- Title
- Synthesis of novel Schiff base cobalt (II) and iron (iii) complexes as cathode catalysts for microbial fuel cell applications
- Creator
- Sen, Pinar, Akagunduz, Dilan, Aghdam, Araz Sheibani, Cebeci, Fevzi C, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2020
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/187015
- Identifier
- vital:44556
- Identifier
- xlink:href="https://doi.org/10.1007/s10904-019-01286-x"
- Description
- In this study, the synthesis and characterization of a new Schiff base and its cobalt(II) and iron(III) complexes were performed fully characterized by common spectroscopic techniques such as 1H-NMR, 13C-NMR, FT-IR, UV–Vis and MS and elemental analysis. The cathodes prepared with only activated carbon, Co-Schiff base complex, and Fe-Schiff base complex mixed with activated carbon as the carrier were examined in single chamber air cathode microbial fuel cells (MFCs). The spectroscopic results confirm the structure of novel Schiff base and its complexes with cobalt (II) and Fe(III). MFC results showed that Fe-Schiff base complex generated higher voltage generation using glucose as the carbon source. Cyclic voltammetry results showed the conductivity and catalytic features of the cathodes developed in this study. Scanning electron microscopic results showed the distribution the complexes on the cathode surface. In conclusion, a novel Schiff base and its complexes with cobalt (II) and iron (III) can be employed into MFC technology to be used in green electricity production, and might help decreasing the operating costs of wastewater treatment plants.
- Format
- computer, online resource, application/pdf, 1 online resource (11 pages), pdf
- Publisher
- Springer Link
- Language
- English
- Relation
- Journal of Inorganic and Organometallic Polymers and Materials, Sen, P., Akagunduz, D., Aghdam, A.S., Cebeci, F.Ç., Nyokong, T. and Catal, T., 2020. Synthesis of novel Schiff base cobalt (II) and iron (iii) complexes as cathode catalysts for microbial fuel cell applications. Journal of Inorganic and Organometallic Polymers and Materials, 30(4), pp.1110-1120, Journal of Inorganic and Organometallic Polymers and Materials volume 30 number 4 p. 1110 2020 1574-1451
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the SpringerLink Terms of Use Statement ( https://link.springer.com/termsandconditions)
- Rights
- Open Access
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Collections
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details | SOURCE1 | Synthesis of novel Schiff base cobalt (II) and iron (iii) complexes.pdf | 1 MB | Adobe Acrobat PDF | View Details |