An investigation of the combustion kinetics of coal-microalgae composite
- Ejesieme, Obialo Vitus, Dugmore, Gary
- Authors: Ejesieme, Obialo Vitus , Dugmore, Gary
- Date: 2018
- Subjects: Microalgae -- Biotechnology , Biomass energy -- South Africa Coal -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/34777 , vital:33447
- Description: Coal mining and handling generate sizeable quantities of ultra-fine coal particles which are heaped as discard material. Use of the ultra-fine coal for co-firing with microalgae biomass appears to be a promising option that would improve combustion of the discard. There is no available traditional biomass binder that can be used to agglomerate, reclaim, and co-fire the discard ultra-fine coal to generate heat. In a recent research, microalgae biomass was identified as an effective natural binder for discard ultra-fine coal. Biomass is a renewable resource, and many have been co-fired on a large scale except microalgae biomass. Researchers have studied co-firing of dry mixed coal-microalgae, however, the kinetics of a wet mix of microalgae biomass and ultra-fine coal, “Coalgae®” patented recently by the Nelson Mandela University needs to be explored. The study aimed at investigating in some detail the oxidation mechanism of coal-microalgae composites. The objective is to understand the impact of microalgae on the kinetic properties of coal which will inform on the application of “Coalgae®”. It involves correlating the small and large-scale combustion properties that will establish the co-firing option on an industrial scenario. The goal is to utilize all grades of discard ultra-fine resource using microalgae biomass as binder and a renewable component which enhances the combustion of coal to supply heat and electricity. The use of microalgae for fuel preparation and upgrading is on the increase due to its high growth potential, reactivity, and ability to store energy more than other biomasses. This research hypothesized that blending of discard ultra-fine coal with live microalgae biomass would improve the kinetic properties of the coal more than expected from linear combination of the dry materials. Thermogravimetric combustion of “Coalgae®” was studied under non-isothermal conditions from 40 °C to 900°C at a heating rate of 15 °C/min and air flow rate of 20 ml/min. The thermogravimetric combustion properties i.e. small-scale was related to the large-scale, John Thompson’s fixed-bed reactor under the above condition. Thermal profiles were transformed into a differential function to reveal overlapped combustion events. The Coat-Redferns kinetic model was applied on the non-de-Ejesieme, O.V. PhD Chemistry (Research), Nelson Mandela Univ. Email: ejevit@yahoo.com , s211266744@live.nmmu.ac.za convoluted reactions set to obtain some of kinetic parameters. The Fraser-Suzuki equation was used to de-convolute the overlapped combustion. Then, rate law combined with Arrhenius equation was used to derive the activation energy E a and pre-exponential factor A, while the integral form of solid states reaction model, g (∝) was applied to deduce the oxidation mechanism. The composite formed a strong and partly renewable blend under controlled temperature conditions, unlike assorted dried biomass mixed with coal. Microalgae biomass upgraded the fuel and kinetics properties of ultra-fine coal more than what was expected from a linear combination. It released heat that promoted the oxidation mechanism of the discard coal. The main effect is that the “Coalgae®” is significantly (p = 0.0570) more reactive than the coal. The co-firing approach is partly renewable and contributes to the utilization of high and low-quality available discard ultra-fine coal. It advances the combustion of coal resources and reduces carbon dioxide, CO2 emission attributed to global warming as well as preserves the natural biomass sources. The combustion of “Coalgae® “will improve economy, environment, and health, heat, and electricity supply to the society.
- Full Text:
- Date Issued: 2018
- Authors: Ejesieme, Obialo Vitus , Dugmore, Gary
- Date: 2018
- Subjects: Microalgae -- Biotechnology , Biomass energy -- South Africa Coal -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/34777 , vital:33447
- Description: Coal mining and handling generate sizeable quantities of ultra-fine coal particles which are heaped as discard material. Use of the ultra-fine coal for co-firing with microalgae biomass appears to be a promising option that would improve combustion of the discard. There is no available traditional biomass binder that can be used to agglomerate, reclaim, and co-fire the discard ultra-fine coal to generate heat. In a recent research, microalgae biomass was identified as an effective natural binder for discard ultra-fine coal. Biomass is a renewable resource, and many have been co-fired on a large scale except microalgae biomass. Researchers have studied co-firing of dry mixed coal-microalgae, however, the kinetics of a wet mix of microalgae biomass and ultra-fine coal, “Coalgae®” patented recently by the Nelson Mandela University needs to be explored. The study aimed at investigating in some detail the oxidation mechanism of coal-microalgae composites. The objective is to understand the impact of microalgae on the kinetic properties of coal which will inform on the application of “Coalgae®”. It involves correlating the small and large-scale combustion properties that will establish the co-firing option on an industrial scenario. The goal is to utilize all grades of discard ultra-fine resource using microalgae biomass as binder and a renewable component which enhances the combustion of coal to supply heat and electricity. The use of microalgae for fuel preparation and upgrading is on the increase due to its high growth potential, reactivity, and ability to store energy more than other biomasses. This research hypothesized that blending of discard ultra-fine coal with live microalgae biomass would improve the kinetic properties of the coal more than expected from linear combination of the dry materials. Thermogravimetric combustion of “Coalgae®” was studied under non-isothermal conditions from 40 °C to 900°C at a heating rate of 15 °C/min and air flow rate of 20 ml/min. The thermogravimetric combustion properties i.e. small-scale was related to the large-scale, John Thompson’s fixed-bed reactor under the above condition. Thermal profiles were transformed into a differential function to reveal overlapped combustion events. The Coat-Redferns kinetic model was applied on the non-de-Ejesieme, O.V. PhD Chemistry (Research), Nelson Mandela Univ. Email: ejevit@yahoo.com , s211266744@live.nmmu.ac.za convoluted reactions set to obtain some of kinetic parameters. The Fraser-Suzuki equation was used to de-convolute the overlapped combustion. Then, rate law combined with Arrhenius equation was used to derive the activation energy E a and pre-exponential factor A, while the integral form of solid states reaction model, g (∝) was applied to deduce the oxidation mechanism. The composite formed a strong and partly renewable blend under controlled temperature conditions, unlike assorted dried biomass mixed with coal. Microalgae biomass upgraded the fuel and kinetics properties of ultra-fine coal more than what was expected from a linear combination. It released heat that promoted the oxidation mechanism of the discard coal. The main effect is that the “Coalgae®” is significantly (p = 0.0570) more reactive than the coal. The co-firing approach is partly renewable and contributes to the utilization of high and low-quality available discard ultra-fine coal. It advances the combustion of coal resources and reduces carbon dioxide, CO2 emission attributed to global warming as well as preserves the natural biomass sources. The combustion of “Coalgae® “will improve economy, environment, and health, heat, and electricity supply to the society.
- Full Text:
- Date Issued: 2018
Evaluating the effect of microalgae biomass on the combustion of coal
- Authors: Ejesieme, Obialo Vitus
- Date: 2013
- Subjects: Co-combustion , Coal -- Combustion , Biomass -- Combustion
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10435 , http://hdl.handle.net/10948/d1020641
- Description: In this work the combustion characteristics of coal, charcoal, microalgae biomass and blends between these three components were evaluated by means of non-isothermal thermogravimetry. Blends between coal, charcoal and microalgae biomass were made according to the specifications of a D-optimal mixture design so as to be able to model interactions between the three components with maximum precision despite multiple constraints built into the design. These constraints specified that coal can have a minimum value of 70 mass percent in any blend, while microalgae can have a maximum value of 20 mass percent. While coal and charcoal were blended by mixing the two respective dry components, microalgae biomass was incorporated into the blends by first absorbing microalgae onto fine coal from concentrated slurry of the microalgae in water. The microalgae in these blends were therefore intimately associated with the coal. This approach differed substantially from the normal practice of preparing coal – biomass blends (which are usually dry-mixed as for coal – charcoal blends). Proximate analyses of the starting materials showed that the microalgae biomass has a significantly higher volatile matter: fixed carbon content than both coal and charcoal, which should improve the combustion of these materials by providing a more stable combustion flame. Analyses of the thermogravimetric data obtained showed that coal and charcoal have much simpler combustion profiles than microalgae biomass for which five different thermal events could be observed in the DTG combustion profile. Qualitative kinetic analyses showed that the combustion of coal and charcoal follows first-order kinetics, but for microalgae biomass combustion, the first two combustion stages appear to follow first-order kinetics. The TG and DTG profiles for coal, charcoal, microalgae and blends of these three components were used to derive values for the so-called comprehensive combustion property index (S-value), which provides a combined measure of the ease of ignition, rate of combustion, and burn-out temperature. The S-values so obtained were used as response variable for the construction of a response surface model in the experimental domain investigated. Following statistical validation of the response surface model, the model was used to predict an optimum S-value or a blend that would display optimum combustion behaviour. Two optimum blends were obtained from the optimisation process, one in which only charcoal is added to coal, and one in which only microalgae is added to coal. Adding both charcoal and microalgae produced an antagonistic effect compared to when only one of these are used. Qualitative kinetic analyses of the combustion data of blends indicate that blends of coal and charcoal combust in a manner similar to the individual components (hence following first-order kinetics), but blends of coal and microalgae follow more complex kinetics despite the fact that the combustion profile is visibly more simple compared to the combustion profile for microalgae alone.
- Full Text:
- Date Issued: 2013
- Authors: Ejesieme, Obialo Vitus
- Date: 2013
- Subjects: Co-combustion , Coal -- Combustion , Biomass -- Combustion
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10435 , http://hdl.handle.net/10948/d1020641
- Description: In this work the combustion characteristics of coal, charcoal, microalgae biomass and blends between these three components were evaluated by means of non-isothermal thermogravimetry. Blends between coal, charcoal and microalgae biomass were made according to the specifications of a D-optimal mixture design so as to be able to model interactions between the three components with maximum precision despite multiple constraints built into the design. These constraints specified that coal can have a minimum value of 70 mass percent in any blend, while microalgae can have a maximum value of 20 mass percent. While coal and charcoal were blended by mixing the two respective dry components, microalgae biomass was incorporated into the blends by first absorbing microalgae onto fine coal from concentrated slurry of the microalgae in water. The microalgae in these blends were therefore intimately associated with the coal. This approach differed substantially from the normal practice of preparing coal – biomass blends (which are usually dry-mixed as for coal – charcoal blends). Proximate analyses of the starting materials showed that the microalgae biomass has a significantly higher volatile matter: fixed carbon content than both coal and charcoal, which should improve the combustion of these materials by providing a more stable combustion flame. Analyses of the thermogravimetric data obtained showed that coal and charcoal have much simpler combustion profiles than microalgae biomass for which five different thermal events could be observed in the DTG combustion profile. Qualitative kinetic analyses showed that the combustion of coal and charcoal follows first-order kinetics, but for microalgae biomass combustion, the first two combustion stages appear to follow first-order kinetics. The TG and DTG profiles for coal, charcoal, microalgae and blends of these three components were used to derive values for the so-called comprehensive combustion property index (S-value), which provides a combined measure of the ease of ignition, rate of combustion, and burn-out temperature. The S-values so obtained were used as response variable for the construction of a response surface model in the experimental domain investigated. Following statistical validation of the response surface model, the model was used to predict an optimum S-value or a blend that would display optimum combustion behaviour. Two optimum blends were obtained from the optimisation process, one in which only charcoal is added to coal, and one in which only microalgae is added to coal. Adding both charcoal and microalgae produced an antagonistic effect compared to when only one of these are used. Qualitative kinetic analyses of the combustion data of blends indicate that blends of coal and charcoal combust in a manner similar to the individual components (hence following first-order kinetics), but blends of coal and microalgae follow more complex kinetics despite the fact that the combustion profile is visibly more simple compared to the combustion profile for microalgae alone.
- Full Text:
- Date Issued: 2013
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