- Title
- The synthesis and photophysical properties of peripherally and non-peripherally substituted ball-type Mg (II) and Zn (II) phthalocyanines
- Creator
- Canlica, Mevlude, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2011
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/248417
- Identifier
- vital:51684
- Identifier
- xlink:href="https://doi.org/10.1039/C0DT00920B"
- Description
- Newly synthesized ball-type Zn(II) and Mg(II) phthalocyanines containing four 1,1′-binaphthol substituents at peripheral and non-peripheral positions are presented. The structures of the synthesized compounds were characterized by using elemental analysis, UV-vis, FT-IR, 1H-NMR and mass spectroscopies. The ΦF values were 0.33, 0.08, 0.20 and 0.08 for 6–9, respectively. The ΦT values were 0.56, 0.85, 0.64 and 0.88 for 6–9, respectively. All the complexes showed reasonably large triplet lifetimes with τT values of 710 (6), 170 (7), 1490 (8) and 380 μs (9) in DMSO. These complexes offer potential as photosensitizers in photodynamic therapy.
- Format
- computer, online resource, application/pdf, 1 online resource (6 pages), pdf
- Publisher
- Royal Society of Chemistry
- Language
- English
- Relation
- Dalton Transactions, Canlica, M. and Nyokong, T., 2011. The synthesis and photophysical properties of peripherally and non-peripherally substituted ball-type Mg (II) and Zn (II) phthalocyanines. Dalton Transactions, 40(7), pp.1497-1502, Dalton Transactions volume 40 number 7 p. 1497 2011 1477-9234
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Royal Society of Chemistry Terms and Conditions Statement (https://0-www.rsc.org.wam.seals.ac.za/help-legal/)
- Rights
- Open Access
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Collections
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
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