘resolution’. The news platforms selected here are diverse: Moneyweb focuses on investments. City Press concerns itself with politics. Afriforum and AFASA are alternative sphericules linked to ethnically- polarised quotidian concerns with land as a key focus. Discourses are central to how citizens see and construct themselves and one another as subjects. As such, media frames can be connected to justice and inter-‘race’ complexities. This is a study of media influences in cultivating certain meanings and understandings of tenuous and fractious political situations characterised by inequality and interracial enmity. The thesis draws from the Epistemologies of the South as well as Marxism to constitute the locus of its enunciation of colonisation, liberal capitalism, land question, justice, ideology, discourse, and framing. This framework is geared towards emic understanding of interrelated local and global contexts of the land question. Conceptual clarity is key to the development of an emancipatory imagination. Qualitative framing analysis and critical discourse analysis are used in this study to examine a diachronic corpus of 124 articles from the four platforms covering 167-days, from the adoption of the LEwC motion through the initial round of public hearings. The findings suggest a strong influence of the structures of coloniality in discourses across a wide political spectrum. The frames and counter-frames in the four platforms are simultaneously divergent and similar. Some are reactionary and conservative, others are liberal-transformational and even radical-prefigurative. All however, orbit around abyssal, North-centric, liberal capitalist normativity as the centripetal centre. The study proposes rethinking of the land question, a radical exorcism from land discourses, of structures of coloniality of power, knowledge, and being. Their mobilisation, predominance and naturalisation in political communication is anti-transformation and helps keep Black South Africans to this day, under the heavy yoke of an oppressive colonial and Apartheid reality as perpetual economic slaves. , Thesis (PhD) -- Faculty of Humanities, Journalism and Media Studies, 2022
- Full Text:
- Date Issued: 2022-10
A case study on responsible leadership in a renewable energy organisation in the Eastern Cape
- Authors: Mdingi, Chulumanco
- Date: 2022-06
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/419101 , vital:71616
- Description: This research was a case study of responsible leadership in a renewable energy organisation in the Eastern Cape. The study aimed to understand and describe how a renewable energy organisation applies responsible leadership to build trust. The four objectives of the study were namely to: (1) describe how the organisation interacts with its stakeholders to build trust; (2) understand how the members of the organisation demonstrate the characteristics of responsible leadership; (3) understand how different stakeholders perceive and experience the interaction of the company with established stakeholders; (4) make recommendations that a renewable energy organisation can exercise the characteristics of responsible leadership to develop its stakeholder engagement framework. In the study the stakeholder theory was applied as the theoretical framework, and the theory encourages organisations to determine the "power, legitimacy, and urgency" of stakeholders with whom they interact. A qualitative approach was used in this study. The data collection method was semi-structured interviews for all 12 participants. Data were analysed through a deductive thematic approach to identify, analyse and report patterns or themes within the data collected. The study showed that the wind farm unintentionally applies some components of responsible leadership among its stakeholders. Openness, transparency, and communication are critical actions that this organisation undertakes to cultivate trust among both its internal and external stakeholders. External stakeholders experience this organisation differently. There are mixed feelings regarding how the wind farm conducts its stakeholder engagement activities, particularly relating to landowners and government institutions. A stakeholder engagement framework is imperative if an organisation is to maintain cordial relations with its stakeholders. , Thesis (MBA) -- Faculty of Commerce, Rhodes Business School, 2023
- Full Text:
- Date Issued: 2022-06
- Authors: Mdingi, Chulumanco
- Date: 2022-06
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/419101 , vital:71616
- Description: This research was a case study of responsible leadership in a renewable energy organisation in the Eastern Cape. The study aimed to understand and describe how a renewable energy organisation applies responsible leadership to build trust. The four objectives of the study were namely to: (1) describe how the organisation interacts with its stakeholders to build trust; (2) understand how the members of the organisation demonstrate the characteristics of responsible leadership; (3) understand how different stakeholders perceive and experience the interaction of the company with established stakeholders; (4) make recommendations that a renewable energy organisation can exercise the characteristics of responsible leadership to develop its stakeholder engagement framework. In the study the stakeholder theory was applied as the theoretical framework, and the theory encourages organisations to determine the "power, legitimacy, and urgency" of stakeholders with whom they interact. A qualitative approach was used in this study. The data collection method was semi-structured interviews for all 12 participants. Data were analysed through a deductive thematic approach to identify, analyse and report patterns or themes within the data collected. The study showed that the wind farm unintentionally applies some components of responsible leadership among its stakeholders. Openness, transparency, and communication are critical actions that this organisation undertakes to cultivate trust among both its internal and external stakeholders. External stakeholders experience this organisation differently. There are mixed feelings regarding how the wind farm conducts its stakeholder engagement activities, particularly relating to landowners and government institutions. A stakeholder engagement framework is imperative if an organisation is to maintain cordial relations with its stakeholders. , Thesis (MBA) -- Faculty of Commerce, Rhodes Business School, 2023
- Full Text:
- Date Issued: 2022-06
An analysis on the skills development needs in the Supply Chain Management unit: a case-study of Eastern Cape Department of Education
- Sidiya, Lukhanyo https://orcid.org/0009-0001-2273-6348
- Authors: Sidiya, Lukhanyo https://orcid.org/0009-0001-2273-6348
- Date: 2022-06
- Subjects: Grahamstown (South Africa) , Eastern Cape (South Africa) , South Africa History
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/28850 , vital:75133
- Description: Supply chain management is very important for any organisation in the world. More so, a government’s supply chain management has to function and perform efficiently for it to be able to accomplish its set goals. In order to achieve this, it needs to ensure that it is staffed with competent, objective and impartial people. However, lack of skills among supply chain management personnel has been recognised as a major obstruction in ensuring that there effective and efficient functioning of supply chain management processes in South Africa. Therefore, there is need to explore the skills development needs in the supply chain management of a public institution. Incidentally, this research explored the skills development needs in the supply chain management unit of the Eastern Cape Department of Education. The study employed a qualitative approach, as such its research design was the case study research design and the interpretivist paradigm. The study made use of qualitative data. To collect the qualitative data semi-structured interviews were utilised. The selection of participants from the Eastern Cape Department of Education was done using purposive sampling. The data collected through fieldwork were analysed using thematic analysis. The standout themes from the data were the essential skills in SCM at the organisation (hard and soft skills), ensuring skills development, skills development needs and challenges, role if skills development in the organisation and strategies used to skills development. Based on the findings, it is suggested that strategies used for skills audit be reviewed so that more advanced skills that can address skills needs challenges immediately, when change occurs as well as meeting future skills needs. The study also recommends improved communication and information dissemination regarding skills development. The study also suggested for the organisation to invest more resources to ensure training of SCM unit personnel. , Thesis (MPA) -- Faculty of Management and Commerce, 2022
- Full Text:
- Date Issued: 2022-06
- Authors: Sidiya, Lukhanyo https://orcid.org/0009-0001-2273-6348
- Date: 2022-06
- Subjects: Grahamstown (South Africa) , Eastern Cape (South Africa) , South Africa History
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/28850 , vital:75133
- Description: Supply chain management is very important for any organisation in the world. More so, a government’s supply chain management has to function and perform efficiently for it to be able to accomplish its set goals. In order to achieve this, it needs to ensure that it is staffed with competent, objective and impartial people. However, lack of skills among supply chain management personnel has been recognised as a major obstruction in ensuring that there effective and efficient functioning of supply chain management processes in South Africa. Therefore, there is need to explore the skills development needs in the supply chain management of a public institution. Incidentally, this research explored the skills development needs in the supply chain management unit of the Eastern Cape Department of Education. The study employed a qualitative approach, as such its research design was the case study research design and the interpretivist paradigm. The study made use of qualitative data. To collect the qualitative data semi-structured interviews were utilised. The selection of participants from the Eastern Cape Department of Education was done using purposive sampling. The data collected through fieldwork were analysed using thematic analysis. The standout themes from the data were the essential skills in SCM at the organisation (hard and soft skills), ensuring skills development, skills development needs and challenges, role if skills development in the organisation and strategies used to skills development. Based on the findings, it is suggested that strategies used for skills audit be reviewed so that more advanced skills that can address skills needs challenges immediately, when change occurs as well as meeting future skills needs. The study also recommends improved communication and information dissemination regarding skills development. The study also suggested for the organisation to invest more resources to ensure training of SCM unit personnel. , Thesis (MPA) -- Faculty of Management and Commerce, 2022
- Full Text:
- Date Issued: 2022-06